Date Issued: March 2004
Supersedes: New
MATERIAL SAFETY DATA SHEET
PRECOR庐 2000TM PLUS PREMISE SPRAY
Wellmark International
Manufacturer:
1100 East Woodfield Road, Suite 500 Schaumburg, IL 60173
Address:
1-800-950-4783
Emergency Phone:
CHEMTREC: 1-800-424-9300
Transportation Emergency Phone:
1. CHEMICAL PRODUCT INFORMATION
Precor庐 2000TM Plus Premise Spray
Product Name:
(S)-Methoprene; isopropyl (2E,4E,7S)-11-methoxy-3,7,11-trimethyl-2,4-
Chemical Name/Synonym:
dodecadienoate, Permethrin; [(3-phenoxyphenyl)methyl(+/-)cis-trans-3- (2,2-
dichloroetheyl)-2,2-dimethyl cyclopropanecarboxylate], Phenothrin: [3-
phenoxyphenyl)methyl 2,2-dimethyl-3-(2-methyl-1-propenyl
cyclopropanecarboxylate], Piperonyl Butoxide; 5-[2-(2-
butoxyethoxy)ethoxymethyl]-6-propyl-1,3-benzodioxole, N-octyl bicycloheptane
dicarboximide; N-(2-ethylhexyl)-5-norbonene-2,3-dicarboximide
Terpenoid/Pyrethroid
Chemical Family:
C21 H20 C12 O3 / C19 H34 O3 / C23 H26 O3 / C19 H30 O5 / C17 H25 N O2
Formula:
2724-490
EPA Registration No.:
9910
RF Number:
2. COMPOSITION / INFORMATION ON INGREDIENTS
CAS Weight Tolerance
Number
(S)-Methoprene: [Isopropyl (2E,4E,7S)-11-methoxy-3,7,11- trimethyl- 65733-16-6 0.085%
2,4-dodecadienoate]
Permethrin: [(3-phenoxyphenyl)methyl(+/-)cis-trans-3- (2,2- 52645-53-1 0.350%
dichloroetheyl)-2,2-dimethyl cyclopropanecarboxylate]
Phenothrin: [3-phenoxyphenyl)methyl 2,2-dimethyl-3-(2-methyl-1- 26002-80-2 0.300%
propenyl cyclopropanecarboxylate]
Piperonyl butoxide 51-03-6 1.400% Not established
N-Octyl bicycloheptene dicarboximide 113-48-4 2.000% Not established
95.865%
Inert ingredients (non-hazardous and/or trade secret):
Propane 24-98-6 1000 ppm
(OSHA TWA),
simple asphyxiant
(ACGIH)
3. HAZARD INFORMATION
PRECAUTIONARY STATEMENT
CAUTION: Keep out of the reach of children. Avoid contact with skin, eyes, or clothing.
Wash thoroughly with soap and water after handling. Avoid contamination of foodstuffs. This
product is not for use on humans. Keep children out of areas during treatment. Vacate room
after treatment and ventilate until all surfaces are dry before reoccupying. Prolonged or
frequently repeated skin contact may cause allergic reactions in some individuals.
Page 1 of 4
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Symptoms of intoxication to permethrin are hypersensitivity, tremors, diarrhea. Intoxication to solvents may cause
dizziness, headache, nausea, narcosis, eye irritation, G.I. tract irritation, and cardiac arrhythmia in certain cases.
Yes
Yes Oral: No
PRIMARY ROUTE OF ENTRY Dermal/Eye: Inhalation:
LD50 (rat): >5,000 mg/kg body weight
ACUTE TOXICITY Oral:
LD50 (rabbit): >5,000 mg/kg body weight
Dermal:
LC50 (rat): >5.19 mg/L in air (S)-Methoprene
Inhalation:
OTHER TOXICOLOGICAL INFORMATION
Moderately irritating to the skin
Skin Irritation:
Not an eye irritant
Eye Irritation:
Weak sensitizer
Sensitizer:
4. FIRST AID MEASURES
Hold eye open and flush slowly and gently with water for 15-20 minutes.
Eye:
Remove contact lenses, if present, after the first five minutes, then continue
rinsing eye. Call a poison control center or doctor for treatment advice.
Take off contaminated clothing. Rinse skin immediately with plenty of water for
Skin:
15-20 minutes. Call a poison control center or doctor ifor treatment advice.
Call a poison control center or doctor immediately for treatment advice. Do not
Ingestion:
induce vomiting unless told to do so by a poison control center or doctor. Do
not give any liquid to the person. Do not give anything by mouth to an
unconscious person.
Remove affected person to fresh air. Apply artificial respiration if indicated.
Inhalation:
Contains petroleum distillates. Vomiting may cause aspiration pneumonia.
Note to Physician:
5. FIRE FIGHTING MEASURES
NFPA Rating: Health: 2 Fire: 4 Reactivity: 0
Level 1 aerosol
Flammability Class:
Flash Point: Negative - no flash at less than 90掳 (C) (propellant-free concentrate)
LEL: 1.8, UEL: 9.5; (propellant-free concentrate)
Explosive Limits (% of Volume):
Water, CO2, dry chemical, or foam
Extinguishing Media:
Firefighters should wear full protective clothing including self-contained
Special Protective Equipment:
breathing apparatus.
Contents under pressure. Exposure to temperatures above 130 F may cause
Fire Fighting Procedures:
bursting. Use water to keep fire exposed containers cool. Do not allow run-off
water to enter waterways or sewers.
Oxides of carbon
Combustion Products:
Contents under pressure. Do not puncture containers. Exposure to
Unusual Fire/Explosion Hazards:
temperatures above 130掳 F may cause bursting.
6. ACCIDENTAL RELEASE MEASURES
Absorb spills with an inert material and put in container for disposal.
Steps to be taken:
Clay granules, sawdust, dirt or equivalent.
Absorbents:
Strong oxidizers
Incompatibles:
Page 2 of 4
7. HANDLING AND STORAGE
Do not puncture or incinerate container. Do not use in food areas of food
Handling:
handling establishments, restaurants or other areas where food is
commercially prepared or processed. Do not use in serving areas while food is
exposed or facility is in operation.
Store in a cool, dry area. Do not store near heat or open flame. Exposure to
Storage:
temperatures above 130掳 F may cause bursting. Do not store or transport
below 32潞 F.
8. EXPOSURE CONTROL / PERSONAL MEASURES
Propane: 1000 ppm (OSHA TWA), simple asphyxiant (ACGIH)
Exposure Limits:
Use in a well ventilated area.
Ventilation:
If prolonged exposure is anticipated,it is recommended for handlers to wear a
Personal Protective Equipment:
MSHA/NIOSH approved organic vapor/pesticide respirator, impervious gloves,
goggles, and other appropriate clothing to avoid skin contact.
9. PHYSICAL AND CHEMICAL PROPERTIES
Turbid to opaque, almost colorless emulsion
Appearance and Odor:
N/A
Boiling Point:
N/A
Melting Point:
N/A
Vapor Pressure (mm Hg):
N/A
Vapor Density (Air = 1):
Specific Gravity: 0.96 at 20掳 F (4掳 C) (propellant-free concentrate); 0.82 at 20掳 F (4掳 C) (end-
use aerosol)
N/A
Bulk Density:
N/A
Solubility:
N/A
Evaporation Rate:
7.89 (propellant-free concentrate)
pH:
10. STABILITY AND REACTIVITY
Stable
Stability:
Non-reactive
Reactivity:
Strong oxidizers
Incompatibility w/ Other
Materials:
None except oxides of carbon
Decomposition Products:
Will not occur
Hazardous Polymerization:
11. TOXICOLOGICAL INFORMATION
CHRONIC TOXICITY [Specific to Active Ingredient(s)]
Methoprene is not considered an oncogenic compound. The NOEL for non-carcinogen effects in an 18-month mouse
study was 250ppm (based on (R,S)-Methoprene).
Permethrin showed no evidence of oncogenicity. A NOEL of 100 mg/kg was based on decreased body weight gain in the
oncogenicity study.
DEVELOPMENTAL/REPRODUCTIVE TOXICITY [Based on (R,S) Methoprene Technical]
Methoprene is not a teratogen. The NOEL for maternal and embryotoxicity in rabbits was 200 mg/kg/day. The NOEL for
reproductive effects in rats was 500 ppm.
Page 3 of 4
Permethrin is not a teratogen. Rats were fed dose levels of 20 and 100 mg/kg diet in a 3-generation study. There was
no effect on mortality, mating, pregnancy or fertility. Pup survival and growth were unaffected. Permethrin does not
adversely affect reproduction in the rat.
MUTAGENICITY [Specific to Active Ingredient(s)]
Methoprene is not a mutagen. [Based on (RS) Methoprene].
Permethrin was determined to be non-mutagenic in the following studies: Ames Test (in vitro), Chromosomal Aberration,
and Host-Mediated.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL FATE [Active Ingredients Only]
Hydrolysis: N/A
N/A
Photolysis:
N/A
Soil half life:
N/A
Water solubility:
ECOTOXICITY [Active Ingredients Only]
Acute Toxicity: This product is not intended for aquatic environments.
Pyrethroids are potentially toxic to aquatic organisms
13. DISPOSAL CONSIDERATIONS
Do not puncture or incinerate! If empty: Place in trash or offer for recycling if available. If partly filled: Call your local
solid waste agency or 1-800-CLEANUP for disposal instructions.
.
14. TRANSPORT INFORMATION
Consumer Commodity, ORM-D
DOT49CFR Description:
Insecticides, O/T Poison N.O.S., NMFC I - 102120
Freight Classification:
15. REGULATORY INFORMATION
Not regulated by CERCLA
CERCLA (Superfund):
Regulated due to ignitability
RCRA:
SARA 311/312 HAZARD CATEGORIES
Immediate Health: Yes (irritant)
Nol
Delayed Health:
Yes
Fire:
Yes
Sudden Pressure:
No
Reactivity:
The information presented herein, while not guaranteed, was prepared by technically knowledgeable personnel and to
the best of our knowledge is true and accurate. It is not intended to be all inclusive and the manner and conditions of use
and handling may involve other or additional considerations.
24-14-033
Page 4 of 4
|