MATERIAL SAFETY DATA SHEET
MSDS Ref. No: 4006
IRON STONE Acrylic Seal Date Prepared: 06/25/2003
Date Revised: 06/25/2003
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME/USE: IRON STONE Acrylic Seal
MSDS CODE: 3138540
PRODUCT CODE: 4006110, 4006520, 4006550
MANUFACTURER
The Butcher Company Butcher Telephone Number: 800-225-9475
8310 16th St. Emergency Telephone (24 hours): 800-228-5635
Sturtevant, WI 53177-0902 CHEMTREC (U.S./Can.): 800-424-9300
CHEMTREC (Int'l): +1 703-527-3887
2. COMPOSITION / INFORMATION ON INGREDIENTS
INGREDIENT(S) CAS# % BY WEIGHT
Diethylene glycol methyl ether 111-77-3 3-5
Dibutyl phthalate 84-74-2 0.25 - 1.0
Ammonia 7664-41-7 < 0.1
See Section 8 for Exposure Limits NA - Not Applicable
OSHA REGULATORY STATUS: This product is classified as hazardous under OSHA regulations.
WHMIS CLASS: Class D-Division 2A
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Slightly Opaque, White Liquid . Mild, Ammonia Odor. Product Does Not Present a Significant Immediate Concern
for Emergency Response Personnel.
POTENTIAL HEALTH EFFECTS (See Section 11 for Toxicological Information)
PRIMARY ROUTE(s) OF EXPOSURE: X Eye X Skin Contact Skin Absorption
X Inhalation X Ingestion
EFFECTS OF ACUTE EXPOSURE
EYES: Non-irritating to the eyes, but may cause temporary redness or discomfort.
SKIN: Non-irritating to the skin.
INHALATION: High concentrations of vapor or mist may cause nose, throat and respiratory tract irritation. Symptoms may include
coughing.
INGESTION: May cause mild mouth, throat and stomach irritation. Symptoms may include nausea.
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EFFECTS OF CHRONIC EXPOSURE: Prolonged or repeated contact may cause skin irritation.
MEDICAL CONDITIONS AGGRAVATED: None known.
4. FIRST AID MEASURES
EYES: Flush eyes with plenty of water while holding eyelids apart. After initial flushing, remove any contact lenses and continue flushing for at
least 15 minutes. Do not put any medication in the victim's eyes unless instructed by a physician. Get medical attention if irritation develops.
SKIN: Flush with water, then wash with soap and water. Remove saturated clothing. Get medical attention if irritation develops.
INHALATION: Remove to fresh air. Get medical attention if symptoms persist.
INGESTION: Do not induce vomiting. Drink large quantities of water. Get medical attention.
5. FIRE FIGHTING MEASURES
FLASH POINT AND METHOD: > 93掳C (200掳F)TCC
FLAMMABLE LIMITS: Not applicable.
AUTOIGNITION TEMPERATURE: Not applicable.
EXTINGUISHING MEDIA: Use extinguishing media appropriate for surrounding fire.
HAZARDOUS COMBUSTION PRODUCTS: Normal products of combustion (carbon monoxide and carbon dioxide).
FIRE AND EXPLOSION HAZARDS: None known.
FIRE FIGHTING INSTRUCTIONS: This product is not flammable. As in any fire, MSHA/NIOSH approved self-contained breathing
apparatus (SCBA) and full protective gear should be worn.
6. ACCIDENTAL RELEASE MEASURES
See Section 8, Exposure Controls/Personal Protection and Section 3, Hazard Identification. Floors may be slippery. Use care to avoid falling.
Contain and isolate spill. Prevent from entering sewers and waterways. Keep non-essential personnel from entering spill area. Use mop,
absorbent, or wet vacuum to collect material for proper disposal. Rinse area with water.
7. HANDLING AND STORAGE
HANDLING: Follow label use directions. Do not mix with other chemicals unless instructed by label directions. Avoid contact with skin, eyes
and clothing. Use with adequate ventilation. Avoid breathing vapor or mist. Wash thoroughly after handling. Remove contaminated clothing. Wash
clothing and equipment before reuse.
STORAGE: Keep container closed when not in use. Keep from freezing.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
PERSONAL PROTECTIVE EQUIPMENT (PPE)
EYE: Not required under normal conditions of use.
SKIN: Where prolonged or repeated contact is possible, chemical-resistant clothing (e.g., gloves) is recommended.
RESPIRATORY: No respiratory protection is required if ventilation is adequate.
ENGINEERING CONTROLS: Good general room ventilation is expected to be adequate. Local exhaust ventilation (e.g., fans) may be necessary
when general ventilation does not keep airborne concentrations below exposure limits.
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EXPOSURE LIMITS:
INGREDIENT(S) OSHA PEL/STEL ACGIH TLV/STEL
Diethylene glycol methyl ether NA NA
Dibutyl phthalate 5 mg/m3 5 mg/m3
Ammonia 50 ppm 35 mg/m3 / 25 ppm 17 mg/m3 /
35 ppm 27 mg/m3 35 ppm 24 mg/m3
NA - Not Available
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Mild, Ammonia
APPEARANCE: Slightly Opaque, White
pH: 8.8 to 9.2
PERCENT VOLATILE BY WEIGHT: 83
VAPOR PRESSURE: Not Available
VAPOR DENSITY: Not Available
BOILING POINT: Not Available
FREEZING/MELTING POINT: Not Available
SOLUBILITY IN WATER: Dispersible
EVAPORATION RATE: Not Available
SPECIFIC GRAVITY: 1.03
VISCOSITY: Water Thin
OCTANOL/WATER PARTITION COEFFICIENT: Not Available
ODOR THRESHOLD: Not Available
10. STABILITY AND REACTIVITY
STABILITY (CONDITIONS TO AVOID): Stable.
POLYMERIZATION: Will not occur.
HAZARDOUS DECOMPOSITION: None.
INCOMPATIBLE MATERIALS: None known.
11. TOXICOLOGICAL INFORMATION
ACUTE DATA: This product was found to be non-irritating to eyes and skin. Acute overexposure to high concentrations of diethylene glycol
methyl ether by ingestion has caused thymus effects in laboratory animals. The following additional data are available for product ingredients:
PRODUCT/INGREDIENT ORAL LD 50 (rat) DERMAL LD 50 (rabbit) INHALATION LC 50 (rat)
Diethylene glycol methyl ether 5500 - mg/kg 6540 - mg/kg 200 - mg/L (1-hr)
Dibutyl phthalate 8000 - mg/kg >20000 - mg/kg 17680 - mg/m3 (4-hr)
Ammonia 350 - mg/kg Not Available 3670 - ppm (4-hr)
SENSITIZATION DATA: No data available.
CHRONIC DATA:
Prolonged overexposure to diethylene glycol methyl ether by ingestion has caused liver, kidney, thymus and testes effects in laboratory
animals; prolonged overexposure by dermal absorption has also caused liver and spleen effects in laboratory animals.
REPRODUCTIVE/TERATOGENIC DATA: Prolonged dermal exposure to diethylene glycol methyl ether has caused slight fetotoxicity
(delayed development) in laboratory animals; prolonged overexposure by ingestion has caused teratogenic effects in laboratory animals. Prolonged
overexposure to dibutyl phthalate by ingestion has caused reproductive and teratogenic effects in laboratory animals.
CARCINOGENIC/MUTAGENIC DATA: Not listed as carcinogenic by NTP, IARC, or ACGIH or regulated as a carcinogen by OSHA.
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SYNERGISTIC MATERIALS: No data available.
12. ECOLOGICAL INFORMATION
No data available.
13. DISPOSAL CONSIDERATIONS
Disposal of this material should be in accordance with local, state or provincial and federal regulations. The unused product, as manufactured, is a
RCRA non-hazardous waste in accordance with 40 CFR 261. The product has not been evaluated by the Toxicity Characteristic Leachate
Procedure (TCLP). According to RCRA, it is the responsibility of the waste generator to ensure proper disposal.
14. TRANSPORT INFORMATION
DOT/TDG HAZARDOUS MATERIAL DESCRIPTION: Not regulated
15. REGULATORY INFORMATION
Not meant to be all-inclusive---selected regulations represented.
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
311/312 HAZARD CATEGORIES: Under 40 CFR 370.2, this product meets the following hazard category: Delayed.
313 REPORTABLE INGREDIENTS: Diethylene glycol methyl ether is subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372 under the chemical category Glycol Ethers.
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT)
CERCLA REGULATORY: This product contains dibutyl phthalate. If 120 gallons of total product are released, notification to the
National Response Center (1-800-424-8802) is required.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA STATUS: This product complies with all TSCA inventory requirements.
MASSACHUSETTS, NEW JERSEY, PENNSYLVANIA RIGHT-TO-KNOW:
INGREDIENT(S) CAS NO. STATE LISTING
Water 7732-18-5 Not Listed
Acrylic polymer NA Not Listed
Diethylene glycol methyl ether 111-77-3 MA, PA
NJ Trade Secret Registry #11173400-5066P NA Not Listed
Tributoxyethyl phosphate 78-51-3 Not Listed
NA - Not Applicable
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM): Class D-Division 2A; reproductive and teratogenic
effects. This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the
MSDS contains all the information required by the CPR.
16. OTHER INFORMATION
NFPA CODES:
HMIS RATING
*0
HEALTH
0
0
FLAMMABILITY
0 0
0
REACTIVITY
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PERSONAL PROTECTION
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IRON STONE Acrylic Seal
APPROVED BY: Product Safety & Regulatory
MSDS STATUS
Revision No: 5
Revision #: 5
This MSDS replaces the April 21, 2003 MSDS. Any changes in information are as follows:
In Section 1
Date Prepared
APPROVAL DATE: 06/25/2003
The information on this data sheet represents our current data and best opinion as to the proper use in handling of the product under normal
foreseeable conditions. Any use of this product which is not in conformance with this data sheet or product label, or which involves using the
product in combination with any other product or any other process is the responsibility of the user.
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