Product Name: Farmoz Platinum Herbicide
Page: 1 of 5
This revision issued: December, 2005
Section 1 - Identification of Chemical Product and Company
Farmoz Pty Ltd, Suite 1, Level 4, Building B Telephone (02)9431 7800 (24 hours)
207 Pacific Highway St Leonards, NSW 2068 Fax (02)9431 7700
ACN 050 328 973
Substance: Active ingredient is a cyclohexanedioneoxime derivative.
Farmoz Platinum Herbicide
Trade Name:
Product Use: Agricultural herbicide for use as described on the product label.
Creation Date: December, 2005
Revision Date: December, 2005
Section 2 - Hazards Identification
Statement of Hazardous Nature
This product is classified as: Hazardous according to the criteria of NOHSC Australia.
This product does not meet the criteria of the Australian Dangerous Goods (ADG) Code. However, this is a C1
Combustible Liquid and for storage meets the definition of Dangerous Goods.
Risk Phrases: R22, R65, R36/38. Harmful if swallowed. Harmful: May cause lung damage if swallowed. Irritating to
eyes and skin.
Safety Phrases: S2, S13, S46, S61, S20/21, S24/25, S36/37. Keep out of reach of children. Keep away from food,
drink and animal feeding stuffs. If swallowed, contact a doctor or Poisons Information Centre immediately and show
this container or label. Avoid release to the environment. Refer to special instructions/Safety Data Sheets. When
using, do not eat, drink or smoke. Avoid contact with skin and eyes. Wear suitable protective clothing and gloves.
SUSDP Classification: S5
ADG Classification: None allocated. Not a Dangerous Good under the ADG Code.
UN Number: None allocated
Emergency Overview
Physical Description & colour: Clear, amber liquid.
Odour: Aromatic odour.
Major Health Hazards: Effects of acute exposure to Clethodim or formulated products may include eye or skin
irritation or central nervous system effects, e.g., salivation, decreased motor activity, incoordination, unsteady gait and
hyperactivity. Product is irritating to eyes and skin, harmful if swallowed, if aspirated, may cause lung damage.
Potential Health Effects
See section 11 for Chronic exposure studies.
Inhalation
Short term exposure: Available data indicates that this product is not harmful. In addition product is unlikely to
cause any discomfort or irritation.
Skin Contact:
Short term exposure: Available data indicates that this product is not harmful. It should present no hazards in
normal use. However product is a skin irritant. Symptoms may include itchiness and reddening of contacted skin.
Other symptoms may also become evident, but all should disappear once exposure has ceased.
Eye Contact:
Short term exposure: This product is an eye irritant. Symptoms may include stinging and reddening of eyes and
watering which may become copious. Other symptoms may also become evident. If exposure is brief, symptoms
should disappear once exposure has ceased. However, lengthy exposure or delayed treatment may cause permanent
damage.
Ingestion:
Short term exposure: Significant oral exposure is considered to be unlikely. Because of the low viscosity of this
product, it may directly enter the lungs if swallowed, or if subsequently vomited. Once in the lungs, it is very difficult to
remove and can cause severe injury or death. This product is unlikely to cause any irritation problems in the short or
long term.
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Farmoz Platinum Herbicide
Page: 2 of 5
This revision issued: December, 2005
Carcinogen Status:
NOHSC: No significant ingredient is classified as carcinogenic by NOHSC.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: No significant ingredient is classified as carcinogenic by IARC.
Section 3 - Composition/Information on Ingredients
TWA (mg/m3) STEL (mg/m3)
Ingredients CAS No Conc,%
Clethodim 99129-21-2 240g/L not set not set
Aromatic hydrocarbons 64742-94-5 626g/L not set not set
Other non hazardous ingredients secret to 100 not set not set
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non
hazardous ingredients are also possible.
The TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5
day working week. The STEL (Short Term Exposure Limit) is an exposure value that should not be exceeded for more than 15 minutes and should
not be repeated for more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is
used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures
General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by
this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all
times. Have this MSDS with you when you call.
Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
Skin Contact: Wash gently and thoroughly with warm water (use non-abrasive soap if necessary) for 10-20 minutes
or until product is removed. Under running water, remove contaminated clothing, shoes and leather goods (e.g.
watchbands and belts) and completely decontaminate them before reuse or discard. If irritation persists, repeat
flushing and seek medical attention.
Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 20 minutes or until
the product is removed, while holding the eyelid(s) open. Take care not to rinse contaminated water into the
unaffected eye or onto the face. Obtain medical attention immediately. Take special care if exposed person is wearing
contact lenses.
Ingestion: If swallowed, do NOT induce vomiting. Wash mouth with water and contact a Poisons Information
Centre, or call a doctor.
Section 5 - Fire Fighting Measures
Fire and Explosion Hazards: This product is classified as a C1 combustible product. There is no risk of an
explosion from this product under normal circumstances if it is involved in a fire. Violent steam generation or eruption
may occur upon application of direct water stream on hot liquids.
Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.
Extinguishing Media: Preferred extinguishing media are carbon dioxide, dry chemical, foam, water fog.
Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade.
Flash point: Not flammable.
Upper Flammability Limit: No data.
Lower Flammability Limit: No data.
Autoignition temperature: No data.
Flammability Class: C1
Section 6 - Accidental Release Measures
Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Wear full
protective clothing including eye/face protection. All skin areas should be covered. See below under Personal
Protection regarding Australian Standards relating to personal protective equipment. Suitable materials for protective
clothing include rubber, PVC. Eye/face protective equipment should comprise as a minimum, protective glasses and,
preferably, goggles. If there is a significant chance that vapours or mists are likely to build up in the cleanup area, we
recommend that you use a respirator. It should be fitted with a type G cartridge, suitable for agricultural chemicals.
Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill
is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains
or waterways. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage,
and dispose of promptly. Recycle containers wherever possible after careful cleaning. Refer to product label for
specific instructions. After spills, wash area preventing runoff from entering drains. If a significant quantity of material
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Farmoz Platinum Herbicide
Page: 3 of 5
This revision issued: December, 2005
enters drains, advise emergency services. Full details regarding disposal of used containers, spillage and unused
material may be found on the label. If there is any conflict between this MSDS and the label, instructions on the label
prevail. Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly launder protective clothing
before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check
Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed.
The measures detailed below under "Storage" should be followed during handling in order to minimise risks to
persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible
materials listed in Section 10.
Storage: Note that this product is combustible and therefore, for Storage, meets the definition of Dangerous Goods
in some states. If you store large quantities (tonnes) of such products, we suggest that you consult your state's
Dangerous Goods authority in order to clarify your obligations regarding their storage.
Make sure that containers of this product are kept tightly closed. Keep containers of this product in a well ventilated
area. Protect this product from light. Store in the closed original container in a dry, cool, well-ventilated area out of
direct sunlight. Make sure that the product does not come into contact with substances listed under "Incompatibilities"
in Section 10. Some liquid preparations settle or separate on standing and may require stirring before use. Check
packaging - there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection
The following Australian Standards will provide general advice regarding safety clothing and equipment:
Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Industrial Clothing: AS2919, Industrial Eye
Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
TWA (mg/m3) STEL (mg/m3)
Exposure Limits
Exposure limits have not been established by NOHSC for any of the significant ingredients in this product.
The ADI for Clethodim is set at 0.01mg/kg/day. The corresponding NOEL is set at 1mg/kg/day. ADI means
Acceptable Daily Intake and NOEL means No-observable-effect-level. Values taken from Australian ADI List, Sept
2005.
No special equipment is usually needed when occasionally handling small quantities. The following instructions are
for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.
Ventilation: No special ventilation requirements are normally necessary for this product. However make sure that
the work environment remains clean and that vapours and mists are minimised.
Eye Protection: Protective glasses or goggles should be worn when this product is being used. Failure to protect
your eyes may cause them harm. Emergency eye wash facilities are also recommended in an area close to where
this product is being used.
Skin Protection: Prevent skin contact by wearing impervious gloves, clothes and, preferably, apron. Make sure that
all skin areas are covered. See below for suitable material types.
Protective Material Types: We suggest that protective clothing be made from the following: rubber, PVC.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned above.
Eyebaths or eyewash stations and safety deluge showers should be provided near to where this product is being
used.
Section 9 - Physical and Chemical Properties:
Physical Description & colour: Clear, amber liquid.
Odour: Aromatic odour.
Boiling Point: Not available.
Freezing/Melting Point: No specific data. Liquid at normal temperatures.
Volatiles: No data.
Vapour Pressure: 1x10-2mPa (clethodim)
Vapour Density: No data.
Specific Gravity: Approx 0.97 at 20掳C
Water Solubility: Emulsifiable.
pH: 4.4 (1% in distilled water)
Volatility: No data.
Odour Threshold: No data.
Coeff Oil/water distribution: No data
Autoignition temp: No data.
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Farmoz Platinum Herbicide
Page: 4 of 5
This revision issued: December, 2005
Section 10 - Stability and Reactivity
Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have
any doubts, contact the supplier for advice on shelf life properties.
Conditions to Avoid: Keep containers tightly closed. Keep containers and surrounding areas well ventilated.
Protect this product from light. Store in the closed original container in a dry, cool, well-ventilated area out of direct
sunlight.
Incompatibilities: No particular Incompatibilities.
Fire Decomposition: Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and
its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas. Water.
Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision,
disturbance of judgment, and unconsciousness followed by coma and death.
Polymerisation: This product will not undergo polymerisation reactions.
Section 11 - Toxicological Information
Toxicity: An information profile for Clethodim is available at http://extoxnet.orst.edu/pips/ghindex.html
Acute Toxicity: Clethodim is harmful by ingestion. The reported oral LD50 is 1,630 mg/kg and 1,360 mg/kg in male
and female rats, respectively. Clethodim is practically non-toxic by dermal absorption. The reported dermal LD50 is
greater than 5,000 mg/kg. The technical product did not cause skin irritation in the rabbit, but formulation caused
moderate skin as well as eye irritation in the rabbit. Eye irritation was reversible within 8-21 days. No data regarding
skin sensitization or eye irritation were available for the technical product. Clethodim is practically non-toxic by the
inhalation route. The reported rodent 4-hour inhalation LC50 for Clethodim technical is greater than 3.9 mg/L. Effects
of acute exposure to Clethodim or formulated products may include eye or skin irritation or central nervous system
effects, e.g., salivation, decreased motor activity, incoordination, unsteady gait and hyperactivity. These latter effects
may be in large measure due to the aromatic constituents of the formulation, as these effects commonly occur upon
exposure to such compounds.
Chronic Toxicity: In a one-year feeding study of dogs, doses of 75 mg/kg/day resulted in increased relative and
absolute liver weights, with anaemia-like alterations in blood chemistry such as reduced haemoglobin, erythrocyte and
hematocrit counts. In a two-year chronic study of rats, no compound-related effects on the structure and function of
the liver were observed, and no changes in liver weights were observed at the highest dose tested, approximately 100
mg/kg/day. Reduced body weight gain was observed in another study on rats at 350 mg/kg/day, but not at 100
mg/kg/day, over an unspecified period.
Reproductive Effects: No effects on fertility, length of gestation or growth and development of offspring were
observed at doses up to and including the highest dose tested, 263 mg/kg/day.
Teratogenic Effects: Data suggests that while there have been documented teratological effects in animal studies,
such effects are unlikely in humans under normal conditions of exposure.
Mutagenic Effects: The available data for mutagenicity and genotoxicity yield no evidence for mutagenic or
genotoxic activity.
Carcinogenic Effects: No carcinogenic effects were observed in mice administered Clethodim at doses of 24
mg/kg/day over an 18 month period. Based on the available data, it appears that Clethodim is not carcinogenic.
Organ Toxicity: The liver was the primary organ affected in chronic animal studies. Although potential effects
associated with acute exposure are reported to include central nervous system effects, no available chronic data
pointed to such effects.
Fate in Humans & Animals: Clethodim is readily absorbed in the gastrointestinal tract, with approximately 90%
absorption of oral doses. It is rapidly metabolized and eliminated (primarily sulfoxide metabolites, ca 63%) with less
than 1% recoverable unchanged.
Section 12 - Ecological Information
Effects on Birds: Clethodim is practically non-toxic to birds. Under likely conditions of use, it is unlikely to pose a
hazard to avian species.
Effects on Aquatic Organisms: Clethodim is slightly toxic to fish and aquatic invertebrate species. No effects were
seen at concentrations of 5.5 mg/L in Daphnia. No significant bioaccumulation has been observed in fish. Under likely
conditions of use, it is unlikely to pose a hazard to aquatic species.
Effects on Other Animals (Nontarget species): Clethodim is practically non-toxic to honeybees with reported LD50s of
greater than 100 碌g/bee for both the technical product and formulated product. EPA has stated that "available wildlife
data indicate that the proposed uses on cotton and soybeans will result in minimal hazard to nontarget and
endangered beneficial insect, avian and freshwater fish and mammalian species". Clethodim is selectively toxic to
plants, affecting only grass species.
ENVIRONMENTAL FATE
Breakdown of Chemical in Soil and Groundwater: Clethodim is of low persistence in most soils with a reported half-life
of approximately 3 days. Breakdown is mainly by aerobic processes, although photolysis may make some
contribution.
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Farmoz Platinum Herbicide
Page: 5 of 5
This revision issued: December, 2005
Breakdown of Chemical in Surface Water: Clethodim may be highly persistent in the aquatic environment.
Reported half-lives for Clethodim in the aquatic environment are 128 days in the aqueous phase and 214 days in the
sediment. The reported hydrolysis half-life at pH 7-9 is approximately 300 days.
Breakdown of Chemical in Vegetation: Clethodim is rapidly degraded on the leaf surfaces by an acid-catalysed
reaction and photolysis. Remaining Clethodim will rapidly penetrate the cuticle and enter the plant.
Section 13 - Disposal Considerations
Disposal: There are many pieces of legislation covering waste disposal and they differ in each state and territory, so
each user must refer to laws operating in their area. In some areas, certain wastes must be tracked. The Hierarchy of
Controls seems to be common - the user should investigate: Reduce, Reuse, and Recycle and only if all else fails
should disposal be considered. Note that properties of a product may change in use, so that the following suggestions
may not always be appropriate. The following may help you in properly addressing this matter for this product. Special
help is available for the disposal of Agricultural Chemicals. The product label will give general advice regarding
disposal of small quantities, and how to cleanse containers. However, for help with the collection of unwanted rural
chemicals, contact ChemClear 1800 008 182 http://www.chemclear.com.au/ and for help with the disposal of empty
drums, contact DrumMuster http://www.drummuster.com.au/ where you will find contact details for your area.
Section 14 - Transport Information
ADG Code: This product is not classified as a Dangerous Good. No special transport conditions are necessary
unless required by other regulations.
Section 15 - Regulatory Information
AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
The following ingredients: Clethodim, liquid hydrocarbon are mentioned in the SUSDP.
Section 16 - Other Information
This MSDS contains only safety-related information. For other data see product literature.
Acronyms:
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail
AICS Australian Inventory of Chemical Substances
CAS number Chemical Abstracts Service Registry Number
IARC International Agency for Research on Cancer
NOHSC National Occupational Health and Safety Commission
NTP National Toxicology Program (USA)
R-Phrase Risk Phrase
SUSDP Standard for the Uniform Scheduling of Drugs & Poisons
UN Number United Nations Number
Contact Points:
Call Farmoz on (02)9431 7800 and ask for the technical manager. Fax: (02)9431 7700
Police and Fire Brigade: Dial 000
Emergency contact: 1800 024 973 (24 hours)
If ineffective: Dial Poisons Information Centre
(13 1126 from anywhere in Australia)
The information contained in this Material Safety Data Sheet is provided in good faith and is believed to be correct at the date
hereof. However, it is expected that individuals receiving the information will exercise their independent judgement in determining
its appropriateness for a particular purpose. Farmoz Pty Ltd makes no representation as to the accuracy or comprehensiveness of
the information and to the full extent allowed by law excludes all liability whatsoever, whether with respect to negligence or
otherwise, for any loss or damage arising from or connection with the supply or use of the information in this Material Safety Data
Sheet.
Please read all labels carefully before using product.
This MSDS is prepared in accord with the NOHSC document 鈥淣ational Code of Practice for the
Preparation of Material Safety Data Sheets鈥? 2nd Edition [NOHSC:2011(2003)]
Copyright 漏 Kilford & Kilford Pty Ltd, December, 2005.
http://www.kilford.com.au/ Phone (02)9251 4532
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
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