Material Name: SBS Self-Adhering Membranes Safety Data Sheet
ID: 3132
Section 1 - Product and Company Identification
Hazard Label Not Required
Company Information
Johns Manville Telephone: 303-978-2000 8:00AM-5:00PM M-F
Roofing Systems Group Internet Address: http://www.jm.com
P.O. Box 5108 Emergency: 800-424-9300 (Chemtrec, In English)
Denver, CO 80127 USA
Trade Names:
Dibiten鈩? SAS Base; DynaGrip庐 Base 250 SD/SA; JMCleanBond鈩? SBS Cap & Base;
Dibiten鈩? SAS Cap; DynaGrip庐 Cap Self-Adhering Membrane; JMCleanBond鈩? Utility Sheet;
DynaGrip庐 Base SA/SA; DynaLastic庐 180 QuickLap鈩?; JM Ice & Water Guard鈩?;
DynaGrip庐 Base SA/SD; JMCleanBond鈩? Base Flashing; Sure Grip鈩? Self-Adhering Membrane
DynaGrip庐 Base SD/SA; JMCleanBond鈩? Cap Flashing;
Section 2 - Composition / Information on Ingredients
CAS # Component Percent
8052-42-4 Asphalt 45-67
9003-55-8 Styrene-Butadiene polymer 2-40
12007-56-6 Calcium Borate (Colemanite) 9-29*
Not Available Roof granules 0-15**
Not Applicable Continuous Glass Filament Mat (see JM MSDS #1013) 0-15***
1317-65-3 Calcium Carbonate 1-12
Not Available Rubber-Based Adhesive 0-10
Not Available Polyester Mat (see JM MSDS #2200) 0-10***
64742-46-7 Petroleum Distillates, Hydrotreated Middle 0-8****
64742-52-5 Petroleum Distillates, Hydrotreated Heavy Naphthenic 0-8****
14808-60-7 Crystalline Silica (Quartz) 0-10*****
Component Related Regulatory Information
* A component of JMCleanBond鈩? SBS Cap & Base, JMCleanBond鈩? Base Flashing, JMCleanBond鈩? Cap Flashing,
& JMCleanBond鈩? Utility Sheet.
** Roof granules are on top surface of "cap" and Dynalastic membranes only; granules are composed of ceramic-coated
granite, which contains 35% crystalline silica. Airborne crystalline silica not expected to be released; is encapsulated in
relatively large (non-respirable) particles that are adhered to product surface.
*** These roofing membranes are reinforced with mats composed of either continuous filament fiber glass or polyester.
**** Component of JMCleanBond鈩? Base Flashing, JMCleanBond鈩? Cap Flashing, JMCleanBond鈩BS Base, &
JMCleanBond鈩? Utility Sheet.
***** Low levels of respirable crystalline silica may be present in sand backing on DynaGrip庐 SD membranes. Respirable
crystalline silica from sand is not expected to be released; sand is adhered to product and is >99.9% too large to become
airborne or to be respirable.
Section 3 - Hazards Identification
Emergency Overview
APPEARANCE AND ODOR: Black pliable solid; rubber or slight acrylic odor.
Under normal conditions of use and handling, this product is not expected to create any health or safety hazards.
During cutting of this product, nuisance dust can be generated. Personal protective equipment as described in Section 8 can
be used to protect against possible temporary irritation of skin, eyes, and respiratory tract.
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Material Name: SBS Self-Adhering Membranes Safety Data Sheet
ID: 3132
Potential Health Effects
Inhalation
None expected. However, irritation of the upper respiratory tract (scratchy throat), coughing, and congestion may occur in
extreme exposures.
Skin
Temporary irritation may occur.
Ingestion
Ingestion of this product is unlikely. However, ingestion of product may produce gastrointestinal irritation and disturbances.
Eyes
Asphalt fumes may cause temporary irritation of the eyes.
Primary Routes of Entry (Exposure)
Skin
Target Organs
Skin
Medical Conditions Aggravated by Exposure
Pre-existing chronic skin diseases.
Section 4 - First Aid Measures
First Aid: Inhalation
Remove to fresh air. If symptoms persist contact a physician.
First Aid: Skin
Wash exposed skin with soap and water. If irritation develops or persists, seek medical attention. Do not eat or drink while
working with this product.
First Aid: Ingestion
Product is not intended to be ingested or eaten. If this product is ingested, severe irritation of the gastrointestinal (GI) tract may
occur, and should be treated symptomatically. Seek medical attention.
First Aid: Eyes
Not applicable
First Aid: Notes to Physician
This product is not expected to produce any chronic health effects from acute exposures. Treatment should be directed toward
removing the source of irritation with symptomatic treatment as necessary.
Section 5 - Fire Fighting Measures
Flash Point: Not applicable Method Used: Not applicable
Upper Flammable Limit (UFL): Not determined Lower Flammable Limit (LFL): Not determined
Auto Ignition: Not determined Flammability Classification: Not determined
Rate of Burning: Not determined
General Fire Hazards
There is no potential for spontaneous fire or explosion.
Fire Fighting Equipment/Instructions
No special procedures are expected to be necessary for this product. Normal fire fighting procedures should be followed to
avoid inhalation of smoke and gases.
Section 6 - Accidental Release Measures
Clean-Up Procedures
Pick up large pieces. Vacuum dust.
Section 7 - Handling and Storage
Handling Procedures
Use protective equipment as described in Section 8 of this safety data sheet when handling uncontained material. Handle in
accordance with good industrial hygiene and safety practices.
Storage Procedures
Warehouse storage should be in accordance with package directions, if any. Material should be kept clean, dry, and in original
packaging.
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Material Name: SBS Self-Adhering Membranes Safety Data Sheet
ID: 3132
Section 8 - Exposure Controls / Personal Protection
Exposure Guidelines
A: General Product Information
Protective equipment should be provided as necessary to prevent excessive skin contact. Wash hands and other exposed
areas before eating or using the restroom.
B: Component Exposure Limits
Asphalt (8052-42-4)
ACGIH: 0.5 mg/m3 TWA (fume, inhalable fraction, as benzene soluble aerosol)
Continuous Glass Filament Mat
ACGIH: 1 fiber/cm3 TWA (respirable fibers, length >5 碌m, aspect ratio >=3:1, as determined by the
membrane filter method at 400-450X magnification [4-mm objective], using phase-contrast
illumination); 5 mg/m3 TWA (inhalable fraction)
Calcium Carbonate (1317-65-3)
OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)
Crystalline Silica (Quartz) (14808-60-7)
ACGIH: 0.025 mg/m3 TWA (respirable fraction)
OSHA: 0.1 mg/m3 TWA (respirable dust)
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Safety glasses with side shields are recommended.
Personal Protective Equipment: Skin
Leather or cotton gloves should be worn to prevent skin contact and irritation.
Personal Protective Equipment: Respiratory
Not required
Ventilation
No special ventilation systems are required under normal conditions of use.
Section 9 - Physical & Chemical Properties
Appearance: Odor:
Black pliable Rubber odor or slight acrylic odor
Physical State: pH:
solid Not applicable
Vapor Pressure: Vapor Density:
Not applicable Not applicable
Boiling Point: Melting Point:
Not determined Not determined
Solubility (H2O): Specific Gravity:
Insoluble Not determined
Freezing Point: Solids Content
Not determined Not applicable
Evaporation Rate: Viscosity:
Not applicable Not applicable
Percent Volatile: VOC:
0 Not determined
Section 10 - Stability & Reactivity Information
Stability
This is a stable material. This product is not reactive.
Hazardous Decomposition
Carbon monoxide, carbon dioxide and miscellaneous hydrocarbons.
Hazardous Polymerization
Will not occur.
Section 11 - Toxicological Information
Acute Toxicity
A: General Product Information
Skin contact may result in slight irritation and possible allergic reactions due to soft rubber products. Fumes from this product
may cause transitory irritation to eyes and upper respiratory passages.
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Material Name: SBS Self-Adhering Membranes Safety Data Sheet
ID: 3132
B: Component Analysis - LD50/LC50
Asphalt (8052-42-4)
Oral LD50 Rat: >5000 mg/kg; Dermal LD50 Rabbit: >2000 mg/kg
Calcium Borate (Colemanite) (12007-56-6)
Oral LD50 Rat: 5600 mg/kg
Petroleum Distillates, Hydrotreated Middle (64742-46-7)
Inhalation LC50 Rat: 4.6 mg/L/4H; Oral LD50 Rat: 7400 mg/kg; Dermal LD50 Rabbit: >2000 mg/kg
Petroleum Distillates, Hydrotreated Heavy Naphthenic (64742-52-5)
Inhalation LC50 Rat: 2.18 mg/L/4H; Oral LD50 Rat: >5000 mg/kg; Dermal LD50 Rabbit: >2000 mg/kg
Crystalline Silica (Quartz) (14808-60-7)
Oral LD50 Rat: 500 mg/kg
Component Carcinogenicity
Asphalt (8052-42-4)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
IARC: Group 3 - Not Classifiable (IARC Supplement 7 [1987], Monograph 35 [1985])
Styrene-Butadiene polymer (9003-55-8)
IARC: Group 3 - Not Classificable (IARC Supplement 7 [1987], Monograph 19 [1979])
Continuous Glass Filament Mat (see JM MSDS #1013) (Not Applicable)
ACGIH: A4 - Not Classifiable as a Human Carcinogen (related to Continuous filament glass fibers)
IARC: Group 3 - Not Classifiable (IARC Monograph 81 [2002] (listed under Man-made mineral fibres),
Monograph 43 [1988])
Crystalline Silica (Quartz) (14808-60-7)
ACGIH: A2 - Suspected Human Carcinogen
NTP: Known Carcinogen (Select Carcinogen)
IARC: Group 1 - Known Human Carcinogen (IARC Monograph 68 [1997] (listed under Crystalline silica
inhaled in the form of quartz or cristobalite from occupational sources))
Chronic Toxicity
Note: Due to the product form, exposures to hazardous dusts or fumes are not expected to occur. Exposure limits are given
for reference only. No chronic health effects are expected from the normal use of this product.
Respirable crystalline silica from sand is not expected to be released; sand is adhered to product and is >99.9% too large to
become airborne or to be respirable. Crystalline silica is considered a hazard by inhalation. The International Agency for
Research on Cancer (IARC) has classified crystalline silica as a Group 1 substance, carcinogenic to humans. This
classification is based on the findings of laboratory animal studies (inhalation and implantation) and epidemiology studies that
were considered sufficient for carcinogenicity. Several studies have been conducted to determine the risk of cancer to workers
exposed to dusts which contain crystalline silica. However, these studies did not consider other factors or elements that
workers may be exposed to. Therefore, the causes of the excess deaths due to cancer could not be precisely determined.
Further studies are being conducted to determine the risk of cancer when working with crystalline silica products. Excessive
exposure to crystalline silica can cause silicosis, a non-cancerous lung disease.
The asphalt in this product exists in a solid state and does not impart any special hazard to the mixture.
Continuous Filament Glass Fiber: No chronic health effects are known to be associated with exposure to continuous filament
fiber glass. Results from epidemiologic studies have not shown any increases in respiratory disease or cancer. The
International Agency for Research on Cancer (IARC) has classified continuous filament fiber glass as a Group 3 substance,
not classifiable as to its carcinogenicity to humans. Because of the large diameter of continuous filament fibers, these products
are not considered respirable.
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Material Name: SBS Self-Adhering Membranes Safety Data Sheet
ID: 3132
Section 12 - Ecological Information
Ecotoxicity
A: General Product Information
No data available for this product.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Petroleum Distillates, Hydrotreated Middle (64742-46-7)
96 Hr LC50 Pimephales promelas: 35 mg/L [flow-through]
Petroleum Distillates, Hydrotreated Heavy Naphthenic (64742-52-5)
96 Hr LC50 Pimephales promelas: >5000 mg/L
48 Hr EC50 Daphnia magna: >1000 mg/L
Section 13 - Disposal Considerations
US EPA Waste Number & Descriptions
A: General Product Information
Test waste using methods described in 40 CFR Part 261 to determine if it meets applicable definitions of a hazardous waste.
If you are unsure of the regulations, contact your local Public Health Department, or the local office of the EPA.
B: Component Waste Numbers
No EPA Waste Numbers are applicable for this product's components.
Disposal Instructions
Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.
Section 14 - Transportation Information
International Transportation Regulations
These products are not classified as dangerous goods according to international transport regulations.
Section 15 - Regulatory Information
US Federal Regulations
A: General Product Information
SARA 311/312: This product is not classified as hazardous under SARA 311/312.
B: Component Analysis
None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR
372.65), or CERCLA (40 CFR 302.4).
State Regulations
A: General Product Information
Other state regulations may apply. Check individual state requirements.
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component CAS # CA FL MA MN NJ PA
Asphalt 8052-42-4 Yes No Yes Yes Yes Yes
Calcium Carbonate 1317-65-3 No No Yes Yes No Yes
Crystalline Silica (Quartz) 14808-60-7 No No Yes Yes Yes Yes
The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65):
WARNING! This product contains a chemical known to the state of California to cause cancer.
Component CAS #
Crystalline Silica (Quartz) 14808-60-7
Other Regulatory Information
A: General Product Information
Calcium Carbonate (1317-65-3) and Calcium Borate (12007-56-6) are listed on the Canada Non-Domestic Substances List
(NDSL).
B: TSCA Status
This product and its components are listed on the TSCA 8(b) inventory.
None of the components listed in this product are listed on the TSCA Export Notification 12(b) list.
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Page 5 of 6 Issue Date: 06/21/2007 Revision: 1.0113
Material Name: SBS Self-Adhering Membranes Safety Data Sheet
ID: 3132
International Regulations
A: General Product Information
These products are considered articles under both U.S. and international product regulations and as such, these products do
not require registration or notification on the various country-specific inventories.
B: Component Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
Component CAS # Minimum Concentration
Continuous Glass Filament Mat (see JM MSDS #1013) Not Applicable 1 % (related to Fibrous glass)
Crystalline Silica (Quartz) 14808-60-7 1%
Section 16 - Other Information
Other Information
Prepared for:
Johns Manville
Roofing Systems Group
P. O. Box 5108
Denver, CO USA 80217-5108
Prepared by:
Johns Manville Technical Center
P.O. Box 625005
Littleton, CO USA 80162-5005
The information herein is presented in good faith and believed to be accurate as of the effective date given. However, no
warranty, expressed or implied, is given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or
provincial, and local laws.
Date MSDS # Reason
08/01/00 3132-1.0000 New MSDS authoring system.
10/30/00 3132-1.0001 Sect. 1 added 'Home Defender鈩?'; LOLI update, minor.
08/08/01 3132-1.0100 Sect 1-Add trade names DynaGrip鈩? Cap; DynaGrip庐 Base
SD/SA; DynaGrip庐 Base SA/SD; Dyna-Grip庐 Base SA/SA
08/16/01 3132-1.0101 Section 1 - editorial change
11/11/02 3132-1.0102 Sect. 1: added DynaLastic庐 180 QuicklLap鈩?. Sect. 2 updated
composition. Sect. 11 update for asphalt IARC Group 3
classification. Misc. edits.
07/07/03 3132-1.0103 Sect. 1: Deleted Nordshield, Home Defender, Roof Defender;
added Dibiten鈩? SAS Cap and Dibiten鈩? SAS Base.
01/15/04 3132-1.0104 Sect. 1 add DynaGrip庐 Base FR SA/SA; Sect. 2 edit composition.
Regulatory review. Minor updates.
2/23/04 3132-1.0105 Sect.1 add DynaGrip庐 FR
05/10/04 3132-1.0106 Regulatory update. Minor edits.
05/21/04 3132-1.0107 Sect.1 Removed trade name DynaGrip Base FR SA/SA and
replaced it with JM CleanBond SBS鈩?.
06/08/04 3132-1.0108 Sect. 1 Removed trade name DynaGrip FR and made minor edits
to trade names.
08/20/04 3132-1.0109 Sect. 1 trade name adjustment: .JMCleanBond SBS Cap and Base.
Minor edits throughout.
09/16/04 3132-1.0110 Sect. 1 addition of trade names .JMCleanBond Base Flashing,
.JMCleanBond Cap Flashing, and .JM Ice and Water Guard. Sect.
2 adjustment of composition.
03/31/05 3132-1.0111 Sect. 1 addition of trade name .JMCleanBond鈩? Utility Sheet.
06/05/06 3132-1.0112 Section 2 granule, mat, and silica composition edits to more
accurate ranges.
06/21/07 3132-1.0113 Addition of DynaGrip 250 SD/SA to trade names. Minor edits
throughout.
This is the end of MSDS # 3132
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