Johnson Matthey
HYDROGEN HEXACHLOROPLATINATE(IV)
181000 6.00 EC Current 02.04.2001
1. PRODUCT AND COMPANY IDENTIFICATION
181000
Product Code
HYDROGEN HEXACHLOROPLATINATE(IV)
Trade Name
Substance
Product Type
Johnson Matthey PLC
Manufacturer/Supplier
Precious Metals Division, Chemicals
Address
Orchard Road
ROYSTON, Hertfordshire
SG8 5HE
+(44) 1763 253000
Phone Number
+(44) 1763 253155
Fax Number
100% H PtCl鈥? Hydrogen Hexachloroplatinate
Composition
also known as Chloroplatinic Acid, CPA.
1
JM Version Number
04/01/91
Date of First Issue
2. COMPOSITION/INFORMATION ON THE COMPONENTS
HYDROGEN HEXACHLOROPLATINATE(IV)
Product Formal Name
Product Chemical Family .Not Specified
16941-12-1
CAS Number
3. HAZARD IDENTIFICATION
Chloroplatinic acid is corrosive to human tissues, and will cause burns to the
eyes, skin and mucous membranes. There is no oral toxicological data for
CPA but by analogy with other compounds containing the hexachloroplatinate
anion, it should be regarded as being toxic if swallowed.
It is highly allergenic and will cause Type 1 sensitisation in susceptible
individuals. Sensitised persons, on re-exposure to platinum salts will show
the clinical features of a Type 1 allergy - asthma and/or rhinitis and/or
conjunctivitis and/or urticaria. A contact dermatitis can also occur. 聽 聽
4. FIRST AID MEASURES
Inhalation of the dust will result in coughing and sneezing and severe irritation
First Aid
of the respiratory tract, and is the main cause of sensitisation. The symptoms
of the allergic reaction to platinum salts may include any of the following;-
itchy red eyes, watering of the eyes, sneezing, runny nose, chest tightness,
wheezing, breathlessness, cough, eczematous or urticarial (nettle rash type)
skin lesions. Exposure to platinum salts in exceedingly small amounts, even
below the level of physico-chemical detection, will produce symptoms in
sensitised persons. Continued exposure will give symptoms of increasing
severity and can eventually lead to chronic asthma. There is a risk of
anaphylactic shock occuring in sensitised persons re-encountering platinum
salts. Therefore, if sensitisation has developed, further exposure to platinum
compounds must not be permitted. "Platinum asthma" is a prescribed
occupational disease in the UK. Ingestion will lead to severe abdominal pain,
with possible chemical burns to the mouth and throat. Contact with the skin
will be irritating. Strong solutions are corrosive, with the possibility of burns in
severe cases. Contact with the eyes will be painful at all levels of exposure. 聽 聽
聽聽
remove from exposure and allow to rest in fresh air. Rinse nose and mouth
First Aid - Inhalation
with clean water. If breathing is difficult, give oxygen if available. Get
immediate medical attention. 聽
rinse mouth with water and give water or milk to drink. Do not induce
First Aid - Ingestion
vomiting. Get immediate medical attention.
irrigate with water or isotonic saline solution for 15 minutes. Get medical
First Aid - Eyes
attention.
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Johnson Matthey
HYDROGEN HEXACHLOROPLATINATE(IV)
181000 6.00 EC Current 02.04.2001
4. FIRST AID MEASURES (continued)
Remove contaminated clothing and wash skin with copious amounts of soap
First Aid - Skin
and water.If irritation persists or tissue is damaged, get medical attention. 聽 聽
Acute allergic reactions are managed symptomatically as indicated by the
First Aid
clinical condition. There is no known antidote.
5. FIRE FIGHTING MEASURES
Although the material is not flammable, toxic fumes will be produced if
involved in a fire. The residue, ash or char left after a fire may have catalytic
properties and may promote the re-ignition of flammable materials and
vapours. Wear self-contained breathing apparatus and personal protective
equipment. Use any extinguisher suitable for the surrounding fire. 聽 聽
6. ACCIDENTAL RELEASE MEASURES
Evacuate non-protected personnel. Wear protective clothing, impervious
gloves, eye protection and filter-type respiratory protection when dealing with
spillages. Solid spills should be carefully collected into a sealable, plastic
lined drum. Solutions should be absorbed in sand or other inert absorbant
and carefully transferred to a plastic lined drum. The site of the spillage may
be treated with an aqueous solution of a reducing agent, to convert any
remaining platinum compounds to the metal. Store accumulated rags, wipes,
mops, sand, vermiculite etc. in suitably labelled containers for return to the
refinery for precious metal recovery. Afterwards, wash the site of the spillage
with copious amounts of water. If the spill has resulted in the dispersion of
dust through the air, the area must be decontaminated by thorough washing
with water. 聽 聽 聽
7. HANDLING AND STORAGE
Good industrial hygiene practices should be observed. Avoid direct contact.
Handling (JM)
Do not eat, drink, smoke or apply cosmetics whilst handling. Exposure to air-
borne particulates must be kept within permissible limits. Use only under
conditions of good local ventilation. 聽 聽 聽 聽 聽 聽
Keep in a secure store, in a sealed, plastic container, away from incompatible
Storage (JM)
materials such as reducing agents. 聽 聽 聽
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
UK MEL for halogeno-platinum compounds - 0.002 mg/m鈥?
USA ACGIH TLV-TWA for soluble platinum salts - 0.002 mg/m鈥?
German MAK for platinum compounds, measured as total dust - 0.002 mg/
m鈥?
Danish ELV for soluble platinum compounds - 0.002 mg/m鈥?
All values calculated as Pt. High risk of sensitization.
Local exhaust extraction should be used. Vapour and fumes from all
operations should be vented to external atmosphere via a collection or
scrubbing system. Personal filter type respiratory protection, impervious
gloves and industrial safety glasses should be worn. Work clothes should be
changed as often as necessary and at least after every working shift. Wash
hands after using this material.
Users of large amounts of the solid or its solutions should consider the
application of engineering control measures, such as total enclosure and
remote operation where possible. Workplace air and the exhaust from the
ventilation system should be monitored for airborne platinum to ensure that
exposure limit are not exceded. This monitoring should include personal
breathing zone sampling. Pre-exposure and periodic medical examinations of
persons exposed to platinum salts are recommended. Further details are
given in the HSE's Guidance Note MS22,"The Medical Monitoring of Workers
Exposed to Platinum Salts" (ISBN 0 11 883575 0). For non UK residents,
information is available from the JM Group Occupational Physician. 聽 聽 聽 聽 聽 聽 聽
聽
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Johnson Matthey
HYDROGEN HEXACHLOROPLATINATE(IV)
181000 6.00 EC Current 02.04.2001
9. PHYSICAL AND CHEMICAL PROPERTIES
Red-brown, hydroscopic crystals
Appearance
No odour.
Odour
The aqueous solution is acidic
pH
decomposes on heating.
Boiling Range/Point
60掳C
Melting Point
not applicable.
Flash Point
not flammable.
Flammability
Not flammable
Auto-flammability
not explosive.
Explosive Properties
not oxidising.
Oxidising Properties
no data.
Vapour Pressure
2.431 gm/cc.
Density
Very soluble in water. Soluble in ethanol and in di-ethyl ether. 聽 聽
Solubility in Water
no data.
Partition Coefficient
聽
General
10. STABILITY AND REACTIVITY
On standing in air, the solid will absorb moisture and may coalesce into a
hard lump. The acidic, aqueous solution will hydrolyse when subjected to
heat and light. Old solutions will contain chloro-hydroxy platinum species.
The solution may be stabilised by the addition of hydrochloric acid. The solid
decomposes on heating, giving off toxic fumes. 聽
11. TOXICOLOGICAL INFORMATION
LD50 (ivn-rat); 49 mg/kg
LD50 (ipr-mouse); 6l mg/kg
LDLo (ivn-rabbit); 125 mg/kg
Mutagenic effects have been observed on tests with bacteria.
There is no oral toxicity data available.
Persons with a history of allergic diseases, such as asthma or hay-fever,
should not work with platinum salts. A history of cardiac or pulmonary disease
may also preclude work with platinum salts - medical opinion should be
sought. Any workers experiencing untoward effects of symptoms should be
removed from exposure and medically examined for platinum sensitivity.
Sensitisation is indicated by positive skin prick test to low concentration
solutions of platinum salts.
12. ECOLOGICAL INFORMATION
*** Revised *** The product is involatile and water soluble and will partition to
Mobility
the aqueous phase.
*** Revised *** The product is expected to be resistant to biodegradation.
Persistence/Degradability
*** Revised *** LC50 salmon 96 hrs, 2.5 mg/lt NOEC 0.3 mg/lt
Ecotoxicity
EC50 daphnia 48 hrs. 0.13 mg/lt. NOEC 0.056 mg/lt
EC50 algae 72 hrs. 1.25 mg/lt. NOEC 0.97 mg/lt
13. DISPOSAL
Return accumulated waste material to the refinery for metal recovery, or
dispose of in accordance with local and national regulations. 聽
14. TRANSPORT INFORMATION
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Johnson Matthey
HYDROGEN HEXACHLOROPLATINATE(IV)
181000 6.00 EC Current 02.04.2001
14. TRANSPORT INFORMATION (continued)
U.N. No. 2507, Class 8, Packing Group III
ADR 2801 11c
Proper Shipping Name - "Chloroplatinic acid, solid." 聽 聽 聽
15. REGULATORY INFORMATION
Toxic
Labelling Information
Corrosive
R25 Toxic if swallowed.
R phrases
R34 Causes burns.
R42/43 May cause sensitisation by inhalation and skin contact.
*** Revised *** R50/53 Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
S22 Do not breathe dust.
S phrases
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
*** Revised *** S57 Use appropriate container to avoid environmental
contamination.
2410107
EINECS Number
2
WGK Classification
T - Toxic
EC Annex I Classification
C - Corrosive
16. OTHER INFORMATION
30 July 1999
MSDS first issued
2 April 2001
MSDS data revised
This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is given in good faith, being based on the latest information
available to Johnson Matthey PLC and is to the best of Johnson Matthey PLC's knowledge and belief, accurate and reliable at
the time of preparation. However, no representation, warranty or guarantee is made as to the accuracy, liability or
completness and Johnson Matthey PLC assumes no responsibility therefore, and disclaims any liability for any loss, damage
or injury howsoever arising (including in respect of any claim brought by any third party) incurred using this information. The
product is supplied on thecondition that the user accepts responsibility to satisfy himself as to the suitability and completness
of such information for his own particular use. Freedom from patent or any other proprietary rights of any third party must not
be assumed. 聽
Reference Sources
REFERENCE SOURCES
Registry of Toxic Effects of Chemical Substances. Published by the National Institute of Occupational Safety and Health. USA.
Oil and Hazardous Materials Technical Assistance Data System. Published by The Office of Water and Waste Management.
Environmental Protection Agency USA.
Chemical Hazard Response Information System. Published by US Coast Guard.
NIOSHTIC Occupational Safety and Health database. Published by the National Institute of Occupational Safety and Health.
USA.
HSELINE Health and Safety Executive Library and Information Service. Published by the Health and Safety Executive. UK.
CISDOC International Occupational Safety and Health Database. Published by the International Labour Organisation. Geneva.
RISKLINE. Published by the National Chemical Inspectorate. Sweden.
TOXLINE. Published by the Chemical Abstracts Service. USA.
Developmental and Reproductive Toxicology. The National Library of Medicine. USA.
Toxicity, Bibliography. The National Library of Medicine. USA.
Environmental Mutagen Information. Oak Ridge National Laboratory. USA.
Environmental Teratology Information. Oak Ridge National Laboratory. USA
BIOSIS. Published by Biological Abstracts Inc. USA.
Epidemiology Information. The Food and Drug Administration. USA
International Pharmaceutical Abstracts. The American Society of Hospital Pharmacists. USA.
Hazardous Materials Technical Center Abstracts. Department of the Army, Hazardous Materials Technical Center. USA.
Toxicology Document and Data Depository. National Technical Information Service. USA.
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Johnson Matthey
HYDROGEN HEXACHLOROPLATINATE(IV)
181000 6.00 EC Current 02.04.2001
16. OTHER INFORMATION (continued)
Federal Research in Progress. National Technical Information Service. USA.
Toxicology Research Projects. National Institutes of Health. USA
Toxic Substances Control Act Test Submissions. The Environmental Protection Agency. USA.
Patty's Industrial Hygiene and Toxicology 3rd edition.
Handbook on the Toxicology of Metals. Friberg, Nordberg and Vouk 2nd edition.
Bretherick's Handbook of Reactive Chemical Hazards. 5th edition.
Grant's Toxicology of the Eye. 3rd edition.
Merck Index 10th edition.
Handbook on Toxicology of Inorganic Compounds. Seiler, Sigel and Sigel.
Catalog of Teratogenic Agents. Shepard. 4th edition
Reproductive Hazards of Industrial Chemicals. Barlow and Sullivan.
Royal Society of Chemistry, Chemical Safety Data Sheets.
National Sales Offices
Johnson Matthey PLC,33 Jeffreys Road, Brimsdown, ENFIELD, Middlesex EN3 7PW, United Kingdom, Tel:- 0208 8048111,
Fax:- 0208 8041918
S.A.Johnson Matthey N.V., 8 Avenue de Bale, 1140 BRUSSEL, Belgi毛 / Belgique, Tel:- 2 729 0711, Fax:- 2 216 9061
Johnson Matthey A/S, Frederikssundsvej 274 D, Br垄nsh垄j 2700, Denmark, Tel:- 38 89 62 00, Fax:- 38 89 62 01
Johnson Matthey PLC, Unit 1 - 2, Blanchardstown Business Centre, Clonsilla Road, Blanchardstown, Dublin 15, Republic of
Ireland, Tel:- 1 820 7722, Fax:- 1 820 7733
Johnson Matthey GmbH, Alfa Products, Zeppelinstrasse 7, Postfach 6540, D-7500 KARLSRUHE 1, Deutschland, Tel:- 721
840070, Fax:- 721 849674
Johnson Matthey SA, 13 Rue de la Perdrix, Z1 PARIS Nord II, BP 50240, 95996 Roissy, CDG Cedix France, Tel:- 1 48 63 22
99, Fax:- 1 48 63 27 02
Oy Johnson Matthey A.B, Kielotie 7A 4KRS, 01300 BANTAA, Soumi, Tel:- 08574 800, Fax:- 08574 807
Johnson Matthey A.B., Victor Hasselblads gata 8, S-421 31 V盲stra Fr枚lunda, Sverige, Tel:- 031 891390, Fax:- 31 477795
Johnson Matthey & Co G.m.b.H, Steckhovengasse 12, 1132 WIEN, 脰sterreich, Tel:- 877 98 90, Fax:- 877 98 933
Johnson Matthey & Brandenberger A.G., Glattalstrasse 18, CH-8052 ZURICH, Switzerland, Tel:- 01 307 1919, Fax:- 01 307
1920
Johnson Matthey GmbH, Otto-Volger-Stra脽e 9B, D-65843 Sulzbach/Ts, Deutschland, Tel:- (0 61 96)70 38-21, Fax:- (0 61 96)
70 38 12
17. 000000000
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