Material Safety Data Sheet
ITW Philadelphia Resins
Part No.: 3080R Page 1
MARINE-TEX POLY-DURA RESIN
This product appears in the following stock number(s):
Last revised: 10/28/05
3080R
1/16/2006
Printed:
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Tradename: MARINE-TEX POLY-DURA RESIN
Product Identifier: EPOXY RESIN
General use: This information applies to the resin component of the two-part kit; handle freshly-mixed resin and
hardener as recommended for the hardener. After curing, the product is not hazardous.
Chemical family: Epoxy resin
MANUFACTURER EMERGENCY INFORMATION
ITW Philadelphia Resins Emergency telephone number
130 Commerce Dr. (800) 424-9300
(CHEMTREC):
Montgomeryville, PA 18936
Other Calls: (215) 855-8450
2. COMPOSITION/INFORMATION ON INGREDIENTS
Exposure limits
HAZARDOUS CONSTITUENTS
Weight ACGIH OSHA Other
Constituent Abbr. CAS No.
percent TLV PEL Limits
Crystalline silica 14808607 0.05 mg/m3 4/(%Q+2)ppm 0.10 mg/m^3
<1
(Canada)
Bisphenol A diglycidyl ether resin DGEBPA 25068386 n/e n/e n/e
40-70
Butylated bisphenol A epoxy resin 71033084 n/e n/e n/e
5-15
4-Nonyl-phenol 84852153 n/e n/e n/e
NPHOH 10-20
"TLV" means the Threshold Limit Value exposure (eight-hour, time-weighted average, unless otherwise noted) established by the American Conference of
Governmental Industrial Hygienists. "STEL" indicates a short-term exposure limit. "PEL" indicates the OSHA Permissible Exposure Limit."n/e" indicates
that no exposure limit has been established. An asterisk (*) indicates a substance whose identity is a trade secret of our supplier and unknown to us.
3. HAZARDS IDENTIFICATION
Emergency Overview
Appearance, form, odor: Viscous grey liquid with phenolic odor.
WARNING! Eye and skin irritant. Potential skin sensitizer.
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Part No.: 3080R Page 2
Potential health effects
Skin contact
Primary routes of exposure: Skin absorption Eye contact Inhalation Ingestion
Symptoms of acute overexposure:
Skin: Irritant (pain, redness, swelling, burns, blistering). Contact at elevated temperatures can cause thermal burns which
may result in permanent damage. May cause skin sensitization (itching, redness, rashes, hives, burning, swelling).
Eyes: Irritant (blinking, stinging, burning sensation, tearing, redness, swelling). Contact at elevated temperatures can cause
thermal burns which may result in permanent damage. Severe eye damage may cause blindness.
Inhalation:
In applications where poorly ventilated, strongly heated or atomized the vapor or mist can cause irritation of the
respiratory tract (nasal discharge, coughing, discomfort/ burning sensation in the nose, throat and lungs).
Ingestion:
May cause burning of mouth, throat and stomach. May cause gastric distress (nausea, vomiting, diarrhea, thirst,
weakness, collapse). Aspiration may occur during swallowing or vomiting, resulting in lung damage.
Effects of chronic overexposure:
Prolonged or repeated skin contact may cause sensitization, with itching, swelling, or rashes on later exposure.
Repeated inhlation may cause lung damage.
Carcinogenicity -- OSHA regulated: No ACGIH: No National Toxicology Program: No
International Agency for Research on Cancer: No
Cancer-suspect constituent(s) : Crystalline Silica
Medical conditions which may be aggravated by exposure:
Preexisting eye and skin disorders (e.g. eczema), asthma and respiratory diseases (e.g. Bronchitis, Emphysema,
inflammatory or fibrotic).
Other effects:
See section 11.
4. FIRST AID MEASURES
First aid for eyes:
Flush eye with clean water for at least 20 minutes while gently holding eyelids open, lifting upper and lower lids. Get
immediate medical attention.
First aid for skin:
Immediately remove contaminated clothing and excess contaminant. Flush skin with water for at least 15 minutes.
Wash thoroughly with soap and warm water. Consult a physician if irritation develops.
First aid for inhalation:
Remove patient to fresh air. Administer oxygen if breathing is difficult. Get medical attention if symptoms persist.
First aid for ingestion:
Do NOT induce vomiting. Administer 3-4 glasses of milk or water. Never give anything by mouth to an unconscious
person. If vomiting occurs spontaneously, keep head below hips (if sitting) or to the side (if lying down) to prevent
aspiration. Get immediate medical attention.
Note to physician :
This product contains nonylphenol which is corrosive. Aspiration of this product during induced emesis may result in
severe lung injury. If evacuation of stomach is necessary, use method least likely to cause aspiration, such as gastric
lavage after endotracheal intubation.
5. FIRE FIGHTING MEASURES
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Material Safety Data Sheet
ITW Philadelphia Resins
Part No.: 3080R Page 3
Extinguishing media:
Carbon dioxide Dry chemical Foam Alcohol foam
Water
Flash Point (掳F): > 300 Method: estimation
Explosive limits in air (percent) -- Lower: n/d Upper: n/d
Special firefighting procedures:
Material will not burn unless preheated. Do not enter confined space without full bunker gear. Firefighters should wear
self-contained breathing apparatus and protective clothing. Cool fire exposed containers with water.
Unusual fire and explosion hazards:
Heating above 300 deg F in the presence of air may cause slow oxidative decomposition and above 500 deg F may
cause polymerization. Personnel in vicinity and downwind should be evacuated.
Hazardous products of combustion:
When heated to decomposition it emits fumes of Cl- , carbon monoxide, other fumes and vapors varying in composition
and toxicity.
6. ACCIDENTAL RELEASE MEASURES
Spill control:
Avoid personal contact. Eliminate ignition sources. Ventilate area.
Containment:
Dike, contain and absorb with clay, sand or other suitable material.
Cleanup:
For large spills, pump to storage/salvage vessels. Soak up residue with an absorbent such as clay, sand, or other
suitable material and dispose of properly. Flush area with water to remove trace residue.
Special procedures:
Prevent spill from entering drainage/sewer systems, waterways, and surface waters. Collect run-off water and transfer to
drums or tanks for later disposal. Notify local health authorities and other appropriate agencies if such contamination
occurs.
7. HANDLING AND STORAGE
Handling precautions:
Avoid contact with skin, eyes, or clothing. Wash thoroughly with soap and water after using and particularly before
eating, drinking, smoking, applying cosmetics, or using toilet facilities.
Launder contaminated clothing and protective gear before reuse. Discard contaminated leather articles.
Handle mixed resin and hardener in accordance with the potential hazard of the curing agent used. Provide appropriate
ventilation/respiratory protection against decomposition products (see Section 10) during welding/flame cutting
operations and to protect against dust during sanding/grinding of cured product.
Storage:
Store in a cool, dry area away from high temperatures and flames.
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ITW Philadelphia Resins
Part No.: 3080R Page 4
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering controls
Ventilation :
Use ventilation that is adequate to keep employee exposure to airborne concentrations below exposure limits (or to the
lowest feasible levels when limits have not been established). Although good general mechanical ventilation is usually
adequate for most industrial applications, local exhaust ventilation is preferred (see ACGIH - Industrial Ventilation).
Local exhaust may be required for confined areas (see OSHA 1910.146).
Other engineering controls :
Have emergency shower and eye wash available.
Personal protective equipment
Eye and face protection:
Chemical goggles if liquid contact is likely, or Safety glasses with side shields.
Skin protection:
Chemical-resistant gloves and other gear as required to prevent skin contact.
Respiratory protection:
None needed in normal use with proper ventilation. In poorly ventilated areas use NIOSH approved organic vapor cartidge
respirator for uncured resin, dust/particle respirator during grinding/sanding operations for cured resin, or fresh airline
respirator as exposure levels dictate (see OSHA 1910.134).
9. PHYSICAL AND CHEMICAL PROPERTIES
Specific gravity: 1.25 Boiling point (掳F): >500
n/d Vapor density (air = 1): >1
Melting point (掳F):
Evaporation rate (butyl acetate = 1): <<1
Vapor pressure (mmHg): < 1 mm Hg at 68 掳F
VOC (grams/liter): 0 Solubility in water: Negligible
Percent volatile by volume: 0 pH (5% solution or slurry in water): neutral
Percent solids by weight: 100
10. STABILITY AND REACTIVITY
This material is chemically stable. Hazardous polymerization will not occur.
Conditions to avoid :
Open flame and extreme heat
Incompatible materials:
Strong Lewis or mineral acids, strong oxidizing agents, strong mineral and organic bases (especially primary and
secondary aliphatic amines).
Hazardous products of decomposition:
Oxides of carbon; aldehydes, ketones, acids and other organic substances may be formed during combustion or
elevated temperature (>500 deg F) degradation.
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Material Safety Data Sheet
ITW Philadelphia Resins
Part No.: 3080R Page 5
Conditions under which hazardous polymerization may occur:
Heat is generated when resin is mixed with curing agents; Run-a-way cure reactions may char and decompose the
resin, generating unidentified fumes and vapors which may be toxic.
11. TOXICOLOGICAL INFORMATION
Acute oral effects: LD50 (rat): Not available.
Acute dermal effects: LD50 (rabbit): Not available.
Component: Extreme skin sensitizer.
Acute inhalation effects: Exposure: 8 hours.
LC50 (rat): Not available.
Eye irritation:
Not available.
Subchronic effects:
Not available.
Carcinogenicity, teratogenicity, and mutagenicity:
1) MUTAGENICITY: Liquid resins based on diglycidyl ether of Bisphenol A (DGEBPA), have proved to be inactive when
tested by in vivo mutagenicity assays. These resins have shown activity in in vitro microbial mutagenicity screening and
have produced chromosomal aberrations in cultured rat liver cells. The significance of these tests to man is unknown.
2) CARCINOGENICITY: Recent 2-year bioassays in rats and mice exposed by the dermal route to DGEBPA yielded no
evidence of carcinogenicity to the skin or any other organs. This study clarifies prior equivocal results from a 2-year
mouse skin painting study, which were suggestive, but not conclusive, for weak carcinogenic activity. 3) The
International Agency for Research on Cancer (IARC) concluded that DGEBPA is not classifiable as a carcinogen (IARC
group 3), that is human and animal evidence of carcinogenicy is inadequate.
Other chronic effects:
Prolonged or repeated skin contact may cause sensitization, with itching, swelling, or rashes on later exposure.
Studies have shown bisphenol A diglycidyl ether resin to cause allergic contact dermititis.
Toxicological information on hazardous chemical constituents of this product:
Oral LD50 Dermal LD50 Inhalation LC50
Constituent
(rat) (rabbit) 4hr, (rat)
Crystalline silica n/d n/d n/d
Bisphenol A diglycidyl ether resin 11.4 g/kg >20 ml/kg no deaths
Butylated bisphenol A epoxy resin > 2000 mg/kg n/d n/d
4-Nonyl-phenol n/d n/d >1 mg/L
'n/d' = 'not determined'
12 ECOLOGICAL INFORMATION
Ecotoxicity:
96 hr LC50 (Fathead Minnow) < 750 mg/L.
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Mobility and persistence:
Not available.
Environmental fate:
Not available.
13. DISPOSAL CONSIDERATIONS Please see also Section 15, Regulatory Information.
Waste management recommendations:
If this resin becomes a waste, it would not be a hazardous waste by RCRA criteria (40CFR 261). Dispose of according
to applicable federal, state, and local regulations. Incineration is the preferred method of disposal.
14. TRANSPORT INFORMATION
ORM-D : Y
Proper shipping name: Environmentally hazardous substances, liquid, n.o.s. *
Technical name : Nonylphenol LtdQty : Y
Hazard class : 9
UN number: 3082
Packing group: III
Emergency Response Guide no.: 171
IMDG page number: N/A
Other: Non-regulated Material (Ground & Air). Marine
Pollutant (nonylphenol).
*Depending upon the size and type of container, this material may be reclassified as "Consumer Commodity,
ORM-D" for shipments within the United States, or "Limited Quantity" elsewhere. Refer to the appropriate
regulation.
15. REGULATORY INFORMATION
U.S. Federal Regulations
TSCA:
All ingredients of this product are listed, or are exempt from listing, on the TSCA inventory.
The following RCRA code(s) applies to this material if it becomes waste:
None
Regulatory status of hazardous chemical constituents of this product:
Extremely Toxic CERCLA TSCA 12B Export
Constituent
Hazardous* Chemical** RQ (lbs) Notification
Crystalline silica No No 0.0 Not required
Bisphenol A diglycidyl ether resin No No 0.0 Not required
Butylated bisphenol A epoxy resin No No 0.0 Required
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Material Safety Data Sheet
ITW Philadelphia Resins
Part No.: 3080R Page 7
Extremely Toxic CERCLA TSCA 12B Export
Constituent
Hazardous* Chemical** RQ (lbs) Notification
4-Nonyl-phenol No No 0.0 Required
*Consult the appropriate regulations for emergency planning and release reporting requirements for substances on the SARA Section 301
Extremely Hazardous Substance list.
**Substances for which the "Toxic Chemical" column is marked "Yes" are on the SARA Section 313 list of
Toxic Chemicals, for which release reporting may be required. For specific requirements, consult the appropriate regulations.
For purposes of SARA Section 312 hazardous materials inventory reporting, the following hazard
classes apply to this material: - Immediate health hazard -- Delayed health hazard -
Canadian regulations
WHMIS hazard class(es) : D2A, D2B
All components of this product are on the Domestic Substances List or the Non-Domestic Substances List
16. OTHER INFORMATION
Hazardous Materials Health Flammability Reactivity
Identification System (HMIS)
3* 1 1
ratings:
The information and recommendations in this document are based on the best information available to us at the time of preparation, but we make no
other warranty, express or implied, as to its correctness or completeness, or as to the results of reliance on this document.
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Material Safety Data Sheet
ITW Philadelphia Resins
Part No.: 3080H Page 1
MARINE-TEX POLY-DURA HARDENER
This product appears in the following stock number(s):
Last revised: 02/03/05
3080H
1/16/2006
Printed:
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Tradename: MARINE-TEX POLY-DURA HARDENER
General use: The following health hazard data pertain to the hardener only. When fully cured, the mixed product is
non-hazardous.
Chemical family: Aliphatic amines
MANUFACTURER EMERGENCY INFORMATION
ITW Philadelphia Resins Emergency telephone number
130 Commerce Dr. (800) 424-9300
(CHEMTREC):
Montgomeryville, PA 18936
Other Calls: (215) 855-8450
2. COMPOSITION/INFORMATION ON INGREDIENTS
Exposure limits
HAZARDOUS CONSTITUENTS
Weight ACGIH OSHA Other
Constituent Abbr. CAS No.
percent TLV PEL Limits
Triethanolamine 102716 5 mg/m3 n/e n/e
TEA 1-10
Piperazine 110850 n/e n/e n/e
<5
Triethylenetetramine 112243 n/e n/e 1 ppm (skin)
TETA <5
(AIHA-WEEL)
Aminoethylpiperazine 140318 n/e n/e n/e
AEP 5-15
TETA, Reaction products with 26950630 n/e n/e n/e
5-15
Propylene Oxide
Dinonylphenol 84962083 n/e n/e n/e
DNP 5-15
"TLV" means the Threshold Limit Value exposure (eight-hour, time-weighted average, unless otherwise noted) established by the American Conference of
Governmental Industrial Hygienists. "STEL" indicates a short-term exposure limit. "PEL" indicates the OSHA Permissible Exposure Limit."n/e" indicates
that no exposure limit has been established. An asterisk (*) indicates a substance whose identity is a trade secret of our supplier and unknown to us.
3. HAZARDS IDENTIFICATION
Emergency Overview
Appearance, form, odor: Amber liquid with ammonia-like, fishy odor.
WARNING! Eye, skin and respiratory irritant. Harmful if absorbed through skin. Potential skin sensitizer.
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Potential health effects
Skin contact
Primary routes of exposure: Skin absorption Eye contact Inhalation Ingestion
Symptoms of acute overexposure:
Skin: Severe irritation (redness, swelling) or burns, necrosis, blistering and permanent injury. Product can be absorbed
through the skin and may cause nausea, headache and general discomfort.
Eyes: Corrosive. Severe irritation (pain, redness, swelling) or burns. May cause lacrimation, conjunctivitis, corneal damage
and may cause permanent injury (ie. blindness).
Inhalation:
Corrosive to the respiratory system. If the hardener is poorly ventilated, strongly heated or atomized, the vapor or mist
can cause severe irritation of the respiratory tract, damage contacted tissue and produce scarring. May cause
dizziness, drowsiness, euphoria, nasal discharge, disorientaion, coughing and pain or tightness in chest, headache;
nausea and vomiting in severe cases. In confined spaces: may cause loss of consciousness and asphyxiation
Ingestion:
Causes severe damage to mucous membranes if swallowed. May cause malaise, headache, discomfort, diarrhea,
bleeding and vomiting of blood.
Effects of chronic overexposure:
Prolonged or repeated overexposure by skin contact or inhalation may cause skin sensitization, with itching, swelling
and rashes upon further exposure. Repeated or prolonged exposure may cause adverse respiratory effects (coughing,
tightness of chest, shortness of breath), nervous system disorders (narcosis, behavioral changes, decreased motor
function), muscular dysfunction, eye effects (conjunctivitis, corneal damage), or skin effects (rash, irritation, corrosion).
Carcinogenicity -- OSHA regulated: No ACGIH: No National Toxicology Program: No
International Agency for Research on Cancer: No
Cancer-suspect constituent(s) : None
Medical conditions which may be aggravated by exposure:
Eye disease, skin disorders and allergies, asthma and respiratory diseases (e.g. Bronchitis, Emphysema). Neurological
disorders.
Other effects:
Repeated and/or prolonged exposure to low concentrations of vapor may cause: sore throat, eye irritation, which are
transient. Corneal edema may give rise to a perception of "blue haze" or "fog" around lights which is transient and has
no known residual effect.
4. FIRST AID MEASURES
First aid for eyes:
Flush eye with clean water for at least 20 minutes while gently holding eyelids open, lifting upper and lower lids. Get
immediate medical attention.
First aid for skin:
Immediately remove contaminated clothing and excess contaminant. Flush skin with water for at least 15 minutes.
Wash thoroughly with soap and warm water. Consult a physician if irritation develops.
First aid for inhalation:
Remove patient to fresh air. Administer oxygen if breathing is difficult. Get medical attention if symptoms persist.
First aid for ingestion:
Do NOT induce vomiting. Administer 3-4 glasses of milk or water. Never give anything by mouth to an unconscious
person. If vomiting occurs spontaneously, keep head below hips (if sitting) or to the side (if lying down) to prevent
aspiration. Get immediate medical attention.
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Part No.: 3080H Page 3
Note to physician :
Highly injurious to all tissues, similar to that of ammonia or ammonia gas. Chemical pneumonitis, pulmonary edema,
laryngeal edema and delayed scarring of the airway or other attected tissues may occur following exposure. Give
supportive treatment similar to thermal burns.
5. FIRE FIGHTING MEASURES
General fire and explosion characteristics:
Class IIIB.
Extinguishing media:
Carbon dioxide Dry chemical Foam Alcohol foam
Water
Flash Point (掳F): > 190 Method: estimate
Explosive limits in air (percent) -- Lower: n/d Upper: n/d
Special firefighting procedures:
Do not enter confined space without full bunker gear. Firefighters should wear self-contained breathing apparatus and
protective clothing to prevent all skin and eye contact with this material. Cool fire exposed containers with water.
Unusual fire and explosion hazards:
Sudden reaction and fire may result if product is mixed with an oxidizing agent. Personnel in vicinity and downwind
should be evacuated.
Hazardous products of combustion:
Acrid and toxic fumes with organic amines, ammonia, oxides of carbon and nitrogen.
6. ACCIDENTAL RELEASE MEASURES
Spill control:
Avoid personal contact. Evacuate area. Eliminate ignition sources. Ventilate area.
Containment:
Dike, contain and absorb with clay, sand or other suitable material.
Cleanup:
Using butyl rubber protective clothing and self-contained breathing apparatus, neutralize and reduce vapors with sodium
bisulfate. Absorb spillage on inert material and discard in closed, nonporous containers.
Special procedures:
Prevent spill from entering drainage/sewer systems, waterways, and surface waters. Collect run-off water and transfer to
drums or tanks for later disposal. Notify local health authorities and other appropriate agencies if such contamination
occurs.
7. HANDLING AND STORAGE
Handling precautions:
Avoid breathing vapors. Avoid contact with skin, eyes, or clothing. Wash thoroughly with soap and water after using
and particularly before eating, drinking, smoking, applying cosmetics, or using toilet facilities.
Launder contaminated clothing and protective gear before reuse. Discard contaminated leather articles.
Handle mixed resin and hardener in accordance with the potential hazard of the curing agent used. Provide appropriate
ventilation/respiratory protection against decomposition products (see Section 10) during welding/flame cutting
operations and to protect against dust during sanding/grinding of cured product. Do NOT mix with sodium nitrite or other
nitrosating agents as cancer-causing nitrosamines could be formed.
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ITW Philadelphia Resins
Part No.: 3080H Page 4
Storage:
Store in a cool, dry area away from high temperatures and flames. Do not store in reactive metal containers. Keep
away from acids, oxidizers. Keep container tightly closed when not in use.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering controls
Ventilation :
Use ventilation that is adequate to keep employee exposure to airborne concentrations below exposure limits (or to the
lowest feasible levels when limits have not been established). Although good general mechanical ventilation is usually
adequate for most industrial applications, local exhaust ventilation is preferred (see ACGIH - Industrial Ventilation).
Local exhaust may be required for confined areas (see OSHA 1910.146).
Other engineering controls :
Have emergency shower and eye wash available.
Personal protective equipment
Eye and face protection:
Full face shield with chemical goggles if liquid contact is likely, or safety glasses with side shields.
Skin protection:
Chemical-resistant rubber (e.g. neoprene, butyl rubber, nitrile) gloves and other protective gear as needed to prevent skin
contact. The breakthrough time of the selected glove(s) must be greater than the intended use period.
Respiratory protection:
None needed in normal use with proper ventilation. In poorly ventilated areas use NIOSH approved ammonia vapor
cartidge respirator for uncured product, dust/particle respirator during grinding/sanding operations for cured product, or
fresh airline respirator as exposure levels dictate (see OSHA 1910.134).
9. PHYSICAL AND CHEMICAL PROPERTIES
Specific gravity: n/d Boiling point (掳F): > 212
Melting point (掳F): n/d Vapor density (air = 1): >1
Evaporation rate (butyl acetate = 1): <1
Vapor pressure (mmHg): <21mm Hg at 70 掳F
VOC (grams/liter): 0 Solubility in water: > 30%
Percent volatile by volume: 0 pH (5% solution or slurry in water): alkaline
Percent solids by weight: 100
10. STABILITY AND REACTIVITY
This material is chemically stable. Hazardous polymerization will not occur.
Conditions to avoid :
Extreme heat or open flame. Product slowly corrodes copper, aluminum, zinc and galvanized surfaces.
Incompatible materials:
Oxidizers, acids, Clorinated organic cmpds. Reactive metals (e.g. Na, Ca, zinc). Sodium/calcium hypochlorite.
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Part No.: 3080H Page 5
Peroxides. Mat'ls reactive with hydroxyl cmpds.
Hazardous products of decomposition:
Acrid, toxic smoke; organic & nitros amines; carbon & nitrogen oxides; nitriles; cyanic acid; isocyanates; cyanogens;
amides; carbamates; nitric acid; ammonia;aldehydes;ketones.
Conditions under which hazardous polymerization may occur:
Heat is generated when resin is mixed with curing agents; Run-a-way cure reactions may char and decompose the
resin, generating unidentified fumes and vapors which may be toxic.
11. TOXICOLOGICAL INFORMATION
Acute oral effects: LD50 (rat): > 1600 mg/kg (estimate)
Acute dermal effects: LD50 (rabbit): > 1000 mg/kg (estimate)
Acute inhalation effects: Exposure: 4 hours.
LC50 (rat): Not available.
Eye irritation:
Not available.
Subchronic effects:
TEA: prolonged and repeated ingestion has caused kidney damage in laboratory animals.
Carcinogenicity, teratogenicity, and mutagenicity:
Results from a battery of short term genotoxicity tests on components in this material indicate mutagenic activity. TEA:
male rats dermally exposed from 32-125 mg/kg/day showed a marginal increase in kidney tumors.
Other chronic effects:
Not available.
Toxicological information on hazardous chemical constituents of this product:
Oral LD50 Dermal LD50 Inhalation LC50
Constituent
(rat) (rabbit) 4hr, (rat)
Triethanolamine 8000 mg/kg >2000 mg/kg n/d
Piperazine 1900 mg/kg 4 g/kg n/d
Triethylenetetramine 2500 mg/kg 550 mg/kg n/d
Aminoethylpiperazine 2140 mg/kg 880 mg/kg n/d
TETA, Reaction products with Propylene Oxide n/d > 2000 mg/kg n/d
Dinonylphenol > 10 g/kg > 8 g/kg n/d
'n/d' = 'not determined'
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12 ECOLOGICAL INFORMATION
Ecotoxicity:
Not available.
Mobility and persistence:
Not available.
Environmental fate:
Not available.
13. DISPOSAL CONSIDERATIONS Please see also Section 15, Regulatory Information.
Waste management recommendations:
If this hardener becomes a waste, it would not be a hazardous waste by RCRA criteria (40CFR 261). Dispose of
according to applicable federal, state, and local regulations. Incineration is the preferred method of disposal.
14. TRANSPORT INFORMATION
ORM-D : N/A
Proper shipping name: Non-regulated
Technical name : N/A LtdQty : N/A
Hazard class : N/A
UN number: N/A
Packing group: N/A
Emergency Response Guide no.: N/A
IMDG page number: N/A
Other: N/A
15. REGULATORY INFORMATION
U.S. Federal Regulations
TSCA:
All ingredients of this product are listed, or are exempt from listing, on the TSCA inventory.
The following RCRA code(s) applies to this material if it becomes waste:
None
Regulatory status of hazardous chemical constituents of this product:
Extremely Toxic CERCLA TSCA 12B Export
Constituent
Hazardous* Chemical** RQ (lbs) Notification
Triethanolamine No No 0.0 Not required
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Material Safety Data Sheet
ITW Philadelphia Resins
Part No.: 3080H Page 7
Extremely Toxic CERCLA TSCA 12B Export
Constituent
Hazardous* Chemical** RQ (lbs) Notification
Piperazine No No 0.0 Not required
Triethylenetetramine No No 0.0 Not required
Aminoethylpiperazine No No 0.0 Not required
TETA, Reaction products with Propylene Oxide No No 0.0 Not required
Dinonylphenol No No 0.0 Not required
*Consult the appropriate regulations for emergency planning and release reporting requirements for substances on the SARA Section 301
Extremely Hazardous Substance list.
**Substances for which the "Toxic Chemical" column is marked "Yes" are on the SARA Section 313 list of
Toxic Chemicals, for which release reporting may be required. For specific requirements, consult the appropriate regulations.
For purposes of SARA Section 312 hazardous materials inventory reporting, the following hazard
classes apply to this material: - Immediate health hazard -- Delayed health hazard -- Fire hazard -
Canadian regulations
WHMIS hazard class(es) : E; B3; D2B
All components of this product are on the Domestic Substances List.
16. OTHER INFORMATION
Hazardous Materials Health Flammability Reactivity
Identification System (HMIS)
2* 2 1
ratings:
Revisions for this issue:
MSDS section Revisions
Formula change
2
Emergency overview
3
Shipping Description
14
Changed Health rating
16
The information and recommendations in this document are based on the best information available to us at the time of preparation, but we make no
other warranty, express or implied, as to its correctness or completeness, or as to the results of reliance on this document.
MSDS0619
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