03 鈥? Section 1 鈥?
Material Safety Data Sheet
Product Identification
Martin Senour Paints Emergency telephone number (216) 566-2917
4440 Warrensville Center Road Information telephone number (216) 566-2902
Warrensville Hts., OH 44128-2837 Date of preparation Januar y 30, 2003
漏2003, The Martin Senour Co.
NITRAM 庐 Acrylic Urethane Mixing Colors 9400/N1
9400 9401 9403 9404 9405 9406 9408 9409
鈥? Section 2 鈥? ACGIH OSHA LD50 LC50 Vapor
Hazardous Ingredients Mixing Oxide QA Lemon
CAS No. TLV PEL Units (Rat-Oral) (Rat) Pressure
mg/kg ppm/4hr. mm White Black Clear Yellow Violet Yellow Magenta Ferrite
(percent by weight)
搂 100 100
100-41-4 Ethylbenzene ppm 3500 NAv 7.1 0.1 P
<125 > <125 >
E
搂
95-63-6 1,2,4-Trimethylbenzene 25 25 ppm NAv NAv 2.0 1 1 1 1 1 R
150 150 C
123-86-4 n-Butyl Acetate ppm 13100 2000 10.0 24 47 52 39 43 29 45 34
<200 > <200 > E
搂 N
112-07-2 2-Butoxyethyl Acetate NAv NAv 2400 NAv 1.0 2 2 2 1 2 1
T
108-65-6 1-Methoxy-2-Propanol Acetate NAv NAv 8500 NAv 1.8 5 9 10 9 7 9 8
B
mg/m3 as Dust Y
13463-67-7 Titanium Dioxide 10 10[5] NAv NAv 46
[Resp. Fraction]
W
1333-86-4 Carbon Black 3.5 3.5 mg/m3 NAv NAv 3
E
1344-37-2 Lead Chromate 0.05 0.05 mg/m3 NAv NAv 34 I
G
搂
Lead Compound [% Lead] 34 [22.6] H
搂 T
Chromium VI Compound [% Chromium] 34 [5.1]
Weight per Gallon (lbs.) 12.37 8.17 8.14 8.76 8.35 11.25 8.21 10.01
VOC (Volatile Organic Compounds) Emitted - lbs./gal. 4.01 5.10 4.59 4.78 4.84 4.56 4.94 4.68
VOC Less Water & Federally Exempt Solvents - lbs./gal. 4.01 5.10 4.59 4.78 4.84 4.56 4.94 4.68
Photochemically Reactive No No No No No No No No
Flash Point (掳F) 72 72 72 72 72 72 72 72
HMIS (NFPA) Rating (health - flammability - reactivity) 2-3-0 2* - 3 - 0 2-3-0 2-3-0 2-3-0 2* - 3 - 0 2-3-0 2-3-0
搂
Ingredient subject to the reporting requirements of the Superfund Amendments and Reauthorization Act (SARA) Section 313, 40 CFR 372.65 C
!!! MSDS Text Page Follows !!! II-6
NITRAM 庐 Acrylic Urethane Mixing Colors 9400/N1
OTHER PRECAUTIONS - These products must be mixed with other components before use. Before opening the
Section 3 鈥? Hazards Identification
packages, READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS.
ROUTES OF EXPOSURE - Exposure may be by INHALATION and/or SKIN or EYE contact, depending on
Certain colors contain Lead (See TABLE and PRODUCT LABEL). Do not apply on toys and other children's articles,
conditions of use. Alcohols and acetates can be absorbed through the skin. Follow recommendations for proper use,
furniture, or any interior surface of a dwelling or facility which may be occupied or used by children. Do not apply on
ventilation, and personal protective equipment to minimize exposure.
any exterior surface of dwelling units, such as window sills, porches, stairs, or railings to which children may be
EFFECTS OF OVEREXPOSURE - Irritation of eyes, skin and upper respiratory system. May cause nervous system
commonly exposed.
depression. Extreme overexposure may result in unconsciousness and possibly death.
Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal.
Certain colors contain Lead (See TABLE and PRODUCT LABEL). Acute occupational exposure to Lead is
Section 9 鈥? Physical and Chemical Properties
uncommon, but results in effects and symptoms similar to chronic overexposure described below.
SIGNS AND SYMPTOMS OF OVEREXPOSURE - Headache, dizziness, nausea, and loss of coordination are PRODUCT WEIGHT See TABLE EVAPORATION RATE Slower than ether
indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate SPECIFIC GRAVITY 0.98 - 1.49 VAPOR DENSITY Heavier than air
eye or excessive skin exposure. BOILING POINT 255 - 384 掳F MELTING POINT Not Available
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE - None generally recognized. VOLATILE VOLUME 54 - 68 % SOLUBILITY IN WATER Not Available
CANCER INFORMATION - For complete discussion of toxicology data refer to Section 11.
Section 10 鈥? Stability and Reactivity
Section 4 鈥? First Aid Measures STABILITY - Stable
If INHALED: If affected, remove from exposure. Restore breathing. Keep warm and quiet. CONDITIONS TO AVOID - None known.
If on SKIN: Wash affected area thoroughly with soap and water. INCOMPATIBILITY - None known.
Remove contaminated clothing and launder before re-use. HAZARDOUS DECOMPOSITION PRODUCTS - By fire: Carbon Dioxide, Carbon Monoxide, Oxides of Metals in
If in EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. Section 2
If SWALLOWED: Do not induce vomiting. Get medical attention immediately. HAZARDOUS POLYMERIZATION - Will not occur
Section 5 鈥? Fire Fighting Measures Section 11 鈥? Toxicological Information
LEL UEL
FLASH POINT CHRONIC HEALTH HAZARDS - Certain colors contain Lead (See TABLE and PRODUCT LABEL). Chronic
See TABLE 0.5 13.1 overexposure to Lead may result in damage to the blood-forming, nervous, urinary, and reproductive systems
FLAMMABILITY CLASSIFICATION - RED LABEL -- Flammable, Flash below 100 掳F (including embryotoxic effects). Symptoms include abdominal discomfort or pain, constipation, loss of appetite,
EXTINGUISHING MEDIA - Carbon Dioxide, Dry Chemical, Foam metallic taste, nausea, insomnia, nervous irritability, weakness, muscle and joint pains, headache and dizziness.
UNUSUAL FIRE AND EXPLOSION HAZARDS - Closed containers may explode when exposed to extreme heat. Certain colors contain CHROMIUM (See TABLE and PRODUCT LABEL). Chromates are listed by IARC and NTP.
Application to hot surfaces requires special precautions. During emergency conditions overexposure to Although studies have associated exposure to Chromium VI compounds with an increased risk of respiratory cancer,
decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain available evidence indicates that Lead Chromate (Chrome Yellow, Molybdate Orange) DOES NOT present this
medical attention. hazard.
SPECIAL FIRE FIGHTING PROCEDURES - Full protective equipment including self-contained breathing apparatus Carbon Black is classified by IARC as possibly carcinogenic to humans (group 2B) based on experimental animal
should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to data, however, there is insufficient evidence in humans for its carcinogenicity.
cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme Ethylbenzene is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in
heat. humans and sufficient evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high
ethylbenzene concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung
Section 6 鈥? Accidental Release Measures
and liver tumors in mice. These effects were not observed in animals exposed to lower
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED - Remove all sources of ignition.
concentrations. There is no evidence that ethylbenzene causes cancer in humans.
Ventilate the area. Remove with inert absorbent.
Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary,
Section 7 鈥? Handling and Storage blood forming and reproductive systems.
STORAGE CATEGORY - DOL Storage Class IB Rats exposed to titanium dioxide dust at 250 mg./m3 developed lung cancer, however, such exposure levels are not
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING - Contents are FLAMMABLE. Keep away from heat, attainable in the workplace.
sparks, and open flame. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous
all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. system damage.
Consult NFPA Code. Use approved Bonding and Grounding procedures. Keep container closed when not in use.
Section 12 鈥? Ecological Information - No data available.
Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the
Section 13 鈥? Disposal Considerations
reach of children.
WASTE DISPOSAL METHOD - Waste from these products may be hazardous as defined under the Resource
Section 8 鈥? Exposure Controls/Personal Protection
Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the
PRECAUTIONS TO BE TAKEN IN USE - Certain colors contain Lead (See TABLE and PRODUCT LABEL). Before
applicable EPA hazardous waste numbers. Waste from products containing Lead or Chromium must also be tested
initial use, consult OSHA's Standard for Occupational Exposure to Lead (29 CFR 1910.1025).
for extractability.
Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash
Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal,
hands after using.
State/Provincial, and Local regulations regarding pollution.
These coatings may contain materials classified as nuisance particulates (listed 鈥渁s Dust鈥? in Section 2) which may
Section 14 鈥? Transport Information - No data available.
be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in
Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg./m3 (total dust), 3 mg./m3 (respirable
Section 15 鈥? Regulatory Information
fraction), OSHA PEL 15 mg./m3 (total dust), 5 mg./m3 (respirable fraction).
CALIFORNIA PROPOSITION 65 - WARNING: These products contain chemicals known to the State of California
VENTILATION - Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is
to cause cancer and birth defects or other reproductive harm.
maintained below applicable exposure limits. Refer to OSHA Standards 1910.94,1910.107, 1910.108.
TSCA CERTIFICATION - All chemicals in these products are listed, or are exempt from listing, on the TSCA
RESPIRATORY PROTECTION - If personal exposure cannot be controlled below applicable limits by ventilation,
Inventory.
wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials
Section 16 鈥? Other Information
in Section 2.
When sanding, wirebrushing, abrading, burning or welding the dried film, wear a particulate respirator approved by These products have been classified in accordance with the hazard criteria of the CPR and the MSDS contains all
NIOSH/MSHA for protection against non-volatile materials in Section 2. of the information required by the CPR.
PROTECTIVE GLOVES - Wear gloves which are recommended by glove supplier for protection against materials in
Section 2. The above information pertains to these products as currently formulated, and is based on the information available
EYE PROTECTION - Wear safety spectacles with unperforated sideshields. at this time. Addition of reducers or other additives to these products may substantially alter the composition and
hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied,
and assume no liability in connection with any use of this information.
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