China Antimony Chemicals Co., Ltd.
MATERIAL SAFETY DATA SHEET
Section 1. Product and company identification
iProduct name:. . BRIGHTSUN'IM Antimony Trioxide..
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Manufacturer:. . China Antimony Chemicals Co., Ltd.
Yongning Coastal Economic COlTidor& Development Zone
!Nanning, Guangxi, China 530221
http://www.chinaantimony.com.cn. 路
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I1-410-715-5687
Telephone numbers for information:. (USA) 86-771-4016991/4016992/4016993 (China)
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iCHEMTREC. 路 1-800- 424-9300 (USA) 1-703-527-3887 (International)..
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Date prepared:
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Chemical family:. 路
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IMSDS number:. 路 ---
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Section 2. Composition/information on ingredients
. .99.5%
IChemical Antimony Trioxide
ingredients:
. .0.1%
Arsenic
. .0.1%
Lead
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I~AS~~mber: .. 1309-64-4
AntimonyTrioxide
Arsenic 7440-38-2
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7439-92-1"
Lead
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Section 3. Hazards identification
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Emergency overview:. 路 I White powder, no odor. May be harmful if swallowed. May be hannful if inhaled.
ICancer hazard. Harmful if absorbed through skin.. .
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Potential health effects: Acute eye: may causes slight iITitation.
.. Acute skin: may cause ilTitation, allergic reaction. ,
Acute inhalation: may cause respiratory tract iITitation.
Acute ingestion: may cause loss of coordination, burns to mouth and esophagus.. . I
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iChronic effects:. 路 This product contains ingredients that are considered to be probable or suspected
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human carcinogens (see Section 11 - Chronic)...
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MARKETED BY
HARWICK STANDARD
DISTRIBUTION CORPORATION
60 S. Seiberling Street. Akron, Ohio 44305
Section 4. First aid measures
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Hold eyelids open and flush with a steady, gentle stream of water for at least 15 minutes. Seek
IEyes:--
immediate medical attention, preferably with an ophthalmologist. - -
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ISkin exposure: - - In case of contact, wash with plenty of soap and water. Seek medical attention if irritation develops or
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persists. - -
Ilm.alation:--::- emove the victim from immediate source of exposure and assure that the victim is breathing. If
breathing is difficult, administer oxygen, if available. If victim is not breathing, administer CPR
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(cardiopulmonary resuscitation). Seek medical attention. - -
If victim is conscious and alert, give large amounts of water to drink and do not induce vomiting.
Ingestion: - -
I Seek immediate medical attention. - -
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Notes All treatments should be based on observed signs and symptoms of distress in the patient.
f Consideration
to physician: -- should be given to the possibility that overexposure to materials other than this product
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may have occurred. Treat symptomatically.
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Section 5. Fire fighting measures
Not flammable- -
,Flash point:--
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IAll conventional
Extinguishing media: - - I
media are suitable- -
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Personal protective equipment:-- MSHA/NIOSH I
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Special procedures:--
ides of antimony; oxides of arsenic; oxides of lead. - -
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Section 6. Accidental release measures
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Evacuation procedures and safety:- - Wear appropriate protective gear for the situation. See personal protection
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I information in Section 8.- -
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~Ieanup and disposal of spill:- - Carefully sweep up material and place in suitable labeled containers for disposal. .
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Residual dusts can be removed by vacuuming. Wash spill area after pick-up is
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complete, collecting all clean up water for appropriate disposal. - -
fEnvironmental and Prevent material from entering public sewer system or any waterways. Spills may
:be reported to the National Response Center (800-424-8802) and to state and/or
regulatory reporting:- -
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local agencies. - -
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Section 7: Handling and Storage
IHandling: -- !Do not breathe dust. Do not get on skin or in eyes. Do not ingest. Use handling, storage and disposal
I Iprocedures that will prevent contamination of water, food or feed. --
I;or~ge: _:- - ~tore in a cool, dry, well-ventilated area away from incompatible materials. Keep container tightly
Iclosed. Protect containers against damage. - - I
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Section 8. Exposure controls/personal protection
.. _ Prevent oating,drinIcing,rooo"", ""'ge
r;:g~'~n' ODd
oo_tio a,.,Heation in ",co, where therei;;;-potentinl fot
I [exposure to the material. Always wash thoroughly after handling. - -
~ye -contact:::Fo avoid eye contact, wear safety glasses with side shields or chemical goggles. - ----
~W;~on~ct:~1 To avoid skin contact, wear rubber gloves, rubber boots, long-sleeved shirt, long pants and a head
covering. - -
To avoid breathing dust, use a particulate filter, NIOSH-approved per 42 CFR Part 84. Select N or R or P
Respiratory
Iprotection: -- I type as appropriate for the oil characteristics of any other air contaminants present. Filter efficiency may
Irange from 95% to 99.97% as appropriate for the size distribution of dusts present. --
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Engineering If needed, use localexhaust to keep exposuresto a minimum. -
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controls: --
~xposure --rAnt~ony Trioxide:0.5 mg/m3as Sb (OSHAPELTWA);0.5 mg/m3as Sb (ACGIHTLV TWA)---I
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Arsenic: 0.0 I mg/m3 (OSHA PEL TWA); 0.0 I mg/m3 Al (ACGIH TLV TWA)
Iguidelines: --
Lead: 0.05 mg/m3 (OSHA PEL TWA) ; 0.05 mg/m3 A3 (ACGIH TLV TWA)- -
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Section 9. Physical and chemical properties
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Color/Appearance White powder- -
IOdor- - Odorless- -
pH Value- - Not applicable- -
ISpecific 5.3-5.7
= 1)--
gravity (Water
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IVapor density -- Not applicable--
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Not applicable--
!Vapor pressure- -
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1425degreesC"
Boiling point- -
ISolubility in water- - Veryslightlysoluble--
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Section 10. Stability and reactivity
Chemical stability Stable at normal temperatures and storage conditions. .
IHazardous Will not occur. 路
polymerization. 路
. 1~,,-._
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IChe~c:. incompatibility. i Strong acids; Strong bases; Hot percWoric acid; Strong oxidizers. 路
-;'azard:us ~e:on:;~~i~~:TThermal decomposition products or combustion: oxides of antu:,ny, ~xid;; of arse:~,-
products.
路 oxides
oflead.
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Section 11. Toxicolog ical information
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Acute Data. 路
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.. - Rabbit mild..
I Irritation: 1100 mg eyes
IOral LDso:.. r;at: >34600mglkg..
IDermal ..
LDso: Rabbit: >2000mg/kg..
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I Intraperitoneal LDso: [Mouse: 172 mg/kg
---- IRat: 3250mg/kg
'Chronic Data..
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.., In a 90 day oral study in male and female rats, no adverse
Chronic toxicity studies: health effects were observed at
doses of 1000,5000 and 20000ppm..路 I
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Mutagenici~:;-ata: prolonged and excessive exposures may result in gastrointestinal discomfort and ulcers,
[ blood effects, livereffectsand neurologicaleffects..路 I
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Prolonged
andexcessive
exposures ayresultinreproductiveffects...
m e
r;eprod~ctivelteratology I I
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Idata: I
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Carcinogenicity data: Antimony trioxide has been classified by IARC as a Class 2B, which exhibits sufficient
I evidence in animal tests (possible human carcinogen) and has been determined by ACGIH to I
be a carcinogenic risk. Antimony trioxide has been identified by the EPA as a suspected lung;
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carcinogen.
Arsenic has been found to be a cancer hazard in humans, causing lung and skin cancer.
Lead has been classifiedby IARC as a possiblehuman carcinogen(Class 2B) and identified I
by ACGIH as a Category A3, Animal Carcinogen.
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Section 12. Ecological information
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iEco-acute toxicity Bluegill slU1fish,96-hour LD50:>530 mg/l
. Fathead minnow, 96-hour LC50:>833 mg/l
. Daphnia magna, 48-hour LC50:423-530 mg/l
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Brachydanio rerio, 96-hour LC50 : > I000 mg/l
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rAntimony
Environmental fate trioxide may biodegrade.
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This material will persist in the environment.
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Antimony oxide is not expected to bioconcentrate.. 路
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Section 13. Disposal considerations
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Procedures:
regulations.. 路
Fo, di""""I, in.;noml,thi, malon.l ., . C"".hly!batrompl." with lo,,~ ""', ond codomll
Section 14. Transportation information
iU.SDOT:
!Proper shipping name:
INot regulated for containers less than 400 lb.
"For containers 400-999 Ib: Environmentally hazardous substances, solid, n.o.s. (Contains
Arsenic)
For containers 1000-4999 Ib: Environmentally hazardous substances, solid, n.o.s. (Contains
Arsenic and Antimony Trioxide)
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'For containers 5000 Ib or greater: Environmentally hazardous substances, solid, n.o.s. (Contains
IArsenic, Lead and Antimony Trioxide) _,
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Hazard class
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UNNo... tUN3077.. I
Packing group. 路
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Section 15. Regulatory information
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OSHA: IFor arsenic see OSHA 29 CFR 1910.1018; For lead see OSHA 29 CFR 1910.1025"
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ISARATitle 3: .. ISections 311/312 Hazardous Categories (40 CFR 370.21):
Acute: Yes; Chronic: Yes; Fire: No; Reactive: No; Pressure: No. 路 I
ISARA 313:
fThe followingmaterialsare subjectto the reportingrequirementsof S;ction 31~f Title III of I
the SuperflU1dAmendments and Reauthorization Act of 1986 and 40 CFR Part 372:
Antimonytrioxide (de minimisconcentration= 1%)
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=0.1%)
Arsenic (de minimis concentration
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=0.1%)
Lead (de minimis concentration
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CERCLA Reportable I Sections 102a/I03HazardousSubstances(40 CFR 302.4):
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Quantity (RQ): Antimony trioxide RQ: 1000 Ib
I Arsenic RQ: lIb
Lead RQ: 10 Ib"
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Antimony trioxide:
IState Regulations:
New Jersey Right to Know Hazardous Substance List (l % reporting limit)
'Massachusetts Substance List
Pennsylvania Environmental Hazard List
California Proposition 65: WARNING: This product contains antimony trioxide, known by the
State of California to cause cancer.
Arsenic:
New Jersey Special Health Hazard Substance List (0,1% reporting limit)
Massachusetts Substance List -Carcinogen
Pennsylvania Environmental Hazard List and Special Hazardous Substance List
California Proposition 65: No-significant risk levels are 0,06 ug/day (inhalation) and 10 ug/day
I(except inhalation)
IWARNING: This product contains arsenic, known by the State of California to cause cancer and
reproductivetoxicity,
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'Lead:
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New Jersey Special Health Hazard Substance List (0,1% reporting limit)
Massachusetts Substance List -Teratogen with sufficient evidence of risk in humans
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!Pennsylvania Environmental Hazard List
California Proposition 65: Acceptable intake level is 0,5 ug/day
WARNING: This product contains lead, known by the State of California to cause
developmental and reproductive toxicity.
International This material (or each component) is listed on the following inventories:
Canada - DSL
regulations
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EU EINECS
Australia- AlCS
Japan - ENCS
Korea - ECL
Philippines- PICCS ,
China - List I
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- Antimony trioxide
Canadian Disclosure List (l %)
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Canadian Disclosure List (0.1%) - Arsenic
.Canadian WHMIS Hazard(0.1%) and Division = D.2.a, D,2.b
CanadianDisclosureList Class - Lead
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Section 16. Other information
= I; Reactivity =I..
National Fire Protection Association (NFPA)!Health=3; Flammability
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ratings.
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3/18/2004. 路
Issue date. 路
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Revised date. 路 108/22/2005 ---
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Supersedes. 路
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_._- China Antimony Chemicals Co., Ltd.
IResponsibility for MSDS. .
Address.
路 Yongning Coastal Economic Conidor & Development Zone
Nanning, Guangxi, China 530221. .
i86-771-401699 1I4016992/40 16993, 4016995 (Fax)"
Telephone. 路
IMPORTANT: The information presented herein, while not guaranteed, was prepared by our competent technical personnel
and is true and accurate to the best of our knowledge. No warranty of merchantability or of fitness for a particular purpose, or
warranty or guaranty of any other kind, expressed or implied, is made regarding performance, suitability, stability or
otherwise. While our technical personnel will be happy to respond to questions regarding safe handling and use procedures,
safe handling and use remains the responsibility of the customer. No suggestions for use are intended to, and nothing herein
shall be construed as a recommendation to, infringe any existing patents or violate any laws, rules, regulations or ordinances
of any governmental entity.
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