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MSDS Material Safety Data Sheet
CAS

15630-89-4
497-19-8
6834-92-0

File Name: 15630-89-4.asp

                   MATERIAL SAFETY DATA                                                  SHEET
Phycomycin SCP
1. Product And Company Identification
Supplier Manufacturer
Applied Biochemists (WI) Advantis Technologies, Inc.
A division of Advantis Technologies, Inc. 1400 Bluegrass Lakes Parkway
W175 N11163 Stonewood Drive, Suite 234 Alpharetta, GA 30004 United States
Germantown, WI 53022
Telephone Number: (262) 255-4449 Telephone Number: (770) 521-5999
FAX Number: (262) 255-4268 FAX Number: (770) 521-5959
Web Site: www.appliedbiochemists.com Web Site: www.poolspacare.com

Supplier Emergency Contacts & Phone Number Manufacturer Emergency Contacts & Phone Number
CHEMTREC - DAY OR NIGHT: (800) 424-9300 CHEMTREC - DAY OR NIGHT:


Issue Date: 11/12/2007
Product Name: Phycomycin SCP
Chemical Name: Sodium Carbonate Peroxyhydrate
CAS Number: 15630-89-4
MSDS Number: 357
Product/Material Uses
Maximum use for potable water is 33 mg/L.

2. Composition/Information On Ingredients

Ingredient CAS Percent Of
Name Number Total Weight
SODIUM CARBONATE 497-19-8

SODIUM CARBONATE PEROXYHYDRATE 15630-89-4
SODIUMMETASILICATE 6834-92-0

Ingredients listed in this section have been determined to be hazardous as defined in 29CFR 1910.1200. Materials
determined to be health hazards are listed if they comprise 1% or more of the composition. Materials identified as
carcinogens are listed if they comprise 0.1% or more of the composition. Information on proprietary materials is available in
29CFR 1910.1200(i)(1).

EMERGENCY OVERVIEW
Toxicity effects principally related to its irritating properties.
Does not present any significant hazard to the environment.
Supports combustion of other substances (oxidizing product).

Hazards Identification (Pictograms)




3. Hazards Identification
Primary Routes(s) Of Entry
Inhalation, skin, ingestion
Eye Hazards
Severe eye irritation, watering, redness; can cause burns to the eyes.
Risk of serious or permanent eye lesions.



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MATERIAL SAFETY DATA SHEET
Phycomycin SCP

3. Hazards Identification - Continued

Skin Hazards
Slight irritation.
In case of repeated contact: risk of dermatitis.
Ingestion Hazards
Severe irritation of the mouth, throat, esophagus and stomach.
Bloating of stomach, belching.
Nausea and vomiting.
Inhalation Hazards
Slight nose and throat irritation.
At high concentrations, cough.
In case of repeated or prolonged exposure; risk of sore throat, nosebleeds, and chronic bronchitis.

First Aid (Pictograms)




4. First Aid Measures
Eye
In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes.
Consult with an ophthalmologist in all cases.
Skin
Wash contaminated area with flowing water. Remove contaminated clothing and wash before reuse. Get medical
attention immediately in case of persistent pain or redness.
Ingestion
Call a physician or a poison control center immediately. DO NOT INDUCE VOMITING. If victim is fully conscious,
give one or two cups of water to drink. Never give anything by mouth to an unconscious victim.
Inhalation
If inhaled, remove to fresh air. Consult Physician in case of respiratory symptoms.

Fire Fighting (Pictograms)




5. Fire Fighting Measures
Flash Point: NA 掳F NA 掳C
Autoignition Point: NA 掳F NA 掳C
Flammability Class: Non-flammable
Fire And Explosion Hazards
Oxidizer
Extinguishing Media
Large quantities of water, water spray.
In case of fire in close proximity, all means of extinguishing are acceptable.
Fire Fighting Instructions
Specific Hazards:
-Oxygen released on exothermic decomposition may support combustion in case of surrounding fire.


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MATERIAL SAFETY DATA SHEET
Phycomycin SCP

5. Fire Fighting Measures - Continued

Fire Fighting Instructions - Continued
-Pressure burst may occur due to decomposition in confined spaces/containers.
-Wet product decomposed exothermally and may cause combustion of organic materials.
-Do not spray the dry product with water, except in case of fire.

Protective measures in case of intervention:
-Evacuate all non-essential personnel.
-Intervention should only be by personnel who are trained and aware of the hazards of the product.

Other Precautions:
If safe to do so, remove the exposed containers.

6. Accidental Release Measures
Precautions:
-Observe protective measures given in sections 5 and 8.
-Avoid materials and products which are incompatible with the product (See section 10).
Avoid direct contact of the product with water.

Cleanup methods:
-Collect the product with suitable means, shovel, or sweep, avoiding dust formation.
-All receiving equipment should be clean, dry, vented, labeled and made of materials compatible with the product.
-Do not return spilled or contaminated material to inventory.
-In order to avoid the risk of contamination, the recovered product must not be returned to the original container.
-Clean area with large quantities of water.
-For disposal methods, refer to section 13.

Precautions for protection of the environment:
-Immediately notify the appropriate authorities in case of reportable spill.

Handling & Storage (Pictograms)




7. Handling And Storage
Handling Precautions
-Clean and dry process and other piping and equipment before using this product.
-Never return unused product to storage container.
-Keep away from incompatible products.
-Containers and equipment used for the peroxide product should be used exclusively for that product.
-Avoid contact with water or humidity.
-For more information, contact the supplier.
Storage Precautions
-Store in a dry area.
-Protect from direct sunlight.
-Store away from heat sources.
-Keep away from incompatible products.
-Store in vented containers.
-Store in temperatures less than 40C (104F).
-Keep in container fillted with safety valve or vent.
-Container must be used exclusively for the product.


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MATERIAL SAFETY DATA SHEET
Phycomycin SCP

7. Handling And Storage - Continued

Work/Hygienic Practices
Suitable packaging include: Stainless Steel, PE, Paper and PE, Glass, Passivated Aluminum.


Protective Clothing (Pictograms)




8. Exposure Controls/Personal Protection
Engineering Controls
Authorized limit Values TLV ACGIH-USA (2002) OSHA PEL

Paticulates not otherwise Inhalable 10 mg/m3 Inhalable 15 mg/m3
classified (PNOC) TWA TWA
Respirable 3 mg/m3 Respirable 5 mg/m3
TWA TWA

No specific TLV-STEL (Short Term Exposure Limit) has been set. Excursions in exposure level may exceed 3 times
the TLV_TWA for no more than a total of 30 minutes during a workday and under no circumstances should they
exceed 5 times the TLV-TWA.
Eye/Face Protection
Wear dustproof goggles.
Skin Protection
For brief contact, few precautions other than clean body-covering clothing should be needed. When prolonged or
frequently repeated contact could occur, use protective full-body clothing such as PVC or rubber, impervious to this
material.

Protective gloves should be made of PVC, neoprene or rubber.
Respiratory Protection
For many conditions, no respiratory protection may be needed; however in dusty or unknown atmospheres or when
exposures exceed limit values, use NIOSH-approved dust respirator.
Other/General Protection
-An eyewash and safety shower should be nearby and ready for use.
-Consult your industrial hygienist or safety manager for the selection of personal protective equipment suitable for the
working conitions.

9. Physical And Chemical Properties
Appearance
Granular solid, White.
Odor
None.
Chemical Type: Mixture
Physical State: Solid
Melting Point: NA 掳F
Boiling Point: NA 掳F
Vapor Pressure: NA
pH Factor: 10.4-10.6 At a Concentration Of 1% Solution


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MATERIAL SAFETY DATA SHEET
Phycomycin SCP

9. Physical And Chemical Properties - Continued

Odor - Continued
Solubility: Water: 140 g/l @ 24C (75F)
Viscosity: NA

10. Stability And Reactivity
Stability: Stable under certain conditions of use with slow gas release
Hazardous Polymerization: Will not occur
Conditions To Avoid (Stability)
-Heat/Sources of heat.
-Moisture.
Incompatible Materials
-Water.
-Acids.
-Bases.
-Salts of Metals.
-Reducing agents.
-Organic materials.
-Flammable substances.
Hazardous Decomposition Products
Oxygen; Decomposition releases steam and heat.

11. Toxicological Information
Eye Effects
Rabbit, Severe damage (eyes)
Skin Effects
Dermal LD50 lo, rabbit, >2000 mg/kg.
Rabbit, slight irritation (skin).
Acute Oral Effects
Oral LD50, rat, 1034 mg/kg.
Acute Inhalation Effects
Inhalation LC50, 1 hour, rat, >4580 mg/m3.

12. Ecological Information
Acute Toxicity - Fish And Invertebrates
Fish, Pimephales promelas; LC50, 70.7 mg/L
Fish, Pimephales promelas; NOEC, 96 hours, 1 mg/L
Crustaceans, Daphnia pulex; EC50, 4.9 mg/L
Crustaceans, Daphnia pulex; NOEC, 48 hours, 1 mg/L
Toxic for aquatic organisms. Nevertheless, hazard for the environment is limited due to product properties:
-No bioaccumulation
-Abiotic degradation
-Low toxicity of degradation prodcuts.


13. Disposal Considerations
Waste treatment: Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide, spray mixture or
rinsate is a violation of Federal law. If these wastes cannot be disposed of by use according to label instructions, contact
your State Pesticide or Environmental Control Agency or Hazardous Waste representative at the nearest EPA Regional
Office for guidance.

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MATERIAL SAFETY DATA SHEET
Phycomycin SCP

13. Disposal Considerations - Continued


Packaging Treatement:
Container disposal:
-Fiber drums with liners: Completely empty by shaking and tapping sides and bottom to loosen clinging particles. Empty
residue into application equipment, then dispose of liner in sanitiary landfill or by incineration if allowed by state and local
authorities. If drum is contaminated and cannot be reused, dispose of in the same manner.
-Bags/Plastic Pails: Completely empty container into application equipment. Triple rinse pail and offer for recycling or
reconditioning. Containers can also be disposed in a sanitary landfill or by incineration if allowed by state and local
authorities. If burned, stay out of smoke.
RCRA Information
Listed as D001 (Ignitable)

14. Transport Information
Proper Shipping Name
Oxidizing solid, n.o.s. (sodium carbonate peroxyhydrate)
Hazard Class
5.1, PGIII
DOT Identification Number
UN1479
DOT (Pictograms)




15. Regulatory Information
SARA Hazard Classes
Fire Hazard
SARA Section 313 Notification
No
Canadian Regulatory Information
WHMIS Classification:
C Oxidizing material.
D2B Poisonous and infectious material - other toxic effects.

NFPA HMIS
HEALTH 2
0
FLAMMABILITY 0
2 1
REACTIVITY 1
OX
X
PERSONAL PROTECTION


16. Other Information
Revision/Preparer Information
MSDS Preparer: JHW




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MATERIAL SAFETY DATA SHEET
Phycomycin SCP

Disclaimer

Although reasonable care has been taken in the preparation of this document, we extend no warranties
and make no representations as to the accuracy or completeness of the information contained therein,
and assume no responsibility regarding the suitablility of this information for the user's intended purposes
or for the consequences of its use. Each individual should make a determination as to the suitability of
the information for their particular purposes(s).
Applied Biochemists (WI)
Printed Using MSDS Generator鈩? 2000




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