MATERIAL SAFETY 3M DATA SHEET 3M Center St. Paul, Minnesota 55144-1000 1-800-364-3577
or (651) 737-6501 (24 hours) Copyright, 2001, Minnesota Mining and Manufacturing Company. All
rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M
products is allowed provided that: 1) the information is copied in full with no changes unless prior
agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otherwise distributed
with the intention of earning a profit thereon. DIVISION: COMMERCIAL CARE DIVISION TRADE
NAME: 3M Brand DEODORIZER - COUNTRY GARDEN - CONCENTRATE .................. (Product
No. 12, Twist 'n Fill (tm) System) ID NUMBER/U.P.C.: 70-0706-3514-2 00-48011-20119-6
70-0707-1411-1 00-48011-20799-0 70-0708-4012-2 00-48011-20119-6 70-0710-0972-7
00-48011-23895-6 ISSUED: March 12, 2001 SUPERSEDES: April 10, 2000 DOCUMENT: 06-8477-9
----------------------------------------------------------------------------- 1. INGREDIENT C.A.S. NO.
PERCENT ----------------------------------------------------------------------------- POLYALKOXY
ALCOHOLS..................... 69013-18-9 30 - 60 FRAGRANCE............................... Unknown 10 - 30
WATER................................... 7732-18-5 10 - 30 SORBITAN POLYETHOXY MONOLAURATE.........
9005-64-5 10 - 30 1-METHOXY-2-PROPANOL.................... 107-98-2 1 - 5 IN CASE OF
EMERGENCY: THE NUMBERS AT THE TOP OF THIS PAGE PROVIDE 24 HOUR RESPONSE
FROM ANY PHONE FOR ALL EMERGENCIES WITH THIS PRODUCT.
----------------------------------------------------------------------------- 2. PHYSICAL DATA
----------------------------------------------------------------------------- BOILING POINT:................. ca. 212 F
VAPOR PRESSURE:................ N/D VAPOR DENSITY:................. N/D EVAPORATION
RATE:.............. N/D SOLUBILITY IN WATER:........... complete SPECIFIC GRAVITY:.............. ca. 1
Water=1 PERCENT VOLATILE:.............. ca. 50 % pH:............................ 6 - 7
VISCOSITY:..................... < 100 centipoise MELTING POINT:................. N/A
----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined
N/A - Not Applicable CA - Approximately MSDS: 3M Brand DEODORIZER - COUNTRY GARDEN -
CONCENTRATE .................. (Product No. 12, Twist 'n Fill (tm) System) March 12, 2001 PAGE 2
----------------------------------------------------------------------------- 2. PHYSICAL DATA (continued)
----------------------------------------------------------------------------- APPEARANCE AND ODOR: Liquid,
clear; dark red color; strong floral fragrance
----------------------------------------------------------------------------- 3. FIRE AND EXPLOSION HAZARD
DATA ----------------------------------------------------------------------------- FLASH POINT:................... >
212 F TCC FLAMMABLE LIMITS - LEL:........ N/D FLAMMABLE LIMITS - UEL:........ N/D
AUTOIGNITION TEMPERATURE:...... N/D EXTINGUISHING MEDIA: Water, Carbon dioxide, Dry
chemical, Foam SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothing, including
helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants,
bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head.
UNUSUAL FIRE AND EXPLOSION HAZARDS: No unusual fire or explosion hazards are anticipated.
NFPA HAZARD CODES: HEALTH: 1 FIRE: 1 REACTIVITY: 0 UNUSUAL REACTION HAZARD:
none ----------------------------------------------------------------------------- 4. REACTIVITY DATA
----------------------------------------------------------------------------- STABILITY: Stable
INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID: Strong Oxidizing Agents.
HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur. HAZARDOUS
DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide, Irritant Vapors or Gases.
----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined
N/A - Not Applicable CA - Approximately MSDS: 3M Brand DEODORIZER - COUNTRY GARDEN -
CONCENTRATE .................. (Product No. 12, Twist 'n Fill (tm) System) March 12, 2001 PAGE 3
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----------------------------------------------------------------------------- 5. ENVIRONMENTAL
INFORMATION ----------------------------------------------------------------------------- SPILL RESPONSE:
Observe precautions from other sections. Ventilate area. Contain spill. Cover with absorbent material.
Collect spilled material. Clean up residue with water. Place in a closed container. RECOMMENDED
DISPOSAL: Incinerate in an industrial or commercial facility in the presence of a combustible material.
ENVIRONMENTAL DATA: Not determined. REGULATORY INFORMATION: Volatile Organic
Compounds: ca. 25 %. VOC Less H2O & Exempt Solvents: N/D. Since regulations vary, consult
applicable regulations or authorities before disposal. U.S. EPA Hazardous Waste Number = None (Not
U.S. EPA Hazardous). TSCA: All components used in the manufacture of this material are in compliance
with the US TSCA inventory. EPCRA HAZARD CLASS: FIRE HAZARD: No PRESSURE: No
REACTIVITY: No ACUTE: Yes CHRONIC: No
----------------------------------------------------------------------------- 6. SUGGESTED FIRST AID
----------------------------------------------------------------------------- EYE CONTACT: Immediately flush
eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. SKIN
CONTACT: Flush skin with large amounts of water. If irritation persists, get medical attention.
INHALATION: If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, call a
physician. IF SWALLOWED: Do not induce vomiting. Drink two glasses of water. Call a physician.
----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined
N/A - Not Applicable CA - Approximately MSDS: 3M Brand DEODORIZER - COUNTRY GARDEN -
CONCENTRATE .................. (Product No. 12, Twist 'n Fill (tm) System) March 12, 2001 PAGE 4
----------------------------------------------------------------------------- 7. PRECAUTIONARY
INFORMATION ----------------------------------------------------------------------------- EYE PROTECTION:
NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical
Dispenser, eye contact with the concentrate is not expected to occur. Avoid eye contact. Wear vented
goggles. SKIN PROTECTION: NOTE: When used as directed and diluted and dispensed with a
TWIST'n FILL (tm) Chemical Dispenser, skin contact with the concentrate is not expected to occur.
Avoid skin contact. RECOMMENDED VENTILATION: NOTE: When used as directed and diluted and
dispensed with a TWIST'n FILL (tm) Chemical Dispenser, special ventilation is not required. Use in a
well-ventilated area. RESPIRATORY PROTECTION: NOTE: When used as directed and diluted and
dispensed with a TWIST'n FILL (tm) Chemical Dispenser, respiratory protection is not required. Avoid
breathing of vapors, mists or spray. PREVENTION OF ACCIDENTAL INGESTION: Wash hands after
handling and before eating. RECOMMENDED STORAGE: Store away from heat. Keep container in
well-ventilated area. Keep out of the reach of children. FIRE AND EXPLOSION AVOIDANCE: Keep
container tightly closed. OTHER PRECAUTIONARY INFORMATION: Not intended for consumer sale
or use. This product is not intended to be used without prior dilution as specified on the product label.
HMIS HAZARD RATINGS: HEALTH: 1 FLAMMABILITY: 1 REACTIVITY: 0 PERSONAL
PROTECTION: X (See precautions, section 7.) EXPOSURE LIMITS INGREDIENT VALUE UNIT
TYPE AUTH SKIN* ----------------------------------------------------------------------------- POLYALKOXY
ALCOHOLS.................. NONE NONE NONE NONE FRAGRANCE............................ NONE NONE
NONE NONE WATER................................ NONE NONE NONE NONE SORBITAN POLYETHOXY
MONOLAURATE...... NONE NONE NONE NONE 1-METHOXY-2-PROPANOL................. 100 PPM
TWA ACGIH 1-METHOXY-2-PROPANOL................. 150 PPM STEL ACGIH
1-METHOXY-2-PROPANOL................. 100 PPM TWA OSHA
1-METHOXY-2-PROPANOL................. 150 PPM STEL OSHA
----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined
N/A - Not Applicable CA - Approximately MSDS: 3M Brand DEODORIZER - COUNTRY GARDEN -
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CONCENTRATE .................. (Product No. 12, Twist 'n Fill (tm) System) March 12, 2001 PAGE 5
EXPOSURE LIMITS (continued) INGREDIENT VALUE UNIT TYPE AUTH SKIN*
----------------------------------------------------------------------------- * SKIN NOTATION: Listed substances
indicated with 'Y' under SKIN refer to the potential contribution to the overall exposure by the cutaneous
route including mucous membrane and eye, either by airborne or, more particularly, by direct contact
with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: -
ACGIH: American Conference of Governmental Industrial Hygienists - OSHA: Occupational Safety and
Health Administration - NONE: None Established
----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA
----------------------------------------------------------------------------- EYE CONTACT: Moderate Eye
Irritation: signs/symptoms can include redness, swelling, pain, tearing, and hazy vision. SKIN
CONTACT: Lung Inflammation: Product contains surfactants which have been shown in animal studies
to cause lung inflammation resulting from prolonged skin contact. Signs/symptoms can include coughing
and shortness of breath. Moderate Skin Irritation: signs/symptoms can include redness, swelling, itching,
and dryness. May be absorbed through the skin in harmful amounts. INHALATION: Single
overexposure, above recommended guidelines, may cause: Central Nervous System Depression:
signs/symptoms can include headache, dizziness, drowsiness, incoordination, slowed reaction time,
slurred speech, giddiness and unconsciousness. Irritation (upper respiratory): signs/symptoms can include
soreness of the nose and throat, coughing and sneezing. IF SWALLOWED: Ingestion is not a likely route
of exposure to this product. Ingestion may cause: Irritation of Gastrointestinal Tissues: signs/symptoms
can include pain, vomiting, abdominal tenderness, nausea, blood in vomitus, and blood in feces.
----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined
N/A - Not Applicable CA - Approximately MSDS: 3M Brand DEODORIZER - COUNTRY GARDEN -
CONCENTRATE .................. (Product No. 12, Twist 'n Fill (tm) System) March 12, 2001 PAGE 6
----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA
(continued) ----------------------------------------------------------------------------- OTHER HEALTH
HAZARD INFORMATION: MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: medical
conditions, if any, known to be aggravated by exposure to this product are indicated in the appropriate
portions of the Health Hazard Data section of this data sheet. CARCINOGENS: components of this
product, if any, known to cause, or suspected of causing, cancer as determined by OHSA, IARC, or NTP
are described in the Health Hazard Data section of this data sheet in accord with the OHSA Hazard
Communications Standard, 29 CFR 1910.1200
----------------------------------------------------------------------------- SECTION CHANGE DATES
----------------------------------------------------------------------------- HEADING SECTION CHANGED
SINCE April 10, 2000 ISSUE -----------------------------------------------------------------------------
Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
----------------------------------------------------------------------------- The information in this Material Safety
Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES,
EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF
PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product
is fit for a particular purpose and suitable for user's method of use or application. Given the variety of
factors that can affect the use and application of a 3M product, some of which are uniquely within the
user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it
is fit for a particular purpose and suitable for user's method of use or application. 3M provides
information in electronic form as a service to its customers. Due to the remote possibility that electronic
file:///Y|/msds2/1/000004.htm (3 of 4) [12/10/2001 11:38:35 AM]
transfer may have resulted in errors, omissions or alterations in this information, 3M makes no
representations as to its completeness or accuracy. In addition, information obtained from a database may
not be as current as the information in the MSDS available directly from 3M.
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