3M MATERIAL SAFETY DATA SHEET 3M鈩LASS CLEANER CONCENTRATE (Product No. 1, Twist 'n Fill鈩ystem)
05/13/2002
Material Safety Data Sheet
Copyright, 2002, Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this
information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no
changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed
with the intention of earning a profit thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M鈩LASS CLEANER CONCENTRATE (Product No. 1, Twist 'n Fill鈩ystem)
MANUFACTURER: 3M
DIVISION: Commercial Care Division
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 05/13/2002
Supercedes Date: 05/13/2002
Document Group: 08-2582-8
Product Use:
Specific Use: Non-streaking cleaner for glass, mirrors, stainless steel, chrome, aluminum, ceramic and
plastic.
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
1-PROPOXY-2-PROPANOL 1569-01-3 60 - 100
LAURETH-6 CARBOXYLIC ACID 157707-83-0 1- 5
2-PROPOXY-1-PROPANOL 10215-30-2 1- 5
DIPROPYLENE GLYCOL 25265-71-8 1- 5
PROPYLENE GLYCOL 57-55-6 1- 5
DIPROPYLENE GLYCOL N-PROPYL ETHER 29911-27-1 1- 5
ETHANOLAMINE 141-43-5 0.5 - 1.5
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Liquid
Odor, Color, Grade: Clear, dark blue color. Ether odor.
General Physical Form: Liquid
Immediate health, physical, and environmental hazards: May cause severe eye irritation. May cause chemical skin burns.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and
Page 1 of 6
3M MATERIAL SAFETY DATA SHEET 3M鈩LASS CLEANER CONCENTRATE (Product No. 1, Twist 'n Fill鈩ystem)
05/13/2002
impaired vision.
Skin Contact:
Corrosive (Skin Burns): Signs/symptoms may include localized redness, swelling, itching, intense pain, blistering, ulceration, and
tissue destruction.
Inhalation:
Single exposure, above recommended guidelines, may cause:
Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness,
and nose and throat pain.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting.
Chemical (Aspiration) Pneumonitis: Signs/symptoms may include coughing, gasping, choking, burning of the mouth, difficulty
breathing, bluish colored skin (cyanosis), and may be fatal.
Target Organ Effects:
Single exposure, above recommended guidelines, may cause:
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination,
nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.
The route of exposure for Central Nervous System Depression is inhalation.
3.3 POTENTIAL ENVIRONMENTAL EFFECTS
A 3M Product Environmental Data Sheet (PED) is available.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water for at least 15 minutes.
Get immediate medical attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person.
Get immediate medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
No Data Available
Autoignition temperature
118 潞F
Flash Point
No Data Available
Flammable Limits - LEL
No Data Available
Flammable Limits - UEL
Class II Combustible Liquid
OSHA Flammability Classification:
Page 2 of 6
3M MATERIAL SAFETY DATA SHEET 3M鈩LASS CLEANER CONCENTRATE (Product No. 1, Twist 'n Fill鈩ystem)
05/13/2002
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure
demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for
exposed areas of the head. Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and
surfaces cool and prevent explosive rupture.
Unusual Fire and Explosion Hazards: Combustible liquid and vapor.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only
non-sparking tools. Ventilate the area with fresh air. Contain spill. Dilute in a large excess of water. Carefully, and with stirring, add
appropriate dilute acid such as sulfamic acid or vinegar. Confirm neutrality. Working from around the edges of the spill inward, cover
with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry.
Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with water. Place in a closed container
approved for transportation by appropriate authorities. Seal the container. Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Avoid contact with oxidizing agents. Avoid eye contact with vapors, mists, or spray. Avoid breathing of vapors, mists or spray. Do
not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks,
open flame, pilot lights and other sources of ignition. Keep container closed when not in use. Keep out of the reach of children.
7.2 STORAGE
Store away from acids. Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Use with appropriate local exhaust ventilation. NOTE: When used as directed and diluted and dispensed with a TWIST 'n
FILL鈩hemical Dispenser, special ventilation is not required.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL鈩hemical Dispenser, eye contact with the
concentrate is not expected to occur. Avoid eye contact.
The following eye protection(s) are recommended: Full Face Shield.
Page 3 of 6
3M MATERIAL SAFETY DATA SHEET 3M鈩LASS CLEANER CONCENTRATE (Product No. 1, Twist 'n Fill鈩ystem)
05/13/2002
8.2.2 Skin Protection
NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL鈩hemical Dispenser, skin contact with the
concentrate is not expected to occur. Avoid skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Butyl Rubber.
8.2.3 Respiratory Protection
NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL鈩hemical Dispenser, respiratory protection is not
required. Avoid breathing of vapors, mists or spray.
Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with
OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges. Consult the current 3M
Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of Swallowing
Do not ingest. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
ETHANOLAMINE ACGIH TWA 3 ppm
ETHANOLAMINE ACGIH STEL 6 ppm
ETHANOLAMINE OSHA TWA 3 ppm Table Z-1A
ETHANOLAMINE OSHA STEL 6 ppm Table Z-1A
PROPYLENE GLYCOL AIHA TWA - 50 ppm as vapor and aerosol
specific form
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Liquid
Specific Physical Form:
Clear, dark blue color. Ether odor.
Odor, Color, Grade:
Liquid
General Physical Form:
No Data Available
Autoignition temperature
118 潞F
Flash Point
No Data Available
Flammable Limits - LEL
No Data Available
Flammable Limits - UEL
Approximately 300 潞F
Boiling point
0.88
Density
No Data Available
Vapor Density
No Data Available
Vapor Pressure
Approximately 0.88 [Ref Std: WATER=1]
Specific Gravity
Approximately 10 [Details: 10% in water]
pH
No Data Available
Melting point
Complete
Solubility in Water
No Data Available
Evaporation rate
>=90 %
Volatile Organic Compounds
>=90 %
Percent volatile
No Data Available
VOC Less H2O & Exempt Solvents
Page 4 of 6
3M MATERIAL SAFETY DATA SHEET 3M鈩LASS CLEANER CONCENTRATE (Product No. 1, Twist 'n Fill鈩ystem)
05/13/2002
<=50 centipoise
Viscosity
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Strong oxidizing agents
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Aldehydes During Combustion
Carbon monoxide During Combustion
Carbon dioxide During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not Determined
CHEMICAL FATE INFORMATION
Not Determined
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in
a permitted hazardous waste facility.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable)
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number UPC ID Number UPC
70-0707-9584-7 00-48011-23357-9 70-0707-9593-8 00-48011-23366-1
70-0708-3892-8 00-48011-23915-1 70-0708-4007-2 00-48011-23357-9
70-0709-8998-6 70-0710-0958-6 00-48011-23915-1
Page 5 of 6
3M MATERIAL SAFETY DATA SHEET 3M鈩LASS CLEANER CONCENTRATE (Product No. 1, Twist 'n Fill鈩ystem)
05/13/2002
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
CHEMICAL INVENTORIES
TSCA: All components used in the manufacture of this material are in compliance with the U.S. TSCA inventory. One or more of the
components in this material is not listed on the TSCA inventory, but is approved for specific commercial use(s) under a U.S. EPA low
volume exemption (up to 1000 kg/yr).
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 3 Flammability: 2 Reactivity: 0 Special Hazards: None
National Fire Protection Agency Hazard Codes are designed for use by firefighters, sheriffs, or other emergency response teams who are concerned
with the hazards of burning or exploding materials. These NFPA codes are not intended to address the hazards of this product other than in a fire
situation.
HMIS Hazard Classification
Health: 3 Flammability: 2 Reactivity: 0 Protection: X - See PPE section.
HMIS codes are intended for use in everyday workplace settings to provide a rapid indication of the occupational hazards associated with chemicals
used in the workplace.
Revision Changes: Not Applicable
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
Page 6 of 6
|