MATERIAL SAFETY DATA SHEET
Page: 1 of 6
MGK 庐
Revision Date: 6/14/2005
McLaughlin Gormley King Company
PRODUCT CODE: 002519
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1. CHEMICAL PRODUCT AND COMPANY INFORMATION
PRODUCT CODE: 002519, EPA REG. NO.: 1021-1583
MULTICIDE铮? Concentrate 2519
PRODUCT NAME:
PRODUCT DESCRIPTION: An Insecticide concentrate for use in non-food areas of horse stables, kennels,
storage areas and zoo鈥檚.
CHEMICAL NAME: Mixture
庐
SYNONYMS: MULTICIDE 2519, MGK 2519
MANUFACTURER: McLaughlin Gormley King Company, 8810 Tenth Avenue North, Minneapolis MN.
55427
TELEPHONE M-F, 8:00-4:30 CST, 14:00-22:30 GMT: (800) 645-6466 or (763) 544-0341
MSDS & Product Information, 8:00-4:30 CST, 14:00-22:30 GMT: (800) 645-6466 or (763) 544-0341
24 HOUR EMERGENCY PHONE (CHEMTREC) CHEMTREC
U.S. and CANADA: (800)-424-9300 (ALL OTHER AREAS): (703) 527-3887
For information regarding MEDICAL EMERGENCIES or PESTICIDE INCIDENTS, call the INTERNATIONAL
POISON Center at:
1-888-740-8712
2. COMPOSITION / INFORMATION ON INGREDIENTS
COMPONENT(s) CAS # EINECS EXPOSURE LIMITS % BY WT.
PYNAMIN FORTE庐 042534-61-2 Not None Established 3.75
[(RS){1R,cis,trans}-chrysanthemate] Available
庐 026002-80-2 247-404-5 None Established 3.75
d-Phenothrin (SUMITHRIN ) [3-
Phenoxybenzyl-(1RS, 3RS; 1RS,
3SR)-2, 2-dimethyl-3-(2-methylprop-
1-enyl) cyclopropane-carboxylate]
Piperonyl Butoxide [Alpha-(2-(2- 000051-03-6 200-076-7 None Established 12.50
butoxyethoxy)ethoxy)-4,5-
methylenedioxy-2-propyltoluene]
OSHA: TWA 100 ppm (300 mg/ m3).
n-Butanol 000071-36-3 200-751-6 10.0 Max.
ACGIH: Ceiling 50 ppm (152 mg/ m3).
PEL = Permissible Exposure Limits. TWA = Time Weighted Average (8 hr).
TLV = Threshold Limit Value. STEL = Short Term Exposure Limit (15 min.).
COMMENTS: Ingredients not identified are proprietary or non-hazardous. Values are not product specifications.
3. HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS: EMERGENCY OVERVIEW
DANGER. CORROSIVE. Causes irreversible eye damage. Wear goggles, face shield, or safety glasses.
OSHA-COMBUSTIBLE LIQUID. Keep away from heat, sparks, and open flame. Harmful if swallowed, absorbed
through the skin, or inhaled. Take prudent precautions to avoid contact with skin, eyes, and clothing. Avoid
breathing vapors and/ or spray mists of this product.
24 HOUR EMERGENCY PHONE US & CAN.: (800)-424-9300 (ALL OTHER AREAS): (703) 527-3887
MATERIAL SAFETY DATA SHEET
Page: 2 of 6
MGK 庐
Revision Date: 6/14/2005
McLaughlin Gormley King Company
PRODUCT CODE: 002519
EYES: DANGER: Causes irreversible eye damage.
SKIN: Can cause skin irritation. Can cause a burning or prickling sensation on more
sensitive areas (face, eyes, mouth). Prolonged or repeated exposure can cause
irritation and reddening of the skin, possibly progressing into dermatitis.
SKIN ABSORPTION: Harmful if absorbed through the skin.
INGESTION: Can cause stomach irritation, resulting in nausea, cramps and vomiting. Can cause
nervous system disorders, such as fatigue, dizziness, headaches, lack of
coordination, tremors and unconsciousness.
INHALATION: Excessive inhalation can cause nasal and respiratory irritation, nausea and nervous
disorders, such as fatigue, dizziness, headaches, lack of coordination, tremors and
unconsciousness.
CHRONIC EFFECTS: None known
ECOLOGICAL: See Section鈥檚 12 and 15.
TOXICOLOGICAL: See Section 11.
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
4. FIRST AID MEASURES
FIRST AID PROCEDURES:
EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact
lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control
center or doctor for treatment advice.
SKIN: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes.
Call a poison control center or doctor for treatment advice.
INHALATION: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give
artificial respiration, preferably by mouth-to-mouth if possible. Call a poison control center or
doctor for further treatment advice.
INGESTION: Call poison control center of doctor immediately for treatment advice. Do not give any liquid to
the person. Do not induce vomiting unless told to do so by a poison control center or doctor.
Do not give anything by mouth to an unconscious person.
NOTE TO PHYSICIANS: Probable mucosal damage may contraindicate the use of gastric lavage.
5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES:
FLASH POINT: 122 潞F/ 50 潞C METHOD: TAG Closed Cup
This product is classified as an OSHA-COMBUSTIBLE LIQUID.
FLAMMABLE LIMITS:
LOWER FLAMMABLE LIMIT: not established.
UPPER FLAMMABLE LIMIT: not established.
AUTOIGNITION TEMPERATURE: not established.
HAZARDOUS COMBUSTION PRODUCTS: This product is classified as a FLAMMABLE LIQUID, and under fire
conditions it will support combustion and decompose to give off toxic
gases such as carbon monoxide, carbon dioxide, and nitrogen oxides.
EXTINGUISHING MEDIA: Foam, carbon dioxide, or dry chemical.
FIRE FIGHTING INSTRUCTIONS: Treat as an oil fire. Use a full-faced self-contained breathing apparatus along
with full protective gear. Keep nearby containers and equipment cool with a
water stream. Contain the run-off, if possible, for proper disposal.
24 HOUR EMERGENCY PHONE US & CAN.: (800)-424-9300 (ALL OTHER AREAS): (703) 527-3887
MATERIAL SAFETY DATA SHEET
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MGK 庐
Revision Date: 6/14/2005
McLaughlin Gormley King Company
PRODUCT CODE: 002519
6. ACCIDENTAL RELEASE MEASURES:
SMALL SPILL: Shut off ignition sources. Stop release, if possible without risk. Dike or contain release, if possible,
and if immediate response can prevent further damage or danger. Isolate and control access to
the release area. Take actions to reduce vapors. Absorb with appropriate absorbent. Clean spill
area of residues and absorbent.
LARGE SPILL: Shut off ignition sources. Stop release, if possible without risk. Dike or contain release, if possible,
and if immediate response can prevent further damage or danger. Isolate and control access to
the release area. Take actions to reduce vapors. Collect product into drums, etc. via drains,
pumps, etc. Absorb with appropriate absorbent. Clean spill area of residues and absorbent
WASTE DISPOSAL METHOD: Contaminated absorbent and wash water should be disposed of according to local,
state, and federal regulations.
7. HANDLING AND STORAGE
HANDLING: Wear appropriate chemically resistant gloves, such as neoprene or nitrile. Wear OSHA-approved
safety glasses, goggles or a face shield. Mechanical ventilation should be used when handling this
product in enclosed spaces. Wearing a respirator is not required when handling this product, but
recommended in the absence of proper mechanical ventilation. Do not contaminate water, feed or
food by storage, handling or disposal. Read and observe all precautions and instructions on the label.
STORAGE: Store containers upright and closed. Store in areas that are cool, dry and well-ventilated. Keep away
from heat, ignition sources and strong oxidizers. Emptied containers may retain product residues.
KEEP OUT OF REACH OF CHILDREN
WORK HYGIENIC PRACTICES: DO NOT SMOKE, EAT, DRINK OR APPLY COSMETICS IN WORK AREA!
Wash Promptly if skin becomes contaminated. Wash at the end of each
work shift and before eating, smoking and using the toilet.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE LIMITS: Not established by OSHA or ACGIH
ENGINEERING CONTROLS: Mechanical ventilation should be used when handling this product in enclosed
spaces. Local exhaust ventilation may be necessary.
RESPIRATORY PROTECTION: Not normally required. Use in well ventilated areas.
SKIN PROTECTION: Wear appropriate chemically resistant gloves and protective clothing.
EYE PROTECTION: Wear OSHA-approved safety glasses, goggles, or a face shield.
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: Hazy, dark amber liquid.
ODOR: Solvent
PHYSICAL STATE: Liquid
VAPOR PRESSURE: Not established
VAPOR DENSITY: Heavier than air.
BOILING POINT: Not established
MELTING POINT: Not applicable
SOLUBILITY IN WATER: Miscible in water
SPECIFIC GRAVITY: 1.044 @ 20掳C (68掳F)
COLOR, (GARDENER): 10.5
pH: 5.5 @ 2.1% in water
VISCOSITY: 1712 cps @ 24掳C (75.2掳F)
REFRACTIVE INDEX: 1.4862 @ 25潞C (77掳F)
VOC: < 16%
24 HOUR EMERGENCY PHONE US & CAN.: (800)-424-9300 (ALL OTHER AREAS): (703) 527-3887
MATERIAL SAFETY DATA SHEET
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MGK 庐
Revision Date: 6/14/2005
McLaughlin Gormley King Company
PRODUCT CODE: 002519
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY: Stable.
INCOMPATIBILITY: Not Compatible with strong acids or bases. Not compatible with strong
oxidizers.
HAZARDOUS DECOMPOSITION Not applicable.
PRODUCTS:
HAZARDOUS POLYMERIZATION: Will not occur
11. TOXICOLOGICAL INFORMATION
ACUTE STUDIES:
INGESTION:
Acute Oral LD50 (rat) = 4.19 gm/kg
SKIN:
Acute Dermal LD50 (rabbit) > 2.0 g/kg
Primary skin irritation (rabbit): Moderate irritation at 72 hours. Irritation Index = 2.54
Dermal Sensitization (guinea pig): Negative; Not a dermal sensitizer.
INHALATION:
Acute Inhalation LC50 (rat) (4 hours) The Acute Inhalation LC50 of this material places it in EPA Toxic
Category IV.
EYE:
Primary eye irritation (rabbit): Irritation present at 21 days.
CHRONIC:
CARCINOGENICITY: None of the components present in this material at concentrations equal
to or greater than 0.1% are listed by IARC, NTP, OSHA or ACGIH as
being carcinogens.
CARCINOGENICITY/ Marginally higher incidences of benign liver tumors in mice were
ONCOGENICITY: PBO observed following lifetime high dose exposures to PBO. The doses at
which tumors were observed for PBO greatly exceeded potential human
exposure from labeled uses.
Doses at which these effects were observed greatly exceed anticipated
human dietary intake. At anticipated dietary exposure levels, it is highly
unlikely that this product will result in carcinogenic effects.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL HAZARDS: This product is highly toxic to fish. Do not apply directly to water or
wetlands (swamps, bogs, marshes, and potholes). Drift from treated
areas may be hazardous to organisms in adjacent aquatic sites.
Cleaning of equipment or disposal of wastes must be done in a manner
that avoids contamination of bodies of water or wetlands. Do not
discharge effluent containing this product into lakes, streams, ponds,
estuaries, oceans, or other waters unless in accordance with the
requirements of a National Pollutant Discharge Elimination System
(NPDES) permit and the permitting authority has been notified in writing
prior to discharge. Do not discharge effluent containing this product into
sewer systems without previously notifying the sewage treatment plant
authority. For guidance, contact your State Water Board or Regional
Office of the EPA.
PERSISTENCE IN THE ENVIRONMENT Not Available.
24 HOUR EMERGENCY PHONE US & CAN.: (800)-424-9300 (ALL OTHER AREAS): (703) 527-3887
MATERIAL SAFETY DATA SHEET
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MGK 庐
Revision Date: 6/14/2005
McLaughlin Gormley King Company
PRODUCT CODE: 002519
13. DISPOSAL CONSIDERATIONS
RCRA \ CERCLA HAZARDOUS WASTE:
INGREDIENT RCRA ID#: CERCLA RQ-VALUE
n-Butanol U031 5,000 Lbs.
DISPOSAL METHOD: Wastes resulting from the use of this product may be disposed of on site or at an approved
waste disposal facility. When disposing of waste or surplus avoid contact with skin, eyes,
and clothing. Wear impervious gloves and chemical safety goggles.
CONTAINER DISPOSAL: Triple rinse (or equivalent) and offer for recycling or reconditioning, or puncture and
dispose of in a sanitary landfill or by other State and Local procedures.
14. TRANSPORT INFORMATION
U.S. DEPARTMENT OF TRANSPORTATION (DOT) INFORMATION:
PROPER SHIPPING NAME: Insecticides, Insect or Animal Repellent, Liquid, N.O.S.
HAZARD CLASS: Non-Hazardous
IDENTIFICATION NUMBER (UN or NA): N/A
PACKING GROUP: N/A
OTHER SHIPPING INFORMATION: Not regulated as Hazardous by the Department of Transportation
for Non-Bulk quantities ( < 119 Gallons/ 450 Liters). Please contact
MGK铮? when shipping in Bulk quantities.
INTERNATIONAL TRANSPORTATION REGULATIONS:
ICAO / IATA DESCRIPTION: Flammable Liquids, N.O.S. (n-Butanol), 3, UN1993, III
IMO DESCRIPTION (IMDG CODE): Not Available.
24 HOUR EMERGENCY PHONE US & CAN.: (800)-424-9300 (ALL OTHER AREAS): (703) 527-3887
MATERIAL SAFETY DATA SHEET
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MGK 庐
Revision Date: 6/14/2005
McLaughlin Gormley King Company
PRODUCT CODE: 002519
15. REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS:
SARA TITLE III: (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
311/ 312 HAZARD CATEGORIES:
FIRE: YES PRESSURE GENERATING: NO REACTIVITY: NO ACUTE: YES
SECTION 313 This product contains the following toxic chemicals of the subject to the reporting
REPORTABLE requirements of Section 313 of the Emergency Planning and Community Right-To-
INGREDIENTS: Know Act of 1986 and of 40 CFR 372:
CAS#: CHEMICAL NAME: % BY WEIGHT:
000051-03-6 Piperonyl Butoxide Alpha-(2-(2-butoxyethoxy)ethoxy)-4,5- 12.50
methylenedioxy-2-propyltoluene]
庐
042534-61-2 3.75
PYNAMIN FORTE [(RS){1R,cis, trans}-chrysanthemate]
庐
026002-80-2 3.75
d-Phenothrin (SUMITHRIN ) [3-Phenoxybenzyl-(1RS, 3RS;
1RS, 3SR)-2, 2-dimethyl-3-(2-methylprop-1-enyl)
cyclopropane-carboxylate]
000071-36-3 n-Butanol 10.0 Max.
302/ 304 EMERGENCY PLANNING
EMERGENCY PLAN: There are no SARA Title III Section 302 extremely hazardous substances
present in this formulation (40 CFR 355).
See Section 13 of this MSDS for the components that are subject to emergency requirements
under CERCLA Section 103(a)(40 CFR 302.4).
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA STATUS: All chemical substances found in this product comply with the Toxic Substances
Control Act鈥檚 inventory reporting requirements.
STATE REGULATIONS:
VOLATILE ORGANIC COMPOUNDS (VOC): This product contains less than 16% VOC鈥檚.
16. OTHER INFORMATION
HMIS RATINGS:
We assign HMIS ratings to this product based on the hazards of its ingredient(s). Since the customer is most aware
of the applications and conditions of use, he must ensure that the proper personal protective equipment is provided
consistent with information contained in Section鈥檚 7 and 8 of this MSDS.
HMIS RATINGS: Health 3
Flammability 2
Reactivity 1
The data contained herein are based on information currently available to McLaughlin Gormley King Company and,
to the best of our knowledge, are accurate and based on sound expert opinion. Our statements herein, however,
are not to be taken as a warranty or representation for which McLaughlin Gormley King Company assumes legal
responsibility.
Material Safety Data Sheet prepared by T. Azzivitto
24 HOUR EMERGENCY PHONE US & CAN.: (800)-424-9300 (ALL OTHER AREAS): (703) 527-3887
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