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Product MSDS Distributor Format Language Quantity
2776553 N/A Hach Company EEC English 1
__________________________________________________________________________________________________________
Total Enclosures: 1
World Headquarters
Hach Company
P.O.Box 389 MSDS No: M01707
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Reagent 3 Ammonia/Monochloramine Hypochlorite Solution
Catalog Number: 2776553
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M01707
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Determination of free ammonia
CAS No.: Not applicable
Hazard: Causes severe eye irritation.
Date of MSDS Preparation:
Day: 26
Month: 07
Year: 2005
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33
-
(0)1-40370404, Italy: +39-0266101029, Netherlands: +31 -(0)30-2748888, Switzerland: +41-(0)1-2515151
-
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2. COMPOSITION / INFORMATION ON INGREDIENTS
Sodium Hydroxide
EEC Number: 2151855
CAS No.: 1310732
--
Percent Range: < 1,0
Percent Range Units: weight / volume
Ingredient EEC Symbol: Xi - IRRITATING
Ingredient R phrase(s) (R phrase details given in Heading 16): R 36
TLV: 2 mg/m鲁
PEL: 2 mg/m鲁
EU Occupational Exposure Limits: 2 mg/m3
Demineralized Water
EEC Number: 2317912
CAS No.: 7732185
--
Percent Range: >98
Percent Range Units: volume / volume
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
Other component
EEC Number: Not applicable
CAS No.: Not applicable
Percent Range: < 1,0
Percent Range Units: Not applicable
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
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3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Clear, colorless liquid
Odor: Odorless
EU Symbols: Xi - IRRITATING
R PHRASES: R 36: Irritating to eyes.
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): Causes irritation
Skin Contact (EC): No effects are anticipated
Skin Absorption (EC): No effects anticipated
Target Organs (SA E): Not applicable
Ingestion (EC): May cause: irritation of the mouth and esophagus
Target Organs (Ing E): None Reported
Inhalation: No data reported.
Target Organs (Inh E): None Reported
Medical Conditions Aggravated: None reported
Chronic Effects: No effects anticipated
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: None reported
Toxicologically Synergistic Products: None reported
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4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with plenty of water.
Ingestion (First Aid): Do not induce vomiting. Give 1-2 glasses of water. Call physician immediately. Never give
anything by mouth to an unconscious person.
Inhalation: Remove to fresh air.
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5. FIRE FIGHTING MEASURES
Flammable Properties: Material will not burn.
Hazardous Combustion Products: This material will not burn.
Fire / Explosion Hazards: None reported
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriate to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear.
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6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Stop spilled material from being released to the environment.
Clean-up Technique: Cover spilled material with a dry acid, such as citric or boric. Scoop up slurry into a large beaker.
Dilute with a large excess of water. Adjust to a pH between 6 and 9. Use sulfuric or citric acid to lower pH. Use soda ash or
sodium bicarbonate to increase pH. Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate as needed to perform spill clean-up. If conditions warrant, increase the size of the
evacuation.
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7. HANDLING AND STORAGE
Handling: Avoid contact with eyes Wash thoroughly after handling. Maintain general industrial hygiene practices when
using this product.
Storage: Keep container tightly closed when not in use.
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Determination of free ammonia
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8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Maintain general industrial hygiene practices when using this
product.
Personal Protective Equipment:
Eye Protection: chemical splash goggles
Skin / Hand Protection: disposable latex gloves
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes Wash thoroughly after handling.
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
______________________________________
9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Clear, colorless liquid
Physical State: Liquid
Odor: Odorless
pH: 12,7
Vapor Pressure: Not determined
Vapor Density (air = 1): Not determined
Boiling Point: Not determined
Melting Point: Not applicable
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not applicable
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): Not determined
Evaporation Rate (water = 1): Not determined
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Miscible
Acid: Reacts with acids
Other: Not determined
Metal Corrosivity:
Steel: Not determined
Aluminum: Not determined
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10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Extreme temperatures
Reactivity / Incompatibility: Incompatible with: strong acids
Hazardous Decomposition: No hazardous decomposition products known.
Hazardous Polymerization: Will not occur.
______________________________________
11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: Sodium hydroxide 1% solution: skin rabbit standard Draize - does NOT meet OSHA
criteria for skin irritant
Mutation Data: None reported
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: Sodium hydroxide: oral rat LDLo = 500 mg/kg
This product does NOT contain any IARC listed chemicals.
______________________________________
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
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13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
______________________________________
14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
--
ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
--
I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regulated
--
A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: NA
A.D.R. Packing Group: NA
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
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15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: Xi - IRRITATING
R PHRASES: R 36: Irritating to eyes.
S PHRASES: S 26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 39:
Wear eye / face protection.
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16. OTHER INFORMATION
References: Air Contaminants, Federal Register, Vol. 54, No. 12. Thursday, January 19, 1989. pp. 2332-2983. In-house
information. Technical Judgment. CCINFO RTECS. Canadian Centre for Occupational Health and Safety. Hamilton,
Ontario Canada: 30 June 1993. EU Occupational Exposure Limits On Line.
R PHRASES: R 36: Irritating to eyes.
Use of the substance/preparation: Determination of free ammonia
Revision Summary: Updates in Section(s) 14,
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Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2005
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