SIGMA-ALDRICH
Material Safety Data Sheet
Date Printed: 21/FEB/2005
Date Updated: 13/MAR/2004
Version 1.3
According to 91/155/EEC
1 - Product and Company Information
Product Name CARBOXYMETHYLCELLULOSE SODIUM LOW
VISCOSITY
Product Number C5678
Company Sigma-Aldrich Pty, Ltd
Unit 2, 14 Anella Avenue
Castle Hill NSW 1765
Australia
Technical Phone # +61 2 9841 0555
Fax +61 2 9841 0500
Emergency Phone # +61 2 9841 0566
2 - Composition/Information on Ingredients
Product Name CAS # EC no Annex I
Index Number
CARBOXYMETHYL CELLULOSE, SODIUM 9004-32-4 None None
SALT
Formula C28H30Na8O27
Synonyms AC-Di-sol. NF * Aku-W 515 * Aquaplast * B 10 * B
10 (Polysaccharide) * Blanose BS 190 * Blanose
BWM * Carbose 1M * Carboxymethylcellulose,
sodium salt * Carmethose * Cellofas * Cellofas B
* Cellofas B5 * Cellofas B6 * Cellofas B50 *
Cellofas C * Cellogel C * Cellogen 3H * Cellogen
PR * Cellogen WS-C * Cellpro * Cellufix FF 100 *
Cellugel * Cellulose glycolic acid, sodium salt
* Cellulose sodium glycolate * CMC 2 * CMC 41A *
CM-Cellulose sodium salt * CMC 7H * CMC 4H1 *
CMC 7H3SF * CMC 7L1 * CMC 7M * CMC 4M6 * CMC 7MT
* CMC 3M5T * CMC sodium salt * Collowel *
Copagel PB 25 * Courlose A 590 * Courlose A 610
* Courlose A 650 * Courlose F 4 * Courlose F 8 *
Courlose F 20 * Courlose F 370 * Courlose F
1000G * Daicel 1150 * Daicel 1180 * Edifas B *
Ethoxose * Fine Gum HES * Glikocel TA * 7H3SF *
KMTs 212 * KMTs 300 * KMTs 500 * KMTs 600 *
Lovosa * Lovosa 20alk. * Lovosa TN * Lucel
(polysaccharide) * Majol PLX * Modocoll 1200 *
NaCm-cellulose salt * Nymcel S * Nymcel slc-T *
Nymcel ZSB 10 * Nymcel ZSB 16 * Polyfibron 120 *
Sanlose SN 20A * Sarcell tel * S 75M * Sodium
carboxmethylcellulose * Sodium carboxymethyl
3 - Hazards Identification
SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Not hazardous according to Directive 67/548/EC.
4 - First Aid Measures
AFTER INHALATION
If inhaled, remove to fresh air. If breathing becomes difficult,
call a physician.
AFTER SKIN CONTACT
In case of contact, immediately wash skin with soap and copious
amounts of water.
AFTER EYE CONTACT
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.
5 - Fire Fighting Measures
EXPLOSION DATA
Dust Potential: This material, like most materials in powder
form, is capable of creating a dust explosion.
CONDITIONS OF FLAMMABILITY
Static charges generated by emptying package in or near
flammable vapors may cause flash fire.
EXTINGUISHING MEDIA
Suitable: Water spray. Carbon dioxide, dry chemical powder, or
appropriate foam.
SPECIAL RISKS
Specific Hazard(s): Emits toxic fumes under fire conditions.
Explosion Hazards: May form explosive mixtures with air
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
6 - Accidental Release Measures
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Exercise appropriate precautions to minimize direct contact with
skin or eyes and prevent inhalation of dust.
METHODS FOR CLEANING UP
Sweep up, place in a bag and hold for waste disposal. Avoid
raising dust. Ventilate area and wash spill site after material
pickup is complete.
7 - Handling and Storage
HANDLING
Directions for Safe Handling: Avoid inhalation. Avoid contact
with eyes, skin, and clothing. Avoid prolonged or repeated
exposure.
STORAGE
Conditions of Storage: Keep tightly closed.
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8 - Exposure Controls / Personal Protection
ENGINEERING CONTROLS
Safety shower and eye bath. Mechanical exhaust required.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: Wear dust mask.
Hand Protection: Protective gloves.
Eye Protection: Chemical safety goggles.
9 - Physical and Chemical Properties
Appearance Color: Faintly beige
Form: Powder
Property Value At Temperature or Pressure
pH 6.5 - 8
BP/BP Range N/A
MP/MP Range 300 掳C
Flash Point N/A
Flammability N/A
Autoignition Temp 370 掳C
Oxidizing Properties N/A
Explosive Properties N/A
Explosion Limits N/A
Vapor Pressure N/A
SG/Density 1.59 g/cm3
Partition Coefficient N/A
Viscosity 500 - 2,500 Pas 4% dry substance in H2O,
25掳C
Vapor Density N/A
Saturated Vapor Conc. N/A
Evaporation Rate N/A
Bulk Density N/A
Decomposition Temp. N/A
Solvent Content N/A
Water Content <8%
Surface Tension N/A
Conductivity N/A
Miscellaneous Data N/A
Solubility N/A
10 - Stability and Reactivity
STABILITY
Stable: Stable.
Materials to Avoid: Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur
11 - Toxicological Information
RTECS NUMBER: FJ5950000
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ACUTE TOXICITY
LD50
Oral
Rat
27000 mg/kg
LC50
Inhalation
Rat
> 5,800 mg/m3
4H
LD50
Oral
Mouse
> 27000 mg/kg
LD50
Oral
Rabbit
> 27000 mg/kg
LD50
Skin
Rabbit
> 2000 mg/kg
LD50
Oral
Guinea pig
16000 mg/kg
SIGNS AND SYMPTOMS OF EXPOSURE
To the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated.
ROUTE OF EXPOSURE
Skin Contact: May cause skin irritation.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: May cause eye irritation.
Inhalation: May be harmful if inhaled. Material may be
irritating to mucous membranes and upper respiratory tract.
Ingestion: May be harmful if swallowed.
CHRONIC EXPOSURE - CARCINOGEN
Rat
Route of Application: Subcutaneous
Exposure Time: 19W
Result: Tumorigenic:Neoplastic by RTECS criteria.
Tumorigenic:Tumors at site or application.
Rat
Route of Application: Subcutaneous
Exposure Time: 19W
Result: Tumorigenic:Neoplastic by RTECS criteria.
Tumorigenic:Tumors at site or application.
Rat
Route of Application: Subcutaneous
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Exposure Time: 22W
Result: Tumorigenic:Neoplastic by RTECS criteria.
Tumorigenic:Tumors at site or application.
CHRONIC EXPOSURE - REPRODUCTIVE HAZARD
Species: Rat
Dose: 140 MG/KG
Route of Application: Oral
Exposure Time: (14D MALE)
Result: Paternal Effects: Prostate, seminal vessicle, Cowper's
gland, accessory glands.
12 - Ecological Information
No data available.
ECOTOXICOLOGICAL EFFECTS
Test Type: LC50 Fish
Species: Lepomis macrochirus (Bluegill) Onchorhynchus
mykiss (Rainbow trout)
Time: 96 h
Value: 100 - 1,000 mg/l
13 - Disposal Considerations
SUBSTANCE DISPOSAL
Contact a licensed professional waste disposal service to dispose
of this material. Dissolve or mix the material with a combustible
solvent and burn in a chemical incinerator equipped with an
afterburner and scrubber. Observe all federal, state, and local
environmental regulations.
14 - Transport Information
RID/ADR
Non-hazardous for road transport.
IMDG
Non-hazardous for sea transport.
IATA
Non-hazardous for air transport.
15 - Regulatory Information
Not hazardous according to Directive 67/548/EC.
COUNTRY SPECIFIC INFORMATION
Germany
WGK: 1
SWITZERLAND
SWISS POISON CLASS: FREI
16 - Other Information
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
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knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2005 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
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