SIGMA-ALDRICH
Material Safety Data Sheet
Date Printed: 21/FEB/2005
Date Updated: 27/JUL/2004
Version 1.2
According to 91/155/EEC
Classified as Hazardous according to the criteria of EU Annex 1 and
NOHSC.
1 - Product and Company Information
Product Name CAMPHOR, 96%
Product Number 148075
Company Sigma-Aldrich Pty, Ltd
Unit 2, 14 Anella Avenue
Castle Hill NSW 1765
Australia
Technical Phone # +61 2 9841 0555
Fax +61 2 9841 0500
Emergency Phone # +61 2 9841 0566
2 - Composition/Information on Ingredients
Product Name CAS # EC no Annex I
Index Number
(+/-)-CAMPHOR, SYNTHETIC 76-22-2 200-945-0 None
Formula C10H16O
Molecular Weight 152.24 AMU
Synonyms Bicyclo(2.2.1)heptan-2-one, 1,7,7-trimethyl- *
Bornane, 2-oxo- * 2-Bornanone * 2-Camphanone *
Camphor, synthetic (ACGIH:OSHA) * Camphor,
natural * Formosa camphor * Gum camphor * Huile
de camphre (French) * Japan camphor * 2-Kamfanon
(Czech) * Kampfer (German) *
2-Keto-1,7,7-trimethylnorcamphane * Laurel
camphor * Matricaria camphor * Norcamphor,
1,7,7-trimethyl- *
1,7,7-Trimethylbicyclo(2.2.1)-2-heptanone
3 - Hazards Identification
SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Highly flammable. Harmful if swallowed. Irritating to eyes,
respiratory system and skin.
4 - First Aid Measures
AFTER INHALATION
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
AFTER SKIN CONTACT
In case of skin contact, flush with copious amounts of water for
at least 15 minutes. Remove contaminated clothing and shoes.
Call a physician.
AFTER EYE CONTACT
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.
5 - Fire Fighting Measures
EXPLOSION DATA
Dust Potential: This material, like most materials in powder
form, is capable of creating a dust explosion.
EXTINGUISHING MEDIA
Suitable: Water spray. Carbon dioxide, dry chemical powder, or
appropriate foam.
SPECIAL RISKS
Specific Hazard(s): Flammable solid. Emits toxic fumes under
fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
6 - Accidental Release Measures
PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area. Shut off all sources of ignition. Use nonsparking
tools.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
METHODS FOR CLEANING UP
Avoid raising dust. Sweep up, place in a bag and hold for waste
disposal. Ventilate area and wash spill site after material
pickup is complete.
7 - Handling and Storage
HANDLING
Directions for Safe Handling: Avoid contact with eyes, skin, and
clothing. Avoid breathing dust. Avoid prolonged or repeated
exposure.
STORAGE
Conditions of Storage: Keep container closed. Keep away from
heat, sparks, and open flame. Store in a cool dry place.
Incompatible Materials: Avoid mixing with and storage near:
chlorates, naphthalene, p-dichlorobenzene, organic solvents,
potassium permanganate. Salts of any kind should not be added to
camphor water
8 - Exposure Controls / Personal Protection
ENGINEERING CONTROLS
Safety shower and eye bath. Use nonsparking tools. Use only in a
chemical fume hood.
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GENERAL HYGIENE MEASURES
Wash thoroughly after handling. Discard contaminated clothing and
shoes.
EXPOSURE LIMITS
Country Source Type Value
Poland NDS 12 MG/M3
Poland NDSCh 18 MG/M3
Poland NDSP -
EXPOSURE LIMITS - DENMARK
Source Type Value
OEL TWA 12 mg/m3
2 ppm
EXPOSURE LIMITS - GERMANY
Source Type Value
TRGS 900 OEL 13 mg/m3
2 ppm
EXPOSURE LIMITS - NORWAY
Source Type Value
OEL 12 mg/m3
2 ppm
EXPOSURE LIMITS - SWITZERLAND
Source Type Value
OEL OEL 13 mg/m3
2 ppm
EXPOSURE LIMITS - UNITED KINGDOM
Source Type Value
OEL OEL 13 mg/m3
2 ppm
OEL STEL 19 mg/m3
3 ppm
PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: Government approved respirator.
Hand Protection: Compatible chemical-resistant gloves.
Eye Protection: Chemical safety goggles.
9 - Physical and Chemical Properties
Appearance Physical State: Solid
Property Value At Temperature or Pressure
pH N/A
BP/BP Range 204 掳C 760 mmHg
MP/MP Range 175 - 177 掳C
Flash Point 64.4 掳C Method: closed cup
Flammability N/A
Autoignition Temp 466 掳C
Oxidizing Properties N/A
Explosive Properties N/A
Explosion Limits Lower: 0.6 %
Upper: 3.5 %
Vapor Pressure 4 mmHg 70 掳C
SG/Density 0.992 g/cm3 25 掳C
Partition Coefficient N/A
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Viscosity N/A
Vapor Density 5.2 g/l
Saturated Vapor Conc. N/A
Evaporation Rate N/A
Bulk Density N/A
Decomposition Temp. N/A
Solvent Content N/A
Water Content N/A
Surface Tension N/A
Conductivity N/A
Miscellaneous Data N/A
Solubility Solubility in Water:1 mg/ml H2O
Other Solvents: ALCOHOLS, ETHER,
CHLOROFORM, BENZENE,GLACIAL ACE
10 - Stability and Reactivity
STABILITY
Stable: Stable.
Materials to Avoid: Strong oxidizing agents, Strong reducing
agents, Chlorinated solvents.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur
11 - Toxicological Information
RTECS NUMBER: EX1225000
ACUTE TOXICITY
LDLO
Oral
Infant
70 mg/kg
Remarks: Sense Organs and Special Senses (Nose, Eye, Ear, and
Taste):Eye:Mydriasis (pupilliary dilation).
Behavioral:Convulsions or effect on seizure threshold.
Gastrointestinal:Changes in structure or function of salivary
glands.
LD50
Subcutaneous
Rat
70 MG/KG
LD50
Oral
Mouse
1310 mg/kg
LD50
Intraperitoneal
Mouse
3 GM/KG
Remarks: Behavioral:Convulsions or effect on seizure threshold.
Behavioral:Change in motor activity (specific assay).
Behavioral:Rigidity (includes catalepsy).
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SIGNS AND SYMPTOMS OF EXPOSURE
Human toxicity: ingestion or injection may cause vertigo, mental
confusion, delirium, clonic convulsions, coma, respiratory
failure, and death. Exposure can cause: Nausea, dizziness, and
headache.
ROUTE OF EXPOSURE
Skin Contact: Causes skin irritation. Causes reddening of the
skin.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: Causes eye irritation.
Inhalation: May be harmful if inhaled. Material is irritating to
mucous membranes and upper respiratory tract.
Ingestion: Harmful if swallowed.
TARGET ORGAN INFORMATION
Central nervous system. Liver. Kidneys.
CHRONIC EXPOSURE - CARCINOGEN
Result: This product is or contains a component that is not
classifiable as to its carcinogenicity based on its IARC, ACGIH,
NTP, or EPA classification.
CHRONIC EXPOSURE - MUTAGEN
Mouse
80 MG/KG
Intraperitoneal
Sister chromatid exchange
12 - Ecological Information
No data available.
13 - Disposal Considerations
SUBSTANCE DISPOSAL
Contact a licensed professional waste disposal service to dispose
of this material. Burn in a chemical incinerator equipped with an
afterburner and scrubber but exert extra care in igniting as this
material is highly flammable. Observe all federal, state, and
local environmental regulations.
14 - Transport Information
RID/ADR
UN#: 2717
Class: 4.1
PG: III
Proper Shipping Name: Camphor
IMDG
UN#: 2717
Class: 4.1
PG: III
Proper Shipping Name: Camphor
Marine Pollutant: No
Severe Marine Pollutant: No
IATA
UN#: 2717
Class: 4.1
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PG: III
Proper Shipping Name: Camphor
Inhalation Packing Group I: No
15 - Regulatory Information
CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
INDICATION OF DANGER: F Xn
Highly Flammable. Harmful.
R-PHRASES: 11 22 36/37/38
Highly flammable. Harmful if swallowed. Irritating to eyes,
respiratory system and skin.
S-PHRASES: 16 26
Keep away from sources of ignition - no smoking. In case of
contact with eyes, rinse immediately with plenty of water and
seek medical advice.
COUNTRY SPECIFIC INFORMATION
Germany
WGK: 1
SWITZERLAND
SWISS POISON CLASS: 3
16 - Other Information
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2005 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
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