SIGMA-ALDRICH
Material Safety Data Sheet
Date Printed: 21/FEB/2005
Date Updated: 14/MAR/2004
Version 1.3
According to 91/155/EEC
Classified as Hazardous according to the criteria of EU Annex 1 and
NOHSC.
1 - Product and Company Information
Product Name CALCIUM PHOSPHIDE
Product Number 400971
Company Sigma-Aldrich Pty, Ltd
Unit 2, 14 Anella Avenue
Castle Hill NSW 1765
Australia
Technical Phone # +61 2 9841 0555
Fax +61 2 9841 0500
Emergency Phone # +61 2 9841 0566
2 - Composition/Information on Ingredients
Product Name CAS # EC no Annex I
Index Number
CALCIUM PHOSPHIDE 1305-99-3 215-142-0 015-003-00-2
Formula Ca3P2
Molecular Weight 182.2 AMU
3 - Hazards Identification
SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Contact with water liberates toxic, extremely flammable gas. Very
toxic if swallowed. Very toxic to aquatic organisms.
4 - First Aid Measures
AFTER INHALATION
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
AFTER EYE CONTACT
Assure adequate flushing of the eyes by separating the eyelids
with fingers.
5 - Fire Fighting Measures
CONDITIONS OF FLAMMABILITY
Reacts with water to liberate flammable and/or explosive gas.
EXTINGUISHING MEDIA
Suitable: Carbon dioxide.
Unsuitable: Do not use water.
SPECIAL RISKS
Specific Hazard(s): Emits toxic fumes under fire conditions.
Flammable solid.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
6 - Accidental Release Measures
PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area. Shut off all sources of ignition.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
METHODS FOR CLEANING UP
Cover with dry-lime, sand, or soda ash. Place in covered
containers using non-sparking tools and transport outdoors.
7 - Handling and Storage
HANDLING
Directions for Safe Handling: Do not breathe dust. Do not get in
eyes, on skin, on clothing. Avoid prolonged or repeated exposure.
STORAGE
Conditions of Storage: Keep tightly closed. Keep away from heat,
sparks, and open flame. Store in a cool dry place. Handle and
store under nitrogen.
Incompatible Materials: Do not allow contact with water Avoid
contact with acid.
8 - Exposure Controls / Personal Protection
ENGINEERING CONTROLS
Use only in a chemical fume hood. Safety shower and eye bath. Use
nonsparking tools.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling.
PERSONAL PROTECTIVE EQUIPMENT
Special Protective Measures: Wear appropriate government approved
respirator, chemical-resistant gloves, safety goggles, other
protective clothing.
9 - Physical and Chemical Properties
Appearance N/A
Property Value At Temperature or Pressure
pH N/A
BP/BP Range N/A
MP/MP Range N/A
Flash Point N/A
Flammability N/A
Autoignition Temp N/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion Limits N/A
Vapor Pressure N/A
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SG/Density N/A
Partition Coefficient N/A
Viscosity N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
Evaporation Rate N/A
Bulk Density N/A
Decomposition Temp. N/A
Solvent Content N/A
Water Content N/A
Surface Tension N/A
Conductivity N/A
Miscellaneous Data N/A
Solubility N/A
10 - Stability and Reactivity
STABILITY
Materials to Avoid: Forms explosive mixtures with:, Oxidizing
agents, Chlorine, Oxygen, Sulfur.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Phosphine, Phosphorous oxides,
Calcium hydroxide.
11 - Toxicological Information
SIGNS AND SYMPTOMS OF EXPOSURE
Symptoms of exposure may include burning sensation, coughing,
wheezing, laryngitis, shortness of breath, headache, nausea, and
vomiting. Exposure can cause: Sweating. Ataxia. Convulsions.
Stomach pains, vomiting, diarrhea.
ROUTE OF EXPOSURE
Multiple Routes: May be fatal if inhaled, swallowed, or absorbed
through skin. High concentrations are extremely destructive to
tissues of the mucous membranes and upper respiratory tract,
eyes, and skin.
12 - Ecological Information
No data available.
13 - Disposal Considerations
14 - Transport Information
RID/ADR
UN#: 1360
Class: 4.3
PG: I
Proper Shipping Name: Calcium phosphide
IMDG
UN#: 1360
Class: 4.3
PG: I
Subrisk: 6.1
Proper Shipping Name: Calcium phosphide
Marine Pollutant: No
Severe Marine Pollutant: No
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IATA
UN#: 1360
Class: 4.3
PG: I
Subrisk: 6.1
Proper Shipping Name: Calcium phosphide
Inhalation Packing Group I: No
15 - Regulatory Information
CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
ANNEX I INDEX NUMBER: 015-003-00-2
INDICATION OF DANGER: F T+ N
Highly Flammable. Very toxic. Dangerous for the environment.
R-PHRASES: 15/29 28 50
Contact with water liberates toxic, extremely flammable gas.
Very toxic if swallowed. Very toxic to aquatic organisms.
S-PHRASES: 22 43 45 61
Do not breathe dust. In case of fire, use special powder for
metal fire. Never use water. In case of accident or if you feel
unwell, seek medical advice immediately (show the label where
possible). Avoid release to the environment. Refer to special
instructions/safety data sheets.
SWITZERLAND
SWISS POISON CLASS: 1
16 - Other Information
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2005 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
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