MATERIAL SAFETY DATA SHEET
Effective Date: 11 November 2002
Chemical Product and Company Identification:
FPPF Chemical Co., Inc. 117 West Tupper Street; Buffalo, NY 14201-2193
(800) 735-3773
Emergency Phone: Chemtrec ?(800) 424-9300
Product Trade Name: Lustre Brite
Product Codes: 00376, 00377, 00378
Synonyms: Acid Cleaner, Stainless Steel Cleaner
Composition Data:
Ingredients CAS No. Percent Hazardous
Phosphoric Acid 7664-38-2 74 ?95% Yes
Water 7732-18-5 5 - 26% No
2-Butoxyethanol 111-76-2 8 ?20% Yes
Glycolic Acid 79-14-1 8 ?20% Yes
Sodium alkyl ether sulfate Mixture 2 - 8% Yes
Alkylary sulphonic acid 27176-93-9 2 - 8% Yes
Hazards Identification
Emergency Overview:
Danger! Corrosive. Causes Severe Irritation and Burns to Every Area of Contact.
Harmful if swallowed or inhaled.
Potential Health Effects:
Inhalation: Inhalation is not an expected hazard unless misted or heated to high temperatures.
Mist or vapor inhalation can cause irritation to the nose, throat, and upper respiratory tract.
Severe exposures can lead to a chemical pneumonitis.
Ingestion: Corrosive. May cause sore throat, abdominal pain, nausea, and severe burns of the
mouth, throat, and stomach. Severe exposures can lead to shock, circulatory collapse, and
death.
Skin Contact: Corrosive. May cause redness, pain, and severe skin burns.
Eye Contact: Corrosive. May cause redness, pain, blurred vision, eye burns, and permanent
eye damage.
Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye
problems or impaired respiratory function may be more susceptible to the effect of the
substance.
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FIRST AID MEASURES:
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Call a physician immediately.
Ingestion: If swallowed, DO NOT INDUCE VOMITING! Give large quantities of water.
Never give anything by mouth to an unconscious person. Get medical attention immediately.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Call a physician, immediately. Wash clothing before
reuse.
Eye Contact: Immediately flush eyes with gentle but large stream of water for at least 15
minutes, lifting lower and upper eyelids occasionally. Call a physician immediately.
FIRE FIGHTING MEASURES:
Fire: Not considered to be a fire hazard. Contact with most metals causes formation of
flammable and explosive hydrogen gas.
Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Water
spray may be used to keep fire exposed containers cool. If water is used, use in abundance to
control heat and acid build-up.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing
apparatus will full facepiece operated in the pressure demand or other positive pressure mode.
ACCIDENTAL RELEASE MEASURES:
Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in
Section labeled Exposure Controls/Personal Protection. Isolate hazard area. Keep
unnecessary and unprotected personnel from entering. Contain and recover liquid when
possible. Neutralize with alkaline material (soda, ash, lime), then absorb with an inert material
(e.g. vermiculite, dry sand, earth), and place in a chemical waste container. Do not use
combustible materials, such as saw dust. Do not flush to sewer! US Regulations (CERCLA)
require reporting spills and releases to soil, water and air in excess of reportable quantities. The
toll free number for the US Coast Guard National Response Center is (800) 424-8802.
HANDLING AND STORAGE:
Keep in a tightly closed container. Protect from physical damage. Store in a cool, dry, ventilated
area away from sources of heat, moisture, incompatibilities, and direct sunlight. Corrosive to
mild steel. Store in rubber lined or 316 stainless steel designed for phosphoric acid. Do not
wash out container and use it for other purposes. When diluting, the acid should always be
added slowly to water and in small amounts. Never use hot water and never add water to the
acid.
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FPPF Chemical Company, Inc. April 10, 2002
HANDLING AND STORAGE (CON'T).
Do not wash out container and use it for other purposes. When diluting, the acid should
always be added slowly to water and in small amounts. Never use hot water and never add
water to the acid. Water added to acid can cause uncontrolled boiling and splashing. Protect
from freezing. Containers of this material may be hazardous when empty since they retain
product residues (vapors, liquid); observe all warnings and precautions listed for the product.
EXPOSURE CONTROLS/PERSONAL PROTECTION:
Airborne Exposure Limits:
-OSHA Permissible Exposure Limit (PEL): 1 mg/m3 (TWA)
-ACGIH Threshold Limit Value (TLV): 1 mg/m3 (TWA), 3 mg/m3 (STEL)
Ventilation System: A system of local and/or general exhaust is recommended to keep
employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally
preferred because it can control the emissions of the contaminant at its source, preventing
dispersion of it into the general work area. Please refer to the ACGIH document, Industrial
Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
If the exposure limit is exceeded, a full facepiece respirator with high efficiency dust/mist filter
may be worn up to 50 times the exposure limit or the maximum use concentration specified by
the appropriate regulatory agency or respirator supplier, whichever is lowest. For emergencies or
instances where the exposure levels are not known, use a full-facepiece positive-pressure, air
supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-
deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron
or coveralls, as appropriate to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is
possible. Maintain eye wash fountain and quick-drench facilities in work area.
Physical & Chemical Properties:
Appearance: Clear, green syrupy liquid.
Odor: Acidic odor.
Solubility: Miscible in all proportions in water
1.15-1.33 @ 250C
Specific Gravity:
pH: 1.5 (0.1 N aqueous solution)
% Volatilize by volume @ 210C (700F): 100%
Boiling Point: Not determined
Melting Point: Not determined
Vapor Density: 3.4-phosphoric acid, 4.07 2-Butoxyethanol
0.03-0.08 @ 200C (680F)
Vapor Pressure (mm Hg):
Evaporation Rate (BuAc=1): No information found
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STABILITY AND REACTIVITY:
Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Phosphorus oxides, Carbon dioxide and carbon
monoxide may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Liberates explosive hydrogen gas when reacting with chlorides and stainless
steel. Can react violently with sodium tetrhydroborate. Exothermic reactions with aldehydes,
amines, amides, alcohols and glycols, azo-compounds,carbamates, esters, caustics, phenols and
cresols, ketones, organophosphates, epoxides, explosives, combustible materials, unsaturated
halides, and organic peroxides, phosphoric acid forms flammable gases with sulfides,
mercaptans, cyanides and aldehydes. It also forms toxic fumes with cyanides, sulfide, fluorides,
organic peroxides, and halogenated organics. Mixtures with nitromethane are explosive.
Conditions to Avoid: Incompatibles.
Ecological Information:
Environmental Fate: When released into the soil, this material may leach into groundwater.
When released to water, acidity may be readily reduced by natural water hardness minerals. The
phosphate, however may persist indefinitely.
Environmental Toxicity: No information found.
DISPOSAL CONSIDERATIONS:
Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and
sent to a RCRA approved incinerator or disposed in a RCRA approved waste facility. Processing,
use or contamination of this product may change the waste management options. State and
local disposal regulations may differ from federal disposal regulations. Dispose of container and
unused contents in accordance with federal, state and local requirements.
TRANSPORT INFORMATION:
Domestic (Land, D.O.T.)
Proper shipping name: Corrosive liquids, n.o.s. (phosphoric acid, glycolic acid)
Hazard Class: 8
UN/NA: UN3265
Packing Group: II
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REGULATORY INFORMATION:
----------Chemical Inventory Status ?Part 1/------------------------------------
Ingredient TSCA EC Japan Australia
Phosphoric Acid(7664-38-2) Yes Yes Yes Yes
Water (7732-18-5) Yes Yes Yes Yes
Glycolic Acid (79-14-1) Yes Yes Yes Yes
2-Butoxyethanol (111-76-2) Yes Yes Yes Yes
------------Chemical Inventory Status ?Part 2/-----------------------------------
SARA 302 - ----------SARA 313 ----------
Ingredient Korea DSL NDSL Phil.
Phosphoric Acid (7664-38-2) Yes Yes Yes Yes
Water (7732-18-5) Yes Yes Yes Yes
Glycolic Acid (79-14-1) Yes Yes Yes Yes
2-Butoxyethanol (111-76-2) Yes Yes Yes Yes
------------Federal, State & International Regulations ?Part 1---------
SARA 302 - ----------SARA 313 -----------
Ingredient RQ TPQ List Chemical Catg.
Phosphoric Acid (7664-38-2) No No No No
Water (7732-18-5 No No No No
Glycolic Acid (79-14-1) No No No No
2-Butoxyethanol (111-76-2) No No No No
------------Federal, State & International Regulations ?Part 2 ------------
-RCRA- -TSCA-
Ingredient CERCLA 261.33 8(d)
Phosphoric Acid (7664-38-2) 5000 No No
Water (7732-18-5) No No No
Glycolic Acid (79-14-1) No No No
2-Butoxyethanol (111-76-2) No No No
Chemical Weapons Convention: No TSCA 12 (b): No CDTA: No
SARA 311/312: Acute: Yes Chronic: No Fire: No Pressure: No
Reactivity: No (Pure / Liquid)
OTHER INFORMATION:
NFPA Ratings: Health: 3; Flammability: 0; Reactivity: 0
Label Hazard Warning: DANGER! CORROSIVE. CAUSES SEVERE IRRITATION AND BURNS TO
EVERY AREA OF CONTACT. HARMFUL IF SWALLOWED OR INHALED.
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FPPF Chemical Company, Inc. April 10, 2002
Label Precautions:
Do not get in eyes, on skin, or on clothing
Keep Container closed.
Use only with adequate ventilation.
Do not breathe vapor or mist.
Wash thoroughly after handling.
Label First Aid:
In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes.
April 2008
Revision date:
Changes: Added product codes
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