MATERIAL SAFETY DATA SHEET
ICE MACHINE CLEANER M.I.I.
MSDS ID: MI0895
Revised: 01-29-2009
Replaces: 04-26-2006
1. PRODUCT AND COMPANY IDENTIFICATION
Product Name: ICE MACHINE CLEANER M.I.I.
MSDS ID: MI0895
Synonyms: O-99725
CAS Number: MIXTURE
Chemical Family: Acid Detergent
Formula: Proprietary Information
DISTRIBUTED BY: EMERGENCY RESPONSE NUMBERS:
Manitowoc Ice, Inc. 24 Hour Emergency #: (920) 682-0161
2110 South 26th St. CHEMTREC Emergency #: (800) 424-9300
Manitowoc, WI 54220
(920) 682-0161
www.manitowocice.com
MANUFACTURED BY: HYDRITE CHEMICAL CO.
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW: DANGER! CORROSIVE. Causes severe burns to eyes, skin, and respiratory tract.
Harmful or fatal if swallowed. Harmful if inhaled. Reacts with most metals to form explosive/flammable hydrogen
gas.
Physical State: Liquid.
Color: Clear. Green.
Odor: No odor.
POTENTIAL HEALTH EFFECTS
Routes Of Exposure: Eyes. Skin. Inhalation. Ingestion.
Target Organs: Eyes. Skin. Respiratory System. Mucous Membranes. No data.
Eye Contact: CORROSIVE-Causes severe irritation and burns. May cause: permanent eye damage.
blindness. redness. pain. swelling. tearing. conjunctivitis. impaired vision. burns. ulcerations. corneal damage.
irritation.
Skin Contact: CORROSIVE-Causes severe irritation and burns. Contact may cause: permanent skin damage.
Contact may not produce an immediate burning sensation, delaying awareness that contact has occurred.
swelling. discomfort. redness. itching. pain. burns. allergic reaction in some individuals. Prolonged and repeated
contact with skin can cause defatting and drying of the skin which may result in skin irritation and dermatitis.
irritation.
Skin Absorption: No absorption hazard expected under normal use. No more than slightly toxic based on
toxicity studies. Prolonged skin contact is unlikely to result in absorption of harmful amounts.
Inhalation: May be corrosive to the respiratory tract. Severe irritation and burns may result. Vapors or mists
may irritate: respiratory tract. Serious cases of inhalation may cause: respiratory problems and late pulmonary
edema. May irritate: mucous membranes. nose. throat. lungs. May cause: coughing. sneezing. shortness of
Page: 1 of 7
MATERIAL SAFETY DATA SHEET
ICE MACHINE CLEANER M.I.I.
MSDS ID: MI0895
Revised: 01-29-2009
Replaces: 04-26-2006
breath. sore throat. chest discomfort. pain. allergic reaction in some individuals. Inhalation of high concentrations
may cause: permanent damage.
Ingestion: CORROSIVE-Causes severe irritation and burns. May irritate or burn: mouth. throat. stomach. May
cause: nausea. vomiting. abdominal discomfort. abdominal pain. burning sensation. Severe exposures may
cause: shock. circulatory collapse. death. gastrointestinal irritation. diarrhea. gastrointestinal disturbances. burns.
hypocalcemia (possible life-threatening lowering of serum calcium). Erosion of teeth is possible. No data
available. Do not swallow.
Medical Conditions Aggravated By Exposure To Product: Eye disorders. Skin disorders. Impaired
respiratory function. Respiratory system disorders. None known.
Other: In animals, effects have been reported on the following organs: lungs.
Cancer Information: This product does not contain 0.1% or more of the known or potential carcinogens listed in
NTP, IARC, or OSHA.
Potential Environmental Effects: See Section 12.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Component CAS Number OSHA Hazard % by Wt.
Phosphoric Acid 7664-38-2 YES < 40 %
Citric Acid 77-92-9 YES 0-5%
4. FIRST-AID MEASURES
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes while holding eyelids open. Tilt
head to avoid contaminating unaffected eye. Get immediate medical attention. Remove contact lens if easy to
do. Remove contact lenses if worn.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated
clothing and shoes. Get medical attention immediately. Do not reuse clothing and shoes until cleaned. Do not
apply oils or ointments unless ordered by the physician. Wash with soap and water. Flush skin with water for at
least 15 minutes.
Inhalation: Remove to fresh air. If breathing is difficult, administer oxygen. If not breathing, give artificial
respiration, preferably mouth-to-mouth. GET MEDICAL ATTENTION IMMEDIATELY. Keep at rest.
Ingestion: If fully conscious, drink a quart of water. DO NOT induce vomiting. CALL A PHYSICIAN
IMMEDIATELY. If unconscious or in convulsions, take immediately to a hospital or a physician. NEVER induce
vomiting or give anything by mouth to an unconscious victim. If vomiting occurs spontaneously, keep head below
hips to prevent aspiration of liquid into the lungs. Give large amounts of water to drink.
Note to Physicians: Treatment is symptomatic and supportive.
5. FIRE FIGHTING MEASURES
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MATERIAL SAFETY DATA SHEET
ICE MACHINE CLEANER M.I.I.
MSDS ID: MI0895
Revised: 01-29-2009
Replaces: 04-26-2006
Extinguishing Media: Not flammable or combustible. For fires in area use appropriate media. For example:
Water spray. Dry chemical. Carbon dioxide. Foam. Alcohol foam. Water. DO NOT USE:
Fire Fighting Methods: Evacuate area of unprotected personnel. Wear protective clothing including NIOSH-
approved self-contained breathing apparatus. Remain upwind of fire to avoid hazardous vapors and
decomposition products. Use water spray to cool fire-exposed containers. Product generates heat upon addition
of water, with possible spattering. Run-off from fire control may cause pollution. Move containers from fire area if
possible without hazard.
Fire And Explosion Hazards: None known. This product may react with certain metals to produce flammable
Hydrogen Gas.
Hazardous Combustion Products: Thermal decomposition may release: Phosphorous oxides. Phosphine.
Toxic vapors. Carbon dioxide. Carbon monoxide. Dense smoke. No data available.
6. ACCIDENTAL RELEASE MEASURES
Spill Clean-Up Procedures: CORROSIVE MATERIAL. Evacuate unprotected personnel from area. Maintain
adequate ventilation. Follow personal protective equipment recommendations found in Section 8. Never exceed
any occupational exposure limit. Contain spill, place into drums for proper disposal. Soak up residue with inert
absorbent material. Place in non-leaking containers for immediate disposal. Flush remaining area with water and
neutralize with Soda Ash, Lime or Limestone and dispose of properly. Adequate ventilation is required if soda
ash is used, because of the consequent release of carbon dioxide gas. Avoid direct discharge to sewers and
surface waters. Notify authorities if entry occurs. Flush remaining area with water and neutralize with Soda Ash
or Lime and dispose of properly.
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes, skin, and clothing. Use with adequate ventilation. Do not swallow. Avoid
breathing vapors, mists, or dust. Do not eat, drink, or smoke in work area. Wash thoroughly after handling.
CORROSIVE MATERIAL.
Storage: CORROSIVE MATERIAL. Store in a cool, well ventilated area, out of direct sunlight. Store in a dry
location away from heat. Keep away from incompatible materials. Keep containers tightly closed. Do not store in
unlabeled or mislabeled containers. Do not freeze. May react with certain metals to produce flammable
hydrogen gas. Protect against physical damage. Citric acid can release explosive hydrogen gas if in contact with
reactive metals (iron, zinc, aluminum). Keep containers tightly closed.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines:
Component OSHA PEL OSHA STEL/C ACGIH TWA ACGIH STEL/C
Phosphoric Acid 1 mg/m3 Not Estab. 1 mg/m3 3 mg/m3
1 mg/m3+ 3 mg/m3+
Citric Acid Not Estab. Not Estab. Not Estab. Not Estab.
Note: + Vacated 1989 OSHA PEL(s).
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MATERIAL SAFETY DATA SHEET
ICE MACHINE CLEANER M.I.I.
MSDS ID: MI0895
Revised: 01-29-2009
Replaces: 04-26-2006
Engineering Controls: General room ventilation and local exhaust are required. Maintain adequate ventilation.
Do not use in closed or confined spaces. Avoid creating dust or mist. Keep levels below exposure limits. To
determine exposure levels, monitoring should be performed regularly. General room ventilation and/or local
exhaust are required.
Eye/Face Protection: Wear chemical safety goggles and a full face shield while handling this product. Do not
wear contact lenses. Wear additional eye protection such as a face shield when the possibility exists for eye
contact with splashing or spraying liquid, or airborne material.
Skin Protection: Prevent contact with this product. Wear gloves and protective clothing depending on condition
of use. Protective gloves: Acid-proof. Gauntlet-type. Rubber. Neoprene. Nitrile. Plastic. Chemical-resistant.
Respiratory Protection: Respiratory protection must be worn if ventilation does not eliminate symptoms or keep
levels below recommended exposure limits. If exposure limits are exceeded, wear: NIOSH-Approved respirator.
Acid gas cartridge. DO NOT exceed limits established by the respirator manufacturer. All respiratory protection
programs must comply with OSHA 29 CFR 1910.134 and ANSI Z88.2 requirements and must be followed
whenever workplace conditions require a respirator's use. If dust or mist is present, wear: NIOSH-Approved
respirator for dusts and mists. NIOSH-Approved self-contained breathing apparatus.
Other Protective Equipment: Eye-wash station. Safety shower. Rubber apron. Chemical safety shoes. Rubber
boots. Protective clothing.
General Hygiene Conditions: Wash with soap and water before meal times and at the end of each work shift.
Good manufacturing practices require gross amounts of any chemical be removed from skin as soon as
practical, especially before eating or smoking.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid.
Color: Clear. Green.
Odor: No odor.
Boiling Point (deg. F): N.D.
Freezing Point (deg. F): N.D.
Melting Point (deg. F): N.D.
Vapor Pressure (mm Hg): N.D.
Vapor Density (air=1): N.D.
Solubility in Water: Complete
pH: < 2 (as is)
Specific Gravity: 1.22-1.24 @25C
% Volatile (wt%): N.D.
Evaporation Rate (nBuAc = 1): N.D.
VOC (wt%): N.D.
VOC (lbs/gal): N.D.
Viscosity: N.D.
Flash Point: N.A.
Flash Point Method:
Lower Explosion Limit: N.A.
Upper Explosion Limit: N.A.
Autoignition Temperature: No Data
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MATERIAL SAFETY DATA SHEET
ICE MACHINE CLEANER M.I.I.
MSDS ID: MI0895
Revised: 01-29-2009
Replaces: 04-26-2006
10. STABILITY AND REACTIVITY
Stability: Stable under normal conditions.
Conditions To Avoid: Contact with water may cause violent reaction with evolution of heat. To dilute: Add
product slowly to lukewarm water; not water to product. Avoid high temperatures. Avoid mist formation. Avoid
elevated temperatures.
Incompatible Materials: Metals. Strong oxidizing agents. Strong reducing agents. Sulfides. Sulfites. Bases.
Fluorine. Sulfur trioxide. Phosphorous pentoxide. Sodium tetrahydroborate. Aldehydes. Amines. Amides.
Alcohols. Azo-compounds. Carbamates. Esters. Caustics. Phenols. Cresols. Ketones. Organophosphates.
Epoxides. Explosives. Combustible materials. Unsaturated halides. Organic peroxides. Mercaptans. Cyanides.
Nitromethane. Glycols. Fluorides. Halogenated organics. Alkalies. Strong bases. Carbonates. Acetates.
Potassium Tartrate. Metal Nitrates. Bicarbonates. Reducing agents. Alkali metals. Aluminum. Magnesium.
Corrosive effect on: Copper, aluminum, zinc and their alloys.
Hazardous Decomposition Products: Thermal decomposition may release: Phosphorous oxides. Phosphine.
Reactions with other materials may liberate toxic and/or explosive gases. Carbon dioxide. Carbon monoxide.
Smoke. No data available.
Possibility of Hazardous Reactions: Hazardous polymerization will not occur under normal conditions. May
react with certain metals to produce flammable hydrogen gas. Mixing with strong bases can cause high heat of
reaction and generate steam. Reacts with chlorides + stainless steel to form explosive hydrogen gas. Phosphoric
acid forms flammable gases with sulfides, mercaptans, cyanides and aldehydes. Phosphoric acid forms toxic
fumes with cyanides, sulfides, fluorides, organic peroxides, and halogenated organics. Phosphoric acid mixtures
with nitromethane are explosive.
11. TOXICOLOGICAL INFORMATION
LD50 Oral: No Data
LD50 Skin: No Data
LC50 Inhalation: No Data
PHOSPHORIC ACID:
Phosphoric acid has a low vapor pressure at room temperature and is not expected to present a significant
inhalation hazard under ambient conditions. Phosphoric acid can, however, be irritating to the respiratory tract if
inhaled as a mist or if the material is vaporized.
12. ECOLOGICAL INFORMATION
Ecotoxicological Information: No data available. CITRIC ACID:
Acute Aquatic Effects:
96-hour LC50 (Fathead Minnow): > 1,000 mg/L
96-hour LC50 (Water Flea): > 1,000 mg/L
96-hour LC50 (Goldfish): 440 - 706 mg/l
48-hour LC50 (Golden orfe minnow): 760 mg/L.
EC0 (bacteria): > 10,000 mg/L
Chemical Fate Information: No data available.
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MATERIAL SAFETY DATA SHEET
ICE MACHINE CLEANER M.I.I.
MSDS ID: MI0895
Revised: 01-29-2009
Replaces: 04-26-2006
13. DISPOSAL CONSIDERATIONS
Hazardous Waste Number: D002
Disposal Method: Dispose of in a permitted hazardous waste management facility following all local, state and
federal regulations. Since emptied containers retain product residue, follow label warnings even after container is
emptied. DO NOT pressurize, cut, weld, solder, drill, grind or expose empty containers to heat, flame, sparks or
other sources of ignition. Disposal methods identified are for the product as sold. For proper disposal of used
material, an assessment must be completed to determine the proper and permissible waste management options
permitted under applicable rules, regulations and/or laws governing your location. Dispose of in a liscensed facility.
14. TRANSPORTATION INFORMATION
DOT (Department of Transportation):
Proper Shipping Name: Corrosive Liquid, N.O.S. (Contains Phosphoric Acid, Citric Acid)
Hazard Class: 8
Identification Number: UN1760
Packing Group: III
Label Required: CORROSIVE
Reportable Quantity (RQ): 5000# (Phosphoric Acid)
Note: The listed Transportation Classification does not address regulatory variations due to changes in
package size, mode of shipment or other regulatory descriptors. In the United States, it may be possible
to reclassify this material as a Consumer Commodity ORM-D based on 49 CFR 173.154 (b)(c).
15. REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS
TSCA Inventory Status: All components of this product are on the TSCA Inventory or are exempt from TSCA
Inventory requirements.
This product or all components of this product are listed on the EPA/TSCA Inventory of Chemical Substances.
SARA Title III Section 311/312 Category:
Immediate (Acute) Health Hazard: Yes
Delayed (Chronic) Health Hazard: No
Fire Hazard: No
Sudden Release Of Pressure Hazard: No
Reactive Hazard: No
SARA Section 302/304/313/HAP:
Component CERCLA RQ SARA RQ SARA TPQ SARA 313 U.S. HAP
Phosphoric Acid 5000 N.A. N.A. NO NO
Citric Acid N.A. N.A. N.A. NO NO
U.S. STATE REGULATIONS
California - The following components are listed under Proposition 65:
Ethylene Oxide (Trace Amounts)
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MATERIAL SAFETY DATA SHEET
ICE MACHINE CLEANER M.I.I.
MSDS ID: MI0895
Revised: 01-29-2009
Replaces: 04-26-2006
Propylene Oxide (Trace Amounts)
1,4-dioxane (Trace Amounts)
Wisconsin - The following components are listed as a Wisconsin HAP:
Phosphoric acid.
16. ADDITIONAL INFORMATION
Hydrite Rating System
Health: 3
Flammability: 0
Reactivity: 0
* = Chronic Health Hazard
NFPA Rating System
Health: 3
Flammability: 0
Reactivity: 0
Special Hazard: None
MSDS Abbreviations
N.A. = Not Applicable
N.D. = Not Determined
HAP = Hazardous Air Pollutant
VOC = Volatile Organic Compound
C = Ceiling Limit
N.E./Not Estab. = Not Established
MSDS Prepared by: JAK
Reason for Revision: Change made in Section 14.
The data in this Material Safety Data Sheet relates to the specific material designated and does not relate
to its use in combination with any other material or process. The data contained is believed to be correct.
However, since conditions of use are outside our control it should not be taken as warranty or
representation for which HYDRITE CHEMICAL CO. assumes legal responsibility. This information is
provided solely for your consideration, investigation, and verification.
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