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7664-38-2 7646-85-7

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GOLDEN HARVEST PLUS 5-18-2
MATERIAL SAFETY DATA SHEET (10/16/96)
SECTION I PRODUCT IDENTIFICATION

NFPA HAZARD RATINGS

HEALTH HAZARD: NONE FIRE HAZARD non-combustible REACTIVITY NONE

SARA/TITLE III HAZARD CATEGORIES (See Section IX)

Immediate (ACUTE) Health: none Reactive Hazard: none
Delayed (Chronic) Health: none Sudden Release of Pressure: not applicable
Fire Hazard: none

Company Name: STOLLER ENTERPRISES, INC.
Address: 4001 W. Sam Houston Pkway E., Suite 100, Houston Texas, 77043
CANUTEC 613-996-6666
Emergency Phone Number:
Phone Number for Information: 713-461-1493
Chemical Family: Organic Salt Solution
Chemical Name & Synonyms: N/A Mixture
Formula: See SECTION II COMPOSITION/INGREDIENTS INFORMATION
Trade name & Synonyms: GOLDEN HARVEST PLUS 5-18-2


SECTION II COMPOSITION/INGREDIENTS INFORMATION

INGREDIENTS: CAS # Approx. % TLV

Phosphoric acid 7664-38-2 30 1.0 mg/m3 Vapour/8 hrs
Zinc Chloride 7646-85-7 3 1.0 mg/m3 as Zinc Chloride


SECTION III PHYSICAL AND CHEMICAL CHARACTERISTICS
BOILING POINT: 2120 F VAPOR PRESSURE: Similar to water
MELTING POINT:N/A VAPOR DENSITY (air = 1): Similar to water
SPECIFIC GRAVITY: 1.46 REACTIVITY IN WATER: N/A
SOLUBILITY IN WATER: yes soluble EVAPORATION RATE : < water
APPEARANCE AND ODOR: thich dark brown liquid, sweet odor,
OTHER:
GOLDEN HARVEST PLUS - (10/16/96)
SECTION IV FIRE AND EXPLOSION DATA
FLASH POINT: N/A
FLAMMABLE LIMITS: N/A LEL: not established UEL: not established
EXTINGUISHER MEDIA: Water, CO2, or Dry Chemicals
SPECIAL FIRE FIGHTING PROCEDURES: Wear self contained breathing apparatus

UNUSUAL FIRE AND EXPLOSION HAZARDS: Toxic fumed may be generated at elevated temperatures

SECTION V PHYSICAL HAZARDS (REACTIVITY DATA)

STABILITY: Stable
CONDITIONS TO AVOID:
INCOMPATIBILITY, MATERIALS TO AVOID:
HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of sulfur, nitrogen, phosphorus
HAZARDOUS POLYMERIZATION: None

SECTION VI HEALTH HAZARDS

A EXPOSURE LIMITS
OSHA Permissible Exposure Limit (PEL): NOT ESTABLISHED
1.0 mg/m3 Vapour/8 hrs for Phosporic acid
Threshold Limit Value (TLV):
1.0 mg/m3 for Zinc Chloride

B CARCINOGEN OR POTENTIAL CARCINOGEN
- NTP: NO
- IARC: NO
- OSHA: NO

C EMERGENCY FIRST AID PROCEDURES:

EYES: Flush with water 15 minutes forcibly holding eyelids apart to ensure complete irrigation of
alland lid tissue. GET MEDICAL ATTENTION
SKIN: Wash with soap and water. Wash clothing before reuse.
IF IRRITATION OCCURS GET MEDICAL ATTENTION
INHALATION: If symptoms develop, get person out of contaminated are to fresh air
INGESTION: NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON.
Have patient drink
several glasses of water then induce vomiting by having patient tickle back of throat with
finger. Keep airwayts clear.
GET MEDICAL
ATTENTION IMMEDIATELY


D ANIMAL TOXICITY DATA
LD50: Zinc Chloride LD50 9oral/rat) 350 mg/kg
Phosphoric acid LD50 (oral/rat) 1.53 mg/kg
GOLDEN HARVEST PLUS - (10/16/96)
SECTION VII SPECIAL PRECAUTIONS & SPILL/LEAK PROCEDURES

HANDLING AND STORAGE: Keep containers closed and dry. Wash hands thoroughly after using.

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED: Collect and contain for salvage or disposal. Absorb
waste on inert media and dispose of as solid waste.

WASTE DISPOSAL METHODS: Landfill in compliance with all federal, provincial and local laws concerning health
and environment.


SECTION VIII - SPECIAL PROTECTION / CONTROL MEASURES

RESPIRATORY PROTECTION: As require by conditions. Use OSHA or NIOSH approved respirator if required.
VENTILATION: General ventilation is usally adequate.
LOCAL EXHAUST: Provide local exhaust ventilation for safe comfortable working conditions..
SPECIAL VENTILATION: not applicable
PROTECTIVE GLOVES: Wear protective gloves as good hygiene dictates.
EYE PROTECTION: Use safety glasses.
OTHER SPECIAL CLOTHING/EQUIPMENT: Eye wash bath and washing facilities should available.
WORK/HYGIENIC PRACTICES: Do not smoke when handling chemicals.

SECTION IX ENVIRONMENTAL EFFECTS DATA

This product has not been tested for environmental effects. If discharged into the marine environment it may be toxic to
fish or other marine organisms, and due to its nutrient value may contribute to eutophication in bodies of water. The
available data on the raw materials does not indicate an undue hazard to the environment under anticipated conditins of
Storage and use except as noted below:




SECTION X TRANSPORTATION DATA

PROPER SHIPPING NAME: GOLDEN HARVEST PLUS
CORROSIVE LIQUID, N.O.S. ( Phosphoric acid and Zinc Chloride)

DOT HAZARD CLASS: 8, UN1760, PG III


PLACARD: YES

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