232376 E. Pacifica Place Rancho Dominguez, CA 90220 (800) 675-1118 www.alliedhightech.com
MATERIAL/CHEMICAL SAFETY DATA SHEET
SECTION 3: HAZARDS IDENTIFICATION
SECTION 1: CHEMICAL PRODUCT & COMPANY IDENTIFICATION
Hazard Statement: None
Product Details
QuickCure Acrylic Powder
Product Name:
170-10000, 10005, -10015,
Allied Item No.:
-10020, -10030, -10035
Chemical Name: Plasticized Methacrylate Polymer
SECTION 4: FIRST AID MEASURES
Company Identification Potential First Aid/
Health Effects Medical Info.
Allied High Tech Products, Inc.
Eye Contact: May cause irritation, Flush with water for 15
2376 East Pacifica Place
tearing, redness, drying minutes, including under
Rancho Dominguez, CA 90220
and/or swelling. eyelids. Seek medical
(310) 635-2466 attention if discomfort
persists.
Contact Point
Transportation for United States
Skin Contact: May cause redness, Wash with soap and
Chemtrec (800) 424-9300 * (202) 483-7616
burning, drying, cracking water. Seek medical
and/or dermatitis. attention if discomfort
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT persists.
Exposure Limits in Air Carcin.
Chemical Name CAS No. ACGIH TLV or TWA OSHA PEL Y/N
Polymer 60-100% 9011-14-7 10 mg/m3 15 mg/m Inhalation: May cause irritation, or Remove to fresh air. Seek
breathing difficulties. medical attention
Diethyl Phthalate 84-66-2 5 mg/m3 5 mg/m3 immediately.
0-20%
Ingestion: Large amounts may Rinse mouth out with
cause irritation of the water. Drink plenty of
digestive tract, nausea, milk or water immediately.
head ache, vomiting, or Do not induce vomiting.
diarrhea. Get medical attention
immediately
Note:
SECTION 5: FIRE FIGHTING MEASURES
Extinguishing Media: Alcohol foam, carbon dioxide, dry chemical or water.
Fire Fighting Instruction: Avoid extinguishing methods which may generate dust
clouds. Water stream can disperse dust into air, producing a fire hazard and
possible explosion hazard if exposed to ignition source. Wear self-contained
breathing apparatus and protective clothing.
Special Hazards: Polymer dust is combustible. The explosive limits of the polymer
particles suspended in air are approximately those of coal dust.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Sweep up to avoid slipping hazard. Keep airborne
particulates at a minimum when cleaning up spills.
HMIS Ratings
Ingredients are listed on the TSCA Inventory of
Health: 1
Chemical Substances.
Flammability: 1
Those not identified are non-hazardous.
Reactivity: 0
Page 1 of 2:
2376 E. Pacifica Place ?Rancho Dominguez, CA 90220 ?(800) 675-1118 ?www.alliedhightech.com
SECTION 7: HANDLING & STORAGE SECTION 12: ECOLOGICAL INFORMATION
Handling: Use in well ventilated areas. Observe Aquatic Toxicity:
good housekeeping practices. For Polymer: None listed
For Diethyl Phthalate: 10-100礚/96H / 53-78 mg/L/96H
Storage: Store in cool dry place. Keep container For Decomposition Product (Methyl Methacrylate): 100-1000 ppm
closed to prevent water absorption and contamina-
tion.
SECTION 8: EXPOSURE CONTROL & PERSONAL PROTECTION SECTION 13: DISPOSAL INFORMATION
Engineering Measures: Use good, local exhaust at processing equipment, This product contains a Phthalate (U-069), inciner-
including buffers, sanders, grinders and polishers.
ate in accordance with Federal, State and Local
regulations.
Respiratory Protection: Use type for Particulates Not Otherwise Classified, if
needed.
Reuse of empty drums or containers is not recom-
mended.
Protective Gloves: Impervious, nitrile, if hot plastic is handled.
Eye Protection: Safety glasses or chemical splash goggles.
Other: Eyewash, safety shower and impervious clothing are recommended.
SECTION 9: PHYSICAL & CHEMICAL PROPERTIES SECTION 14: TRANSPORT INFORMATION
DOT Shipping Name: Polymer, NOI
Appearance: Fine white powder
Odor: Faint odor in bulk
National Motor Freight Classification NMFC: 46030
Solubility: Insoluble
Boiling Point: NA
Export Schedule B Number: 3907.91.000
Melting Point: NA
Flash Point: 580癋 (304癈)
Vapor Pressure: NA
Vapor Density: NA
Evaporation Rate: 3.0
SECTION 15: REGULATORY INFORMATION
Specific Gravity: 1.25
Flammable Limits LEL: NA Canadian WHMIS: This product has been classified in accordance
with the hazardous criteria of the CPR and the MSDS contains all of
Flammable Limits UEL: NA the information required by the CPR. None of the components of this
product are listed on the Priorities Substances List.
SECTION 10: STABILITY & REACTIVITY
Risk Statements:
R36/37/38 - Irritating to eyes and respiratory system, and skin.
Conditions to Avoid/Incompatibles: Excessive heat.
Strong oxidizing agents. Safety Statements:
S7/8 Keep container tightly closed and dry.
Decomposition Products: Methacrylate Monomer and S20-21 When using do not eat, drink or smoke.
Oxides of Carbon when burned. S37/39 Wear suitable gloves and eye/face protection.
SECTION 16: OTHER INFORMATION
Hazardous Polymerization: Will not occur.
Legend
SECTION 11: TOXICOLOGICAL INFORMATION NAIF: No Applicable Information Found
NA: Not Available/Applicable
Target Organs NE: None Established
For Polymer: None listed DISCLAIMER: The above information and recommendations are
For Diethyl Phthalate: None listed believed accurate and reliable. Because it is not possible to anticipate
all conditions of use, additional safety precautions may be required.
For Trade Secret: None listed ALLIED HIGH TECH PRODUCTS, INC. makes no warranty, either
For Decomposition Products express or implied, as to its accuracy or completeness and none is
made as to the fitness of this material for any purpose. The
(Methyl Methacrylate): Nose, liver and kidneys manufacturer/distributor shall not be liable for damages to person or
property resulting from its use. Nothing herein shall be construed as a
recommendation for use in violation of any patent.
Page 2 of 2: Form Prepared By: Allied High Tech Products, Inc. January 2010
232376 E. Pacifica Place Rancho Dominguez, CA 90220 (800) 675-1118 www.alliedhightech.com
MATERIAL/CHEMICAL SAFETY DATA SHEET
SECTION 3: HAZARDS IDENTIFICATION
SECTION 1: CHEMICAL PRODUCT & COMPANY IDENTIFICATION
Hazard Statement: Flammable. Hazardous polymerization may
Product Details occur. Irritant by inhalation, in contact with skin and eye and if
swallowed. May cause sensitization by skin contact.
QuickCure Acrylic Liquid
Product Name:
Hydroquinone is listed as a suspect carcinogen by NTP. All data
given is for the dry powder, not as a component of a liquid mixture.
170-10000, -10010,
Allied Item No.:
-10015, -10025 Routes of Entry: Skin, eyes and/or inhalation.
Chemical Name: Methyl Methacrylate Monomer
SECTION 4: FIRST AID MEASURES
Company Identification Potential First Aid/
Health Effects Medical Info.
Allied High Tech Products, Inc.
Eye Contact: Liquid and vapors can Flush with water for 15
2376 East Pacifica Place
cause moderate irritation, minutes. Seek medical
Rancho Dominguez, CA 90220
tears, blurred vision, attention.
(310) 635-2466 swelling and redness.
Contact Point
Transportation for United States
Skin Contact: May cause irritation. Can Wash affected area with
Chemtrec (800) 424-9300 * (202) 483-7616
cause skin sensitization. soap and water. Wash
For Hydroquinone may contaminated clothing
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENT cause contact dermatitis before reuse. Discard
Exposure Limits in Air Carcin. and poisoning. contaminated shoes. Seek
Chemical Name CAS No. ACGIH TLV or TWA OSHA PEL Y/N medical attention.
Methyl Methacrylate 80-62-6 100 ppm/ 100 ppm/ Inhalation: High concentration is Remove to fresh air. If not
~100% 410 mg/m3 410 mg/m3 irritant to the respiratory breathing, give artificial
tract and may cause respiration. If breathing is
Standard grades dizziness, head ache and difficult, give oxygen.
contain inhibitors from anesthetic effects. Seek medical attention.
among the following
(4-1000 ppm) Ingestion: Causes irritation, a If swallowed do NOT
burning sensation of the induce vomiting.
Hydroquinone 123-31-9 2 m/m3 2 m/m3 N
mouth, throat and Immediately give 2
gastrointestinal tract and glasses of water. Seek
p-Methoxyphenol 150-76-5 NA NA
abdominal pain. medical attention.
2,4-Dimethyl-6-t- 1879-09-0 NA NA
Note: Prolonged and/or repeated exposure may lead to kidney, lung, liver and heart damage.
Butylphenol
For Dimethyl-p-Toluidine: Liquid is rapidly absorbed through skin. Absorption of this product into the
body causes the formation of methemoglobin, which in sufficient concentration causes cyanosis,
Octadecyl 3, 5-Di- 2082-79-3 NA NA symptoms include headache, dizziness, nausea and abdominal pain. In case of blue discoloration
(cyanosis) of skin, lips or fingernails give oxygen to breathe. No alcohol or physical exertion. Seek
Tert-Butyl-4-
medical attention.
Hydroxycinnamate
SECTION 5: FIRE FIGHTING MEASURES
Dimethyl-p-Toluidine 99-97-8 NE NE N
Extinguishing Media: Alcohol foam, carbon dioxide or dry chemical.
Ethylene Glycol 97-90-5 NE NE N
Dimethacrylate Fire Fighting Instruction: Cool tank/container with water spray. Fight fire from a
distance, heat may rupture containers. Wear self-contained breathing apparatus
and protective clothing.
Special Hazards: Fine mists are explosive below the flash point. Flammable liquid.
Vapor forms explosive mixture with air. Heat can cause polymerization with rapid
release of energy which may rupture container explosively. Vapors are heavier than
air and may travel to ignition sources and flash back. Sensitive to static discharge.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Evacuate personnel, thoroughly ventilate area, use self-
contained breathing apparatus. Remove source of heat,
sparks, flame, impact, friction or electricity. Dike spill. Prevent
HMIS Ratings
Ingredients are listed on the TSCA Inventory of
material from entering sewers, waterways or low areas. Soak
2
Health:
Chemical Substances.
up with sand, oil dry or other absorbent, non-combustible
Flammability: 3
Those not identified are non-hazardous.
material. Cleaned-up material is a RCRA Hazardous Waste.
Reactivity: 2
Spills on porous surfaces can contaminate the groundwater.
Page 1 of 2:
2376 E. Pacifica Place ?Rancho Dominguez, CA 90220 ?(800) 675-1118 ?www.alliedhightech.com
SECTION 7: HANDLING & STORAGE SECTION 12: ECOLOGICAL INFORMATION
Environmental Fate & Distribution: High tonnage material produced in
Handling: Do not breathe vapor or mist. Avoid contact with eyes, skin and
clothing. Wash thoroughly after handling product. Close container after wholly contained systems. Liquid with moderate volatility. Sparingly
each use. Ground container when pouring. Keep away from heat, direct soluble in water. Product has low potential for bioaccummulation. The
sunlight, sparks and flames. Observe good housekeeping practices. product is predicted to have high mobility in soil.
Storage: Vapors are uninhibited and may form polymers in vents or flame
Persistence & Degradation: Not readily biodegradable.
arresters, resulting in blockage of vents. Keep container in a cool place. Do
NOT expose to direct sunlight. Store in a well ventilated place. Keep
Toxicity: Low toxicity to fish. Harmful to aquatic invertebrates. Low
container tightly closed. Store in accordance with National Fire Protection
toxicity to algae.
Association recommendations. Maintain air space inside storage
containers. Avoid conditions which remove all oxygen from the store liquid.
Effects on Effluent Treatment: Product is substantially removed in
Inhibitor requires air contact to function. Check inhibitor levels after 6
biological treatment processes.
months and return to original level.
SECTION 8: EXPOSURE CONTROL & PERSONAL PROTECTION SECTION 13: DISPOSAL INFORMATION
Engineering Measures: General and/or local exhaust ventilation that is adequate Treatment, incineration, storage, transportation and
to keep level of air contaminants below exposure limits.
disposal must be in accordance with Federal, State and
Local regulations. Do not flush to surface water or
Respiratory Protection: Use OSHA/NIOSH approved respirator with organic vapor
cartridge if level of air contaminants is excessive. sanitary sewer system. Do not incinerate in closed
containers. Do not allow material to contaminate ground
Protective Gloves: Nitrile gloves, impervious apron and boots.
water systems.
Eye Protection: Safety glasses or splash proof goggles.
Reuse of empty drums or containers is not recom-
Other: Eyewash and safety shower are recommended.
mended.
SECTION 9: PHYSICAL & CHEMICAL PROPERTIES SECTION 14: TRANSPORT INFORMATION
DOT Shipping Name: TGD Shipping Name:
Appearance: Clear, yellowish liquid Methyl Methacrylate Monomer, Stabilized* Methyl Methacrylate Monomer, Stabilized
Odor: Characteristic odor
DOT Hazard Class: 3 TGD Class: 3.2 (9.2)
Solubility: 1.6 wt. 68癋 (20癈)
Boiling Point: 211癋 (99癈) DOT Id Number: UN1247 TGD Id Number: UN1247
Melting Point: -54癋 (-48癈) DOT Packing Group: II TGD Packing Group: II
Flash Point: 52癋 (11癈)
Vapor Pressure: 28 mm/Hg @ 68癋 (20癈) **If material is shipped in quantities greater than 1000 lb. per container, the proper
shipping name is RQ Methyl Methacrylate Monomer, Stabilized.
Vapor Density: 3.5
Evaporation Rate: NA
SECTION 15: REGULATORY INFORMATION
Specific Gravity: 0.935
Toxic Substance Control Act TSCA: All ingredients are TSCA listed.
Flammable Limits LEL: 2.1 CERCLA: This product is not classified as hazardous.
Flammable Limits UEL: 12.0 SARA Title III: 311, 312 This product is categorized as an Acute Health risk.
Canada WHMIS Hazard Class: B2: flammable liquid, D-2B: Toxic, F: Dangerously reactive material.
EINECS: All chemical listed
EEC Classification: Highly flammable and irritant
SECTION 10: STABILITY & REACTIVITY Risk Statements:
R36/37/38 - Irritating to eyes, skin and respiratory system.
R43 May cause sensitization by skin contact.
Stability: Unstable with heat
Safety Statements:
S3 Keep in a cool place
Conditions to Avoid/Incompatibles: Oxidizing, reducing agents and UV light. S7/9 Keep container tightly closed in a well ventilated place.
Contact with peroxides may result in violent reactions. Material is a strong S16 Keep away from sources of ignition. No smoking.
S20 When using do not eat or drink
solvent and can soften paints and rubber.
S29 Do not empty into drains.
S37/39 Wear suitable gloves and eye/face protection.
Decomposition Products: Decomposes with heat. Hazardous gases/vapors
SECTION 16: OTHER INFORMATION
produced are carbon monoxide, carbon dioxide, nitrogen and smoke.
Hazardous Polymerization: Can occur with excessive heat, storage in absence of
inhibitor and inadvertent addition of catalyst.
Legend
SECTION 11: TOXICOLOGICAL INFORMATION NAIF: No Applicable Information Found
NA: Not Available/Applicable
Teratology (Birth Defect) Info: Developmental toxicity observed in animal tests but only
NE: None Established
at levels toxic to the mother.
DISCLAIMER: The above information and recommendations are
Long Term Exposure: Repeated exposure to high levels produces adverse effects on
believed accurate and reliable. Because it is not possible to anticipate
the heart, lungs, liver and kidneys. Repeated exposure of animals by inhalation to
all conditions of use, additional safety precautions may be required.
levels at or above the occupational exposure level produces adverse effects on the
ALLIED HIGH TECH PRODUCTS, INC. makes no warranty, either
nasal epithelium (levels of 100-400 ppm). There is no reason to believe that methyl
express or implied, as to its accuracy or completeness and none is
methacrylate represents a carcinogenic or mutagenic hazard to man based upon
evidence from well conducted animal studies, relevant mutagenicity studies and made as to the fitness of this material for any purpose. The
adequate epidemiology studies in relevant cohorts. Recent studies in animals have manufacturer/distributor shall not be liable for damages to person or
shown that high exposures do not produce embryo or feototoxic nor teratogenic property resulting from its use. Nothing herein shall be construed as a
effects in the presence or maternal toxicity. None of these effects are likely to occur in
recommendation for use in violation of any patent.
human provided exposure is maintained at or below the occupational exposure limit.
Page 2 of 2: Form Prepared By: Allied High Tech Products, Inc. January 2010
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