SAFETY DATA SHEET
HARMONY VIOLET CTP REPLENISHER
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
Harmony Violet CTP Replenisher
PRODUCT NAME:
A Plate Replenisher for Lithographic use
PRODUCT USE:
Xant?br>
SUPPLIER:
2800 Dauphin St.
ADDRESS:
Mobile, AL 36606 USA
USA 251-473-6502
Toll Free 800-926-8839
ChemTel: North America: 1-800-255-3924
EMERGENCY PHONE:
International: +01-813-248-0585
A aqueous blend
CHEMICAL FAMILY:
8/17/07
ISSUE DATE:
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
The product may contain additional non-hazardous or trade-secret components.
INGREDIENT:
EC NO. CAS NO. % WT % VOL
Dipropylene Glycol Methyl Ether 252-104-2 34590-94-8 1 -5 % NA
Ethylenediaminetetraacetic Acid
Tetrasodium Salt 200-537-9 64-02-8 0.2 ?1 % NA
Potassium Hydroxide 215-181-3 1310-58-3 <1% NA
Triethanolamine 203-049-8 102-71-6 1?% NA
Trisodium Nitrilo Triacitate 225-768-6 18662-53-8 1?% NA
Dipropylene Glycol Methyl Ether
ppm mg/m3
600 mg/m3
100 ppm
OSHA PEL-TWA:
NA NA
OSHA PEL STEL :
NA NA
OSHA PEL CEILING:
100 ppm NA
ACGIH TLV-TWA:
150 ppm NA
ACGIH TLV STEL:
NA NA
ACGIH TLV CEILING:
OTHER:
600 ppm
IDHL
Ethylenediaminetetraacetic Acid
Tetrasodium Salt
ppm mg/m3
NA NA
OSHA PEL-TWA:
NA NA
OSHA PEL STEL :
NA NA
OSHA PEL CEILING:
NA NA
ACGIH TLV-TWA:
NA NA
ACGIH TLV STEL:
NA NA
ACGIH TLV CEILING:
Issue Date: 8/17/07
HARMONY VIOLET CTP REPLENISHER
Potassium Hydroxide
ppm mg/m3
NA NA
OSHA PEL-TWA:
NA NA
OSHA PEL STEL :
NA NA
OSHA PEL CEILING:
NA NA
ACGIH TLV-TWA:
NA NA
ACGIH TLV STEL:
NA NA
ACGIH TLV CEILING:
ST ?2 mg/m3
WEL Workplace Exposure Limits
Triethanolamine
ppm mg/m3
NA NA
OSHA PEL-TWA:
NA NA
OSHA PEL STEL :
NA NA
OSHA PEL CEILING:
NA NA
ACGIH TLV-TWA:
NA NA
ACGIH TLV STEL:
NA NA
ACGIH TLV CEILING:
Trisodium Nitrilo Triacitate
ppm mg/m3
NA NA
OSHA PEL-TWA:
NA NA
OSHA PEL STEL :
NA NA
OSHA PEL CEILING:
NA NA
ACGIH TLV-TWA:
NA NA
ACGIH TLV STEL:
NA NA
ACGIH TLV CEILING:
SECTION 3: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
ROUTE(S) OF ENTRY:
POTENTIAL HEALTH EFFECTS SHORT TERM/ACUTE EXPOSURE:
Product is considered to be Hazardous according to OSHA and WHMIS criteria
Eyes Yes Inhalation: No Skin: Yes Ingestion: Unlikely
Direct contact may cause irritation.
EYES:
Prolonged contact may cause irritation, and dryness.
SKIN:
No inhalation hazards
INHALATION:
INGESTION: Ingesting large amounts may cause tissue damage.
No further data known
CHRONIC HEALTH HAZARDS:
NTP: NO ARC Monographs: NO OSHA Regulated: NO
CARCINOGENICITY:
None known
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE:
Page 2 of 7
Issue Date: 8/17/07
HARMONY VIOLET CTP REPLENISHER
SECTION 4: FIRST AID MEASURES
Remove contact lenses from eyes. Flush with large amounts of running water for at least 15 minutes while
EYES:
holding upper and lower lids open. If irritation persists get medical attention immediately.
SKIN: Remove from source of contamination. Wash with water and soap or mild detergent. If irritation persists get
medical attention immediately.
INGESTION: Do not induce vomiting. Get medical attention immediately
INHALATION: Move the exposed person to fresh air. For breathing difficulties oxygen may be necessary. If
breathing stops, provide artificial respiration. Keep the person warm at rest. If irritation persists get medical
attention immediately.
NOTES TO PHYSICIANS OR FIRST AID PROVIDERS: No further data known
SECTION 5: FIRE-FIGHTING MEASURES
FIRE AND EXPLOSIVE PROPERTIES:
NA
FLAMMABLE LIMITS IN AIR, UPPER:
NA
(% BY VOLUME) LOWER:
HMIS HAZARD CLASSIFICATION
PERSONAL PROTECTION B
HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 0
EXTINGUISHING MEDIA: Alcohol foam, carbon dioxide or water spray.
SPECIAL FIRE FIGHTING PROCEDURES: Self contained breathing apparatus and full protective clothing must be worn
in case of ire. Containers close to fire should be removed or cooled with water.
Wear protective gloves and in case of splashes chemical goggles or face shield. In case of
CLEAN-UP MEASURES: :
inadequate ventilation, use respiratory protection. Remove sources of ignition. Stop spill or leak if it can be done
safely. Large spills should be absorbed in vermiculite, dry sand or earth and recovered for disposal. Waste
materials should be disposed of in accordance with all government regulations. Transfer contaminated
absorbent, soil and other materials to containers for disposal.
SECTION 7: HANDLING AND STORAGE
HANDLING: As with any chemical, handle the product in a manner that minimizes exposure to practicable levels.
Prior to handling, consult Section 8 of this MSDS to evaluate personal protective equipment needs. Open
containers slowly to relieve any pressure. Follow all other standard industrial hygiene practices. Empty containers
may contain product residue. All safety precautions taken when handling this product should also be taken when
handling empty drums and containers. Keep containers closed when not in use.
Page 3 of 7
Issue Date: 8/17/07
HARMONY VIOLET CTP REPLENISHER
STORAGE: Store in tightly closed containers. Store in a cool, dry area away from combustibles and reactive
chemicals. Keep in original container
OTHER PRECAUTIONS: For Industrial & Institutional use only.
_________________________________________________________________________________________________________________
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: Normal general ventilation is expected to be adequate. It is recommended that ventilation
be designed in all instances to maintain airborne concentrations at lowest practicable levels. Ventilation should at
a minimum, prevent airborne concentrations from exceeding any exposure limits listed in Section 2 of this MSDS.
When using in a confined area, provide adequate ventilation or exhaust otherwise
RESPIRATORY PROTECTION:
none needed.
Where splashing may occur, chemical goggles or full face shield is recommended.
EYE PROTECTION:
SKIN PROTECTION: Protective nitrile gloves are not normally needed but they are recomended for long term
exposure.
Wear full protective clothing for prolonged exposure and/or High
OTHER PERSONAL PROTECTIVE EQUIPMENT:
concentrations.
Do not eat drink or smoke in work area! Wash hands after use and before eating, drinking,
HYGIENIC PRACTICES:
smoking or using the toilet. Wash promptly if skin becomes wet. Promptly remove contaminated clothing. Keep
containers closed when not in use.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Colorless Liquid Mild
APPEARANCE: ODOR:
Liquid 12 - 13
PHYSICAL STATE: pH AS SUPPLIED:
> 100 oC (>365 oF)OF NA
BOILING POINT: MELTING POINT:
NA NA
FREEZING POINT: VAPOR PRESSURE:
NA NA
VAPOR DENSITY (AIR = 1): PERCENT VOLATILE:
Miscible with water. NA
SOLUBILITY IN WATER: PERCENT SOLIDS:
Mixture NA
MOLECULAR WEIGHT: VISCOSITY:
1.05
SPECIFIC GRAVITY (H2O = 1):
SECTION 10: STABILITY AND REACTIVITY
Product is stable under normal temperatures conditions.
STABILITY:
Increased temperatures for prolonged periods of time.
CONDITIONS TO AVOID (STABILITY):
NA
INCOMPATIBILITY (MATERIAL TO AVOID):
Page 4 of 7
Issue Date: 8/17/07
HARMONY VIOLET CTP REPLENISHER
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: None
HAZARDOUS POLYMERIZATION: Will not occur
Will not polymerize
CONDITIONS TO AVOID (POLYMERIZATION):
SECTION 11: TOXICOLOGICAL INFORMATION
Prolonged contact may cause irritation to the eyes.
EYE EFFECTS:
Prolonged contact may cause irritation to the skin
SKIN EFFECTS:
ORAL EFFECTS: No further toxicological data known.
No further toxicological data known.
INHALATION EFFECTS:
Not expected to be hazardous to the environment..
ECOTOXICOLOGICAL INFORMATION:
MOBILITY: The product is soluble in water.
BIOACCUMULATION: No data available.
No data available.
DEGRADABILITY:
ACUTE FISH TOXICITY: No data available.
SECTION 13: DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: Ensure that collection, transport, treatment, and disposal of waste product, containers
and rinsate complies with all applicable laws and regulations. Note that use, mixture, processing, or
contamination of the product may cause the material to be classified as a hazardous waste. It is the responsibility
of the product user or owner to determine at the time of disposal, whether the product is regulated as a
hazardous waste.
WASTE CLASS: Regulation 2000/532/EC ?Chapter Heading: Waste from MFSU of fine chemicals and chemical
products not otherwise specified ?090102. Description: Water based offset plate developer solutions
RCRA HAZARD CLASS: NA
SECTION 14: TRANSPORT INFORMATION
The product is not covered by international regulation on the transport of
TRANSPORT NOTES:
dangerous goods (IMDG, IATA and ADR/RID).
Not subject to DOT regulations
DOT PROPER SHIPPING NAME:
SECTION 15: REGULATORY INFORMATION
R22 Harmful if swallowed
RISK PHRASES:
R35 Causes severe burns
NC Not classified
SAFETY PHRASES:
U.S. FEDERAL REGULATIONS
Page 5 of 7
Issue Date: 8/17/07
HARMONY VIOLET CTP REPLENISHER
SARA 313: This product contains none of the substances subject to the reporting requirements of Section 313 of
Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CLEAN WATER ACT / OIL POLLUTION ACT: This product contains none of the chemicals subject to regulation by
Section 311 of the Clean Water Act and the Oil Pollution Act. Releases of the product into or leading to surface
waters must be reported to the National Response Center at 1-800-424-8802.
CERCLA REPORTABLE QUANTITY: Any components listed below have been assigned a reportable quantity (RQ) by
the Federal EPA. Release of the product into the environment that exceed the RQ for a particular component
must be reported to the National Response Center at 1-800-424-8802.
None
COMPONENT:
TOXIC SUBSTANCES CONTROL ACT: The components of this product are listed on the TSCA Inventory.
OZONE DEPLETING SUBSTANCES: This product contains no ozone depleting substances as defined by the
Clean Air Act.
HAZARDOUS AIR POLLUTANTS: Any components listed below are defined by the Federal EPA as hazardous
air pollutants.
None
COMPONENT:
STATE REGULATIONS: Check with the appropriate state agency to determine whether regulations exists.
INTERNATIONAL REGULATIONS
EU DIRECTIVES: Dangerous Substances Directive (67/548/EEC). Dangerous Preparations Directive (1999/45/EC).
Safety Data Sheets Directive (91/155/EEC)(As amended).
STATUTORY INSTRUMENTS: Chemicals (Hazard Information and Packaging) Regulations.
APPROVED CODE OF PRACTICE: Classification and labeling of Substances and Preparations Dangerous for Supply
GUIDANCE NOTES: Workplace Exposure Limits EH40. Introduction to local Exhaust Ventilation HS(G)37. CHIP for
everyone HSG108)
INVENTORIES
COMPONENT CAN US EU AUS JAP KOR CHN PHLP
DIPROPYLENE GLYCOL METHYL ETHER DSL YES EINECS YES NO YES YES YES
POTASSIUM HYDROXIDE DSL NA EINECS YES YES YES YES YES
EDTA TETRASODIUM SALT DSL YES EINECS YES YES YES YES YES
TRIETHANOAMINE DSL YES EINECS YES YES YES YES YES
COMPONENT CAS CA FL MA MN NJ PA RI
DIPROPYLENE GLYCOL METHYL ETHER 34590-94-8 NO YES YES NO YES YES YES
NO YES YES YES YES
POTASSIUM HYDROXIDE 1310-58-3 YES YES
NO NO NO NO NO NO
EDTA TETRASODIUM SALT 64-02-8 NO
NO YES YES
TRIETHANOlAMINE 102-71-6 YES YES YES NO
WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM - WHMIS
LABEL(S) FOR SUPPLY
Materials Causing Other Toxic Effects
Page 6 of 7
Issue Date: 8/17/07
HARMONY VIOLET CTP REPLENISHER
SECTION 16: OTHER INFORMATION
GENERAL INFORMATION: Conforms to UK Printing Solvent Substitution Scheme. AIII Class. It is the aim of the
scheme to reduce the use of low boiling point organic solvents in the printing industry in accordance with the
principles of the Control of Substances Hazardous to Health(COSHH) Regulations 1999 and promote improved
control of solvents exposure in line with the guidance given in the booklet COSSHH Essentials for Printer's.
Xant?br>
ISSUED BY:
8/17/07 International Version
DATE OF ISSUE:
7/05/07 US and EU versions
DATE OF LAST REVISION:
DISCLAIMER
The information in this material Safety Data Sheet is based on the present state of our knowledge and on the current EC and National
Regulations. The information relates to the specific product designated and may not be valid if it is used in combination with other materials
or process. Nothing herein is to be continued as warranty, expressed or implied. It is always the responsibility of the user to take the
necessary steps in order to fulfill the demands laid down in the rules and legislation. The product is for industrial use only.