MATERIAL SAFETY DATA SHEET
Phenyl chloroformate, 99% (gc)
* SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
*
MSDS Name: Phenyl chloroformate, 99% (gc)
Company Identification: Atul Ltd.- PP Site
P.O.-Atul 396020
Dist ?Valsad, Gujarat, India
Telephone no: + 91 2632 233621 / 233474 / 230 184
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS
****
CAS# Chemical Name % EINECS#|
1885-14-9 Phenyl chloroformate 97% 217-547-8
Hazard Symbols: T C
Risk Phrases: 21/22 23 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Appearance: clear colorless to faint colored. Flash Point: 69 deg C.
Moisture sensitive. Mutagen.
Target Organs: None.
Potential Health Effects
The toxicological properties of this material have not been investigated. Use
appropriate procedures to prevent opportunities for direct contact with the
skin or eyes and to prevent inhalation.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower lids.
Skin:
Flush skin with plenty of soap and water for at least 15 minutes
while removing contaminated clothing and shoes.
Ingestion:
May cause methemoglobinemia, cyanosis, convulsions, and death.
Inhalation:
Remove from exposure to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-
demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Do NOT use water directly on fire. Use foam, dry chemical, or carbon dioxide.
Autoignition Temperature: 560 deg C ( 1,040.00 deg F)
Flash Point: 69 deg C ( 156.20 deg F)
NFPA Rating: Not published.
Explosion Limits, Lower: Not available.
Upper: Not available.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material, (e.g., dry sand or earth), then place into a
chemical waste container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Not available.
Storage:
Refrigerator (approx 4狢).
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
OSHA Vacated PELs:
Phenyl chloroformate, 97%:
No OSHA Vacated PELs are listed for this chemical. Personal Protective
Equipment
Eyes:
Wear safety glasses and chemical goggles if splashing is possible.
Skin:
Wear appropriate protective gloves and clothing to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece
airline respirator in the positive pressure mode with emergency escape
provisions.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Not available.
Appearance: clear colorless to faint colored
Odor: None reported.
pH: Not available.
Vapor Pressure: 20 mmHg @ 83 C
Vapor Density: Not available.
Evaporation Rate: Not available.
Viscosity: Not available.
Boiling Point: 74.0 - 75.0 deg C @ 13.00mm Hg
Freezing/Melting Point: - 20.00 - - 0.00 deg
Decomposition Temperature: Not available.
Solubility: decomposes
Specific Gravity/Density: 1.2480g/cm3
Molecular Formula: C7H5ClO2
Molecular Weight: 156.57
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Bases - strong bases - alcohols - amines - moist air or water.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1885-14-9: FG3850000
LD50/LC50:
CAS# 1885-14-9: Skin, rabbit: LD50 = 3970 mg/kg.
Carcinogenicity:
Phenyl chloroformate, 97% -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Not available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
RCRA D-Series Maximum Concentration of Contaminants:
None listed.
RCRA D-Series Chronic Toxicity Reference Levels: None listed.
RCRA F-Series: None listed.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Not listed as a material banned from land disposal according to RCRA.
**** SECTION 14 - TRANSPORT INFORMATION ****
US DOT
Shipping Name: PHENYL CHLOROFORMATE
Hazard Class: 6.1
UN Number: 2746
Packing Group: II
IMO
Shipping Name: PHENYL CHLOROFORMATE
Hazard Class: 6.1
UN Number: 2746
Packing Group: II
IATA
Shipping Name: PHENYL CHLOROFORMATE
Hazard Class: 6.1
UN Number: 2746
Packing Group: II
RID/ADR
Shipping Name: PHENYL CHLOROFORMATE
Dangerous Goods Code: 6.1(27B)
UN Number: 2746
Canadian TDG
Shipping Name: PHENYL CHLOROFORMATE
Hazard Class: 6.1(8)
UN Number: UN2746
**** SECTION 15 - REGULATORY INFORMATION ****
US FEDERAL
TSCA
CAS# 1885-14-9 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
Section 302 (RQ)
None of the chemicals in this material have an RQ.
Section 302 (TPQ)
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous
Substances under the CWA.
None of the chemicals in this product are listed as Priority
Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants
under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by
OSHA.
STATE
Phenyl chloroformate, 97% can be found on the following state right to know
lists: New Jersey.
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T C
Risk Phrases:
R 21/22 Harmful in contact with skin and if swallowed.
R 23 Toxic by inhalation.
R 34 Causes burns.
Safety Phrases:
S 33 Take precautionary measures against static discharges.
S 45 In case of accident of if you feel unwell, seek medical advice
immediately (show the label where possible).
WGK (Water Danger/Protection)
CAS# 1885-14-9: 2
Canada
CAS# 1885-14-9 is listed on Canada's DSL/NDSL List.
This product does not have a WHMIS classification.
CAS# 1885-14-9 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
**** SECTION 16 - ADDITIONAL INFORMATION ****
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall Atul be liable for
any claims, losses, or damages of any third party or for lost profits or any
special, indirect, incidental, consequential or exemplary damages, howsoever
arising, even if Atul has been advised of the possibility of such damages.
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