MATERIAL SAFETY DATA SHEET
Page 1 of 4
1. PRODUCT AND COMPANY IDENTIFICATION
NAME: SOLID DISH MACHINE DETERGENT
USE: MECHANICAL DISH DETERGENT
LABEL BRAND: U S CHEMICAL
MSDS # 105864 CODE # 077708
U S CHEMICAL, 316 HART STREET, WATERTOWN, WI 53094 USA
MEDICAL EMERGENCY #: 1-866-923-4913 USA
SPILL EMERGENCY #: 1-800-424-9300 USA
PRODUCT INFORMATION #: 1-800-558-9566 (8 A.M. TO 5 P.M. CST MONDAY TO FRIDAY)
INTERNET ADDRESS: WWW.USCHEMICAL.COM
REVIEWED 2-2-10 REVISED 2-2-10 SECTION REVISED: 1
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
DANGER. CORROSIVE. CAUSES EYE AND SKIN BURNS.
HARMFUL OR FATAL IF SWALLOWED.
PRINCIPLE ROUTES OF EXPOSURE: EYES, SKIN, INGESTION, INHALATION.
POTENTIAL ACUTE HEALTH EFFECTS
EYES: CORROSIVE. CAUSES EYE BURNS. MAY CAUSE PERMANENT DAMAGE INCLUDING BLINDNESS
WITHOUT IMMEDIATE FIRST AID TREATMENT.
SKIN: CORROSIVE. CAUSES SKIN BURNS. MAY CAUSE PERMANENT DAMAGE.
HARMFUL CONTACT MAY NOT CAUSE IMMEDIATE PAIN.
INHALATION: CORROSIVE. INHALATION OF DUST OR MISTS MAY CAUSE CORROSIVE EFFECTS TO NOSE,
THROAT AND RESPIRATORY SYSTEM.
CORROSIVE. MAY CAUSE BURNS TO MOUTH, THROAT AND STOMACH.
INGESTION:
HARMFUL OR FATAL IF SWALLOWED.
MEDICAL CONDITIONS AGGRAVATED: NONE KNOWN.
3. COMPOSITION / INFORMATION ON INGREDIENTS
% BY WT LC50/LD50
HAZARDOUS INGREDIENT CAS #
SEE 11.0
SODIUM HYDROXIDE 1310-73-2 10.0 ?30.0
STATE RIGHT TO KNOW: THIS PRODUCT CONTAINS:
SODIUM TRIPOLYPHOSPHATE/7758-29-4, SODIUM HYDROXIDE/1310-73-2,
TRISODIUM NITRILOTRIACETATE/18662-53-8, SODIUM POLYACRYLATE/9003-04-7,
BLOCK COPOLYMER/9003-11-6
SOLID DISH MACHINE DETERGENT MSDS # 105864
4. FIRST AID MEASURES Page 2 of 4
EYES: IMMEDIATELY FLUSH EYES WITH RUNNING WATER FOR 15-20 MINUTES, KEEPING
EYELIDS OPEN. SKIN: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15-20 MINUTES.
REMOVE AND WASH CONTAMINATED CLOTHING AND FOOTWEAR BEFORE RE-USE.
IF SWALLOWED: GIVE A CUPFUL OF WATER OR MILK. THEN IMMEDIATELY CONTACT A
PHYSICIAN OR POISON CENTER. DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON.
INHALATION: IF BREATHING IS AFFECTED: REMOVE TO FRESH AIR.
ADMINISTER FIRST AID TREATMENT AS STATED ABOVE, THEN CALL 1-866-923-4913 OR
CONTACT PHYSICIAN FOR FURTHER MEDICAL INSTRUCTIONS.
NOTE TO PHYSICIAN: CALL 1-866-923-4913 FOR ASSISTANCE WITH THE MANAGEMENT OF EXPOSURES.
5. FIRE-FIGHTING MEASURES
FLAMMABILITY: NO HAZARD.
FLASH POINT: N.AP.
PRODUCTS OF COMBUSTION: SEE SECTION 10.
SUITABLE EXTINGUISHING MEDIA: FOR FIRES IN AREA, USE APPROPRIATE MEDIA.
FOR EXAMPLE: WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE, OR ALCOHOL FOAM.
SPECIFIC HAZARDS: CORROSIVE PRODUCT MAY REACT WITH CERTAIN METALS.
SEE 8. AND 10. THIS PRODUCT MAY REACT VIOLENTLY WITH WATER.
SPECIFIC METHODS: NORMAL FIRE FIGHTING PROCEDURES MAY BE USED.
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS: CORROSIVE. PUT ON PERSONAL PROTECTIVE EQUIPMENT. SEE 8.
SPILL RESPONSE: THIS MATERIAL IS A SOLID IN A PLASTIC CANISTER WHICH CANNOT BE
SPILLED OR LEAK. HOWEVER, DURING USE THE PRODUCT IS DISSOLVED AND THIS DILUTED
SOLUTION SHOULD BE TREATED AS FOLLOWS: FLUSH SMALL SPILLS WITH WATER TO LOCAL
SANITARY SEWER AS PERMITTED. AFTER SPILL COLLECTION, FLUSH AREA WITH WATER AND
FOLLOW WITH NORMAL CLEAN-UP PROCEDURES. BE CAREFUL AS SPILLS ARE SLIPPERY.
7. HANDLING AND STORAGE
HANDLING: FOLLOW ALL LABEL DIRECTIONS. INSTRUCT PERSONNEL ABOUT
PROPER USE, HAZARDS, PRECAUTIONS, AND FIRST AID MEASURES.
AVOID INHALATION, INGESTION, AND CONTACT WITH SKIN, EYES AND CLOTHING.
DO NOT TASTE OR SWALLOW. REMOVE AND WASH CONTAMINATED CLOTHING AND
FOOTWEAR BEFORE RE-USE. PRODUCT RESIDUE MAY REMAIN IN EMPTY CONTAINERS.
HANDLE CAREFULLY TO AVOID DAMAGING CONTAINER.
STORAGE: ROTATE STOCK REGULARLY. KEEP CONTAINER CLOSED WHEN NOT IN USE.
AVOID TEMPERATURES ABOVE 120癋. STORAGE AT AMBIENT TEMPERATURES IN A DRY
AREA OUT OF DIRECT SUNLIGHT IS RECOMMENDED. KEEP AWAY FROM FOOD AND DRINK.
KEEP OUT OF CHILDREN'S REACH.
SOLID DISH MACHINE DETERGENT MSDS # 105864
8. EXPOSURE CONTROLS / PERSONAL PROTECTION Page 3 of 4
EXPOSURE LIMITS:
SODIUM HYDROXIDE = 2 MG/M3 CEILING LIMIT (ACGIH), 2 MG/M3 TWA (OSHA)
ENGINEERING CONTROLS: NONE REQUIRED. GENERAL ROOM VENTILATION IS TYPICALLY ADEQUATE.
PERSONAL PROTECTION
EYES: SPLASH PROOF SAFEY GLASSES, SAFETY GOGGLES AND AN EYE WASH STATION.
HANDS: CHEMICAL RESISTANT GLOVES: RUBBER OR NEOPRENE. LONG TYPE IF NEEDED.
RESPIRATORY: NONE REQUIRED WITH NORMAL USE.
FEET: TYPICALLY NOT NEEDED. WEAR BOOTS DURING SPILL & WHEN EXPOSURE IS POSSIBLE.
BODY: IF MAJOR EXPOSURE IS POSSIBLE, WEAR FULL-COVER PROTECTIVE CLOTHING.
9. PHYSICAL AND CHEMICAL PROPERTIES
COLOR: OFF-WHITE FLASH POINT: N.AP.
ODOR: NONE UEL: N.AP.
pH CONCENTRATE: ABOVE 12.0 (BASIC) LEL: N.AP.
pH @ 2500 PPM SOLUTION: 11.5 (BASIC) EVAPORATION RATE: N.AP.
pH @ USE DILUTION: N.AV. ODOR THRESHOLD: N.AP
PHYSICAL STATE: SOLID VAPOR PRESSURE: N.AP
SPECIFIC GRAVITY: 1.450 VAPOR DENSITY: N.AP.
VISCOSITY: N.AP. COEFF. OIL/WATER: N.AP.
BOILING POINT: N.AP. WATER SOLUBILITY: MODERATE
OTHER: N.AP.
MELTING POINT: ABOVE 120癋
10. STABILITY AND REACTIVITY
STABLE: YES
CONDITIONS TO AVOID: AVOID TEMPERATURES ABOVE 120癋.
MATERIALS TO AVOID: AVOID MIXING DIRECTLY WITH ANY OTHER CLEANING PRODUCT.
AVOID ACIDS AND VARIOUS METALS (ALUMINUM, ZINC, TIN, BRASS OR BRONZE) WHICH CAN
GENERATE FLAMMABLE HYDROGEN GAS. MIX ONLY WITH WATER.
DECOMPOSITION PRODUCTS: FIRE OR MIXING WITH INCOMPATIBLE MATERIALS MAY
PRODUCE OXIDES OF CARBON AND OTHER TOXIC OR IRRITATING FUMES.
POSSIBILITY OF HAZARDOUS REACTIONS: AVOID MIXING DIRECTLY WITH ACIDS.
11. TOXICOLOGICAL INFORMATION
ACUTE EFFECTS: CORROSIVE. SEE SECTION 2.
CHRONIC EFFECTS: NONE KNOWN. NO REPORTABLE CARCINOGENS, MUTAGENS,
SENSITIZERS, SYNERGISTIC MATERIALS, TERATOGENS, OR REPRODUCTIVE TOXINS.
LC50/LD50: SODIUM HYDROXIDE 50%: 220 MG/KG ORAL-RAT LD50
SODIUM HYDROXIDE: 1350 MG/KG DERMAL-RABBIT LD50
TARGET ORGANS: EYES, SKIN, RESPIRATORY SYSTEM.
OTHER TOXIC EFFECTS: NONE KNOWN.
SOLID DISH MACHINE DETERGENT MSDS # 105864
12. ECOLOGICAL INFORMATION Page 4 of 4
NOT AVAILABLE.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: UNDILUTED PRODUCT IS REGULATED UNDER ENVIRONMENTAL
AND TRANSPORTATION LAWS AS A CORROSIVE WASTE (RCRA CLASS D002).
DISPOSE OF ACCORDING TO ALL FEDERAL, STATE, PROVINCIAL AND LOCAL LAWS AND
REGULATIONS. CONSULT STATE AND LOCAL AUTHORITIES FOR RESTRICTIONS ON
DISPOSAL OF CHEMICAL WASTE. MANAGE CHEMICAL WASTES THROUGH AN APPROVED
WASTE TREATMENT FACILITY. DO NOT REUSE EMPTY CONTAINER.
RINSE EMPTY CONTAINER THOROUGHLY WITH WATER BEFORE DISCARDING
CONTAINER IN ACCORDANCE WITH CURRENT LOCAL COMMUNITY CODES. PLEASE
RECYCLE EMPTY CONTAINER WHENEVER POSSIBLE.
14. TRANSPORT INFORMATION
DOT/TDG: SODIUM HYDROXIDE, SOLID, MIXTURE, 8, UN1823, II
DOT RQ: N.AP.
DOT ERG #: 154
15. REGULATORY INFORMATION
EPA CERCLA RQ: SODIUM HYDROXIDE = 1000 LB
EPA REGISTERED: NO
EPA VOC: 0.00%
EPA VOC RULE: THIS PRODUCT DOES NOT CONTAIN VOLATILE ORGANIC COMPOUNDS.
OSHA HAZARDOUS: YES
PHOSPHORUS CONTENT: SEE LABEL
PROPOSITION 65: N.AP.
SARA 311/312 HAZARDS: ACUTE
SARA 313 CHEMICALS: NO
STATE RIGHT TO KNOW: SEE SECTION 3 FOR CHEMICAL NAMES.
TSCA INVENTORY STATUS: ALL COMPONENTS ARE LISTED ON THE INVENTORY.
WHMIS CLASS: E
16. OTHER INFORMATION
NFPA RATING: HEALTH-3/FLAMMABILITY-0/REACTIVITY-0/SPECIAL HAZARD-N.AP.
HMIS RATING: HEALTH-3/FLAMMABILITY-0/REACTIVITY-0/PERSONAL PROTECTION-SEE 8.0
N.AV. = NOT AVAILABLE N.AP. = NOT APPLICABLE PREPARED BY: HEALTH AND SAFETY
NOTICE TO READER
THIS DOCUMENT HAS BEEN PREPARED USING DATA FROM SOURCES CONSIDERED TECHNICALLY
RELIABLE. IT DOES NOT CONSTITUTE A WARRANTY, EXPRESS OR IMPLIED, AS TO THE ACCURACY
OF THE INFORMATION CONTAINED WITHIN. ACTUAL CONDITIONS OF USE AND HANDLING ARE
BEYOND SELLER'S CONTROL. USER IS RESPONSIBLE FOR EVALUATING ALL AVAILABLE
INFORMATION WHEN USING PRODUCT FOR ANY PARTICULAR USE AND TO COMPLY WITH ALL
FEDERAL, STATE, PROVINCIAL AND LOCAL LAWS AND REGULATIONS.
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