Report Date : 29/01/2008
REVISION DATE: 08/03/2006 SDS No.: 10200
SAFETY DATA SHEET
WL-200 WASH
1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING
PRODUCT NAME WL-200 WASH
PRODUCT NO. WL-200
APPLICATION Printing Ink related material
SUPPLIER Domino UK Ltd
Bar Hill
Cambridge
CB23 8TU
Tel: +44 (0) 1954 782551
Fax: +44 (0) 1954 782874
Email: msds@domino-uk.com
EMERGENCY TELEPHONE +44(0)1954 782551 (24 Hours)
2 HAZARDS IDENTIFICATION
Highly flammable. Irritating to eyes. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and
dizziness.
CLASSIFICATION Xi;R36. F;R11. R66, R67.
3 COMPOSITION/INFORMATION ON INGREDIENTS
Name EC No. CAS-No. Content Classification
BUTANONE 201-159-0 78-93-3 90-100% F;R11 Xi;R36 R66 R67
The Full Text for all R-Phrases are Displayed in Section 16
4 FIRST-AID MEASURES
GENERAL INFORMATION
NOTE! Keep affected person away from heat, sparks and flames! Keep the affected person warm and at rest. Get prompt medical
attention.
INHALATION
Move the exposed person to fresh air at once. Perform artificial respiration if breathing has stopped. Keep the affected person warm and
at rest. Get prompt medical attention.
INGESTION
NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Promptly get affected person to drink large volumes of water to
dilute the swallowed chemical. Do not induce vomiting. If vomiting occurs, the head should be kept low so that stomach vomit doesn''t
enter the lungs. Get medical attention.
SKIN CONTACT
Remove affected person from source of contamination. Wash the skin immediately with soap and water. Get medical attention if any
discomfort continues.
EYE CONTACT
Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention.
5 FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA
Use: Alcohol resistant foam. Powder. Dry chemicals, sand, dolomite etc.
SPECIAL FIRE FIGHTING PROCEDURES
Keep run-off water out of sewers and water sources. Dike for water control. If risk of water pollution occurs, notify appropriate authorities.
Use water to keep fire exposed containers cool and disperse vapours. Move container from fire area if it can be done without risk.
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Report Date : 29/01/2008
REVISION DATE: 08/03/2006 SDS No.: 10200
WL-200 WASH
UNUSUAL FIRE & EXPLOSION HAZARDS
Vapours are heavier than air and may spread near ground to sources of ignition. May explode when heated or when exposed to flames or
sparks. May form explosive or toxic mixtures with air.
SPECIFIC HAZARDS
Fire creates: Toxic gases/vapours/fumes of Carbon monoxide (CO). Carbon dioxide (CO2).
PROTECTIVE MEASURES IN FIRE
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
6 ACCIDENTAL RELEASE MEASURES
SPILL CLEAN UP METHODS
Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Clean-up personnel should use respiratory and/or
liquid contact protection. Runoff or release to sewer, waterway or ground is forbidden. Small Spillages Collect with absorbent,
non-combustible material into suitable containers. Large Spillages Absorb in vermiculite, dry sand or earth and place into containers.
Inform Authorities if large amounts are involved.
7 HANDLING AND STORAGE
USAGE PRECAUTIONS
Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use
approved respirator if air contamination is above accepted level. Risk of vapour concentration on the floor and in low-lying areas. Static
electricity and formation of sparks must be prevented.
STORAGE PRECAUTIONS
Flammable/combustible - Keep away from oxidisers, heat and flames. Store in tightly closed original container in a dry, cool and
well-ventilated place. Keep in original container.
STORAGE CLASS
Flammable liquid storage.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Name Std LT - ppm LT - mg/m3 ST - ppm ST - mg/m3
BUTANONE WEL 600 mg/m3(Sk) 300 ppm(Sk) 899 mg/m3(Sk)
200 ppm(Sk)
INGREDIENT COMMENTS
WEL = Workplace Exposure Limits
PROTECTIVE EQUIPMENT
PROCESS CONDITIONS
Provide eyewash station.
ENGINEERING MEASURES
Well-ventilated area.
RESPIRATORY EQUIPMENT
No specific recommendation made, but respiratory protection must be used if the general level exceeds the Recommended Workplace
Exposure Limit.
HAND PROTECTION
Use protective gloves made of: Polyvinyl alcohol (PVA). P.T.F.E (Teflon). Nitrile.
EYE PROTECTION
Wear splash-proof eye goggles to prevent any possibility of eye contact.
OTHER PROTECTION
Wear appropriate clothing to prevent any possibility of skin contact.
HYGIENE MEASURES
DO NOT SMOKE IN WORK AREA! Promptly remove any clothing that becomes wet or contaminated. Wash promptly if skin becomes wet
or contaminated. Use appropriate hand lotion to prevent defatting and cracking of skin. When using do not eat, drink or smoke. Wash at
the end of each work shift and before eating, smoking and using the toilet.
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Report Date : 29/01/2008
REVISION DATE: 08/03/2006 SDS No.: 10200
WL-200 WASH
9 PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE Liquid
COLOUR Clear
ODOUR Ketonic.
SOLUBILITY Soluble in Organic solvents Slightly soluble in water.
MOL. WEIGHT 72.1 BOILING POINT (癈) ~ 75 - 85 760 mm Hg
MELTING POINT (癈) - 86.5 RELATIVE DENSITY 0.80 @ 20 癱
VAPOUR DENSITY (air=1) 2.4 VAPOUR PRESSURE 8.9 kPa @ 20 癱
VOLATILE BY VOL. (%) 100 VISCOSITY 1.00 cps @ 20 癱
FLASH POINT (癈) -4 CC (Closed cup). FLAMMABILITY LIMIT - LOWER(%) 1.8
FLAMMABILITY LIMIT - UPPER(%) 11.5
10 STABILITY AND REACTIVITY
STABILITY
Stable under normal temperature conditions.
CONDITIONS TO AVOID
Avoid contact with strong oxidisers.
HAZARDOUS POLYMERISATION
Will not polymerise.
HAZARDOUS DECOMPOSITION PRODUCTS
Fire creates: Toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2).
11 TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION
No data recorded.
INHALATION
CNS depressant. Prolonged inhalation of high concentrations may damage respiratory system.
INGESTION
Narcotic effect.
EYE CONTACT
Irritation of eyes and mucous membranes.
HEALTH WARNINGS
EYE CONTACT. Irritant of eyes and mucous membranes. INGESTION. Narcotic effect. INHALATION. CNS depressant. Prolonged
inhalation of high concentrations may damage respiratory system. SKIN CONTACT. Acts as a defatting agent on skin. May cause
cracking of skin, and eczema.
Other Health Effects
IARC Not Listed. OSHA Not Regulated.
ROUTE OF ENTRY
Ingestion. Skin absorption. Inhalation.
MEDICAL SYMPTOMS
NERVOUS SYSTEM. Drowsiness, dizziness, disorientation, vertigo. Mild intoxication (incl. fatigue, lassitude, irritability, headache,
nausea).
12 ECOLOGICAL INFORMATION
ECOTOXICITY
Little danger to the environment.
LC 50, 96 Hrs, FISH mg/l >100
EC 50, 48 Hrs, DAPHNIA, mg/l >100
IC 50, 72 Hrs, ALGAE, mg/l >100
DEGRADABILITY
Will degrade.
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Report Date : 29/01/2008
REVISION DATE: 08/03/2006 SDS No.: 10200
WL-200 WASH
ACUTE FISH TOXICITY
May be harmful to aquatic organisms in large quantities.
WATER HAZARD CLASSIFICATION
WGK 1
13 DISPOSAL CONSIDERATIONS
GENERAL INFORMATION
Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority.
DISPOSAL METHODS
Contact specialist disposal companies. Do not allow runoff to sewer, waterway or ground. Empty containers must not be burned because
of explosion hazard. Absorb in vermiculite or dry sand, dispose in licensed hazardous waste. Dispose of waste and residues in
accordance with local authority requirements.
14 TRANSPORT INFORMATION
PROPER SHIPPING NAME ETHYL METHYL KETONE (METHYL ETHYL KETONE)
UN NO. ROAD 1193 CEFIC TEC(R) NO. 30GF1-I+II
UN NO. SEA 1193 IMDG CLASS 3
EMS F-E, S-D MFAG See Guide
MARINE POLLUTANT No. UN NO. AIR 1193
AIR CLASS 3 AIR PACK GR. II
15 REGULATORY INFORMATION
LABELLING
Irritant Highly Flammable
RISK PHRASES
R11 Highly flammable.
R36 Irritating to eyes.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
SAFETY PHRASES
S16 Keep away from sources of ignition - No smoking.
S33 Take precautionary measures against static discharges.
S7/9 Keep container tightly closed and in a well-ventilated place.
S24/25 Avoid contact with skin and eyes.
S60 This material and its container must be disposed of as hazardous waste.
STATUTORY INSTRUMENTS
Chemicals (Hazard Information and Packaging) Regulations.
Control of Substances Hazardous to Health.
APPROVED CODE OF PRACTICE
Safety Data Sheets for Substances and Preparations.
Classification and Labelling of Substances and Preparations.
Chemical Industries Association - Guidance on the compilation of safety data sheets.
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Report Date : 29/01/2008
REVISION DATE: 08/03/2006 SDS No.: 10200
WL-200 WASH
GUIDANCE NOTES
Workplace Exposure Limits EH40.
16 OTHER INFORMATION
INFORMATION SOURCES
Dangerous Properties of Industrial Materials Report, N.Sax et.al. Croner磗: Emergency Spillage Guide. Croner磗: Substances Hazardous
to Health. Croner磗: Emergency First Aid Guide. Croner磗: Dangerous Substances.
REVISION DATE 08/03/2006
REV. NO./REPL. SDS GENERATED 6
RISK PHRASES IN FULL
R11 Highly flammable.
R36 Irritating to eyes.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
DISCLAIMER
This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of Domino's knowledge and belief, accurate and
reliable as of the date indicated. However, no warranty, guarantee or representation is made as to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.
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