MATERIAL SAFETY DATA SHEET
Section 1. Product and Company Information
MANUFACTURER: Freecom, Inc.
P.O. Box 2119
Big Spring, Texas 79721-2119
TELEPHONE: For information purposes 8:00 a.m. to 5:00 p.m. CDT
(915) 263-8497 (800) 346-4299
EMERGENCY: (915) 263-8497 (800) 346-4299
DATE OF PREPARATION: February 20, 2007
SUPERSEDES MSDS DATED: July 28, 2006
PRODUCT NAME: CeRam-Kote 54?TZS
Section 2. Composition and Ingredient Information
Common Name Chemical Name CAS Number Weight %
PART-A CeRam-Kote 54?br>
TZS(Base)
Ceramic Filler Ceramic Filler 67762-90-71344-28- 43 to 78
114807-96-6
*Proprietary #1 Epoxy Resin 041638-13-5 2 to 6
*Proprietary #2 Epoxy Resin 28064-14-4 1 to 8
*Proprietary #3 Epoxy Resin 25068-38-6 6 to 20
Isopropanol 2-Propanol 67-63-0 1 to 4
Methyl Ethyl Ketone 2-Butanone 78-93-3 4 to 7
Methyl Isobutyl Ketone 4-Methyl-2-Pentanone 108-10-1 2 to 5
PART-B CeRam-Kote 54?br>
TZS(Curing Agent)
Modified Aliphatic Polyamine *Trade Secret Not Available 2 to 3
Diethylenetriamine Mixture N-(2-Aminoethyl)-1,2- 111-40-0 2 to 3
Ethanediamine
Bisphenol A 4,4'-(1-Methylethylidene) 80-05-7 2 to 3
Bisphenol
*The specific chemical identity of this ingredient is declared proprietary information under 29 CFR 1910.1200, section (i) Trade
Secret. Hazard Information is provided in this MSDS for this ingredient.
Section 3. Physical Data
Description CeRam-Kote 54?TZS PART-A: CeRam-Kote PART-B: CeRam-Kote
(Catalyzed) 54?TZS (Base) 54?TZS (Curing
Agent)
1.78 1.8612 1.07
Specific Gravity (kg/l)
N/A 241癋 (116癈) >200癈
Boiling Point
> Air 3.2 > Air
Vapor Density (Air = 1)
N/A Insoluble Miscible
Solubility in Water
900 to 1500 cP 1200 to 2000 cP 3,000 to 5,000 cP
Viscosity (centapoise)
N/A Not Applicable 11
pH
Neutral Base is Neutral Base is Liquid, amine odor
Appearance and odor
translucent, aromatic translucent, aromatic
odor odor
13.7 lbs/gal (6.21 kg.) 13.0 lbs/gal (5.9 kg.) 0.70 lbs/pint (0.32 kg.)
Density - packaged(on
average)
10 to 12% 10 to 12% Nil
Total Volatiles
89 to 91% 88 to 90% 100%
Non-Volatiles
1.63 lbs/gal (196 g/l)less 1.76 lbs/gal (210.92 0 lbs/gal (0 g/l)
VOC content
water g/l)less water
Section 4. Fire Fighting Measures
Description CeRam-Kote 54?TZS (catalyzed) and/or PART-B: CeRam-Kote 54?br>
PART-A: CeRam-Kote 54?TZS (Base) TZS (Curing Agent)
64癋 (17.8癈) when catalyzed >200癋
Flashpoint
LFL: 1.2 - MIBKUFL: 8.0 - MIBK N/A
Flammable Limits
750癋 (399癈) - IPA N/A
Auto Ignition
Temperature
Extinguishing Media Foam, CO2, or dry chemical Foam, CO2, or dry chemical.
A water spray can also be
used.
Product is a NFPA Class 1B flammable liquid. Decomposition and
Unusual Fire and
Prevent smoking, open flame, static and other combustion products may be
Explosion Hazards
electrical sparking. Excessive heat may cause toxic.
lids of containers to pop open from excessive
vapor pressure.
Treat as a flammable liquid type fire. In a Use self contained breathing
Fire Fighting
sustained fire wear self-contained breathing apparatus.
Instructions
apparatus and full protective bunker turnout
gear
Primary combustion products are carbon Carbon monoxide, carbon
Hazardous
Combustion Products monoxide, carbon dioxide, and low molecular dioxide, aldehydes, and
weight hydrocarbons. Other undetermined nitrogen oxides
compounds could be released in small
quantities.
Section 5. Reactivity Data
Description CeRam-Kote 54?TZS (catalyzed) and/or PART-B: CeRam-Kote 54?br>
PART-A: CeRam-Kote 54?TZS (Base) TZS (Curing Agent)
Avoid High Heat Stable
Stability
Avoid organic peroxides and oxidizers Avoid strong oxidizing agents,
Incompatibility
acids, copper and its alloys
Various hydrocarbon fragments. See section 4 Carbon monoxide, carbon
Hazardous
of MSDS for combustion products statement. dioxide, aldehydes, and nitrogen
Decomposition
oxides
Products
May occur. Avoid excessive heat, contamination Will not occur.
Hazardous
and prolonged storage above 70癋
Polymerization
Section 6. Health and Safety
CeRam-Kote 54?TZS (catalyzed) and/or PART- PART-B: CeRam-Kote
A: CeRam-Kote 54?TZS (Base) 54?TZS (Curing Agent)
Inhalation, skin, eye Dermal
Primary Routes of
Exposure
Acute (short term): This product if inhaled may
Potential Health Overexposure effects:
cause nose, throat, and mucous membrane irritation Direct or prolonged skin
Effects
and possible central nervous system effects or eye contact can cause
including headaches, nausea, vomiting, dizziness, skin and eye burns.
drowsiness, loss of coordination, impaired judgment, Swallowing liquid can
and general weakness. It may cause moderate burn mouth and cause
irritation to the skin with dryness, cracking, and nausea, vomiting,
possible dermatitis with prolonged or repeated diarrhea, abdominal pain
contact. Direct eye contact with this product may and collapse. Can cause
cause immediate irritation to the eyes with redness, allergic skin and
burning, tearing and blurred vision. It may cause respiratory reactions after
mouth, throat and gastrointestinal irritation, nausea, repetitive exposure.
vomiting, and diarrhea if ingested. Aspiration of Animal studies on
material into the lungs can cause chemical component (s) have
pneumonitis which can be fatal. shown effects on liver
and fetus.
Chronic (long term): Prolonged or repeated skin
contact may result in irritation, dermatitis marked by
rough, dry cracking skin. Contact with the epoxy
resin may cause sensitization. In lab animals,
overexposure by inhalation to MIBK has been
reported to cause liver and kidney abnormalities,
and lung and brain damage. Kidney disorders have
been reported from human ingestion of isopropanol.
Medical Conditions Persons with a history of chronic respiratory disease, Persons with a history of
skin disease, or central nervous system disorders allergic conditions may
Aggravated by
may be at increase risk for worsening their be at increased risk for
Exposure
conditions from exposure to this product. worsening their
conditions from exposure
to this product.
Section 7. First Aid Measures
Description CeRam-Kote 54?TZS (catalyzed) and/or PART-B: CeRam-Kote 54?TZS
PART-A: CeRam-Kote 54?TZS (Base) (Curing Agent)
Remove individual to fresh air. If breathing Remove to fresh air. Give oxygen if
Inhalation
is difficult, administer oxygen and obtain breathing is difficult
medical aid.
Flush with running water for at least 15 Immediately flush eyes with water for at
Eyes
minutes. Seek medical attention least 15 minutes. Get immediate
medical assistance.
Wash with flowing water. Remove Promptly wash thoroughly with mild
Skin
contaminated clothing and launder before re- soap and water
wearing. If irritation persists, seek medical
attention
DO NOT induce vomiting. Seek medical DO NOT induce vomiting. Seek
Ingestion
attention. medical attention.
Section 8. Exposure Controls and Personal Protection
Exposure Contrls
INGREDIENT OSHA PEL (8-HR TWA) ACGIH TLV (8-HR TWA)
5 mg/m?(respirable fraction)15 mg/m?10 mg/m?br>
*Proprietary #1, #2, #3
(total fraction)
400 PPM 400 PPM, STEL 500 PPM
Isopropyl Alcohol
200 PPM, STEL 300 PPM 200 PPM, STEL 300 PPM
Methyl Ethyl Ketone
100 PPM 50 PPM, STEL 75 PPM
Methyl Isobutyl Ketone
2 mg/m? 2 mg/m?br>
Ceramic Filler
None established None established
Modified Aliphatic
Polyamine
1 PPM 1 PPM (skin)
Diethylenetriamine
Mixture
Personal Protection
Description CeRam-Kote 54?TZS (catalyzed) and/or PART- PART-B: CeRam-Kote 54?TZS
A: CeRam-Kote 54?TZS (Base) (Curing Agent)
Engineering General dilution ventilation and/or exhaust Good general mechanical
ventilation should be provided as necessary to ventilation is recommended.
controls
maintain exposures below regulatory limits. Local exhaust recommended.
Respiratory If irritation occurs, or if the TLV or PEL is exceeded, Organic chemical cartridge
use a NIOSH/MSHA approved air purifying respirator, if needed.
Protection
respirator with organic vapor cartridges or canisters,
or supplied air respirators. Use respiratory
protection in accordance with your company's
respiratory program, local regulations or OSHA
regulations under 29 CFR 1910.134.
Loose fitting long sleeved shirt, long pants and Wear impervious rubber gloves
Dermal
chemical resistant gloves such as neoprene or
Protection
natural rubber gloves.
Chemical protective goggles. Splash-proof chemical goggles
Eye
Protection
Section 9. Spills, Leaks and Disposal
Description CeRam-Kote 54?TZS (catalyzed) PART-B: CeRam-Kote 54?TZS
and/or PART-A: CeRam-Kote 54? (Curing Agent)
TZS (Base)
Prevent material from entering sewers Avoid all personal contact. Take up
Land Spill
or waterways. Remove all sources of with absorbent material. Shovel into
ignition (flames, hot surfaces, and closable containers. Flush
electrical static or frictional sparks). contaminated area with water.
Ventilate area. Absorb with inert
materials (vermiculite or sand) and
place in a closed container for disposal
as solid waste. Wash area well with
trisodium phosphate and water.
Material is mostly insoluble. The This product is miscible in water.
Water Spill
material will sink. Notify local That means it is totally dissolved
environmental, health and wildlife when mixed with water. Due to this
authorities, and water intake property, this is considered a marine
operators. Contain with booms and pollutant; however, when mixed with
minimize spread on water. Disperse part A, and after the product cures, it
any remaining residue to reduce is totally inert.
aquatic harm.
Spills of this material may release This product reacts with air by
Air Release
volatile organic compounds into the absorbing the moisture out of the
air. Spills should be cleaned or air. Take up with absorbent material.
covered to prevent volatilization Shovel into closable containers.
Flush contaminated area with water.
Characteristic hazardous waste Not a hazardous waste under RCRA
Disposal
(D001) due to ignitability (40 CFR 261).
Considerations
Section 10. Transport Information
Description PART-A: CeRam-Kote 54?TZS PART-B: CeRam-Kote 54?TZS
(Base) (Curing Agent)
Resin Solution Amines, Liquid, Corrosive,
DOT/IATA/IMDG Shipping
N.O.S.,(Diethylenetriamine
Names
Mixture)
3 8
Hazard Class or Division
None None
Secondary
UN 1866 UN 2735
UN Identification Number
III III
Packing Group
Flammable (3) Corrosive (8)
Label(s) required
Quantity Limitations(Air only)
60 liters (15 gallons) 5 liters (5 quarts)
Passenger Aircraft
220 liters (58 gallons) 60 liters (15 gallons)
Cargo Aircraft
Packing Instructions
309 818
Passenger Aircraft
310 820
Cargo Aircraft
Section 11. Regulatory Information
Description PART-A: CeRam-Kote 54?TZS PART-B: CeRam-Kote 54?TZS (Curing
(Base) Agent)
26 N/A
ERG Number
Each ingredient is on the inventory Chemical components listed on inventory
TSCA Status
Sec 304: MIBKSec 313: MIBK Sec 313: 4,4'-Isopropylidenediphenol
SARA Title III
MIBK listed as a HAP N/A
Clean Air Act
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