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Hitachi Industrial Equipment Systems Co., Ltd JP-K33 Version 2.00 issue 2005.08.31 revision 2008.10.23
MATERIAL SAFETY DATA SHEET
1 IDENTIFICATION
Product name :JP-K33
Name of company :Hitachi Industrial Equipment Systems Co., Ltd
Address :1-1,Higashitaga-cho 1-chome, Hitachi-shi, Ibaraki-ken, Japan
Tel :+81-294-36-8682
Fax :+81-294-36-8975
Recommended use of the chemical
and restrictions on use :Printing Ink for industrial Marking
2 HAZARDS IDENTIFICATION
Classification of the substance or mixture :mixture
Physico-chemical endpoints :Flammable liquid category 2
Acute toxicity - oral :Category 5
Acute toxicity - dermal :Not available
Acute toxicity - inhalation vapors :Not identified
Acute toxicity - inhalation dust, mist :Not identified
Skin corrosion/irritation :Category 2
Eye damage/irritation :Category 2
Sensitization - respiratory :Not identified
Sensitization - skin :Not identified
Germ cell mutagenicity :Not available
Carcinogenicity :Not available
Toxic to reproduction :Category 1
Effects on or via lactation :Not identified
Specific target organ systemic toxicity
(Single exposure) :Category 1
(Repeated exposure) :Category 1
Aspiration toxicity :Category 2
Hazardous to the aquatic environment
-Acute hazard :Not available
-Chronic hazard :Not identified
To the best of our knowledge, the information contained here in is accurate. However, neither the above
named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.
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Hitachi Industrial Equipment Systems Co., Ltd JP-K33 Version 2.00 issue 2005.08.31 revision 2008.10.23
GHS label elements
Hazard symbols:Flame,Exclamation mark,Health hazard
Signal word: Danger
Hazard statement and precautionary statement
?Highly flammable liquid and vapour
?May be harmful if swallowed
?Causes skin irritation
?Causes eye irritation
?May damage fertility or the unborn child
?Causes damage to organs-single exposure
?Causes damage to organs through prolonged or repeated exposure.
?May be harmful if swallowed and enters airways
Precautionary statements:
?Keep out of reach of children. Read label before use. If medical advice is needed: Have product
container or label at hand.
Prevention
?Keep away from ignition sources such as heat/sparks/open flame?No smoking.
?Take precautionary measures against static discharge.
?Wear protective gloves and eye/face protection as specified by the competent authority.
?Do not breathe dust/mist/vapors.
?Use only in a well-ventilated area. Call a doctor/physician if you feel unwell.
?Do not eat, drink or smoke when using this product.
?Avoid contact during pregnancy/while nursing.
?Wash hands thoroughly after handling.
Response
?In case of fire, use dry chemical, CO2, water splay (fog) or form for extinction.
?IF SWALLOWED: Call a doctor/physician if you feel unwell. Rinse mouth.
?IF ON SKIN: Gently wash with plenty of soap and water.
?Wash/Decontaminate removed clothing before reuse.
?If skin irritation occurs, seek medical advice/attention.
?IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
?IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. Immediately call a doctor/physician.
?Collect spillage.
Storage
?Store in cool/well-ventilated place. Store locked up.
?Call a doctor/physician if exposed or you feel unwell.
Disposal
To the best of our knowledge, the information contained here in is accurate. However, neither the above
named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.
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Hitachi Industrial Equipment Systems Co., Ltd JP-K33 Version 2.00 issue 2005.08.31 revision 2008.10.23
? Waste must be disposed of according to applicable regulations.
3 Composition/information on ingredients
Substance or mixture; mixture
Composition;
Chemical name concentration (%) CAS number
2-butanone 80-90 78-93-3
Chrome -Complex Dye 5-10 Registered
toluene 1 108-88-3
4 First-aid measures
Inhalation;
Remove the victim from the contamination immediately to fresh air. Keep the victim warm and quiet and
arrange for transport to the neatest medial facility for examination and treatment by a physician as soon
as possible.
Skin contact;
Remove all contaminated clothing, shoes and socks from the affected areas as quickly as possible.
Wash the affected area under running water using a mild soap. If irritation persists, arrange for transport
to the nearest medical facility for examination and treatment by a physician as son as possible.
Eye contact;
Gently rinse the affected eyes with clean water for at least 15 minutes. Remove contact lenses if easily
possible. and refer for medical attention.
Ingestion;
Never give anything by mouth to someone who is unconscious or convulsing. If the victim is responsive,
give him one or two glasses of water. And refer for medial attention.
5 Fire-fighting measures
Suitable extinguishing media;
Use dry chemical, CO2, water splay (fog) or form.
Fire fighting procedures;
Use water spray to cool fire-exposed surfaces and to protect personnel. Shut off "fuel" to fire. If a leak
or spill has not ignited, use water spray to disperse the vapors.
Avoid spraying water directly into storage containers due to danger of boil over.
Unusual fire/explosion hazard;
Flammable liquid, can release vapors that form flammable mixtures at temperatures at or above the
flashpoint.
Special protective equipment and precautions for fire fighters;
Fire fighters should wear boots, overalls, gloves, eye and face protection and breathing apparatus.
6 Accidental release measures
Shut off all sources of ignition; No smoking or flames in area. Absorb spill with inert material (e.g.,
To the best of our knowledge, the information contained here in is accurate. However, neither the above
named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.
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Hitachi Industrial Equipment Systems Co., Ltd JP-K33 Version 2.00 issue 2005.08.31 revision 2008.10.23
dry sand or earth), then place in closed containers using non-sparking tools. Flush residual spill
(area) with copious amounts of water.
7 Handling and storage
Handling;
Use only in the well-ventilated areas.
Make available in the work area emergency shower and eyes wash.
Avoid contact with skin or eyes.
Storage;
Close up the container and keep it in dark cool(0~20 ) place.
Keep away from combustible materials and sources of ignition.
8 Exposure controls/personal protection
Exposure guidelines;
ACGIH TLV-TWA (ppm)
2-butanone :200
Chrome -Complex Dye :None known
toluene :20(skin)
ACGIH STEL(ppm)
2-butanone :300
Chrome -Complex Dye :None known
toluene :No data
9 Physical and chemical properties
Appearance
Physical state :Liquid
Color :Black
Odor :Solvent odor
Boiling point :80 2-butanone)
Flash point :-4.1 closed cup
Upper/lower flammability or explosive limits :Lower 1.8 vol Upper 11.5 vol 2-butanone)
Vapor pressure :10.5kPa (20 ) 2-butanone)
Relative density (Air 1) :2.41 2-butanone)
Relative density :0.851(20
Solubility Water :29g/100mL (20 ) 2-butanone)
Partition coefficient: n-octanol/water :0.29 2-butanone)
Auto-ignition temperature :505 2-butanone)
Decomposition temperature :No measurement
10 Stability and reactivity
Stability: The product is stable.
Conditions and materials to avoid: Not available
Hazardous decomposition products: These products are carbon oxides
11 Toxicological information
To the best of our knowledge, the information contained here in is accurate. However, neither the above
named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.
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Hitachi Industrial Equipment Systems Co., Ltd JP-K33 Version 2.00 issue 2005.08.31 revision 2008.10.23
Acute toxicity;
2-butanone
Category 5:Oral 5520(Rat LD50 (mg/kg))
Not available:Dermal 8000(Rabbit LD50 (mg/kg))
Category 5:Inhalation 11700 Vaper (Rat LC50(ppm/4h))
Chrome -Complex Dye
Not identified:Oral No data
Not identified:Dermal No data
Not identified:Inhalation No data
toluene
Category 5:Oral 636(Rat LD50(mg/kg))
Not available:Dermal 14100(RabbitLD50(礚/kg))
Not available:Inhalation 49(Rat LC50(gm/m3/4H))
Skin corrosion/irritation;
2-butanone
Category 2:Frequent/prolonged contact may irritate and cause dermatitis. Low order of toxicity.
Chrome -Complex Dye
Not identified
toluene
Category 2:Skin; rabbit; 20mg/24H; Moderate(85JCAE -, 29, 1986)
Serious eye damage/irritation;
2-butanone
Category 2B:Eye contact:severely irritating. If not removed promptly, will injure eye tissue, which
may result in permanent damage.
Chrome -Complex Dye
Not identified
toluene
Category 2B:rabbit; ; Moderate(EU-RAR No.30, 2003)
Respiratory or skin sensitization;
2-butanone
Not identified
Chrome -Complex Dye
Not identified
toluene
Not available
Germ cell mutagenicity;
2-butanone
Not available
Chrome -Complex Dye
Not identified
toluene
Not available:Micronucleus test; mouse; ipr; 433?g/kg/24H(ARTODN 58, 106, 1985)
Sister chromatid exchange; human; ihl; 252?g/L/19Y(MUREAV 519, 171, 2002)
Carcinogenicity;
2-butanone
Not available
Chrome -Complex Dye
Not identified
toluene
To the best of our knowledge, the information contained here in is accurate. However, neither the above
named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.
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Hitachi Industrial Equipment Systems Co., Ltd JP-K33 Version 2.00 issue 2005.08.31 revision 2008.10.23
Not available:TDLo(orl,rat): 16mL/kg(6-21 D preg); Effects on Newborn - phisycal(REPEBL 47, 362,
2000)
TCLo(ihl,rat): 1800ppm(7-20 D preg); Specific Developmental Abnormalities - Central Nervous
System(ARTODN 75, 103, 2001)
Human; "the study suggests an increased risk of late spontaneous abortions associated with
exposure to toluene at levels around 88 ppm (range 50-150 ppm). The results of this study are
used as a basis for the risk characterisation of developmental toxicity in humans."(EU-RAR No.30,
2003), (IRIS 2005, IARC 71,1999, EHC 52,1986, ATSDR 2000)
Reproductive toxicity;
2-butanone
Not available
Chrome -Complex Dye
Not identified
toluene
Category 1A
STOST-single exposure;
2-butanone
Category 1:(Central nervous system),Category 2(Kidney),Category 3(Respiratory)
Chrome -Complex Dye
Not identified
toluene
Category 1(Central nervous system),Category 3(Respiratory system,Anesthetizing action) Human;
ihl, 50-100ppm, feebleness, sleepiness, dizziness(CERI hazard sheet, 96-4,1997)
Human; ihl, 200-400ppm, paresthesia, vomiturition(CERI hazard sheet, 96-4,1997)
Human; ihl, 500-800ppm, drunkenness, derangement, gait abonormality(CERI hazard sheet,
96-4,1997)
Human: irritation for eye, nose and throat(EU-RAR No.30, 2003)
STOST-repeated exposure;
2-butanone
Category 1:(Central nervous system,Peripheral nervous system)
Chrome -Complex Dye
Not identified
toluene
Category 1(Central nervous system,Kidney,Liver) Human; ihl, stenosis for range of vision,
headache with deafness and eye nystagmus, trembling, dynamic ataxia, amnesia, cerebral atrophy,
renal dysfunction(CERI hazard sheet, 96-4,1997)
Human; The increasing of SGOT, hepatotoxicity with the adipose degeneration in liver cell and
lymphocyte cell wetting(EU-RAR No.30, 2003)
Aspiration hazard.
2-butanone
Category 1:Vapor concentrations above exposure
Chrome -Complex Dye
Not identified
toluene
Not available
LD50 50% Lethal Dose LC50 (50% Lethal Concentration)
12 Ecological information
Toxicity
2-butanone
To the best of our knowledge, the information contained here in is accurate. However, neither the above
named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.
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Hitachi Industrial Equipment Systems Co., Ltd JP-K33 Version 2.00 issue 2005.08.31 revision 2008.10.23
killifish 96 -LC50(mg/L) >100
killifish 14 -LC50 (mg/L) 100
killifish 14 -NOEC (mg/L) 100
Chrome -Complex Dye
None known
toluene
orange-red killifish 96h-LC50(mg/L) 25
dephnids 48h-EC50(mg/L) 4.1
Persistence and degradability:
2-butanone
None known
Chrome -Complex Dye
None known
toluene
This material is biodegradable.
Bioaccumulative potential:
2-butanone
None known
Chrome -Complex Dye
None known
toluene
None known
Mobility in soil:
2-butanone
None known
Chrome -Complex Dye
None known
toluene
None known
13 Disposal considerations
Scrap materials may be disposed by licensed contractor or burn in an approved incinerator.
Do not dump into sewer, on the ground or into any body of water.
Follow national and local regulations.
14 Transport information
Follow all regulations in your country.
UN Number :1210
UN Proper Shipping Name :Printing ink, flammable
Transport hazard class :Class 3(Flammable liquid)
Packing Group :
Environmental hazards :No
15 Regulatory information
Follow all regulations in your country.
Content of RoHS Directive material Cd<100ppm Pb, Hg, Hexavalent Cr, PBB, PBDE<1000ppm
16 References
1) Solvent, dye MSDS
To the best of our knowledge, the information contained here in is accurate. However, neither the above
named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.
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Hitachi Industrial Equipment Systems Co., Ltd JP-K33 Version 2.00 issue 2005.08.31 revision 2008.10.23
2) Results of Eco-toxicity tests of chemicals conducted by Ministry of the Environment in Japan (-2006)
3) International Chemical Safety Cards
To the best of our knowledge, the information contained here in is accurate. However, neither the above
named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.
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