Safety Data Sheet according to 91/155/EEC
Hitachi Europe GmbH
Revision date : 10.01.2006 Revision no. : 1,01
Ink JP-W73
00509-0027
1. Identification of the substance/preparation and of the company/undertaking
1.1 Identification of the substance or preparation
Ink JP-W73
Use of the substance/preparation
Printing Ink
1.2 Company/undertaking identification
Hitachi Europe GmbH
Am Seestern 18
D-40547 D黶seldorf
Telephone : +49 (0) 211 52 83-0
Telefax : +49 (0) 211 52 83-649
Contact person :
Emergency telephone :++49 (0) 6132 / 84463 GBK Gefahrgut Buero GmbH, Ingelheim
2. Composition/information on ingredients
( preparation )
Chemical characterization
Ink Jet printing ink in organic solvents.
Hazardous components
EC-No. CAS-No. Chemical name Quantity Classification
201-159-0 78-93-3 Butanon 45 - 55 % F, Xi R11-36-66-67
200-751-6 71-36-3 butan-1-ol, n-butanol 1 - 3 % Xn, Xi R10-22-37/38-41-67
236-675-5 13463-67-7 Titanium dioxide 5 - 10 %
200-578-6 64-17-5 Ethanol 1 - 10 % F R11
200-659-6 67-56-1 Methanol 1 - 3 % F, T R11-23/24/25-39/23/24/25
Full text of each relevant R phrase can be found in heading 16.
3. Hazards identification
Classification
Symbols : Highly flammable, Harmful, Irritant
R-phrases :
Highly flammable.
Harmful if swallowed.
Irritating to eyes.
Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness.
4. First aid measures
General information
Remove contaminated soaked clothing immediately.
Keep warm and calm injured person.
Take away from danger area and lay down affected person.
After inhalation
Move to fresh air in case of accidental inhalation of vapours or decomposition products.
Refer for medical treatment.
GB - EN Page 1 of 7
Safety Data Sheet according to 91/155/EEC
Hitachi Europe GmbH
Revision date : 10.01.2006 Revision no. : 1,01
Ink JP-W73
00509-0027
After contact with skin
Wash off immediately with soap and plenty of water.
Consult a doctor if skin irritation persists.
After contact with eyes
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Seek medical treatment by eye specialist.
After ingestion
Induce vomiting only upon the advice of a physician.
Immediately give plenty of water (if possible charcoal slurry).
Do not induce vomiting.
Summon a doctor immediately.
5. Fire-fighting measures
Suitable extinguishing media
Alcohol-resistant foam, dry chemical, carbon dioxide (CO2), water-spray.
Extinguishing media which must not be used for safety reasons
Full water jet
Special exposure hazards arriving from substance or preparation itself, combustion products,
resulting gases
Carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx).
Special protective equipment for fire-fighters
Use breathing apparatus with independent air supply.
Additional information
Vapours are heavier than air and spread along ground.
The vapour/air mixture is explosive, even in empty, uncleaned receptacles.
Risk of bursting of the receptacle.
Cool containers at risk with water spray jet.
6. Accidental release measures
Personal precautions
In case of vapour formation use respirator.
Ensure adequate ventilation.
Use personal protective clothing.
Keep away sources of ignition.
Environmental precautions
Do not discharge into the drains/surface waters/groundwater.
Methods for cleaning up/taking up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder).
Shovel into suitable container for disposal.
Additional information
Clean contaminated surface thoroughly.
7. Handling and storage
7.1 Handling
Advice on safe handling
GB - EN Page 2 of 7
Safety Data Sheet according to 91/155/EEC
Hitachi Europe GmbH
Revision date : 10.01.2006 Revision no. : 1,01
Ink JP-W73
00509-0027
Keep container tightly closed.
Do not breathe vapours.
Use only in thoroughly ventilated areas.
Avoid contact with skin, eyes and clothing.
Advice on protection against fire and explosion
Do not smoke - volatile.
Keep away from heat and sources of ignition.
Take precautionary measures against static discharges.
Use only explosion-proof equipment.
7.2 Storage
Requirements for storage rooms and vessels
Keep container tightly closed in a dry, cool and well-ventilated place.
Pay attention to anti-explosion rules.
Advice on storage compatibility
Incompatible with oxidizing agents.
Further information on storage conditions
Keep away from food, drink and animal feeding stuffs.
3A
Storageclass (VCI) :
8. Exposure controls/personal protection
8.1 Exposure limit values
Exposure limits (EH40)
CAS No. Substance ml/m? mg/m? F/ml Category Origin
71-36-3 Butan-1-ol - - TWA (8 h) WEL
Butan-1-ol 50 154 STEL (15 min) WEL
78-93-3 Butan-2-one (methyl ethyl ketone) 200 600 TWA (8 h) WEL
Butan-2-one (methyl ethyl ketone) 300 899 STEL (15 min) WEL
64-17-5 Ethanol 1000 1920 TWA (8 h) WEL
Ethanol - - STEL (15 min) WEL
67-56-1 Methanol 200 266 TWA (8 h) WEL
Methanol 250 333 STEL (15 min) WEL
13463-67-7 Titanium dioxide, respirable - 4 TWA (8 h) WEL
Titanium dioxide, respirable - - STEL (15 min) WEL
8.2 Exposure controls
Occupational exposure controls
Ensure adequate ventilation, especially in confined areas.
Protective and hygiene measures
Do not inhale vapours.
Avoid contact with eyes and skin.
Wash hands before breaks and immediately after handling the product.
When using, do not eat, drink or smoke.
Take off immediately all contaminated clothing.
Respiratory protection
In case of insufficient ventilation wear suitable respiratory equipment (gas filter type A).
Hand protection
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Safety Data Sheet according to 91/155/EEC
Hitachi Europe GmbH
Revision date : 10.01.2006 Revision no. : 1,01
Ink JP-W73
00509-0027
Protective gloves resistant to chemicals made off viton, Minimum coat thickness 0,7 mm, Permeation
resistance (wear duration) approx. 10 minutes, i.e. protective glove made by www.kcl.de.
This recommendation refers exclusively to the chemical compatibility and the lab test conforming to EN
374 carried out under lab conditions.
Requirements can vary as a function of the use. Therefore it is necessary to adhere additionally to the
recommendations given by the manufacturer of protective gloves.
Eye protection
Eye wash bottle with pure water.
Tightly fitting goggles
Skin protection
Long sleeved clothing.
9. Physical and chemical properties
9.1 General information
Physical state : Liquid
Colour : White
Odour : Irritant
9.2 Important health, safety and environmental information
Test method
Changes in the physical state
Flash point : Closed cup
< -8,1 癈
Lower explosion limits : 1,8 vol. %
Upper explosion limits : 11,5 vol. %
0,95 hPa
Vapour pressure :
at (20 癈)
Density (at 20 癈) : 0,94-0,96 g/cm?br>
Insoluble
Water solubility :
at (20 癈)
Viscosity / kinematic : 3 mm?s
Solvent content
< 90 %
10. Stability and reactivity
Conditions to avoid
Vapour/air mixtures are explosive at intensive warming.
Heating can release vapours which can be ignited.
Materials to avoid
Oxidizing agents (strong).
Hazardous decomposition products
Carbon monoxide and carbon dioxide.
Chlorine compounds
Additional information
No decomposition if stored and applied as directed.
11. Toxicological information
Empirical data on effects on humans
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Safety Data Sheet according to 91/155/EEC
Hitachi Europe GmbH
Revision date : 10.01.2006 Revision no. : 1,01
Ink JP-W73
00509-0027
Irritating to eyes.
Vapours may cause drowsiness and dizziness.
12. Ecological information
Additional information
Do not flush into surface water or sanitary sewer system.
Slightly water hazardous.
13. Disposal considerations
Advice on disposal
Where possible recycling is preferred to disposal.
Can be incinerated, when in compliance with local regulations.
Waste disposal number of waste from residues/unused products :
080312 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF
COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS
AND PRINTING INKS; wastes from MFSU of printing inks; waste ink containing dangerous
substances
Classified as hazardous waste.
Contaminated packaging
Empty containers should be taken for local recycling, recovery or waste disposal.
Contaminated packagings are to be treated like the product itself.
14. Transport information
Land transport (ADR/RID)
ADR/RID class : 3
Hazard-no. : 33
UN number : 1210
Hazard label : 3
ADR/RID packing group : II
Description of the goods
Printing ink
Remarks (land transport)
LQ 6: combination packaging: 5 l / 30 kg (total gross mass); trays: 1 l / 20 kg (total gross mass).
Inland waterways transport
Marine transport
3
IMDG code :
UN number : 1210
Marine pollutant : No
EmS : F-E, S-D
IMDG packing group : II
Description of the goods
PRINTING INK
Air transport
ICAO/IATA-DGR : 3
UN/ID number : 1210
Hazard label : 3
ICAO packing group : II
GB - EN Page 5 of 7
Safety Data Sheet according to 91/155/EEC
Hitachi Europe GmbH
Revision date : 10.01.2006 Revision no. : 1,01
Ink JP-W73
00509-0027
Description of the goods
PRINTING INK
Remarks (air transport)
PAC 305 (5 L), CAC 307 (60 L)
15. Regulatory information
15.1 Labelling
Indication of danger : F - Highly flammable; Xn - Harmful
Labelling according to EC-guidelines : According to EC-regulations the product is to be labelled as follows:
Hazardous component(s) to be indicated on label
Methanol
R phrases :
11 Highly flammable.
22 Harmful if swallowed.
36 Irritating to eyes.
66 Repeated exposure may cause skin dryness or cracking.
67 Vapours may cause drowsiness and dizziness.
S phrases :
02 Keep out of the reach of children.
46 If swallowed, seek medical advice immediately and show this container or label.
15.2 National regulations
Water contaminating class : 1 - slightly water contaminating
Additonal information
Content of RoHS Directive material Cd < 100ppm; Pb, Hg, Hexavalent Cr, PBB, PBDE < 1000ppm.
16. Other information
List of relevant R phrases
10 Flammable.
11 Highly flammable.
22 Harmful if swallowed.
36 Irritating to eyes.
41 Risk of serious damage to eyes.
66 Repeated exposure may cause skin dryness or cracking.
67 Vapours may cause drowsiness and dizziness.
23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
37/38 Irritating to respiratory system and skin.
39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and
if swallowed.
Other data
Data of items 4 to 8, as well as 10 to 12, do partly not refer to the use and the regular employing of the
product (in this sense consult information on use and on product), but to liberation of major amounts in
case of accidents and irregularities.
The information describes exclusively the safety requirements for the product (s) and is based on the
present level of our knowledge.
The delivery specifications are contained in the corresponding product sheet.
This data does not constitute a guarantee for the characteristics of the product(s) as defined by the legal
warranty regulations.
GB - EN Page 6 of 7
Safety Data Sheet according to 91/155/EEC
Hitachi Europe GmbH
Revision date : 10.01.2006 Revision no. : 1,01
Ink JP-W73
00509-0027
Changes
Changes in chapter: 15
(The data for the hazardous ingredients were taken respectively from the last version of the
sub-contractor's safety data sheet.)
GB - EN Page 7 of 7
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