MATERIAL SAFETY DATA SHEET
Prepared to U.S. OSHA, CMA, ANSI and Canadian WHMIS, And European Community Standards
PART I What is the material and what do I need to know in an emergency?
1. PRODUCT IDENTIFICATION
TRADE NAME (AS LABELED):
Genova ABS Low VOC Solvent Cement
CHEMICAL NAME/CLASS: ABS / Solvent Mixture
PRODUCT USE: Solvent Cement for ABS Material
COMPANY: Genova Products Inc.
U.S. BUSINESS PHONE: 1-800-521-7488; 1-810-744-4500
U.S. ADDRESS: 7034 E. Court St.
Davison, MI 48423
U.S. EMERGENCY PHONE: CHEMTREC:
1-800-424-9300 (U.S. and Canada)
1-703-527-3887 (International)
DATE OF PREPARATION: November 12 2008
2. COMPOSITION and INFORMATION ON INGREDIENTS
CHEMICAL CAS # EINECS # % w/w EXPOSURE LIMITS IN AIR
NAME
ACGIH OSHA
TLV STEL PEL STEL IDLH OTHER
ppm Ppm ppm ppm ppm
NIOSH REL:
Acetone 67-64-1 200-662-2 10 ?30% 500 A4 (Not 750 1000 NE 2500
TWA = 250
Classifiable as (based
750 1000
a Human on LEL)
DFG MAK: 500
(vacated (vacated
Carcinogen)
1989 1989 PEL)
Carcinogen: EPA-
PEL)
D
NIOSH REL:
Methyl Ethyl 78-93-3 201-159-0 50-75% 200 300 200 300 3000
Ketone (vacated
TWA = 200
1989 PEL)
STEL = 300
DFG MAK: 200
Carcinogen: EPA-
D
ABS Resin 9003-56-9 NA 18-40% NE NE NE 300 ppm NE OSHA TWA 200
NE = Not Established. C = Ceiling Limit. See Section 16 for Definitions of Terms Used.
NOTE: All WHMIS and EC required information is included. It is located in appropriate sections based on the ANSI Z400.1-1993 format.
ABS CEMENT PRODUCTS
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3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW: This is an extremely flammable liquid with an ether-like odor. Inhalation overexposures to
the vapors of this product can cause central-nervous system effects (e.g., dizziness, drowsiness, nausea, and
headaches). This product can be mildly to severely irritating to the eyes, skin, and other contaminated tissue. Vapors of
this product are heavier than air and may travel to a source of ignition and flashback to a leak or open container.
Emergency responders must wear the proper personal protective equipment (and have appropriate fire protection)
suitable for the situation to which they are responding.
SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The most significant routes of occupational overexposure
are inhalation and contact with skin and eyes. The symptoms of overexposure to this product, via route of exposure, are as
follows:
INHALATION: Inhalation of vapors, mists, or sprays of this product can be irritating to the nose, throat, mucous membranes,
and other tissues of the respiratory system. Symptoms of overexposure
can include coughing, sneezing, and shortness of breath. Additionally, the HAZARDOUS MATERIAL INFORMATION SYSTEM
components of this product are central nervous system depressants.
Symptoms of over-exposure can include drowsiness, dizziness, headache,
HEALTH (BLUE) 2
nausea, and general anesthetic effects. Inhalation of high concentrations of
this product (as may occur in a poorly ventilated area) may be fatal.
This product must be used with adequate ventilation. Mechanical
exhaust may be needed. Ensure exposure to vapors is minimized by use of
FLAMMABILITY (RED) 3
appropriate engineering controls, work practices, and personal protective
equipment, as described in the remainder of this document.
CONTACT WITH SKIN or EYES: Contact with this product can be irritating
to contaminated skin and eyes. Vapors of this product can redden and
REACTIVITY (YELLOW) 0
irritate the eyes. If the eyes are contaminated with splashes, sprays or
mists of this product, reddening, tearing, and corneal opacity can occur. The
liquid can be mildly to severely irritating to contaminated skin (depending on
C/D
duration of exposure). Prolonged or repeated skin over-exposures can lead PROTECTIVE EQUIPMENT
to dermatitis.
EYES HANDS BODY
RESPIRATORY
SKIN ABSORPTION: Skin absorption is not reported to be a significant
SEE SECTION 8
route of exposure for any component of this product.
INGESTION: Ingestion is not anticipated to be a significant route of
For routine applications.
occupational overexposure for this product. If ingestion occurs, refer to
Section 4 (First-Aid Measures) and get medical help immediately. If
ingestion of this product does occur, symptoms of such over-exposure can See Section 16 for Definition of Ratings
include nausea, vomiting, and other symptoms described for "Inhalation".
Ingestion can also lead to liver and kidney damage. Ingestion of this product may be fatal.
INJECTION: Injection is not anticipated to be a significant route of over-exposure for this product. If injection does occur (i.e.
through a puncture by an object contaminated with the product), local irritation and swelling can occur. Additional symptoms
may include those described for "Inhalation".
HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms.
ACUTE: Over-exposures to this product can be irritating to the eyes, skin, and mucous membranes, and can also cause
central-nervous system effects (dizziness, drowsiness, nausea and headaches). Ingestion of this product, or inhalation of
high concentrations of this product's vapors, may be fatal.
CHRONIC: Prolonged or repeated skin exposures can lead to dermatitis (dryness, reddening and irritation of the skin).
There is limited evidence from animal studies that Methyl Ethyl Ketone, a component of this product, is a reproductive toxin.
Refer to Section 11 (Toxicological Information) for additional information.
TARGET ORGANS: Acute: Skin, eyes, respiratory system, central nervous system. Chronic: Liver, kidneys.
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PART II What should I do if a hazardous situation occurs?
4. FIRST-AID MEASURES
SKIN EXPOSURE: If this product contaminates the skin, immediately begin decontamination with running water. Minimum
flushing is for 15 minutes. Remove exposed or contaminated clothing, taking care not to contaminate eyes. The
contaminated individual must seek medical attention if any adverse effect occurs.
EYE EXPOSURE: If this product's liquid or vapors enter the eyes, open victim's eyes while under gently running water. Use
sufficient force to open eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes. The contaminated individual
must seek immediate medical attention.
INHALATION: If vapors, mists, or sprays of this product are inhaled, remove victim to fresh air. If necessary, use artificial
respiration to support vital functions. Remove or cover gross contamination to avoid exposure to rescuers.
INGESTION: If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT
INFORMATION. If professional advice is not available, do not induce vomiting. The contaminated individual should drink
milk, egg whites, or large quantities of water. Never induce vomiting or give diluents (milk or water) to someone who is
unconscious, having convulsions, or unable to swallow.
The contaminated individual must be taken for medical attention, especially if any adverse effect occurs. Rescuers should be
taken for medical attention, if necessary. Take a copy of label and MSDS to health professional with victim.
5. FIRE-FIGHTING MEASURES
The following information is variable, depending on the blend. The following
NFPA RATING
information is for the main solvent component of this product.
FLASH POINT: FLAMMABILITY
Methyl Ethyl Ketone: -9癈 (15癋) 3
AUTOIGNITION TEMPERATURE:
2 0
Methyl Ethyl Ketone: 404癈 (759癋) HEALTH REACTIVITY
FLAMMABLE LIMITS (in air by volume):
Methyl Ethyl Ketone: Lower (LEL): 1.8% Upper (UEL): 10.0%
OTHER
The following information is for the product.
FIRE EXTINGUISHING MATERIALS:
See Section 16 for
Water Spray: YES (for cooling only) Carbon Dioxide: YES Definition of Ratings
Foam: YES Dry Chemical: YES
Halon: YES Other: Any "B" Class.
UNUSUAL FIRE AND EXPLOSION HAZARDS: This is a Class I-B Flammable Liquid. When involved in a fire, this material
may ignite and produce irritating vapors and toxic gases (e.g., carbon monoxide, carbon dioxide). This material will readily
ignite at room temperature. The vapors are heavier than air and may travel to a source of ignition, and flash back to a leak or
open container.
Explosion Sensitivity to Mechanical Impact: Not sensitive.
Explosion Sensitivity to Static Discharge: The vapors of this product can be ignited by static electrical energy.
SPECIAL FIRE-FIGHTING PROCEDURES: Incipient fire responders should wear eye protection. Structural firefighters
must wear Self-Contained Breathing Apparatus and full protective equipment. If it is safe to do so, allow small fires involving
this product to burn-out, while protecting exposures. If possible, prevent runoff water from entering storm drains, bodies of
water, or other environmentally sensitive areas. If necessary, rinse contaminated equipment thoroughly before returning
such equipment to service.
6. ACCIDENTAL RELEASE MEASURES
RELEASE RESPONSE: In case of a spill, clear the affected area and protect people. Uncontrolled releases should be
responded to by trained personnel using pre-planned procedures. Proper protective equipment should be used.
Small releases (e.g., 1-pint) must be cleaned-up by personnel wearing gloves, goggles, and appropriate eye protection.
Face shields must be worn if splashes or sprays of this product may be generated. In the event of a non-incidental release
(e.g., five, 1-gallon containers leaking simultaneously in a poorly-ventilated area), the minimum Personal Protective
Equipment should be Level B: triple-gloves (rubber gloves and nitrile gloves, over latex gloves), chemically resistant
suit and boots, hard-hat, and Self-Contained Breathing Apparatus. Level B should always be used during responses in
which the oxygen level is below 19.5% or unknown.
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6. ACCIDENTAL RELEASE MEASURES (Continued)
Eliminate all sources of ignition before spill clean-up begins. Use non-sparking tools. Absorb spilled liquid with activated
carbon, polypads or other suitable absorbent materials. Monitor the area for combustible vapors and the level of oxygen.
Monitoring must indicate less than 10% of the LEL (see Section 5, Fire-Fighting Measures) and greater than 19.5% Oxygen
is in the atmosphere before personnel are permitted in the area without Level B Protection. Place all spill residue in an
appropriate container and seal. Dispose of in accordance with U.S. Federal, State, or local procedures, the applicable
standards of Canada and its Provinces, or the appropriate requirements of European Community member States (see
Section 13, Disposal Considerations).
PART III How can I prevent hazardous situations from occurring?
7. HANDLING and STORAGE
WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU.
Wash thoroughly after handling this product. Do not eat, drink, smoke, or apply cosmetics while handling this product. Avoid
breathing vapors or mists generated by this product. Use in a well-ventilated location. Remove contaminated clothing
immediately.
STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained to handle it safely.
Containers of this product must be properly labeled. If this mixture is used in other types of containers, only use portable
containers approved for flammable liquids. Post "NO SMOKING" signs, where appropriate in storage and use areas. Use
non-sparking tools. Bond and ground during transfer of material. Store containers of in a cool, dry location, away from direct
sunlight, sources of intense heat, or where freezing is possible. Material should be stored in secondary containers, or in a
diked area, as appropriate. Store containers away from incompatible chemicals. Keep container tightly closed when not in
use. Storage areas should be made of fire-resistant materials. Inspect all incoming containers before storage, to ensure
containers are properly labeled and not damaged. Refer to NFPA 30, Flammable and Combustible Liquids Code for
additional information on storage. Empty containers may contain residual flammable liquid or vapors. Therefore, empty
containers should be handled with care. Do not expose "empty" containers to welding touches, or any other source of
ignition.
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in
Section 6 (Accidental Release Measures). Make certain that application equipment is locked and tagged-out safely, if
necessary. Collect all rinsates and dispose of according to applicable U.S. Federal, State, or local procedures, the
applicable standards of Canada and its Provinces, or the appropriate requirements of European Community member States.
8. EXPOSURE CONTROLS - PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation. Mechanical exhaust may be needed.
Emergency eye-wash/safety showers: where there is any possibility that an employee's eyes may be exposed to this
substance, the employer should provide an eye-wash fountain/safety shower within the immediate work area for emergency
use.
RESPIRATORY PROTECTION: Respiratory protection is not generally needed when using this product. Maintain airborne
contaminant concentrations below guidelines listed in Section 2 (Composition, Information on
Ingredients). If respiratory protection is needed, use only protection authorized in 29 CFR
1910.134 or applicable State regulations. Use supplied air respiration protection if oxygen levels
are below 19.5% or are unknown.
EMERGENCY OR PLANNED ENTRY INTO UNKNOWN CONCENTRATIONS OR IDLH CONDITIONS: Positive pressure,
full-facepiece SCBA or positive pressure, full-facepiece SAR with an auxiliary positive pressure
SCBA.
ESCAPE: Gas mask with organic vapor canister or escape-type SCBA.
EYE PROTECTION: Splash goggles or safety glasses. Face shield should be worn when working in situations in which
splashes or sprays can be generated.
HAND PROTECTION: Wear gloves for routine industrial use to protect hands from contact. For long exposures, or unusual
contact, such as spill cleanup, chemical resistant gloves may be required. See section 6.
BODY PROTECTION: Use body protection appropriate for task (e.g., Apron or Tyvek suit).
9. PHYSICAL and CHEMICAL PROPERTIES
RELATIVE VAPOR DENSITY (air = 1): > 1 EVAPORATION RATE (nBuAc = 1): > 1
SPECIFIC GRAVITY (water = 1): < 1.0 FREEZING/MELTING POINT: Not established.
SOLUBILITY IN WATER @ 25癈: Somewhat soluble. BOILING POINT: Not established.
VAPOR PRESSURE, mm Hg @ 20癈: Not established. pH: Not established.
ODOR THRESHOLD: Not established.
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COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): Not established.
9. PHYSICAL and CHEMICAL PROPERTIES (Continued)
ODOR THRESHOLD: 2.48-3.47 ppm FORM: Liquid.
COLOR: Variable color. ODOR: Ethereal.
VISCOSITY: Not available. FLASH POINT: Methyl Ethyl Ketone: -9癈 (15癋)
HOW TO DETECT THIS SUBSTANCE (warning properties): The color and odor of the product may be distinctive properties
of this product.
10. STABILITY and REACTIVITY
STABILITY: Stable.
DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, silicon and chloride compounds.
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: This product will not be compatible with strong oxidizers,
lithium aluminum hydride, and alkaline earth hydroxides.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Avoid exposure or contact to extreme temperatures, sources of ignition, incompatible chemicals.
PART IV Is there any other useful information about this material?
11. TOXICOLOGICAL INFORMATION
TOXICITY DATA: The specific toxicology data available for components greater than 1% in concentration are as follows:
TCLo - Inhalation - mouse: 3000 ppm/7H: Sex chromosome loss and nondisjunction:
female 6-15 day(s) after conception: Yeast - Saccharomyces cerevisiae: 47600
METHYL ETHYL KETONE:
Reproductive - Effects on Embryo or ppm
Eye effects-Human 350 ppm
Fetus - fetotoxicity
Skin-Rabbit, adult 500 mg/24 hours; Moderate
irritation effects Skin-Rabbit, adult 402
ACETONE:
mg/24 hours; Mild irritation effects
Eye Irritancy (human) = 500 ppm
Skin-Rabbit, adult 13,780 mg/24H open Mild
Skin Irritancy (rabbit) = 395 mg/ open; mild
irritation effects
Skin Irritancy (rabbit) = 500 mg/ 24 hours;
Eye effects-Rabbit, adult 80 mg
mild
Sex Chromosome Loss and Nondisjunction -
Eye Irritancy (rabbit) = 3950 g; severe
Saccharomyces cerevisiae; 33,800 ppm
Eye Irritancy (rabbit) = 20 mg/ 24 hours;
Inhalation-Rat TCLo: 1000 ppm/(6-15D
moderate
preg):Teratogenic effects
Cytogenetic Analysis (Saccharomyces
Inhalation-Human TCLo: 100 ppm/ 5
cerevisiae) = 200 mmol/tube
minutes: Irritant effects
Sex Chromosome Loss and Nondisjunction
Oral-Rat LD50: 2737 mg/kg
(Saccharomyces cerevisiae) = 47,600
Inhalation-Rat LC50: 23,500 mg/m3/8 hours;
ppm
Intraperitoneal-Rat LD50: 607 mg/kg 3
TDLo (inhalation, man) = 440 g/m / 6
Oral-Mouse LD50: 4050 mg/kg 3
TDLo (inhalation, man) = 10 mg/m / 6
Inhalation-Mouse LC50: 40 g/m3/2 hours
hours
Intraperitoneal-Mouse LD50: 616 mg/kg
TCLo (inhalation, human) = 500 ppm; eye
Skin-Rabbit, adult LD50: 6450 mg/kg
effects
Intraperitoneal-Guinea Pig, adult LDLo: 2 g/kg
TCLo (inhalation, man) = 12,000 ppm/ 4
Inhalation-Unspecified effects LC50: 38 g/m3
hours; gastrointestinal tract effects
Inhalation-Rat TCLo: 5000 ppm/6H/90 days -
LD50 (intravenous, rat) = 5500 mg/kg
Intermittent
LD50 (oral, rat) = 5800 mg/kg
TDLo - Subcutaneous - cat: 55500 mg/kg/37 3
LC50 (inhalation, rat) = 50,100 mg/m / 8
weeks - Intermittent: Reproductive -
hours
Tumorigenic effects - other reproductive
LDLo (intraperitoneal, rat) = 500 mg/kg
system tumors
LD50 (intravenous, rat) = 5500 mg/kg
TCLo - Inhalation - rat: 3000 ppm/7 hours:
LD50 (oral, mouse) = 3000 mg/kg
female 6-15 day(s) after conception: 3
LCLo (inhalation, mouse) = 110 g/m / 1
Reproductive - Specific Developmental
hour
Abnormalities - craniofacial (including
LD50 (intraperitoneal, mouse) = 1297 mg/kg
nose and tongue) , urogenital system ,
LDLo (intravenous, mouse) = 4 g/kg
homeostasis
LDLo (oral, dog) = 8 g/kg
TCLo - Inhalation - rat: 1000 ppm/7 hours:
LD50 (oral, rabbit) = 5340 mg/kg
female 6-15 day(s) after conception:
LD50 (skin, rabbit) = 20 g/kg
Reproductive - Effects on Embryo or
TDLo - Oral - rat: 273 gm/kg: male 13
Fetus - fetotoxicity (except death, e.g.,
week(s) pre-mating: Reproductive -
stunted fetus) Reproductive - Specific
Paternal Effects - spermatogenesis
Developmental Abnormalities -
TCLo - Inhalation: Mammal - species
musculoskeletal system
unspecified: 31500 ug/m3/24H: female
1-13 day(s) after conception
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11. TOXICOLOGICAL INFORMATION (Continued)
This product's components are not found on the following lists: FEDERAL OSHA Z LIST, NTP, IARC, and CAL/OSHA and
therefore are neither considered to be nor suspected to be cancer-causing agents by these agencies.
IRRITANCY OF PRODUCT: This product is expected to mildly to severely irritate the skin and eyes.
SENSITIZATION TO THE PRODUCT: No component of this product is known to be a sensitizer with prolonged or repeated
use.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of this product and its
components on the human reproductive system.
Mutagenicity: This product is not reported to produce mutagenic effects in humans. Animal mutation data are available
for Methyl Ethyl Ketone (components of this product); these data were obtained during clinical studies on specific animal
tissues or micro-organisms exposed to high doses of these compounds.
Embryotoxicity: This product is not reported to produce embryotoxic effects in humans.
Teratogenicity: This product is not reported to cause teratogenic effects in humans. Three animal studies involving
Methyl Ethyl Ketone (a component of this product) have shown fetotoxicity (skeletal anomalies) at doses, which did not
produce significant maternal toxicity.
Reproductive Toxicity: This product is not reported to cause reproductive effects in humans. Reproductive toxicity data
are available for Methyl Ethyl Ketone (a component of this product); these data were obtained from clinical studies on test
animals exposed to relatively high doses.
A mutagen is a chemical which causes permanent changes to genetic material (DNA) such that the changes will propagate
through generational lines. An embryotoxin is a chemical, which causes damage to a developing embryo (i.e. within the first
eight weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a
chemical which causes damage to a developing fetus, but the damage does not propagate across generational lines. A
reproductive toxin is any substance which interferes in any way with the reproductive process.
ACGIH BIOLOGICAL EXPOSURE INDICES: Currently, there are ACGIH Biological Exposure Indices (BEIs) associated with
components of this product, as follows:
CHEMICAL DETERMINANT SAMPLING TIME BEI
ACETONE
?Acetone in urine ?End of shift ?100 mg/L
METHYL ETHYL KETONE (MEK)
?MEK in urine ?End of shift ?2 mg/L
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Preexisting respiratory problems, dermatitis, and other skin
disorders, as well as conditions involving the "Target Organs" (see Section 3, Hazard Identification) can be aggravated by
exposure to this product.
RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate overexposure. If necessary, review for brain and
central nervous system effects and conduct pulmonary function test. Other tests for lung, kidney, and liver effects may also
prove useful.
12. ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ENVIRONMENTAL STABILITY: The components of this product will biodegrade into other organic compounds.
Environmental data are available for components of this product, as follows:
METHYL ETHYL KETONE: Log Kow = 0.29. Water Solubility = 239,000 mg/L. Methyl Ethyl Ketone is rapidly volatilized from water and undergoes slow
biodegradation. It undergoes moderate atmospheric photodegradation.
EFFECT OF MATERIAL ON PLANTS or ANIMALS: This product can be harmful or fatal to contaminated plant or animal life,
especially if released in large quantities into the environment. Refer to Section 11 (Toxicological Information) for information
regarding the effect of this product's components on test animals.
EFFECT OF CHEMICAL ON AQUATIC LIFE: This product can be harmful or fatal to contaminated aquatic plant or animal
life, especially if released in large quantity in a body of water. The following aquatic toxicity data are available for the
components of this product:
EFFECT OF CHEMICAL ON AQUATIC LIFE:
ACETONE:
LC50 (Japanese quail) = 40,000 ppm, in diet, age 14 days, (no mortality to 40,000 ppm)
LC50 (Ring-necked pheasant) = 40,000 ppm, in diet, age 10 days, (no mortality to 40,000 ppm)
LC50, F (fingerling trout) = 6,100 mg/L/ 24 hours
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12. ECOLOGICAL INFORMATION (Continued)
ACETONE (continued):
LC50 (Salmo gairdeneri, rainbow trout) = 5,540 mg/L/ 86 hours/ 12癈; (95% confidence limit 4,740-6,330 mg/L) , wt 1.0 g (static bioassay)
LD100 (Asellus aquaticus) = 3 mL/L/ within 3 days; (within 3 days of exposure) (conditions of bioassay not specified)
LD100 (Gamarus fossarum) = 10 mL/L/ within 48 hours; (conditions of bioassay not specified)
LC50 (Pimephaleus promelas) = 8,120 mg/L/ 96 hours, (conditions of bioassay not specified)
TLm (Daphnia magna) = 10 mg/L/ 24 and 48 hours, (conditions of bioassay not specified)
TLm (brine shrimp) = 2100 mg/L 24 and 48 hours, (conditions of bioassay not specified)
TLm (mosquito fish) = 13000 mg/L/ 24, 48, and 96 hours, (conditions of bioassay not specified)
LC50 (Lepomis macrochirus, bluegill sunfish) = 8300 mg/L 96 hours, (conditions of bioassay not specified)
LD50 (goldfish) = 5000 mg/L/ 24 hours, (conditions of bioassay not specified)
LC50 (Poecilia reticulata, guppy) = 7,032 ppm/ 14 days, (conditions of bioassay not specified)
LC50 (Mexican axolotl) = 20.0 mg/L/ 48 hours/ 3-4 weeks after hatching, (conditions of bioassay not specified)
LC50 (clawed toad) = 24.0 mg/L/ 48 hours/ 3-4 weeks after hatching, (conditions of bioassay not specified)
METHYL ETHYL KETONE:
EC0 (Scenedesmus quadricauda, green algae) = 4300 mg/L/ 8 days
EC0 (Entosiphon sulcatum, protozoa) = 190 mg/L/ 72 hours
EC0 (Uronema parduczi Chatton-Lwoff, protozoa) = 2830 mg/L
EC0 (Pseudomonas putida, bacteria) = 1150 mg/L/ 16 hoursC50 (Pimephales promelas, fathead minnow) = 3200 mg/L/96 hour
VOC INFORMATION: This product emits VOC's (volatile organic compounds) in its use. Make sure that use of this
product complies with local VOC emission regulations, where they exist.
VOC Level: 325 g/l per SCAQMD Test Method 316A
13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate U.S. Federal, State, and
local regulations, those of Canada and its Provinces, as well as those applicable to the EC Member States. This product, if
unaltered by use, may be disposed of by treatment at a permitted facility or as advised by your local hazardous waste
regulatory authority.
U.S. EPA WASTE NUMBER: D001 (Characteristic/Ignitability)
14. TRANSPORTATION INFORMATION
THIS MATERIAL IS HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF
TRANSPORTATION.
PROPER SHIPPING NAME: Flammable Liquid nos (acetone, methyl ethyl ketone)
HAZARD CLASS NUMBER and DESCRIPTION: 3 (Flammable Liquid)
UN IDENTIFICATION NUMBER: UN 1993
PACKING GROUP: II
DOT LABEL(S) REQUIRED: Flammable Liquid
NOTE: Shipments of containers holding 1-liter or less in volume qualify for a "Limited Quantity" exception. Refer to 49 CFR
173.150 for additional information.
NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER, 1996: 127
MARINE POLLUTANT: No component of this product is designated as a Marine Pollutant by the DOT (per 49 CFR
172.101, Appendix B).
TRANSPORT CANADA, TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: THIS MATERIAL IS
CONSIDERED AS DANGEROUS GOODS. Use the above information for the preparation of Canadian Shipments.
IMO DESIGNATION: THIS MATERIAL IS CONSIDERED AS DANGEROUS GOODS BY THE INTERNATIONAL
MARITIME ORGANIZATION
PROPER SHIPPING NAME: Flammable Liquid, n.o.s. (acetone, methyl ethyl ketone)
HAZARD CLASS NUMBER and DESCRIPTION: 3.2 (Flammable Liquid; Intermediate Flash Point)
UN IDENTIFICATION NUMBER: UN 1993
PACKING GROUP: II
LABEL(S) REQUIRED: Flammable Liquid
IMDG CODE: 3230
MARINE POLLUTANT: This product is not designated by the IMO to be a Marine Pollutant.
EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD
(ADR): This material is considered by the United Nations Economic Commission for Europe to be dangerous goods.
Additional information is as follows:
Substance Identification No.: 1993
Name of Substance: Flammable liquid, n.o.s.
Hazard Identification No. (Description): 33
Label: Flammable Liquid
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Class and Item Number: 3,1?(a), 2?(a), (b), 3?(b), 5?(c)
15. REGULATORY INFORMATION
ADDITIONAL UNITED STATES REGULATIONS:
U.S. SARA REPORTING REQUIREMENTS: The components of this product are subject to the reporting requirements of
Sections 302, 304, and 313 of Title III of the Superfund Amendments and Reauthorization Act, and are listed as follows:
CHEMICAL NAME SARA 302 SARA 304 SARA 313
(40 CFR 355, Appendix (40 CFR Table 302.4) (40 CFR 372.65)
A)
Acetone No Yes No
Methyl Ethyl Ketone No Yes Yes
U.S. SARA THRESHOLD PLANNING QUANTITY: Not applicable.
U.S. CERCLA REPORTABLE QUANTITY (RQ): Acetone = 5000 lb.; Methyl Ethyl Ketone: 5000 lb.;
U.S. TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
OTHER U.S. FEDERAL REGULATIONS: Not applicable.
U.S. STATE REGULATORY INFORMATION: Components of this product are covered under specific State regulations, as
denoted below:
Alaska - Designated Toxic and Hazardous Massachusetts - Substance List: Acetone, Pennsylvania - Hazardous Substance List:
Methyl Ethyl Ketone Acetone, Methyl Ethyl Ketone
Substances: Acetone, Methyl Ethyl Ketone
Michigan - Critical Materials Register: No. Rhode Island - Hazardous Substance List:
California - Permissible Exposure Limits for
Acetone, Methyl Ethyl Ketone
Minnesota - List of Hazardous Substances:
Chemical Contaminants: Acetone, Methyl
Acetone, Methyl Ethyl Ketone Texas - Hazardous Substance List: Acetone,
Ethyl Ketone
Methyl Ethyl Ketone
Missouri - Employer Information/Toxic
Florida - Substance List: Acetone, Methyl Ethyl
West Virginia - Hazardous Substance List:
Ketone Substance List: Acetone, Methyl Ethyl
Acetone, Methyl Ethyl Ketone
Ketone
Illinois - Toxic Substance List: Acetone,
Wisconsin - Toxic and Hazardous
Methyl Ethyl Ketone New Jersey - Right to Know Hazardous
Substances: Acetone, Methyl Ethyl Ketone
Kansas - Section 302/313 List: Acetone, Methyl Substance List: Acetone, Methyl Ethyl
Ethyl Ketone Ketone
North Dakota - List of Hazardous Chemicals,
Reportable Quantities: Acetone, Methyl
Ethyl Ketone
CALIFORNIA, SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): This product may
contain trace constituents, such as vinyl chloride, present in one of the product's components. Under common usage,
exposures to these trace constituents at levels exceeding the "no significant risk level" (NSRL) would not occur. Users are
expected to follow normal PPE and ventilation guidelines such as those in section 8 and other portions of this MSDS.
VOC Information: This product emits volatile organic compounds (VOC's) during use and cure. Users should determine if
local regulations regarding use of VOC containing products exist in their area and if this product complies.
ANSI STANDARD LABELING (Z129.1): DANGER! EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPOR MAY
CAUSE FLASH FIRE. MAY BE HARMFUL IF INHALED. MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS. MAY
CAUSE SKIN AND EYE IRRITATION. ASPIRATION HAZARD - CAN CAUSE LIFE-THREATENING LUNG DAMAGE IF
SWALLOWED. MAY CAUSE REPRODUCTIVE EFFECTS, BASED ON ANIMAL TESTS. Keep away from heat, sparks,
and flame. Avoid breathing vapor or mists. Avoid contact with skin or clothing. Use only with adequate ventilation. Keep
container closed. Wash thoroughly after handling. The recommended storage temperature is 21-32癈 (70-90癋).
Recommended maximum shelf life for unopened containers is 2 years. FIRST AID: In case of contact, immediately flush
skin or eyes for at least 15 minutes. If inhaled, move to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. IN CASE OF FIRE: Use fog, foam, dry chemical or CO2. Liquid will float and may re-ignite on the
surface of water. IN CASE OF SPILL: Absorb spill with inert material (e.g. activated carbon) then place in suitable container.
Refer to Material Safety Data Sheet for additional information on this product.
ADDITIONAL CANADIAN REGULATIONS:
CANADIAN DSL/NDSL INVENTORY STATUS: The components of this product are on the DSL Inventory.
OTHER CANADIAN REGULATIONS: Not applicable.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LIST: The components of this
product are not on the CEPA Priorities Substances List.
CANADIAN WHMIS SYMBOLS: Class B2: Flammable Liquid
Class D2A/B: Materials Causing Other Toxic Effects
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15. REGULATORY INFORMATION (Continued)
EUROPEAN COMMUNITY INFORMATION:
EUROPEAN COMMUNITY INFORMATION FOR PRODUCT:
EC LABELING AND CLASSIFICATION: Based on the information on the product's components and an assessment of the
physical and health hazards associated with the material, the following assignments have been made (per council directive
67/548/EEC)
EC CLASSIFICATION: Highly flammable. Irritant. [F;Xi]
EC RISK PHRASES: Highly flammable.. Irritating to eyes and respiratory system. [R:11-19-36/37]
EC SAFETY PHRASES: Keep out of reach of children.* Keep away from sources of ignition - No smoking. Do not
empty into drains. Do not breathe vapors. Avoid contact with the eyes. Take precautionary measures against static
discharges. [S:(2-)*16-23-25-29-33] *This safety phrase can be omitted from the label when the substance or
preparation is sold for industrial use only.
EUROPEAN COMMUNITY ANNEX II HAZARD SYMBOLS:
EUROPEAN COMMUNITY INFORMATION FOR CONSTITUENTS: The following information is available for primary
constituents in the components of this product.
ACETONE:
EC CLASSIFICATION: Highly flammable. [F]
EC RISK PHRASES: Highly flammable. [R: 11].
EC SAFETY PHRASES: Keep out of reach of children.* Keep container in a well-ventilated place. Keep away from sources of ignition. No smoking. Do
not breathe vapors. [S: (2-)*9-16-23-33].
EC COMMENTS: *This safety phrase can be omitted from the label when the substance or preparation is sold for industrial use only.
METHYL ETHYL KETONE:
EC CLASSIFICATION: Highly flammable. Irritant. [F; Xi] (
EC RISK PHRASES: Highly flammable. Irritating to the eyes and respiratory system. [R: 11-36/37].
EC SAFETY PHRASES: Keep out of reach of children.* Keep container in a well-ventilated place. Keep away from sources of ignition. No smoking.
Avoid contact with the eyes. Take precautionary measures against static discharges. [S: (2-)*9-16-25-33].
EC COMMENTS: *This safety phrase can be omitted from the label when the substance or preparation is sold for industrial use only.
EC COMMENTS :
CONCENTRATIONS GREATER THAN OR EQUAL TO 25 PERCENT: Irritant. Irritating to eyes and respiratory system. [Xi; R36/37]
16. OTHER INFORMATION
PREPARED BY: CHEMICAL SAFETY ASSOCIATES, Inc.
9163 Chesapeake Drive, San Diego, CA 92123-1002
619/565-0302
EDITED/UPDATED BY: John Brown, E-Z Weld, Inc
DATE OF PRINTING: March 27, 2009
The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of these
data or the results to be obtained from the use thereof. Cookson assumes no responsibility for injury to the vendee or third persons proximately caused
by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, Cookson assumes no responsibility for
injury to vendee or third persons proximately caused by abnormal use of the material even if reasonable safety procedures are followed. Furthermore,
vendee assumes the risk in his use of the material.
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DEFINITIONS OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these which are commonly used include the following:
CAS #: This is the Chemical Abstract Service Number which uniquely identifies each constituent. It is used for computer-related searching.
EXPOSURE LIMITS IN AIR: FLAMMABILITY LIMITS IN AIR:
Much of the information related to fire and explosion is derived from the National Fire
ACGIH - American Conference of Governmental Industrial Hygienists, a professional
association which establishes exposure limits. Protection Association (NFPA). Flash Point - Minimum temperature at which a liquid
gives off sufficient vapors to form an ignitable mixture with air. Autoignition
TLV - Threshold Limit Value - an airborne concentration of a substance which
Temperature: The minimum temperature required to initiate combustion in air with no
represents conditions under which it is generally believed that nearly all workers may
other source of ignition. LEL - the lowest percent of vapor in air, by volume, that will
be repeatedly exposed without adverse effect. The duration must be considered,
explode or ignite in the presence of an ignition source. UEL - the highest percent of
including the 8-hour Time Weighted Average (TWA), the 15-minute Short Term
vapor in air, by volume, that will explode or ignite in the presence of an ignition source.
Exposure Limit, and the instantaneous Ceiling Level (C). Skin absorption effects must
also be considered.
TOXICOLOGICAL INFORMATION:
OSHA - U.S. Occupational Safety and Health Administration.
Human and Animal Toxicology: Possible health hazards as derived from human
PEL - Permissible Exposure Limit - This exposure value means exactly the same as a
data, animal studies, or from the results of studies with similar compounds are
TLV, except that it is enforceable by OSHA. The OSHA Permissible Exposure Limits
presented. Definitions of some terms used in this section are: LD50 - Lethal Dose
are based in the 1989 PELs and the June, 1993 Air Contaminants Rule (Federal
(solids & liquids) which kills 50% of the exposed animals; LC50 - Lethal Concentration
Register: 58: 35338-35351 and 58: 40191). Both the current PELs and the vacated
(gases) which kills 50% of the exposed animals; ppm concentration expressed in
PELs are indicated. The phrase, "Vacated 1989 PEL," is placed next to the PEL
parts of material per million parts of air or water; mg/m3 concentration expressed in
which was vacated by Court Order.
weight of substance per volume of air; mg/kg quantity of material, by weight,
IDLH - Immediately Dangerous to Life and Health - This level represents a
administered to a test subject, based on their body weight in kg. Other measures of
concentration from which one can escape within 30-minutes without suffering escape-
toxicity include TDLo, the lowest dose to cause a symptom and TCLo the lowest
preventing or permanent injury. The DFG - MAK is the Republic of Germany's
concentration to cause a symptom; TDo, LDLo, and LDo, or TC, TCo, LCLo, and
Maximum Exposure Level, similar to the U.S. PEL. NIOSH is the National Institute of
LCo, the lowest dose (or concentration) to cause lethal or toxic effects. Cancer
Occupational Safety and Health, which is the research arm of the U.S. Occupational
Information: The sources are: IARC - the International Agency for Research on
Safety and Health Administration (OSHA). NIOSH issues exposure guidelines called
Cancer; NTP - the National Toxicology Program, RTECS - the Registry of Toxic
Recommended Exposure Levels (RELs). When no exposure guidelines are
Effects of Chemical Substances, OSHA and CAL/OSHA. IARC and NTP rate
established, an entry of NE is made for reference.
chemicals on a scale of decreasing potential to cause human cancer with rankings
HAZARD RATINGS: from 1 to 4. Subrankings (2A, 2B, etc.) are also used. Other Information: BEI -
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM: Health Hazard: 0 (minimal ACGIH Biological Exposure Indices, represent the levels of determinants which are
most likely to be observed in specimens collected from a healthy worker who has been
acute or chronic exposure hazard); 1 (slight acute or chronic exposure hazard); 2
exposed to chemicals to the same extent as a worker with inhalation exposure to the
(moderate acute or significant chronic exposure hazard); 3 (severe acute exposure
TLV. Ecological Information: EC is the effect concentration in water. BCF =
hazard; onetime overexposure can result in permanent injury and may be fatal); 4
Bioconcentration Factor, which is used to determine if a substance will concentrate in
(extreme acute exposure hazard; onetime overexposure can be fatal). Flammability
lifeforms which consume contaminated plant or animal matter. Coefficient of
Hazard: 0 (minimal hazard); 1 (materials that require substantial pre-heating before
Oil/Water Distribution is represented by log Kow or log Koc and is used to assess a
burning); 2 (combustible liquid or solids; liquids with a flash point of 38-93癈 [100-
substance's behavior in the environment.
200癋]); 3 (Class IB and IC flammable liquids with flash points below 38癈 [100癋]); 4
(Class IA flammable liquids with flash points below 23癈 [73癋] and boiling points
REGULATORY INFORMATION:
below 38癈 [100癋]. Reactivity Hazard: 0 (normally stable); 1 (material that can
U.S. AND CANADA: This section explains the impact of various laws and regulations
become unstable at elevated temperatures or which can react slightly with water); 2
on the material. U.S.: EPA is the U.S. Environmental Protection Agency. DOT is the
(materials that are unstable but do not detonate or which can react violently with
U.S. Department of Transportation. SARA is the Superfund Amendments and
water); 3 (materials that can detonate when initiated or which can react explosively
Reauthorization Act. TSCA is the U.S. Toxic Substance Control Act. CERCLA (or
with water); 4 (materials that can detonate at normal temperatures or pressures).
Superfund) refers to the Comprehensive Environmental Response, Compensation,
NATIONAL FIRE PROTECTION ASSOCIATION: Health Hazard: 0 (material that on
and Liability Act). Labeling is per the American National Standards Institute (ANSI
exposure under fire conditions would offer no hazard beyond that of ordinary
Z129.1). CANADA: CEPA is the Canadian Environmental Protection Agency.
combustible materials); 1 (materials that on exposure under fire conditions could
WHMIS is the Canadian Workplace Hazardous Materials Information System. TC is
cause irritation or minor residual injury); 2 (materials that on intense or continued
Transport Canada. DSL/NDSL are the Canadian Domestic/Non-Domestic
exposure under fire conditions could cause temporary incapacitation or possible
Substances Lists.
residual injury); 3 (materials that can on short exposure could cause serious temporary
EUROPEAN and INTERNATIONAL: EC is the European Community (formerly
or residual injury); 4 (materials that under very short exposure could cause death or
known as the EEC, European Economic Community). EINECS: This the European
major residual injury). Flammability Hazard and Reactivity Hazard: Refer to
Inventory of Now-Existing Chemical Substances. IMO is the International Maritime
definitions for "Hazardous Materials Identification System".
Organization. The ARD is the European Agreement Concerning the International
Carriage of Dangerous Goods by Road and the RID are the International Regulations
Concerning the Carriage of Dangerous Goods by Rail.
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