Material Safety Data Sheet
Preparation Date: 30-Dec-2009 Revision Date: 29-Dec-2009 Revision Number: 0
1. PRODUCT AND COMPANY IDENTIFICATION
Product Code F073-11WHA
Trade Name ENDURA-SHIELD WHITE
Contact Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372
Emergency Telephone Number 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
DANGER!
FLAMMABLE LIQUID AND VAPOR.
HARMFUL IF INHALED.
HARMFUL OR FATAL IF SWALLOWED.
MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.
MAY BE HARMFUL IF ABSORBED THROUGH SKIN.
Potential Health Effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute Effects
Eyes Moderately irritating to the eyes.
Skin Irritating to skin.
Inhalation Irritating to respiratory system. Respirable crystalline silica (quartz) can cause silicosis, a
fibrosis (scarring) of the lungs.
Ingestion May be harmful if swallowed.
Chronic Effects
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous
system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Cancer hazard.
Contains crystalline silica which can cause cancer. (Risk of cancer depends on duration and level of exposure.)
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions Central nervous system. Gastrointestinal tract. Kidney disorders. Liver disorders. Skin
disorders.
Interactions with Other Chemicals Use of alcoholic beverages may enhance toxic effects.
Potential Environmental Effects See Section 12 for additional Ecological information
Target Organ Effects Blood, Central nervous system, Gastrointestinal tract, Eyes, Kidney, Liver, Lungs,
Respiratory system, Skin
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3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Components
CAS-No Weight %
Component
13463-67-7 10 - 30
TITANIUM DIOXIDE (TOTAL DUST)
108-65-6 16.8532
PROPYLENE GLYCOL MONOMETHYL
ETHER ACETATE
14808-60-7 15.6602
CRYSTALLINE SILICA (QUARTZ)
78-93-3 3.6056
METHYL ETHYL KETONE
7631-86-9 1-5
AMORPHOUS SILICA
1344-28-1 1-5
ALUMINUM OXIDES
1330-20-7 1.6235
XYLENE
100-41-4 0.3795
ETHYL BENZENE
4. FIRST AID MEASURES
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes.
Skin Contact Wash off immediately with soap and plenty of water.
Ingestion If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable Properties Flammable.
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -
Foam - Dry chemical
Hazardous Decomposition Products Oxides of carbon, hydrocarbons.
Specific Hazards Arising from the Chemical
Thermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective Equipment and Precautions for Firefighters
Use water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away from
heat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers. Solvent vapors are heavier than
air and may spread along floors. Flash back possible over considerable distance.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove all
sources of ignition.
Environmental Precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary
sewer system.
Methods for Cleaning Up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated
absorbent, container and unused contents in accordance with local, state and federal
regulations.
Other Information Not applicable
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7. HANDLING AND STORAGE
Handling
Close container after each use. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. If
splashes are likely to occur, wear goggles. Wear protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum.
When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
Storage
Keep away from heat, sparks and flame. VAPORS MAY CAUSE FLASH FIRE. Use only in an area containing flame proof equipment.
Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and other sources of ignition during use and until all
vapors are gone. Prevent build-up of vapors by opening all windows and doors to achieve cross ventilation.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)
TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: 10 mg/m3 STEL:
TITANIUM DIOXIDE (TOTAL
15 mg/m3 20 mg/m3
DUST)
TWA: 270 mg/m3 TWA:
PROPYLENE GLYCOL
MONOMETHYL ETHER 50 ppm
ACETATE
TWA: 0.025 mg/m3 TWA: 0.1 mg/m3 TWA: 0.1 mg/m3 TWA: 0.10 mg/m3 TWA: 0.1 mg/m3
CRYSTALLINE SILICA
(QUARTZ)
TWA: 200 ppm TWA: TWA: 150 mg/m3 TWA:
METHYL ETHYL KETONE TWA: 200 ppm STEL: TWA: 200 ppm TWA: TWA: 200 ppm TWA:
590 mg/m3 STEL: 885 50 ppm STEL: 100 ppm 590 mg/m3 STEL: 300 590 mg/m3 STEL: 300
300 ppm
mg/m3 STEL: 300 ppm STEL: 300 mg/m3 ppm STEL: 885 mg/m3 ppm STEL: 885 mg/m3
3 3
TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: 10 mg/m3
ALUMINUM OXIDES TWA: 1 mg/m TWA: 10 mg/m TWA: 5
mg/m3 TWA: 15 mg/m3
TWA: 100 ppm STEL: TWA: 435 mg/m3 TWA: TWA: 434 mg/m3 TWA: TWA: 100 ppm TWA: TWA: 435 mg/m3 TWA:
XYLENE
435 mg/m3 STEL: 150
150 ppm 100 ppm STEL: 150 100 ppm STEL: 150 100 ppm STEL: 150
ppm STEL: 655 mg/m3 ppm STEL: 651 mg/m3 ppm STEL: 650 mg/m3 ppm STEL: 655 mg/m3
TWA: 100 ppm STEL: TWA: 435 mg/m3 TWA: TWA: 434 mg/m3 TWA:
ETHYL BENZENE TWA: 100 ppm TWA: TWA: 100 ppm TWA:
435 mg/m3 STEL: 125 435 mg/m3 STEL: 125
125 ppm 100 ppm STEL: 545 100 ppm STEL: 125
mg/m3 STEL: 125 ppm ppm STEL: 543 mg/m3 ppm STEL: 540 mg/m3 ppm STEL: 545 mg/m3
Engineering Measures Ensure adequate ventilation, especially in confined areas
Personal Protective Equipment
Skin Protection Lightweight protective clothing, Apron, Impervious gloves
Eye/face Protection If splashes are likely to occur, wear Goggles.
Respiratory Protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache or
dizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,
wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.
Follow respirator manufacturer's directions for respirator use.
General Hygiene Handle in accordance with good industrial hygiene and safety practice.
Considerations Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash Point 13癈 / 55.0癋
Boiling Point/Range 78 - 142癈 / 172.0 - 288.0癋
Upper Exposure Limits No information available
Lower Exposure Limits No information available
Evaporation Rate No information available
Vapour Pressure No information available
Vapour Density No information available
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9. PHYSICAL AND CHEMICAL PROPERTIES
Specific Gravity 1.52727
Density 12.70920
VOC Content (lbs/gal) 3.083
% Volatile by Weight 24.2590
% Volatile by Volume 40.3343
10. STABILITY AND REACTIVITY
Chemical stability Stable. Conditions to Avoid Heat, flames and sparks. Reacts
with air to form peroxides.
Incompatible Products Strong oxidizing agents. Acids. Possibility of Hazardous None under normal processing
Reactions
11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 Inhalation
TITANIUM DIOXIDE (TOTAL DUST) 10000 mg/kg ( Rat )
PROPYLENE GLYCOL 8532 mg/kg ( Rat ) 5000 mg/kg ( Rabbit )
MONOMETHYL ETHER ACETATE
CRYSTALLINE SILICA (QUARTZ) 500 mg/kg ( Rat )
METHYL ETHYL KETONE 2737 mg/kg ( Rat ) 6480 mg/kg ( Rabbit )
AMORPHOUS SILICA 5000 mg/kg ( Rat ) 2000 mg/kg ( Rabbit ) 2.2 mg/L ( Rat ) 1 h
ALUMINUM OXIDES 5000 mg/kg ( Rat )
XYLENE 4300 mg/kg ( Rat ) 1700 mg/kg ( Rabbit ) 47635 mg/L ( Rat ) 4 h 5000 ppm (
Rat ) 4 h
ETHYL BENZENE 3500 mg/kg ( Rat ) 15354 mg/kg ( Rabbit ) 17.2 mg/L ( Rat ) 4 h
Irritation No information available
Corrosivity No information available
Sensitization No information available
Chronic Toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Component ACGIH IARC NTP OSHA Mexico
TITANIUM DIOXIDE (TOTAL Group 2B X
DUST)
CRYSTALLINE SILICA A2 Group 1 Known X
(QUARTZ)
ETHYL BENZENE A3 Group 2B X
Mutagenic Effects No information available
Reproductive Effects No information available
Developmental Effects No information available
Teratogenicity No information available
Target Organ Effects Blood, Central nervous system, Gastrointestinal tract, Eyes, Kidney, Liver, Lungs,
Respiratory system, Skin.
Endocrine Disruptor Information No information available
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12. ECOLOGICAL INFORMATION
Ecotoxicity
.
Component Freshwater Algae Freshwater Fish Microtox Water Flea
PROPYLENE GLYCOL LC50= 161 mg/L Pimephales EC50 > 500 mg/L 48 h
MONOMETHYL ETHER promelas 96 h
ACETATE
METHYL ETHYL KETONE LC50= 3220 mg/L Pimephales EC50 = 3426 mg/L 5 min EC50 = 520 mg/L 48 h EC50 =
promelas 96 h LC50= 1690 EC50 = 3403 mg/L 30 min 5091 mg/L 48 h
mg/L Lepomis macrochirus 96
h
AMORPHOUS SILICA EC50 = 440 mg/L 72 h LC50= 5000 mg/L Brachydanio EC50 = 7600 mg/L 48 h
rerio 96 h
XYLENE LC50= 13.4 mg/L Pimephales EC50 = 0.0084 mg/L 24 h EC50 = 3.82 mg/L 48 h LC50
promelas 96 h LC50= 8.05 = 0.6 mg/L 48 h
mg/L Oncorhynchus mykiss 96
h LC50= 16.1 mg/L Lepomis
macrochirus 96 h LC50= 26.7
mg/L Pimephales promelas 96
h
ETHYL BENZENE EC50 = 4.6 mg/L 72 h EC50 > LC50= 14.0 mg/L EC50 = 9.68 mg/L 30 min EC50 1.8 - 2.4 mg/L 48 h
438 mg/L 96 h Oncorhynchus mykiss 96 h EC50 = 96 mg/L 24 h
LC50= 9.09 mg/L Pimephales
promelas 96 h LC50= 150.0
mg/L Lepomis macrochirus 96
h LC50= 4.2 mg/L
Oncorhynchus mykiss 96 h
LC50= 32 mg/L Lepomis
macrochirus 96 h LC50= 48.5
mg/L Pimephales promelas 96
h LC50= 9.6 mg/L Poecilia
reticulata 96 h
13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods Keep container tightly closed. If spilled, contain spilled material and remove with inert
absorbent. Dispose of contaminated absorbent, container and unused contents in accordance
with local, state and federal regulations.
Contaminated Packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for other modes of Transportation.
Proper Shipping Name UN1263,PAINT,3,PGIII,ERG 128
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Does not Comply
CHINA Does not Comply
ENCS Does not Comply
KECL Does not Comply
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PICCS Does not Comply
AICS Does not Comply
Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)
This product contains the following HAPs:
Component
XYLENE
ETHYL BENZENE
U.S. Federal Regulations
SARA 313
Component CAS-No Weight % SARA 313 - Threshold
Values
METHYL ETHYL KETONE 78-93-3 3.6056 1.0
XYLENE 1330-20-7 1.6235 1.0
ETHYL BENZENE 100-41-4 0.3795 0.1
SARA 311/312 Hazardous Categorization
Chronic Health Hazard No
Acute Health Hazard Yes
Fire Hazard Yes
Sudden Release of Pressure Hazard No
Reactive Hazard No
Component CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances
Quantities
XYLENE 100 lb X
ETHYL BENZENE 1000 lb X X X
CERCLA
Component Hazardous Substances RQs CERCLA EHS RQs
METHYL ETHYL KETONE 5000 lb
XYLENE 100 lb
ETHYL BENZENE 1000 lb
U.S. State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals:
Component CAS-No California Prop. 65
CRYSTALLINE SILICA (QUARTZ) 14808-60-7 Carcinogen
ETHYL BENZENE 100-41-4 Carcinogen
State Right-to-Know
Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island
TITANIUM DIOXIDE (TOTAL X X X X
DUST)
CRYSTALLINE SILICA X X X X
(QUARTZ)
METHYL ETHYL KETONE X X X X X
AMORPHOUS SILICA X X
ALUMINUM OXIDES X X X X
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XYLENE X X X X X
ETHYL BENZENE X X X X X
Other International Regulations
Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and
the MSDS contains all the information required by the CPR.
WHMIS Hazard Class
B2 Flammable liquid
D2A Very toxic materials
Component NPRI
PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE Part 5 Substance
METHYL ETHYL KETONE Part 1, Group 1 Substance; Part 5 Substance
ALUMINUM OXIDES Part 1, Group 1 Substance (fibrous form)
XYLENE Part 1, Group 1 Substance; Part 5 Substance
ETHYL BENZENE Part 1, Group 1 Substance
Legend
NPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date: 29-Dec-2009
Revision Summary No information available
HMIS Health 0 Flammability 0 Reactivity 1
Disclaimer
For specific information regarding occupational safety and health standards, please refer to the Code of Federal
Regulations, Title 29, Part 1910.
To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any
of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that
these are the only hazards which exist.
End of MSDS
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Material Safety Data Sheet
Preparation Date: 30-Dec-2009 Revision Date: 29-Dec-2009 Revision Number: 0
1. PRODUCT AND COMPANY IDENTIFICATION
Product Code F073-0073B
Trade Name ENDURA-SHIELD CONVERTER
Contact Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372
Emergency Telephone Number 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
DANGER!
HARMFUL IF INHALED.
MAY CAUSE LUNG INJURY.
MAY CAUSE ALLERGIC RESPIRATORY REACTION; EFFECTS MAY BE PERMANENT.
MAY CAUSE ALLERGIC SKIN REACTION; EFFECTS MAY BE PERMANENT.
HARMFUL OR FATAL IF SWALLOWED.
MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.
COMBUSTIBLE LIQUID AND VAPOR.
Potential Health Effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute Effects
Eyes Moderately irritating to the eyes. Risk of serious damage to eyes.
Skin Irritating to skin. May cause sensitization by skin contact.
Inhalation Irritating to respiratory system. May cause allergic respiratory reaction.
Ingestion May be harmful if swallowed.
Chronic Effects
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous
system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions No information available
Interactions with Other Chemicals No information available
Potential Environmental Effects See Section 12 for additional Ecological information
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Components
CAS-No Weight %
Component
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3. COMPOSITION/INFORMATION ON INGREDIENTS
28182-81-2 30 - 60
HEXAMETHYLENE DIISOCYANATE (HDI)
POLYMER
98-56-6 49.003
BENZENE, 1-CHLORO-4-
(TRIFLUOROMETHYL)-
822-06-0 0.357
HEXAMETHYLENE DIISOCYANATE (HDI)
MONOMER
4. FIRST AID MEASURES
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes.
Skin Contact Wash off immediately with soap and plenty of water.
Ingestion If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable Properties Combustible material.
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -
Foam - Dry chemical
Hazardous Decomposition Products Oxides of carbon, hydrocarbons. Oxides of nitrogen. Hydrogen cyanide. Chlorine. Fluorine.
Specific Hazards Arising from the Chemical
Keep product and empty container away from heat and sources of ignition
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective
gear.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove all
sources of ignition.
Environmental Precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary
sewer system.
Methods for Cleaning Up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated
absorbent, container and unused contents in accordance with local, state and federal
regulations.
Other Information Not applicable
7. HANDLING AND STORAGE
Handling
Use only with adequate ventilation.Avoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene
and safety practice. Remove and wash contaminated clothing before re-use. Do not eat, drink or smoke when using this product.
When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
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Storage
Close container after each use. Keep away from heat, sparks and flame. Use only in an area containing flame proof equipment.
Prevent build-up of vapors by opening all windows and doors to achieve cross ventilation.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)
TWA: 2.5 mg/m3 TWA: 2.5 mg/m3 TWA: 2.5 mg/m3
BENZENE, 1-CHLORO-4-
(TRIFLUOROMETHYL)-
TWA: 0.034 mg/m3
HEXAMETHYLENE TWA: 0.005 ppm TWA: 0.005 ppm TWA:
0.2 祄ol/m3 CEV: 0.02
DIISOCYANATE (HDI) TWA: 0.005 ppm
ppm CEV: 0.8 祄ol/m3
MONOMER
Engineering Measures Ensure adequate ventilation, especially in confined areas
Personal Protective Equipment
Skin Protection Lightweight protective clothing, Apron, Impervious gloves
Eye/face Protection Safety glasses with side-shields
Respiratory Protection INDIVIDUALS WITH LUNG OR BREATHING PROBLEMS OR PRIOR REACTION TO
ISOCYANATES MUST NOT BE EXPOSED TO VAPOR OR SPRAY MIST. Do not breathe
vapor or spray mist. Wear an appropriate, properly fitted respirator (NIOSH/MSHA approved)
during and after application unless air monitoring demonstrates vapor/mist levels are below
applicable limits. An airline respirator (TC 19C NIOSH/MSHA) is recommended. A vapor-
particulate respirator (TC 23C NIOSH/MSHA) may be appropriate where air monitoring
demonstrates vapors are less than ten times the applicable exposure limits and the
isocyanate concentration is less than its applicable exposure limit. The use of an air-supplied
respirator is mandatory whenever the airborne concentration of isocyanate monomer is
unknown.
General Hygiene Handle in accordance with good industrial hygiene and safety practice.
Considerations Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash Point 40癈 / 104癋
Method Pensky Martens - Closed Cup
Boiling Point/Range 139癈 / 282癋
Upper Exposure Limits No information available
Lower Exposure Limits No information available
Evaporation Rate No information available
Vapour Pressure No information available
Vapour Density No information available
Specific Gravity 1.23332
Density 10.26311
VOC Content (lbs/gal) .000
% Volatile by Weight 49.0030
% Volatile by Volume 44.9040
10. STABILITY AND REACTIVITY
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10. STABILITY AND REACTIVITY
Chemical stability Stable. Conditions to Avoid Heat, flames and sparks.
Amines.
Incompatible Products Strong oxidizing agents. Water, Possibility of Hazardous None under normal processing
alcohols, amines, strong bases, Reactions
metal components, surface
active materials.
11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Component Information
Component LD50 Oral LD50 Dermal LC50 Inhalation
18500 mg/m3 ( Rat ) 1 h
HEXAMETHYLENE DIISOCYANATE
(HDI) POLYMER
BENZENE, 1-CHLORO-4- 13 g/kg ( Rat ) 2 mg/kg ( Rabbit ) 33 mg/L ( Rat ) 4 h
(TRIFLUOROMETHYL)-
HEXAMETHYLENE DIISOCYANATE 710 mg/kg ( Rat ) 570 mg/kg ( Rabbit ) 0.29 mg/L ( Rat ) 1 h 0.15 mg/L ( Rat
(HDI) MONOMER )4h
Irritation No information available
Corrosivity No information available
Sensitization No information available
Chronic Toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Mutagenic Effects No information available
Reproductive Effects No information available
Developmental Effects No information available
Teratogenicity No information available
Target Organ Effects No information available
Endocrine Disruptor Information No information available
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
Component Freshwater Algae Freshwater Fish Microtox Water Flea
BENZENE, 1-CHLORO-4- EC50 = 11.1 mg/L 5 min EC50 EC50 = 3.68 mg/L 48 h
(TRIFLUOROMETHYL)- = 13.4 mg/L 15 min EC50 =
14.3 mg/L 30 min
HEXAMETHYLENE LC50= 26.1 mg/L Brachydanio EC50 = 53.2 mg/L 5 min EC50
DIISOCYANATE (HDI) rerio 96 h = 25.5 mg/L 15 min EC50 =
MONOMER 15.7 mg/L 30 min
13. DISPOSAL CONSIDERATIONS
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13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods Keep container tightly closed. If spilled, contain spilled material and remove with inert
absorbent. Dispose of contaminated absorbent, container and unused contents in accordance
with local, state and federal regulations.
Contaminated Packaging Empty containers should be taken for local recycling, recovery or waste disposal
14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for other modes of Transportation.
Proper Shipping Name PAINT IN OIL
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Complies
CHINA Complies
ENCS Does not Comply
KECL Complies
PICCS Complies
AICS Complies
Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)
This product contains the following HAPs:
Component
HEXAMETHYLENE DIISOCYANATE (HDI) MONOMER
U.S. Federal Regulations
SARA 313
Component CAS-No Weight % SARA 313 - Threshold
Values
HEXAMETHYLENE DIISOCYANATE (HDI) MONOMER 822-06-0 0.357 1.0
SARA 311/312 Hazardous Categorization
Chronic Health Hazard Yes
Acute Health Hazard Yes
Fire Hazard Yes
Sudden Release of Pressure Hazard No
Reactive Hazard No
Component CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances
Quantities
BENZENE, 1-CHLORO-4- X
(TRIFLUOROMETHYL)-
CERCLA
Component Hazardous Substances RQs CERCLA EHS RQs
HEXAMETHYLENE DIISOCYANATE (HDI) MONOMER 100 lb
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U.S. State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals:
State Right-to-Know
Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island
BENZENE, 1-CHLORO-4- X X X
(TRIFLUOROMETHYL)-
HEXAMETHYLENE X X X
DIISOCYANATE (HDI)
MONOMER
Other International Regulations
Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and
the MSDS contains all the information required by the CPR.
WHMIS Hazard Class
B3 Combustible liquid
D2A Very toxic materials
Legend
NPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date: 29-Dec-2009
Revision Summary No information available
HMIS Health 2 Flammability 2 Reactivity 1
Disclaimer
For specific information regarding occupational safety and health standards, please refer to the Code of Federal
Regulations, Title 29, Part 1910.
To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any
of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that
these are the only hazards which exist.
End of MSDS
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