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Sheet
Rust-Oleum Corp.
www.rustoleum.com
Section 1 - Chemical Product / Company Information
Industrial Choice Aerosol - Solvent
Product Name: Revision Date: 06/07/2006
Based Inverted Marking Paint
1634838, 1652838, 1668838, 1675838,
Identification
201516, 203022, 203024, 203025,
Number:
203026, 203029, 203030, 239007
Industrial Choice - Precision Line
Product Use/Class:
Marking Paint/Aerosol
Rust-Oleum Corporation Rust-Oleum Corporation
Supplier: Manufacturer:
11 Hawthorn Parkway 11 Hawthorn Parkway
Vernon Hills, IL 60061 Vernon Hills, IL 60061
USA USA
Preparer: Regulatory Department
Section 2 - Composition / Information On Ingredients
Chemical Name CAS Number Weight % Less Than ACGIH TLV-TWA ACGIH TLV-STEL OSHA PEL-TWA OSHA PEL -CEILING
Liquefied Petroleum Gas 68476-86-8 35.0 1000 PPM N.E. 1000 PPM N.E.
Acetone 67-64-1 30.0 500 PPM 750 PPM 750 PPM N.E.
Toluene 108-88 -3 20.0 50 PPM 150 PPM 200 PPM 300 PPM
Aliphatic Hydrocarbon 64742-89-8 15.0 300 PPM N.E. 300 PPM N.E.
Xylene 1330 -20-7 15.0 100 PPM 150 PPM 100 PPM N.E.
Titanium Dioxide 13463-67-7 15.0 10 mg/m3 N.E. 10 mg/m3 N.E.
N-Butyl Acetate 123-86 -4 15.0 150 PPM 200 PPM 150 PPM N.E.
Aliphatic Petroleum Distillates 64742-48-9 10.0 400 PPM N.E. 400 PPM N.E.
Naphtha 8032 -32-4 10.0 300 PPM N.E. N.E. N.E.
Magnesium Silicate 14807-96-6 5.0 10 mg/m3 N.E. 15 mg/m3 N.E.
Ethylbenzene 100-41 -4 5.0 100 PPM 125 PPM 100 PPM N.E.
Aluminum Flake 7429 -90-5 5.0 10 mg/m3 N.E. 15 mg/m3 N.E.
Pigment Black 7 1333 -86-4 5.0 3.5 mg/m3 N.E. 3.5 mg/m3 N.E.
Pigment Yellow 73 13515-40-7 5.0 2 mg/m3 N.E. 2 mg/m3 N.E.
Pigment Red 122 980-26 -7 1.0 15mg/m3 N.E. 5mg/m3 N.E.
Section 3 - Hazards Identification
*** Emergency Overview ***: Harmful if inhaled. May affect the brain or nervous system causing dizziness,
headache or nausea. Vapors may cause flash fire or explosion. Extremely flammable liquid and vapor. Contents
Under Pressure. Harmful if swallowed.
Effects Of Overexposure - Eye Contact: Causes eye irritation.
Effects Of Overexposure - Skin Contact: Prolonged or repeated contact may cause skin irritation. Substance may
cause slight skin irritation.
Effects Of Overexposure - Inhalation: High vapor concentrations are irritating to the eyes, nose, throat and lungs.
Avoid breathing vapors or mists. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Harmful if
inhaled.
Effects Of Overexposure - Ingestion: Aspiration hazard if swallowed; can enter lungs and cause damage.
Substance may be harmful if swallowed.
Effects Of Overexposure - Chronic Hazards: IARC lists Ethylbenzene as a possible human carcinogen (group 2B).
May cause central nervous system disorder (e,g.,narcosis involving a loss of coordination, weakness, fatigue,
mental confusion, and blurred vision) and/or damage. Reports have associated repeated and prolonged
occupational overexposure to solvents with permanent brain and nervous system damage. Overexposure to xylene
in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood damage as
well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac
abnormalities and nervous system damage. Overexposure to toluene in laboratory animals has been associated
with liver abnormalities, kidney, lung and spleen damage. Effects in humans have included liver and cardiac
abnormalities.
Contains carbon black. Chronic inflammation, lung fibrosis, and lung tumors have been observed in some rats
experimentally exposed for long periods of time to excessive concentrations of carbon black and several insoluble
fine dust particles. Tumors have not been observed in other animal species (i.e., mouse and hampster) under
similar circumstances and study conditions. Epidemiological studies of North American workers show no evidence
of clinically significant adverse health effects due to occupational exposure to carbon black.
Carbon black is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC and is proposed to be listed as
A4- "not classified as a human carcinogen" by the American Conference of Govermental Industrial Hygienists.
Significant exposure is not anticipated during brush application or drying. Risk of overexposure depends on
duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual concentration
of carbon black in the formula.
Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation, Eye Contact
Section 4 - First Aid Measures
First Aid - Eye Contact: Hold eyelids apart and flush with plenty of water for at least 15 minutes. Get medical
attention.
First Aid - Skin Contact: Wash with soap and water. Get medical attention if irritation develops or persists.
First Aid - Inhalation: If you experience difficulty in breathing, leave the area to obtain fresh air. If continued
difficulty is experienced, get medical assistance immediately.
First Aid - Ingestion: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material
can enter the lungs and cause severe lung damage. Get immediate medical attention.
Section 5 - Fire Fighting Measures
Flash Point: -156 F LOWER EXPLOSIVE LIMIT: 0.7 %
(Setaflash) UPPER EXPLOSIVE LIMIT : 12.8 %
Extinguishing Media: Dry Chemical, Foam, Water Fog
Unusual Fire And Explosion Hazards: FLASH POINT IS LESS THAN 20 ? F. - EXTREMELY FLAMMABLE LIQUID
AND VAPOR! Water spray may be ineffective. Closed containers may explode when exposed to extreme heat.
Vapors may form explosive mixtures with air. Vapors can travel to a source of ignition and flash back. Keep
containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Perforation of the
pressurized container may cause bursting of the can.
Special Firefighting Procedures: Evacuate area and fight fire from a safe distance.
Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Contain spilled liquid with sand or earth. DO NOT use
combustible materials such as sawdust. Remove all sources of ignition, ventilate area and remove with inert
absorbent and non-sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not
incinerate closed containers.
Section 7 - Handling And Storage
Handling: Use only in a well-ventilated area. Avoid breathing vapor or mist. Follow all MSDS/label precautions even
after container is emptied because it may retain product residues. Wash thoroughly after handling. Wash hands
before eating.
Storage: Contents under pressure. Do not expose to heat or store above 120 ?F. Do not store above 120 ?F. Store
large quantities in buildings designed and protected for storage of NFPA Class I flammable liquids. Keep containers
tightly closed. Isolate from heat, electrical equipment, sparks and open flame.
Section 8 - Exposure Controls / Personal Protection
Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control
airborne levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows
to achieve cross-ventilation. Use explosion-proof ventilation equipment.
Respiratory Protection: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements
must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying
respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where
airborne concentrations are expected to exceed exposure limits.
Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is
any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air
purifying respirators may not provide adequate protection.
Skin Protection: Nitrile or Neoprene gloves may afford adequate skin protection. Use impervious gloves to prevent
skin contact and absorption of this material through the skin.
Eye Protection: Use safety eyewear designed to protect against splash of liquids.
Other protective equipment: Refer to safety supervisor or industrial hygienist for further information regarding
personal protective equipment and its application.
Hygienic Practices: Wash thoroughly with soap and water before eating, drinking or smoking.
Section 9 - Physical And Chemical Properties
Boiling Range: -34 - 900 F Vapor Density: Heavier than air
Odor: Odor Threshold:
Solvent Like ND
Appearance: Evaporation Rate:
Liquid Faster than Ether
Solubility in H2O: Slight
Freeze Point: Specific Gravity:
ND
Vapor Pressure: PH: NE
Physical State: Liquid
(See section 16 for abbreviation legend)
Section 10 - Stability And Reactivity
Conditions To Avoid: Avoid temperatures above 120 ?F. Avoid all possible sources of ignition. Flammable
hydrogen gas will evolve when product comes in contact with water or damp air. Heat will be generated. The
amount of heat generated will depend upon the volume of material in contact.
Incompatibility: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
Hazardous Decomposition: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it
emits acrid smoke and irritating fumes.
Hazardous Polymerization: Will not occur under normal conditions.
Stability: This product is stable under normal storage conditions.
Section 11 - Toxicological Information
Product LD50: ND Product LC50: ND
Chemical Name LD50 LC50
Liquefied Petroleum Gas N.D. N.D.
Acetone N.D. N.D.
Toluene N.D. N.D.
Aliphatic Hydrocarbon N.D. N.D.
Xylene N.D. N.D.
Titanium Dioxide >7500 mg/kg (ORAL, RAT)N.D.
N-Butyl Acetate 13100 mg/kg (ORAL, RAT)2000 PPM (INH 4 Hr, RAT)
Aliphatic Petroleum Distillates N.D. N.D.
Naphtha >5000 mg/kg (ORAL, RAT)N.D.
Magnesium Silicate N.D. TCLo:11mg/m3 inh.
Ethylbenzene 3500 mg/kg (ORAL, RAT) N.D.
Aluminum Flake N.D. N.D.
Pigment Black 7 >8000 mg/kg (ORAL, RAT)N.D.
Pigment Yellow 73 N.D. N.D.
Pigment Red 122 N.D. N.D.
Section 12 - Ecological Information
Ecological Information: Product is a mixture of listed components.
Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance to local, state and federal regulations and ordinances. Do
not allow to enter storm drains or sewer systems.
Section 14 - Transportation Information
DOT Proper Shipping Name: Aerosol Packing Group: ---
DOT Technical Name: --- Hazard Subclass: ---
DOT Hazard Class: 2.1 Resp. Guide Page: 126
DOT UN/NA Number: UN1950
Section 15 - Regulatory Information
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA "Hazard Categories" promulgated under Sections 311and
312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD, CHRONIC HEALTH HAZARD, FIRE HAZARD
SARA Section 313:
Listed below are the substances (if any) contained in this product that are subject to the reporting requirements of
Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS Number
Toluene 108-88-3
Xylene 1330-20-7
Ethylbenzene 100-41-4
Toxic Substances Control Act:
Listed below are the substances (if any) contained in this product that are subject to the reporting requirements of
TSCA 12(B) if exported from the United States:
None known
U.S. State Regulations: As follows -
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product.
Chemical Name CAS Number
Calcium Carbonate 1317-65-3
C-9 HYDROCARBON RESIN UNSATURATED 71302-83-5
Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%.
Chemical Name CAS Number
Calcium Carbonate 1317-65-3
C-9 HYDROCARBON RESIN UNSATURATED 71302-83-5
Modified Alkyd PROPRIETARY
Modified Alkyd PROPRIETARY
Water 7732-18-5
Barium Sulfate 7727-43-7
California Proposition 65:
WARNING! This product contains a chemical(s) known by the State of California to cause cancer.
WARNING! This product contains a chemical(s) known to the state of California to cause birth defects or other
reproductive harm.
International Regulations: As follows -
CANADIAN WHMIS:
This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16
headings.
CANADIAN WHMIS CLASS: AB5, D2A, D2B
Section 16 - Other Information
HMIS Ratings:
Health: 2* Flammability: 4 Reactivity: 0 Personal Protection: X
VOLATILE ORGANIC COMPOUNDS, g/l: NA
REASON FOR REVISION:
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
The information contained on this MSDS has been checked and should be accurate. However, it is the
responsibility of the user to comply with all Federal, State, and Local laws and regulations.
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