PRODUCT NAME: Urethane Grade Reducer Slow DATE: 5/4/2006
PRODUCT CODE: CP82 PAGE 1 of 7
MATERIAL SAFETY DATA SHEET
This Material Safety Data Sheet conforms to the requirements of ANSI Z-400.1.
THIS MSDS COMPLIES WITH 29 CFR 1910.1200 (HAZARD COMMUNICATION STANDARD)
IMPORTANT: Read this MSDS before handling & disposing of this product.
Pass this information on to employees, customers, & users of this product.
SECTION 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY
PRODUCT IDENTITY: BLEND #2010 / CP82
COMPANY IDENTITY: Cumberland Products, Inc.
COMPANY ADDRESS: 50 Commerce Parkway
COMPANY CITY: Hodgenville, KY 42748
COMPANY PHONE: 1-800-223-1918
CHEMTREC PHONE: 1-800-424-9300
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS
CONTAINS: 25-30% PROPYLENE GLYCOL METHYL ETHER ACETATE (108-65-6)
10-20% METHYL ETHYL KETONE (78-93-3)[201-159-0]
5-15% LIGHT ALIPHATIC SOLVENT NAPHTHA (*64742-89-8)
5-15% ETHYL-3-ETHOXY PROPIONATE (763-69-9)
5-15% N-BUTYL ACETATE (123-86-4)[204-658-1]
5-15% TOLUENE (108-88-3) [203-625-9]
0-5% MIXED XYLENES (1330-20-7) [215-535-7]
SECTION 3. HAZARDS IDENTIFICATION
RISK STATEMENTS:
R11 Highly Flammable.
R18 In use, may form flammable/explosive vapor-air mixture.
R65 Harmful: may cause lung damage if swallowed.
R36/37/38 Irritating to eyes, respiratory system and skin.
R20/65 Harmful by inhalation, may cause lung damage if swallowed.
SAFETY STATEMENTS:
S9 Keep container in a well-ventilated place.
S16 Keep away from sources of ignition. No smoking.
S29 Do not empty into drains.
S45 In case of accident, or if you feel unwell, seek medical advice immediately. (Show
the label where possible).
S53 Avoid exposure ?Obtain special instructions before use.
S24/25 Avoid contact with skin and eyes.
SECTION 4. FIRST AID MEASURES
EYE CONTACT:
For eyes, flush with plenty of water for 15 minutes & get medical attention.
PRODUCT NAME: Urethane Grade Reducer Slow DATE: 5/4/2006
PRODUCT CODE: CP82 PAGE 2 of 7
SKIN CONTACT:
In case of contact with skin immediately remove contaminated clothing. Wash thoroughly with
soap & water. Wash contaminated clothing before reuse.
INHALATION:
After high vapor exposure, remove to fresh air. If breathing is difficult, give oxygen. If breathing
has stopped give artificial respiration.
SWALLOWING:
If swallowed, CALL A PHYSICIAN IMMEDIATELY! Do NOT induce vomiting. Have patient lie
down & keep warm. Vomiting may lead to pneumonitis, which may be fatal.
SECTION 5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA:
NFPA Class B extinguishers [Carbon Dioxide or Foam] for Class I B liquid fires.
SPECIAL FIRE FIGHTING PROCEDURES:
Water spray may be ineffective on fire but can protect fire fighters & cool closed containers. Use
fog nozzles if water is used. Do not enter confined fire-space without full bunker gear. (Helmet
with face shield, bunker coats, gloves & rubber boots). Use NIOSH approved positive-pressure
self-contained breathing apparatus.
UNUSUAL EXPLOSION AND FIRE PROCEDURES:
HIGHLY FLAMMABLE!! VAPORS CAN CAUSE FLASH FIRE
Keep container tightly closed.
Isolate from oxidizers, heat, sparks, electric equipment and open flame.
Closed containers may explode if exposed to extreme heat.
Applying to hot surfaces requires special precautions.
Empty container very hazardous! Continue all label precautions!
SECTION 6. ACCIDENTAL RELEASE MEASURES
CONTAINMENT TECHNIQUES:
Stop spill at source. Dike area & contain.
CLEAN-UP PROCEDURES:
Clean up remainder with absorbent materials. Mop up & dispose of. Persons without proper
protection should be kept from area until cleaned up.
SECTION 7. HANDLING AND STORAGE
HANDLING:
Isolate from oxidizers, heat, sparks, electric equipment & open flame. Use only with adequate
ventilation. Avoid breathing of vapor or spray mist. Avoid contact with skin & eyes. Wear OSHA
Standard goggles or face shield. Consult Safety Equipment Supplier. Wear gloves, apron &
footwear impervious to this material. Wash clothing before reuse. Avoid free fall of liquid. Ground
PRODUCT NAME: Urethane Grade Reducer Slow DATE: 5/4/2006
PRODUCT CODE: CP82 PAGE 3 of 7
containers when transferring. Do not flame cut, saw, drill, braze, or weld. Empty container very
hazardous! Continue all label precautions!
STORAGE:
Do not store above 49 C / 120 F. Store large amounts in structures made for OSHA Class I B
liquids. Keep container tightly closed & upright when not in use to prevent leakage.
OSHA Class I B liquids.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
EXPOSURE CONTROLS:
Use vapor, mist gas mask within use limits, or ventilate to keep vapors of this material below 50
ppm. If over TLV, in accordance with 29 CFR 1910.134, use NIOSH approved positive-pressure
self-contained breathing apparatus. Consult Safety Equipment Supplier. Use explosion-proof
equipment.
VENTILATION:
LOCAL EXHAUST: Necessary
MECHANICAL (GENERAL): Acceptable
SPECIAL: None
OTHER: None
PERSONAL PROTECTIONS:
Wear OSHA Standard goggles or face shield. Consult Safety Equipment Supplier. Wear gloves,
apron & footwear impervious to this material. Wash clothing before reuse.
WORK & HYGIENIC PRACTICES:
Provide readily accessible eye wash stations & safety showers. Wash at end of each workshift &
before eating, smoking or using the toilet. Promptly remove clothing that becomes contaminated.
Destroy contaminated leather articles. Launder or discard contaminated clothing.
SECTION 9. PHYSICAL DATA
APPEARANCE: Liquid, Water-White
ODOR: Ketone
BOILING RANGE: 86 120 165* C / 188 249 329* F (*=End Point)
AUTO IGNITION TEMPERATURE: 287 C / 550 F (Lowest Component)
LOWER FLAMMABLE LIMIT IN AIR (% by vol): 1.5
FLASH POINT (TEST METHOD): -2 C / 28 F (TCC) (Lowest component)
FLAMMABILITY CLASSIFICATION: Class I B
GRAVITY @ 60 F:
API: 29.8
SPECIFIC GRAVITY (Water=1): .877
POUNDS/GALLON: 7.309
VOC'S (>0.44 Lbs./sq. Inch): 51.5 Vol. % / 451.9 g/L / 3.764 Lbs/Gal
TOTAL VOC'S (TVOC): 93.0 Vol. % / 816.0 g/L / 6.797 Lbs/Gal
NONEXEMPT VOC'S (CVOC): 93.0 Vol. % / 816.0 g/L / 6.797 Lbs/Gal
PRODUCT NAME: Urethane Grade Reducer Slow DATE: 5/4/2006
PRODUCT CODE: CP82 PAGE 4 of 7
HAZARDOUS AIR POLLUTANTS (HAPS): 29.1 Wt. % / 244.6 g/L / 2.037 Lbs/Gal
VAPOR PRESSURE (mm of Hg) @ 20 C: 25.9
NONEXEMPT VOC PARTIAL PRESSURE (mm of Hg @ 20 C): 25.9
VAPOR DENSITY (air=1): 3.7
WATER ABSORPTION: Appreciable
REFRACTIVE INDEX: 1.415
SECTION 10. STABILITY & REACTIVITY
STABILITY:
Stable
CONDITIONS TO AVOID:
Isolate from oxidizers, heat, sparks, electric equipment & open flame.
MATERIALS TO AVOID:
Isolate from strong oxidizers such as permanganates, chromates & peroxides.
HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide, Carbon Dioxide from burning.
HAZARDOUS POLYMERIZATION:
Will not occur.
SECTION 11. TOXICOLOGICAL INFORMATION
MATERIAL CAS # TWA (OSHA) TLV (ACGIH) HAP
Propylene Glycol Methyl Ether Acetate 108-65-6 None Known 100 ppm No
Methyl Ethyl Ketone 78-93-3 200 ppm 200 ppm Yes
Light Aliphatic Solvent Naphtha *64742-89-8 500 ppm 300 ppm No
Ethyl-3-Ethoxypropionate 763-69-9 50 ppm 50 ppm No
n-Butyl Acetate 123-86-4 150 ppm 150 ppm No
Toluene 108-88-3 200 ppm 50 ppm A4 Yes
Mixed Xylenes 1330-20-7 100 ppm 100 ppm A4 Yes
In addition to EPA Hazardous Air Pollutants showing 'Yes' under "HAP" above, using
manufacturers' data, based on EPA Method 311, the following EPA Hazardous Air Pollutants
may be present in trace amounts (less than 0.1%): Benzene, Cumene
MATERIAL CAS # CEILING STEL
(OSHA/ACGIH)
Methyl Ethyl Ketone 78-93-3 None Known 300 ppm
Light Aliphatic Solvent Naphtha *64742-89-8 None Known 5.3E3 ppm
n-Butyl Acetate 123-86-4 None Known 200 ppm
Mixed Xylenes 1330-20-7 None Known 150 ppm
PRODUCT NAME: Urethane Grade Reducer Slow DATE: 5/4/2006
PRODUCT CODE: CP82 PAGE 5 of 7
ACUTE HAZARDS
EYE & SKIN CONTACT:
Primary irritation to skin - defatting, dermatitis.
Absorption thru skin increases exposure.
Primary irritation to eyes ?redness, tearing, blurred vision.
Liquid can cause eye irritation. Wash thoroughly after handling.
INHALATION:
Anesthetic. Irritates respiratory tract. Acute overexposure can cause serious nervous system
depression. Vapor harmful. Breathing vapor can cause irritation. Acute overexposure can cause
damage to kidneys, blood, nerves, liver & lungs.
SWALLOWING:
Harmful or fatal if swallowed.
Swallowing can cause abdominal irritation, nausea, vomiting & diarrhea.
SUBCHRONIC HAZARDS / CONDITIONS AGGRAVATED:
CONDITIONS AGGRAVATED:
Persons with severe skin, liver or kidney problems should avoid use.
CHRONIC HAZARDS
CANCER, REPRODUCTIVE & OTHER CHRONIC HAZARDS:
Leukemia been reported in humans from Benzene. This product may contain less than 46 ppm of
Benzene. Not considered hazardous in such low concentrations. Absorption thru skin may be
harmful. Studies with laboratory animals indicate this product can cause damage to fetus.
SECTION 12. ECOLOGICAL INFORMATION
MAMMALIAN INFORMATION:
MATERIAL CAS# LOWEST KNOWN LETHAL DOSE DATA
LOWEST KNOWN LD50 (ORAL)
Toluene 108-88-3 3000.0 mg/kg (Rats)
LOWEST KNOWN LC50 (VAPORS)
Methyl Ethyl Ketone 78-93-3 2000 ppm (Rats)
LOWEST KNOWN LD50 (SKIN)
Toluene 108-88-3 4000.0 mg/kg (Rabbits)
AQUATIC ANIMAL INFORMATION:
The most sensitive known marine group to any component of this product is:
Flatworm .032 ppm or mg/L (96 hour exposure). Keep out of sewers and natural water supplies.
MOBILITY:
This material is a mobile liquid.
PRODUCT NAME: Urethane Grade Reducer Slow DATE: 5/4/2006
PRODUCT CODE: CP82 PAGE 6 of 7
DEGRADABILITY:
This product is partially biodegradable.
ACCUMULATION:
This product does not accumulate or biomagnify in the environment.
SECTION 13. DISPOSAL CONSIDERATIONS
Recycle / dispose of observing national, regional, state, provincial and local health, safety &
pollution laws. If questions exist, contact the appropriate agencies.
SECTION 14. TRANSPORT INFORMATION
DOT SHIPPING NAME: RQ, Paint Related Material
( Contains: Methyl Ethyl Ketone, Toluene) 3, UN1263, PG-II
DRUM LABEL: (FLAMMABLE LIQUID)
IATA / ICAO: RQ, Paint Related Material
( Contains: Methyl Ethyl Ketone, Toluene) 3, UN1263, PG-II
IMO / IMDG: RQ, Paint Related Material
( Contains: Methyl Ethyl Ketone, Toluene) 3, UN1263, PG-II
EMERGENCY RESPONSE GUIDEBOOK NUMBER: 127
SECTION 15. REGULATORY INFORMATION
STATE REGULATIONS:
CALIFORNIA PROPOSITION 65: This product contains the following chemical known to the
State of California to cause reproductive toxicity: Toluene
EPA REGULATIONS:
SARA SECTION 311/312 HAZARDS: Acute Health, Fire
All components of this product are on the TSCA list.
SARA Title III Section 313 Supplier Notification
This product contains the indicated <*> toxic chemicals subject to the reporting requirements of
Section 313 of the Emergency Planning & Community Right-To-Know Act of 1986 & of 40 CFR
372. This information must be included in all MSDSs that are copied and distributed for this
material.
SARA TITLE III INGREDIENTS
CAS# WT.% (REG. SECTION) RQ (LBS)
*Methyl Ethyl Ketone 78-93-3 16 (311, 312, 313, RCRA) 5000
*Toluene 108-88-3 10 (311, 312, 313, RCRA) 1000
*Mixed Xylenes 1330-20-7 <2 (311, 312, 313, RCRA) None
IF > 9168 POUNDS OF THIS PRODUCT IS IN ONE CONTAINER THE "RQ" OF TOLUENE IS
EXCEEDED.
PRODUCT NAME: Urethane Grade Reducer Slow DATE: 5/4/2006
PRODUCT CODE: CP82 PAGE 7 of 7
INTERNATIONAL REGULATIONS:
The components of this product are listed on the chemical inventories of the following countries:
Australia, Canada, Europe (EINECS), Japan, Korea, United Kingdom.
SECTION 16. OTHER INFORMATION
HAZARD RATINGS:
HEALTH (NFPA): 1
HEALTH (HMIS): 2
FLAMMABILITY: 3
REACTIVITY: 0
This information is intended solely for the use of individuals trained in the NFPA & HMIS hazard
rating systems.
EMPLOYEE TRAINING:
Employees should be made aware of all hazards of this material (as stated in this MSDS) before
handling it.
NOTICE
The supplier disclaims all expressed or implied warranties of merchantability or fitness for a
specific use, with respect to the product or the information provided herein, except for
conformation to contracted specifications. All information appearing herein is based upon data
obtained from manufacturers and/or recognized technical sources. While the information is
believed to be accurate, we make no representations as to its accuracy or sufficiency. Conditions
of use are beyond our control, and therefore users are responsible for verifying the data under
their own operating conditions to determine whether the product is suitable for their particular
purposes and they assume all risks of their use, handling, and disposal of the product. Users also
assume all risks in regards to the publication or use of, or reliance upon, information contained
herein. This information relates only to the product designated herein, and does not relate to its
use in combination with any other material or process.
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