SAFETY DATA SHEET according to EC directive 2001/58/EC
SUBLICOAT TRASP. SOL.A
Version 1 Print Date 15/04/2004
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING
Product information
Product name : SUBLICOAT TRASP. SOL.A
Product code : MVA..408102
Company : Lechler SpA
Via Cecilio 17
22100 Como
Telephone : +39031586111
Telefax : +39031586206
In order to get more information and in case of emergencies please address to Lechler Group Security
Office. (Tel. +39-031-586.301).
: Tel. +39-031-586301
Fax +39-031-586299
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature : Dual compound enamel - finish coat
Hazardous components :
Components CAS-No. EEC-No. Symbol(s): R-phrase(s) Concentration
[%]
Xylene 1330-20-7 601-022-00-9 Xn R20/21, >= 12,5 - < 20
R38, R10
Ethyl Acetate 141-78-6 607-022-00-5 F, Xi R11, R67, >= 1 - < 3
R36, R66
N-Butyl Acetate 123-86-4 607-025-00-1 R10, R66, >= 12,5 - < 20
R67
2-Methoxy -1-Methylethyl 108-65-6 607-195-00-7 Xi R10, R36 >= 12,5 - < 20
Acetate
3. HAZARDS IDENTIFICATION
Harmful
Hazardous components : Xylene
R-phrase(s) :
Flammable.
Harmful by inhalation and in contact with skin.
S-phrase(s) :
Keep container in a well-ventilated place.
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SAFETY DATA SHEET according to EC directive 2001/58/EC
SUBLICOAT TRASP. SOL.A
Version 1 Print Date 15/04/2004
Avoid contact with the skin.
Wear suitable gloves.
4. FIRST AID MEASURES
General advice : When symptoms persist or in all cases of doubt seek medical advice.
Never give anything by mouth to an unconscious person.
After Inhalation : Remove to fresh air.
Keep patient warm and at rest.
If breathing is irregular or stopped, administer artificial respiration.
If unconscious place in recovery position and seek medical advice.
After Skin contact : Take off all contaminated clothing immediately.
Wash skin thoroughly with soap and water or use recognized skin
cleanser.
Do NOT use solvents or thinners.
Put shower on working place
After Eye contact : Irrigate copiously with clean, fresh water for at least 10 minutes,
holding the eyelids apart.
Remove contact lenses.
Seek medical advice.
Put eye-washer on working place
After Ingestion : If accidentally swallowed obtain immediate medical attention.
Keep at rest.
Do not induce vomiting.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon
dioxide.
Keep containers and surroundings cool with water spray.
Extinguishing media which : Do NOT use water jet.
must not be used for safety
reasons
Specific hazards during fire : As the product contains combustible organic components, fire will
fighting produce dense black smoke containing hazardous products of
combustion (see section 10).
Exposure to decomposition products may be a hazard to health.
Cool closed containers exposed to fire with water spray.
Collect contaminated fire extinguishing water separately. This must
not be discharged into drains.
Fire residues and contaminated fire extinguishing water must be
disposed of in accordance with local regulations.
Special protective equipment : Wear self contained breathing apparatus for fire fighting if necessary.
for fire-fighters
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SAFETY DATA SHEET according to EC directive 2001/58/EC
SUBLICOAT TRASP. SOL.A
Version 1 Print Date 15/04/2004
6. ACCIDENTAL RELEASE MEASURES
Environmental precautions : Try to prevent the material from entering drains or water courses.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Methods for cleaning up : Clean with detergents. Avoid solvents.
Contain and collect spillage with non-combustible absorbent material,
(e.g. sand, earth, diatomaceus earth, vermiculite) and place in
container for disposal according to local / national regulations (see
section 13).
Additional advice : Refer to section 15 for specific national regulation.
7. HANDLING AND STORAGE
Handling
Safe handling advice : Avoid exceeding of the given occupational exposure limits (see
section 8).
Use only in area provided with appropriate exhaust ventilation.
Avoid contact with skin, eyes and clothing.
Smoking, eating and drinking should be prohibited in the application
area.
Avoid inhalation of vapour or mist.
For personal protection see section 8.
Thoroughly mix before using
After using, store in a well-sealed container
Advice on protection against : Prevent the creation of flammable or explosive concentrations of
fire and explosion vapour in air and avoid vapour concentration higher than the
occupational exposure limits.
When transferring from one container to another apply earthing
measures and use conductive hose material.
No sparking tools should be used.
The product should only be used in areas from which all naked lights
and other sources of ignition have been excluded.
No smoking.
Storage
Requirements for storage : Observe label precautions.
areas and containers Containers which are opened must be carefully resealed and kept
upright to prevent leakage.
Solvent vapours are heavier than air and may spread along floors.
Vapours may form exp losive mixtures with air.
Electrical installations / working materials must comply with the
technological safety standards.
Keep away from sources of ignition - No smoking.
Store between 5?an 35癈 in a dry, well ventilated place away from
source of heat, ignition and direct sunlight.
Store in accordance with the particular national regulations.
Advice on common storage : Keep away from oxidising agents and strongly acid or alkaline
materials.
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SAFETY DATA SHEET according to EC directive 2001/58/EC
SUBLICOAT TRASP. SOL.A
Version 1 Print Date 15/04/2004
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Components with workplace control parameters
Components CAS-No. Value Value Basis
[mg/m3 ] [ppm]
Xylene 1330-20-7 434,00 100,00
Ethyl Acetate 141-78-6 1.400,00 400,00
N-Butyl Acetate 123-86-4 713,00 150,00
2-Methoxy -1-Methylethyl Acetate 108-65-6 275,00 50,00
Personal protective equipment
Respiratory protection : Apply technical measures to comply with the occupational exposure
limits.
This should be achieved by a good general extraction and -if
practically feasible- by the use of a local exhaust ventilation.
If the occupational exposure limits cannot be met, in exceptional
cases suitable respiratory equipment should be worn only for a short
period of time.
Hand protection : For prolonged or repeated contact use protective gloves.
Barrier creams may help to protect the exposed areas of skin, they
should however not be applied once exposure has occurred.
Skin should be washed after contact.
Wash your hands and put on barrier creams
Eye protection : Chemical resistant goggles must be worn.
Skin and body protection : Skin should be washed after contact.
Working clothes must not consist of textiles, which show a dangerous
melting behaviour in case of fire.
Personnel should wear protective clothing
Workers should wear antistatic footwear.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form : liquid
Flash point : > 23 - 55 癈
Density : 1 g/cm3
Viscosity : > 60 s
Transversale section: 6 mm
Method: 2431 '84 (ISO 6)
Solids by weight : 48 %
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SAFETY DATA SHEET according to EC directive 2001/58/EC
SUBLICOAT TRASP. SOL.A
Version 1 Print Date 15/04/2004
10. STABILITY AND REACTIVITY
Conditions to avoid : Our products were manufactured in compliance with safety standards
to avoid decomposition and degrading under the defined conditions.
Taking the product type into account, it is advisable to leave the
product in its original packaging thus avoiding transferring it.
Hazardous reactions : Keep away from oxidising agents, strongly alkaline and strongly acid
materials in order to avoid exothermic reactions.
11. TOXICOLOGICAL INFORMATION
Acute inhalation toxicity : Exposure to component solvent vapours concentration in excess of
the stated occupational exposure limit may result in adverse health
effects.
Such as: mucous membrane irritation, respiratory system irritation,
adverse effects on kidney, liver and central nervous system.
Symptoms and signs: headache, dizziness, fatigue, muscular
weakness, drowsiness and in extreme cases loss of consciousness.
Inhalation of airborne droplets may cause irritation of the respiratory
tract.
Skin irritation : Repeated or prolonged contact with the preparation may cause
removal of natural fat from the skin resulting in desiccation of the
skin.
The product may be absorbed through the skin.
Note : The concentration of each substance should be borne in mind in
assessing the toxicological effects deriving from the preparation.
Ethyl Acetate OBSERVATIONS ON HUMAN SUBJECTS: 400 ppm: eye irritant.
Serious toxic effects at 2,000 ppm/60 mins, symptoms of malaise at
800 ppm. Inhalatory toxicity: TCLo 400 ppm, irritation to nose, eyes,
and respiratory system.
N-Butyl Acetate OBSERVATIONS ON HUMAN SUBJECTS: Inhalation: 3300 ppm
(16 mg/l), for short periods, cause serious irritation to the eyes and to
the nose. Inhalation: 200-300 ppm (1-1.4 mg/l), for short periods, cause
moderate irritation to the eyes and to the nose. Inhaling the vapours can
irritate the respiratory system. The vapours can cause headache and
nausea. As a liquid it can irritate the eyes and cause conjunctivitis, it can
irritate the skin and cause dermatitis and, if swallowed, causes
inebriation, hallucinations and sedation. Symptoms of illness at 500
ppm. Serious toxic effects at 2,000 ppm for 60 min. TCLo: 200 ppm
12. ECOLOGICAL INFORMATION
Further information : There is no data available for this product.
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SAFETY DATA SHEET according to EC directive 2001/58/EC
SUBLICOAT TRASP. SOL.A
Version 1 Print Date 15/04/2004
13. DISPOSAL CONSIDERATIONS
Product : The product should not be allowed to enter drains, water courses or
the soil.
Disposal together with normal waste is not allowed. Special disposal
required according to local regulations.
14. TRANSPORT INFORMATION
ADR : UN-No 1263
Class 3
Code F1
Packaging group III
Description of the PAINT
goods
IMDG : UN-No 1263
Class 3
EmS F-E, S-E
Packaging group III
Marine pollutant
Description of the PAINT
goods
IATA : UN-No 1263
Class 3
Packaging group III
Description of the Paint
goods
15. REGULATORY INFORMATION
Hazardous components which must be listed on the label:
?Xylene
Symbol(s): : Xn Harmful
R-phrase(s) : R10 Flammable.
R20/21 Harmful by inhalation and in contact with skin.
S-phrase(s) : S9 Keep container in a well-ventilated place.
S24 Avoid contact with the skin.
S37 Wear suitable gloves.
National legislation
Germany
Risk classification according : not applicable
to VbF (Germany)
Water contaminating class : water endangering
(Germany)
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SAFETY DATA SHEET according to EC directive 2001/58/EC
SUBLICOAT TRASP. SOL.A
Version 1 Print Date 15/04/2004
16. OTHER INFORMATION
Further information
Xylene R20/21 Harmful by inhalation and in contact with skin.
R38 Irritating to skin.
R10 Flammable.
Ethyl Acetate R11 Highly flammable.
R67 Vapours may cause drowsiness and dizziness.
R36 Irritating to eyes.
R66 Repeated exposure may cause skin dryness or
cracking.
N-Butyl Acetate R10 Flammable.
R66 Repeated exposure may cause skin dryness or
cracking.
R67 Vapours may cause drowsiness and dizziness.
2-Methoxy -1-Methylethyl Acetate R10 Flammable.
R36 Irritating to eyes.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and
belief at the date of its publication. The information given is designed only as a guidance for safe handling,
use, processing, storage, transportation, disposal and release and is not to be considered a warranty or
quality specification. The information relates only to the specific material designated and may not be valid
for such material used in combination with any other materials or in any process, unless specified in the text.
Version: 1.4 Revision date 11.03.2004
SDS updated to the 28th adjustment EEC directive 1999/45/CE.
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