MONO93 v1.0
Revision Date: 23-Mar-2007
SAFETY DATA SHEET
Print Date: 23-Mar-2007
en/GB Page 1 - 9
1. Identification of the substance/preparation and of the company/undertaking
Product name MONO93 MONOPRIME 93
Product code MONO93
Intended use of the substance/preparation
Coating for professional use
Company/Undertaking Identification
Importer DuPont de Nemours (Belgium) BVBA
Street/Box Antoon Spinoystraat 6
Nat.-Code/Postal code/City BE 2800 Mechelen
Telephone +32 (0)15 44 10 11
Telefax +32 (0)15 44 14 09
Information on SDS
Responsible Department Regulatory Affairs
Telephone +49 (0)202 529-2385
Telefax +49 (0)202 529-2804
Emergency Information
Emergency telephone +44 (0)845 600-6640
For further information, please also consult our Internet site:
http://www.dupont.com
2. Composition/information on ingredients
Chemical characterization
Mixture of synthetic resins, pigments, and solvents
Hazardous components
Substances presenting a health or environmental hazard within the meaning of the DSD 67/548/EEC incl. 29. ATP
EC-No. CAS-No. Chemical Name Concentration Classification
204-658-1 123-86-4 n-butyl acetate 25.00 - < 35.00 % R10
R66
R67
200-751-6 71-36-3 n-butanol 15.00 - < 20.00 % R10
Xi; R37/38
Xn; R22
R67
Xi; R41
200-746-9 71-23-8 propan-1-ol 7.00 - < 10.00 % F; R11
Xi; R41
R67
215-535-7 1330-20-7 xylene 7.00 - < 10.00 % R10
Xn; R20/21
Xi; R38
500-033-5 25068-38-6 epoxy resin (number average molecular 3.00 - < 5.00 % R43
weight 700 <= 1200 ) Xi; R36/38
231-944-3 7779-90-0 trizinc bis(orthophosphate) 3.00 - < 5.00 % N; R50/53
202-849-4 100-41-4 ethylbenzene 1.00 - < 2.00 % F; R11
Xn; R20
Additional advice
To avoid misinterpretation in any case of risk assessment it is not allowed to accumulate the above mentioned percentages. See
full text of R-phrases in chapter 16.
Copyright 2007 E. I. duPont de Nemours and Company. All rights reserved. Copies may be made only for those using DuPont products.
MONO93 v1.0
Revision Date: 23-Mar-2007
SAFETY DATA SHEET
Print Date: 23-Mar-2007
en/GB Page 2 - 9
3. Hazards identification
The preparation is classified as dangerous in accordance with Directive 1999/45/EC.
Human health hazards
Classification : harmful; irritant; sensitizing; dangerous for the environment; flammable;
Flammable. Harmful by inhalation, in contact with skin and if swallowed. Irritating to skin. Risk of serious damage to eyes. May
cause sensitization by skin contact. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Special hazard instructions for humans and environment
Contains epoxy constituents. See information supplied by the manufacturer.
4. First aid measures
General advice
When symptoms persist or in all cases of doubt seek medical advice. Never give anything by mouth to an unconscious person.
Inhalation
Avoid inhalation of vapour or mist. Move to fresh air in case of accidental inhalation of vapours. If breathing is irregular or
stopped, administer artificial respiration. If unconscious place in recovery position and seek medical advice. If symptoms persist,
call a physician.
Skin contact
Do NOT use solvents or thinners. Take off all contaminated clothing immediately. Wash skin thoroughly with soap and water or
use recognized skin cleanser. If skin irritation persists, call a physician.
Eye contact
Remove contact lenses. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart. Seek
medical advice.
Ingestion
If swallowed, seek medical advice immediately and show this container or label. Do not induce vomiting. Keep at rest.
5. Fire-fighting measures
Hazardous combustion products
Fire will produce dense black smoke containing hazardous combustion products (see heading 10). Exposure to decomposition
products may be a hazard to health.
Fire and Explosion Hazards
Flammable liquid. Vapours may form explosive mixtures with air. Remove all sources of ignition.
Suitable extinguishing media
Universal aqueous film-forming foam, carbon dioxide (CO2), dry chemical, water spray.
Extinguishing media which must not be used for safety reasons
high volume water jet
Special Protective Equipment and Fire Fighting Procedures
Wear as appropriate: full protective flameproof clothing. Wear self contained breathing apparatus for fire fighting if necessary. In
the event of fire, cool tanks with water spray. Do not allow run-off from fire fighting to enter drains or water courses.
Additional advice
Cool closed containers exposed to fire with water spray.
6. Accidental release measures
Personal precautions
Keep in a well-ventilated place. Keep away from sources of ignition. Comply with safety directives (see chapters 7 and 8). Do
not inhale vapours.
Environmental precautions
Do not let product enter drains. Notify the respective authorities in accordance with local law in the case of contamination of
rivers, lakes or waste water systems.
Copyright 2007 E. I. duPont de Nemours and Company. All rights reserved. Copies may be made only for those using DuPont products.
MONO93 v1.0
Revision Date: 23-Mar-2007
SAFETY DATA SHEET
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Methods for cleaning up
Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite, diatomaceous earth and
place in container for disposal according to local regulations. Clean preferably with a detergent; avoid use of solvents.
7. Handling and storage
Handling
Persons with a history of skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be
employed in any process in which this preparation is being used.
Safe handling advice
Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration higher than the
occupational exposure limits. The product should only be used in areas from which all naked lights and other sources of ignition
have been excluded. Preparation may charge electrostatically: always use grounded leads when transferring from one container
to another. Operators should wear antistatic footwear and clothing. No sparking tools should be used. Avoid skin and eye
contact. Do not breathe vapours or spray mist. Smoking, eating and drinking should be prohibited in the application area. For
personal protection see section 8. Comply with the health and safety at work laws. If material is a coating, do not sand, flame
cut, braze or weld dry coating without an appropriate respirator or appropriate ventilation, and gloves.
Advice on protection against fire and explosion
Solvent vapours are heavier than air and may spread along floors. Vapours may form explosive mixtures with air. Never use
pressure to empty container: container is not a pressure vessel. Always keep in containers of same material as the original one.
The accumulation of contaminated rags may result in spontaneous combustion. Good housekeeping standards and regular
safe removal of waste materials will minimize the risks of spontaneous combustion and other fire hazards.
Storage
Requirements for storage areas and containers
Observe label precautions. Store between 5 and 25 C in a dry, well ventilated place away from sources of heat, ignition and
direct sunlight. No smoking. Prevent unauthorized access. Containers which are opened must be carefully resealed and kept
upright to prevent leakage. The storage and use of this product is subject to the requirements of the Dangerous Substances
and Explosive Atmospheres Regulations (DSEAR). Up to 50 litres of such highly flammable liquids may be stored in a work area
provided they are kept in a fire-proof cupboard or bin. Larger quantities must be kept in a separate storeroom conforming to the
structural requirements of the regulations. Further guidance is contained in the HSE ACOP L135, "Storage of Dangerous
Substances."
Advice on common storage
Store separately from amines, oxidizing agents, strongly alkaline and strongly acidic materials.
8. Exposure controls / personal protection
Persons with a history of skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be
employed in any process in which this preparation is being used.
Additional technical information on the plant
Provide adequate ventilation. This should be achieved by a good general extraction and -if practically feasible- by the use of a
local exhaust ventilation. If these are not sufficient to maintain concentrations of particulates and solvent vapour below the OEL,
suitable respiratory protection must be worn.
National occupational exposure limits
CAS-No. Chemical Name Source Time Type Value Note
123-86-4 n-butyl acetate STEL 966 mg/m3
STEL 200 ppm
TWA 724 mg/m3
TWA 150 ppm
71-36-3 n-butanol STEL 50 ppm
Stel 154 mg/m3
71-23-8 propan-1-ol STEL 625 mg/m3
STEL 250 ppm
TWA 500 mg/m3
Copyright 2007 E. I. duPont de Nemours and Company. All rights reserved. Copies may be made only for those using DuPont products.
MONO93 v1.0
Revision Date: 23-Mar-2007
SAFETY DATA SHEET
Print Date: 23-Mar-2007
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TWA 200 ppm
1330-20-7 xylene STEL 441 mg/m3
STEL 100 ppm
TWA 220 mg/m3
TWA 50 ppm
100-41-4 ethylbenzene STEL 552 mg/m3
STEL 125 ppm
TWA 441 mg/m3
TWA 100 ppm
Protective equipment
Personal protective equipment should be worn to prevent contact with eyes, skin or clothing.
Respiratory protection
When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.
Hand protection
Chemical Name Glove material Glove thickness Break through time
Viton R
n-butyl acetate 0.7 mm 10 min
nitrile rubber 0.33 mm 30 min
R
n-butanol Viton 0.7 mm 480 min
nitrile rubber 0.33 mm 480 min
R
propan-1-ol Viton 0.7 mm 480 min
nitrile rubber 0.33 mm 481 min
xylene nitrile rubber 0.33 mm 30 min
R
Viton 0.7 mm 480 min
The protective glove should be checked in each case for their work specific suitability (e.g. mechanical stability, product
compatibility, and anti-static properties). When the intended use is for spray application a nitrile glove of the chemical resistance
group 3 (e.g. Dermatril R glove) is to be used. After contamination, the glove has to be changed. If immersing the hands into the
product is not avoidable (e.g. maintenance work) a butyl or fluorocarbon rubber glove should be used. When skin exposure may
occur to materials specified in section 2 of this SDS, advice should be sought from the glove supplier as to appropriate type to
use with this product and the permeation breakthrough times. Care should be taken when working with sharp edged articles as
these can easily damage the gloves and make them ineffective. The instructions and information provided by the glove supplier
on use, storage, maintenance and replacement must be followed. Damaged gloves or those showing signs of wear should be
replaced immediately.
Eye protection
Wear protective eyewear for protection against solvent spatter.
Skin protection
Wear suitable protective clothing. Personnel should wear antistatic clothings made of natural fiber or of high temperature
resistant synthetic fiber.
Hygiene measures
Wash skin thoroughly with soap and water or use recognized skin cleanser. Do not use organic solvents!
Copyright 2007 E. I. duPont de Nemours and Company. All rights reserved. Copies may be made only for those using DuPont products.
MONO93 v1.0
Revision Date: 23-Mar-2007
SAFETY DATA SHEET
Print Date: 23-Mar-2007
en/GB Page 5 - 9
Environmental exposure controls
Do not let product enter drains. For ecological information refer to section 12.
9. Physical and chemical properties
General information (appearance)
Physical state: liquid Colour: milky
Important health, safety and environmental information
Value Method
24 C
Flash point DIN 53213/ISO1523
343 ?466 C
Autoignition temperature DIN 51794
46 ?140 C
Boiling point/range
Lower explosion limit 1%
Upper explosion limit 13.7 %
Vapour pressure 6.8 hPa
1.1 g/cm3
Relative density DIN 53217/ISO 2811
Water solubility appreciable
Viscosity (23 C) 58 s ISO 2431-1993 6 mm
Solvent separation test < 3% ADR/RID
Content of volatile components (including water) 62.1% Basis Vapour pressure >= 0.01 kPa
pH Not applicable.
Conductivity Not applicable.
10. Stability and reactivity
Stability
Stable
Conditions to avoid
Stable under recommended storage and handling conditions (see section 7).
Materials to avoid
Keep away from oxidising agents, strongly alkaline and strongly acid materials in order to avoid exothermic reactions.
Hazardous decomposition products
When exposed to high temperatures may produce hazardous decomposition products such as carbon monoxide and dioxide,
smoke, oxides of nitrogen.
11. Toxicological information
General observations
There are no data available on the product itself. The product is classified and labelled in accordance with EC directives or
respective national laws. See sections 2 and 15 for details.
Practical experience
Exposure to component solvents vapours concentration in excess of the stated occupational exposure limit may result in adverse
health effect such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous
system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss
of consciousness. Components of the product may be absorbed into the body through the skin. Repeated or prolonged contact
with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption
through the skin. The liquid splashed in the eyes may cause irritation and reversible damage. Based on the properties of the
epoxy constituent(s) and considering toxicological data on similar preparations, this preparation may be a skin sensitiser and an
irritant. Low molecular epoxy constituents are irritating to eyes, mucous membranes and skin. Repeated skin contact may lead
to irritation and to sensitization, possibly with cross-sensitization to other epoxies. Avoid skin and eye contact. Avoid inhalation of
vapour or mist. Contains epoxy resin (number average molecular weight 700 <= 1200 ). May produce an allergic reaction.
Toxicity Test Type Value Time Species
n-butyl acetate
Oral LD50 9.3 ml/kg rat
Dermal LD50 10 ml/kg Guinea Pig
Inhalation LC50 > 6,335 ppm 4h rat
n-butanol
Copyright 2007 E. I. duPont de Nemours and Company. All rights reserved. Copies may be made only for those using DuPont products.
MONO93 v1.0
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Oral LD50 790 mg/kg 8h rat
Dermal LD50 3,400 mg/kg 8h rabbit
Inhalation LC50 8,000 ppm 4h rat
propan-1-ol
Oral LD50 1.87 g/kg rat
Dermal LD50 4 g/kg rabbit
Inhalation LC50 9.8 mg/l 4h rat
xylene
Oral LD50 4,300 mg/kg rat
Dermal LD50 12,180 mg/kg rabbit
Inhalation LC50 5,000 ppm 4h rat
trizinc bis(orthophosphate)
Oral LD50 > 5,000 mg/kg rat
ethylbenzene
Oral LD50 3,500 mg/kg rat
Dermal LD50 17,800 mg/kg rabbit
Inhalation LC50 4,000 ppm 4h rat
12. Ecological information
There are no data available on the product itself. The product should not be allowed to enter drains or watercourses.
Acute toxicity aquatic invertebrates
EINECS-No. Chemical Name Species Type Exposure Value Method
time
231-944-3 trizinc bis(orthophosphate) Daphnia EC50 48 h 1 mg/l
Acute and extended toxicity of fishes
EINECS-No. Chemical Name Species Type Exposure Value Method
time
231-944-3 trizinc bis(orthophosphate) Oncorhynchus LC50 96 h 1 mg/l
mykiss (rainbow
trout)
Toxicity with aquatic plants
EINECS-No. Chemical Name Species Type Exposure Value Method
time
231-944-3 trizinc bis(orthophosphate) Algae EC50 72 h 0.3 mg/l
Mobility
No information available.
Persistence and degradability
No information available.
Bioaccumulative potential
No information available.
Other adverse effects
The preparation has been assessed following the conventional method of the Dangerous
Preparations Directive 1999/45/EC and is classified for eco-toxicological properties accordingly. See Sections 2 and 15 for details.
13. Disposal considerations
Dispose of in accordance with local regulations.
Product:
Recommendation:
A disposal process that converts the waste into energy is recommended. If this is not possible the hazardous waste must be
disposed of by incineration.
Copyright 2007 E. I. duPont de Nemours and Company. All rights reserved. Copies may be made only for those using DuPont products.
MONO93 v1.0
Revision Date: 23-Mar-2007
SAFETY DATA SHEET
Print Date: 23-Mar-2007
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Waste Key Number Description
Waste Key Number Description
08 01 11 waste paint and varnish containing organic solvents or other dangerous substances
Uncleaned packaging:
Recommendation:
Properly emptied containers are to be scrap processed or reconditioned. Improperly emptied containers are considered
hazardous waste (waste key number 150110). Waste, including emptied containers, is controlled waste. Do not allow into drains
or watercourses or dispose of where ground or surface waters may be affected. If fully drained containers are compacted they
can be regarded as Controlled Waste and disposed of in accordance with the requirements of the Control of Pollution Act 1974
and the Environmental Protection Act 1990 (GB), the Pollution Control and Local Government (NI) Order 1978 (NI) or of the EC
(Waste) Regulations 1979 and the EC (Toxic & Dangerous Waste) Regulations 1982 (IRL).
14. Transport information
Transport only in accordance with the requirements of the Carriage of Dangerous Goods by Road and Rail (Classification,
Packaging and Labeling), ADR for road, RID for rail, IMDG for sea and ICAO/IATA for air transport.
ADR/RID (Land transport)
Proper shipping name: PAINT
UN-No: 1263
Hazard Class: 3
Subsidiary Hazard Class: Not applicable.
Packing group: III
Special Provision: 640E
Hazchem: 3[Y]
IMDG (Sea transport)
Proper shipping name: PAINT
UN-No: 1263
Hazard Class: 3
Subsidiary Hazard Class: Not applicable.
Packing group: III
Marine Pollutant: N
EmS: F-E,S-E
ICAO/IATA (Air transport)
Proper shipping name: PAINT
UN-No: 1263
Hazard Class: 3
Subsidiary Hazard Class: Not applicable.
Packing group: III
15. Regulatory information
In accordance with the CHIP Regulations 2002 the product is labelled as follows:
Symbol and indicating of hazard
Xn Harmful
N Dangerous for the environment
Contains epoxy resin (number average molecular weight 700 <= 1200 ).
R-phrase(s)
R10 Flammable.
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.
R43 May cause sensitization by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environ-
ment.
Copyright 2007 E. I. duPont de Nemours and Company. All rights reserved. Copies may be made only for those using DuPont products.
MONO93 v1.0
Revision Date: 23-Mar-2007
SAFETY DATA SHEET
Print Date: 23-Mar-2007
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S-phrase(s)
S23 Do not breathe gas/fumes/vapour/spray.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S38 In case of insufficient ventilation, wear suitable respiratory equipment.
S61 Avoid release to the environment. Refer to special instructions/safety data sheets.
Contains epoxy constituents. See information supplied by the manufacturer.
National legislation
This safety datasheet has been prepared according to British legislation.
The product is labeled according to the Chemicals (Hazard Information and Packaging for Supply) Regulations 2002 as
amended (CHIP Regulations). The risk associated with the use of this product must be assessed in accordance with the Control
of Substances Hazardous to Health (COSHH) Regulations and the Dangerous Substances and Explosive Atmospheres
Regulations.
16. Other information
Full text of R phrases with no. appearing in section 2
R10 Flammable.
R11 Highly flammable.
R20 Harmful by inhalation.
R20/21 Harmful by inhalation and in contact with skin.
R22 Harmful if swallowed.
R36/38 Irritating to eyes and skin.
R37/38 Irritating to respiratory system and skin.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.
R43 May cause sensitization by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic en-
vironment.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
Information taken from reference works and the literature.
Substance No. CAS no: www.cas.org./EO/regsys.html
EC no: http://ecb.jrc.it/esis/index.php?PGM=ein
Substances presenting a health or environ- http://ecb.jrc.it/existing-chemicals/
mental hazard within the meaning of Directive http://ecb.jrc.it/classification-labelling/
67/548/EEC. http://toxnet.nlm.nih.gov/cgi-bin/sis/htmlgen?HSDB
http://www.cdc.gov(niosh/ipcs/icstart.html
Other directives, limitations and prohibitory Directive 76/769/EC
regulations Directive 98/24/EC
Directive 90/394/EC
Directive 793/93/EC
Directive 1999/45/EC
Directive 2006/8/EC
EUR-LEX: http://europa.eu.int/eur-lex/
Exposure limit for the pure substance http://osha.europa.eu/OSHA
Copyright 2007 E. I. duPont de Nemours and Company. All rights reserved. Copies may be made only for those using DuPont products.
MONO93 v1.0
Revision Date: 23-Mar-2007
SAFETY DATA SHEET
Print Date: 23-Mar-2007
en/GB Page 9 - 9
Training advice
Directive 76/769/EC
Directive 98/24/EC
Further information
The information of this SDS is based on the present state of our knowledge and meets the requirements of EU and national
laws. The user's working conditions however, are beyond our knowledge and control. The product is not to be used for purposes
other than those specified under section 1 without a written permission. It remains the responsibility of the user to ensure that
the necessary steps are taken to meet the laws and regulations. Handling of the product may only be done by people above 18
years of age, who are satisfactorily informed of how to do the work, the hazardous properties and necessary safety precautions.
The information given in this SDS is to describe the product only in terms of health and safety requirements and should not,
therefore, be construed as guaranteeing specific properties.
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Version Changes
1.0
Revision Date: 23-Mar-2007
Copyright 2007 E. I. duPont de Nemours and Company. All rights reserved. Copies may be made only for those using DuPont products.
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