Page 1/5
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 03.02.2010
* 1 Identification of substance:
?Product details:
?Trade name: Super Hand Cleaner V2178
?Article number: V2178
?Application of the substance / the preparation Hand cleaning agent
?Manufacturer/Supplier:
Barnes Group KENT Limited
Pitreavie Crescent
Pitreavie Business Park
Dunfermline
Fife
KY11 8UQ
Tel: 01383 737393
Fax: 01383 620079
Monday - Thursday 8.30am - 5.30pm, Friday 9.00am - 3.00pm
?Informing department: Product Safety Department
?Emergency information: fullertonj@kenteurope.com
* 2 Hazards identification
?Hazard designation:
@
?
G Xi Irritant
?Information pertaining to particular dangers for man and environment
The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in
the latest valid version.
R 36 Irritating to eyes.
?Classification system
The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by information
furnished by supplier companies.
?GHS label elements
~
Danger
H318 - Causes serious eye damage.
~
Warning
H317 - May cause an allergic skin reaction.
Warning
H315 - Causes skin irritation.
Safety data sheet available on request.
?Prevention:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
?Response:
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
GB
(Contd. on page 2)
Page 2/5
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 03.02.2010
Trade name: Super Hand Cleaner V2178
(Contd. of page 1)
* 3 Composition/information on ingredients
?Chemical characterization
?Description: Mixture of the substances listed below with harmless additions.
?Dangerous components:
CAS: 68585-34-2 Sodium Laureth Sulphate >10%
G
@
? Xi; R 36/38
Warning: ~ 3.2/2, 3.3/2
CAS: 7647-14-5 sodium chloride 1-10%
EINECS: 231-598-3
CAS: 68603-42-9 Coconut Diethanolamine 1-10%
EINECS: 271-657-0 ? Xi; R 38-41
G
@
Danger: ~ 3.3/1
Warning: 3.2/2
Alcohol ethoxylate 1-10%
@
G
? Xn, ? Xi; R 22-36/38
@
G
Warning: ~ 3.1.O/4, 3.2/2, 3.3/2
CAS: 56-81-5 glycerol 1-10%
EINECS: 200-289-5
Fragrance <1%
@
G
? Xi; R 43-52/53
Warning: ~ 3.4.S/1
4.1.C/3
CAS: 122-99-6 2-Phenoxyethanol <0.1%
EINECS: 204-589-7 ? Xn, ? Xi; R 22-36
G
@ G
@
Warning: ~ 3.1.O/4, 3.3/2
CAS: 35691-65-7 1,2-Dibromo-2,4-dicyanobutane <0.1%
EINECS: 252-681-0 ? Xn; R 22
@
G
Warning: ~ 3.1.O/4
CAS: 55965-84-9 mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2Hisothiazol-3-one <0.1%
[EC no. 220-239-6] (3:1) mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-
methyl-4-isothiazolin-3-one [EC no. 220-239-6] (3:1)
@
F
? T, ? C, ? N; R 23/24/25-34-43-50/53
A
@ @
D
Danger: ~ 3.1.O/3, 3.1.D/3, 3.1.I/3; ~ 3.2/1B
Warning: ~ 4.1.C/1; 3.4.S/1
CAS: 6359-98-4 Yellow dye <0.1%
?Additional information For the wording of the listed risk phrases refer to section 16.
* 4 First aid measures
?After inhalation Supply fresh air; consult doctor in case of symptoms.
?After skin contact Rinse with warm water.
?After eye contact Rinse opened eye for several minutes under running water. Then consult doctor.
?After swallowing
Do not induce vomiting; instantly call for medical help.
Rinse out mouth and then drink plenty of water.
5 Fire fighting measures
?Suitable extinguishing agents
CO2, extinguishing powder or water haze. Fight larger fires with water haze or alcohol-resistant foam.
?Protective equipment: No special measures required.
* 6 Accidental release measures
?Person-related safety precautions: Particular danger of slipping on leaked/spilled product.
?Measures for environmental protection:
Do not allow to enter drainage system, surface or ground water.
(Contd. on page 3)
GB
Page 3/5
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 03.02.2010
Trade name: Super Hand Cleaner V2178
(Contd. of page 2)
Inform respective authorities in case product reaches water or sewage system.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to item 13.
* 7 Handling and storage
?Handling
?Information for safe handling: Keep away from heat and direct sunlight.
?Information about protection against explosions and fires: No special measures required.
?Storage
?Requirements to be met by storerooms and containers: Store in cool location.
?Information about storage in one common storage facility: Do not store together with acids.
?Further information about storage conditions:
Keep container tightly sealed.
Protect from frost.
* 8 Exposure controls and personal protection
?Additional information about design of technical systems: No further data; see item 7.
?Components with limit values that require monitoring at the workplace:
glycerol
WEL Long-term value: 10 mg/m?br>
?Additional information: The lists that were valid during the compilation were used as basis.
?Personal protective equipment
?General protective and hygienic measures
Take off immediately all contaminated clothing
Keep away from foodstuffs, beverages and food.
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes.
?Breathing equipment: Use breathing protection only when aerosol or mist is formed.
?Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from
manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be
calculated in advance and has therefore to be checked prior to the application.
?Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
?Eye protection: Safety glasses
* 9 Physical and chemical properties:
?General Information
Form: Viscous
Colour: Yellow
Odour: Pleasant
?Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: Not determined
?Flash point: Not applicable
?Self-inflammability: Product is not selfigniting.
(Contd. on page 4)
GB
Page 4/5
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 03.02.2010
Trade name: Super Hand Cleaner V2178
(Contd. of page 3)
?Danger of explosion: Product is not explosive.
?Density at 20癈 1.09 g/cm?br>
?Solubility in / Miscibility with
Water: Fully miscible
* 10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
?Materials to be avoided:
?Dangerous reactions Reacts with acids
?Dangerous products of decomposition: No dangerous decomposition products known
* 11 Toxicological information
?Acute toxicity:
?LD/LC50 values that are relevant for classification:
glycerol
Oral LD50 250 mg/kg (mouse)
?Primary irritant effect:
?on the skin: No irritant effect.
?on the eye: Irritant effect.
?Sensitization: Sensitization possible by skin contact.
?Additional toxicological information:
Irritant
The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for
Preparations as issued in the latest version:
The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for
Preparations as issued in the latest version:
* 12 Ecological information:
?Additional ecological information:
?General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
13 Disposal considerations
?Product:
?Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
?Uncleaned packagings:
?Recommendation: Disposal must be made according to official regulations.
?Recommended cleaning agent: Water, if necessary with cleaning agent.
14 Transport information
?Land transport ADR/RID (cross-border)
?ADR/RID-GGVS/E Class: n/a
?Maritime transport IMDG:
?IMDG Class: n/a
?Marine pollutant: No
(Contd. on page 5)
GB
Page 5/5
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 03.02.2010
Trade name: Super Hand Cleaner V2178
(Contd. of page 4)
?Air transport ICAO-TI and IATA-DGR:
?ICAO/IATA Class: n/a
?UN "Model Regulation": n/a
15 Regulatory information
?Designation according to EC guidelines:
The product has been classified and labelled in accordance with EC Directives / Ordinance on Hazardous Materials (GefStoffV)
?Code letter and hazard designation of product:
@
G
? Xi Irritant
?Hazard-determining components of labelling:
mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2Hisothiazol-3-one [EC no. 220-239-6] (3:1)
mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-4-isothiazolin-3-one [EC no. 220-239-6] (3:1)
?Risk phrases:
36 Irritating to eyes.
?Safety phrases:
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
?Special designation of certain preparations:
Safety data sheet available for professional user on request.
?National regulations
?Technical instructions (air):
Class Share in %
NK 5.1
?Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
16 Other information:
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features
and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
22 Harmful if swallowed.
23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
34 Causes burns.
36 Irritating to eyes.
36/38 Irritating to eyes and skin.
38 Irritating to skin.
41 Risk of serious damage to eyes.
43 May cause sensitisation by skin contact.
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
?Department issuing data specification sheet: Environment protection department
?Contact: Marketing Department
?Abbreviations and acronyms:
ADR: Accord europ閑n sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road)
RID: R鑗lement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous
Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
GB
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