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Procter & Gamble
PGP TN 6
2 Procter & Gamble Plaza
Cincinnati, OH 45202
MATERIAL SAFETY DATA SHEET
MSDS #: FH/C/2006/BCWT-6RWPY Issue Date: September 5, 2006, Reviewed 4/09
Supersedes: FH/C/2005/TWTG-6E8QW7 Issue Date: July 25, 2006
SECTION I - CHEMICAL PRODUCT
Identity: Liquid Hard Surface Cleaner
Brands: P&G PRO LINE Heavy Duty Spray Cleaner Concentrate
Hazard Rating: Health: 2 4=EXTREME
Flammability: 2 3=HIGH
Reactivity: 0 2= MODERATE
1=SLIGHT
0=NO SIGNIFICANT RISK
Customer Service: 1-888-474-7765 or call Local Poison Control Center
Emergency (24 hour) Telephone Number: CHEMTREC 1-800-424-9300
SECTION II - COMPOSITION AND INGREDIENTS
Ingredients/Chemical Name: Cleaning agents (nonionic surfactant, glycol ethers, MEA), water, colorant and
perfume
Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200., and/or WHMIS under the HPA
Common Name CAS No. Recommended Limits Composition LD50/LC50
Chemical Name
Range
Monoethanol- 141-43-5 5-10% 1720 mg/kg
2-aminoethanol ACGIH TLV: 3 ppm
amine
OSHA PEL: 3 mg/m3
OSHA PEL: 6 ppm (15 min)
EGPhE 122-99-6 5-10% 1400-3000
Ethylene Glycol
mg/kg
Monophenyl
Ether
SECTION III - HAZARDS IDENTIFICATION
Health Hazards (Acute and Chronic):
Eye Contact: Concentrate causes eye damage. Use dilution may cause mild eye irritation
Skin: Concentrate may cause skin burns. Use dilution may cause mild skin irritation.
Ingestion: Mucous membrane irritant. may result in mild gastrointestinal irritation with nausea,
vomiting and/or diarrhea. Large ingestions may cause temporary dizziness,
uncoordination and headache.
Inhalation: Mucous membrane irritant.
P&G PRO LINE Heavy Duty Spray Cleaner Concentrate MSDS (Continued) Page 2 of 4
SECTION IV - FIRST AID INFORMATION
Emergency and First Aid Procedures:
Eye contact: Flush immediately with water and remove contact lenses if applicable. Hold eyelids open
and flush with a steady, gentle stream of water for 15 minutes. Get medical attention.
Skin irritation: Wash with plenty of soap and water. Get medical attention if irriation persists..
Oral ingestion: DO NOT induce vomiting. Rinse mouth with water. Promptly drink a large quantity of water
or milk. If vomiting occurs, keep head below hips to reduce risk of aspiration. Give water
again. NEVER give anything by mouth to an unconscious or convulsing person. Call a
doctor or get medical attention immediately.
Inhalation: If a large amount of product is inhaled, get fresh air.
**NOTE TO PHYSICIAN: Treat exposed patients symptomatically.
Other: Product package has a caution statement: DANGER: KEEP OUT OF REACH OF CHILDREN.
Corrosive. Causes irreversible eye damage. Causes skin burns. Do not get in eyes, on skin or on clothing. Wear
goggles or face shield, protective clothing and rubber gloves when handling concentrate. Wash thoroughly
with soap and water after handling. Remove contaminated clothing and wash before reuse.
SECTION V - FIRE FIGHTING INFORMATION
Flash Point (Method Used): > 64篊 /147篎 Explosive Limits: LEL: N/A UEL: N/A
Extinguishing Media: Use water spray, dry chemical, carbon dioxide or foam extinguishing agents unless
contraindicated by surrounding environment.
Special Fire Fighting Procedures: Prevent human exposure to fire, smoke, fumes or products of combustion.
All ignition sources should be extinguished. Fire fighters should wear appropriate protective equipment, including
self-contained breathing apparatus and impervious clothing. Keep containers cooled with water spray to prevent
rupture from excess heat.
SECTION VI - ACCIDENTAL RELEASE MEASURES
Personal Precautions: N/A
Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL,
STATE/PROVINCIAL AND LOCAL REGULATIONS. Waste from this product is regulatd as a RCRA
"Corrosive" D002 waste. Check pH before sewering. pH trim is necessary in industrial settings if waste has a pH
of 12.5 or above. Liquids should not be landfilled. See Section XIII
Steps To Be Taken in Case Large Amounts Material are Released or Spilled: Contain the spill. Try to prevent
large quantities from reaching watereway or sewer. Use sorbents if needed. Dispose of resulting waste as
appropriate. Use water spray to dilute and/or wash away spills to avoid exposure and to protect persons working to
stop/repair leak.
SECTION VII - HANDLING AND STORAGE
Precautions To Be Taken in Handling and Storing:. Avoid contact with skin or eyes. Avoid breathing vapor,
spray or mist. Use product only according to label directions. If unsure about safe use, contact your supervisor
immediately. Wash with soap and water after handling. Store in original container in a cool, dry, well-ventilated
area. Store away from food or feed. Containers should be kept tightly closed when not in use. Keep in an area
inaccessible to small children.
P&G PRO LINE Heavy Duty Spray Cleaner Concentrate MSDS (Continued) Page 3 of 4
SECTION VIII - EXPOSURE CONTROLS, PERSONAL PROTECTION
Respiratory Protection (Specify Type): None required with normal use. Where exposure cannot be adequately
controlled by general or local ventilation, use appropriate respiratory protection to avoid overexposure. An
approved dust/mist respirator would be recommended.
Ventilation: General. In areas where sprays or mists may be generated, proper ventilation in accordance with
good industrial hygiene should be provided.
Eye Protection: Chemical resistant goggles or face shield required when handling concentrate. None required at
use dilution.
Protective Gloves: Rubber gloves are required when handling concentrate. None required at use dilution.
Other Protective Equipment: None required with normal use. Easily accessible water source is needed.
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
Specific Gravity (H2O=1): 1.022
Boiling Point 篊 /癋: 82 ?100篊 /180-212篎
Vapor Pressure (mm Hg): N/A Percent Volatile by Volume (%): >90%
Vapor Density (Air=1): N/A Evaporation Rate (nBuOAc=1): > water
Freezing Point: < 32OF
Odor Threshold: N/A
Solubility in Water: Complete pH (100% solution): 12.0-13.0
Appearance and Odor: Dark violet liquid. Reserve Alkalinity: N/A
Product is perfumed with pine scent.
SECTION X - STABILITY AND REACTIVITY
Possible Hazardous Reactions/Conditions/By Products: None known
Conditions to Avoid: Temperatures above 54篊 /130篎 or below 0篊 /32篎
Materials to Avoid: Do not mix with other chemicals. Hazardous conditions may arise from improper mixing of
chemicals.
Hazardous Decomposition Products: Thermal decomposition may generate toxic materials such as oxides of
carbon and nitrogen.
Other Recommendations: None
Stability: Stable at ambient temperatures
Hazardous Polymerization: Will not occur.
SECTION XI - TOXICOLOGICAL INFORMATION
No toxicological tests have been conducted on this formula.
SECTION XII - ECOLOGICAL INFORMATION
No concerns at relevant environmental concentrations.
P&G PRO LINE Heavy Duty Spray Cleaner Concentrate MSDS (Continued) Page 4 of 4
SECTION XIII - DISPOSAL CONSIDERATIONS
Waste Disposal Method: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH FEDERAL,
STATE/PROVINCIAL AND LOCAL REGULATIONS. Undiluted product is regulated as a RCRA Corrosive
waste when disposed. Check pH before disposing. Treatment to reduce pH may be necessary before disposal. Do
not landfill liquids.
SECTION XIV - TRANSPORT INFORMATION
? Ground Transport (DOT): Consumer Commodity ORM-D
? Air Transport (IATA): Corrosive Liquid, basic, inorganic, n.o.s. (Monoethanolamine, 1-octyl 2-
pyrrolidinone), 8, UN3266, PGIII
? Marine/Water Transport (IMDG): Corrosive Liquid, basic, inorganic, n.o.s. (Monoethanolamine, 1-octyl 2-
pyrrolidinone), 8, UN3266, PGIII,).
SECTION XV - ADDITIONAL REGULATORY INFORMATION
All intentionally added components are listed on the US TSCA Inventory.
No components of P&G ProLine Heavy Duty Spray Cleaner for Automatic Dilution are subject to California
Proposition 65.
The product is in compliance with State laws. Information will be sent to the states upon request. The following
chemicals are listed on state right-to-know lists or state worker exposure lists:
Glycol Ether EPH (CAS# 122-99-6) CA, IL, LA, NJ, PA
Monoethanolamine (CAS# 141-43-5) CA, CN, IL, IN, KY, MA, MN, NC, NJ, OR, PA, RI
Procter & Gamble's importation of this product into Canada is in compliance with all CEPA NSN Regulations.
This product has been classified with the Hazard Criteria of the Canadian Control Products Regulation (CPR) and
this MSDS contains all information required by the Controlled Products Regulation.
SECTION XVI - OTHER INFORMATION
*N/A. - Not Applicable *N/K. - Not Known
The submission of this MSDS may be required by law, but this is not an assertion that the substance is hazardous
when used in accordance with proper safety practices and normal handling procedures. Data supplied is for use
only in connection with occupational safety and health.
The information contained herein has been compiled from sources considered by Procter & Gamble to be
dependable and is accurate to the best of the Company's knowledge. The information relates to the specific
material designated herein, and does not relate to the use in combination with any other material or any other
process. Procter & Gamble assumed no responsibility for injury to the recipient or third persons, for any damage to
any property resulting from misuse of the controlled product.
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