MATERIAL SAFETY DATA SHEET
SECTION I ?Chemical Product and Company Identification
Product Name: 7824T BLACK INK
Product Number: 201-1531
Manufacturer: Xandex, Inc.
1125 N. McDowell Blvd.
Petaluma, CA 94954
USA
Web Site: www.xandex.com
Emergency Telephone: (800) 767-9543, or (707) 763-7799
SECTION II ?Composition/Information on Ingredients
COMPONENTS % CAS# RISK STATEMENTS HAZARD SYMBOLS
Diacetone Alcohol 12 123-42-2 R11-36 Xi, F
2-Phenoxyethanol 47 122-99-6 R22-36 Xn
Nigrosine Dye 4 8005-02-5 R21/22, R40, R48/24/25 T
SECTION III ?Hazards Identification
NFPA Rating System: HMIS II Rating System:* HMIS III Rating System:
Health: 2 Health: 2 Health: 2
Flammability: 2 Flammability: 2 Flammability: 2
Instability: 0 Reactivity: 0 Physical Hazard: 0
PPE (protection) : B PPE (protection): B
* HMIS II has been replaced by HMIS III
Carcinogen: NTP - No IARC - No OSHA ?No
Effects of Overexposure:
Eyes: Product can cause severe irritation to eyes on contact.
Skin: Product can cause moderate irritation to skin on contact.
Inhalation: Vapor or mist can cause irritation to the nose and throat.
Ingestion: Harmful if swallowed.
Additional Health Hazard Information:
2-Phenoxyethanol: The manufacturer has established an internal industrial hygiene guide of 25 ppm
(skin) (8 hour TWA) for exposure.
At doses that increased liver weight in treated F0 mice, 2-Phenoxyethanol produced significant
reproductive and developmental toxicity. The substance caused significant toxicity in growing animals
as evidenced by the decreased body weight in neonates and the large increase in post-natal lethality as
the F1 animals grew to the age of mating.
Reproductive Assessment by Continuous Breeding: Evolving Study Design and Summaries of Ninety
Studies, Robert E. Chapin and Richard A. Sloane.
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7824T Black
MATERIAL SAFETY DATA SHEET
Environmental Health Perspectives, 105 (Suppl1):199-395 (1997).
SECTION IV ?First Aid Measures
Eyes: Flush with water for 15 minutes. Call physician immediately.
Skin: Wash with soap and water. Launder contaminated clothing before reuse.
Inhalation: Remove to fresh air.
Ingestion: If employee is conscious, give two glasses of water. Get medical attention immediately.
SECTION V ?Fire Fighting Measures
Extinguishing Media: Dry chemical, C02, alcohol foam.
Unusual Fire and Explosion Hazards: Emits toxic fumes under fire conditions.
Special Fire fighting Methods: Wear self-contained breathing apparatus and protective clothing to
prevent contact with skin and eyes.
SECTION VI ?Accidental Release Measures
Eliminate all sources of ignition. Wear protective clothing and gloves. Absorb spilled material with
vermiculite or floor absorbent.
SECTION VII ?Handling and Storage
Maximum 25C (77o F)
Storage Temperature:
Store away from excessive heat (e.g., steampipes, radiators), from sources of ignition and from reactive
materials. Avoid contact with skin, eyes, and clothing.
PLEASE READ TECHNICAL DATA SHEET BEFORE HANDLING THIS PRODUCT.
SECTION VIII ?Exposure Controls/Personal Protection
Eye Protection: Safety goggles
Respiratory Protection: For continuous exposure to large quantities, wear respirator
(MSHA/NIOSH approved) as required for concentrations of air
contaminants encountered.
Skin Protection: Chemical resistant gloves. Avoid repeated or prolonged exposure. Wash
thoroughly after handling.
Ventilation Requirements: Sufficient to prevent operator discomfort.
SECTION IX ?Physical and Chemical Properties
>69.5o C
Flash Point:
Vapor Pressure: <1 @ 20 C (mm Hg)
Solubility in Water: Non-Soluble
Evaporation Rate: <1 (Butyl Acetate = 1)
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MATERIAL SAFETY DATA SHEET
Odor: Alcoholic odor
Appearance: Opaque black liquid
Vapor Density: >4 (Air = 1)
Specific Gravity: 1.076 (Water = 1)
Volatile / Non-Volatile (Solids): 83.9% Volatile / 16.1% Non-Volatile
SECTION X ?Stability and Reactivity
Stability: Stable under normal conditions
Conditions to Avoid: Heat and flame
Hazardous Combustion Products: CO, C02, and oxides of nitrogen
Materials to Avoid: Strong oxidizing agents
SECTION XI ?Toxicological Information
Acute Effects:
Harmful if swallowed
May be harmful if inhaled or absorbed through skin.
May cause skin irritation.
Material may be irritating to mucous membranes and upper respiratory tract.
Toxicity Data, 2-Phenoxyethanol:
LD50 dermal (rabbit): 5 ml/kg
LD50 oral (rat): 1260 mg/kg
The chemical, physical, and toxicological properties of this material have not been thoroughly investigated.
SECTION XII ?Ecological Information
Data not yet available.
SECTION XIII ?Disposal Considerations
This combustible material may be burned in a chemical incinerator equipped with an afterburner and
scrubber. Observe all federal, state, and local environmental regulations.
SECTION XIV ?Transport Information
No restrictions if shipped in cartridges.
SECTION XV ?Regulatory Information
European Information:
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MATERIAL SAFETY DATA SHEET
Xn: R22
Harmful if swallowed.
Xi: R36/37/38
Irritating to eyes, respiratory system, and skin.
S26
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
RCRA Status:
Not a hazardous waste under RCRA (40 CFR 261)
CERCLA Status:
Not listed
TSCA Status:
TSCA Listed
SARA Title III:
This product contains the following toxic chemicals subject to the routine annual "Toxic Chemical Release
Notification" under Section 313 (40 CFR 372).
Chemical Name CAS Number % By Weight
2-Phenoxyethanol 122-99-6 47%
California Right to Know Act (Prop. 65):
The following is a required statement:
WARNING!!!
This product may contain trace amounts of a chemical known to the state of California to cause
cancer.
Chemical Name CAS Number % By Weight
Aniline 62-53-3 < .1%
SECTION XVI ?Other Information
The above information is believed to be correct but does not purport to be all-inclusive and shall be used only
as a guide. See reverse side of invoice or packing slip for additional terms and conditions of sale.
Date of last revision: 10/09.