MATERIAL SAFETY DATA SHEET
Total Solutions
P.O. Box 240014
Milwaukee, WI 53224
GENERAL INFORMATION NUMBER: (414) 354-6417 REVISION DATE: August 10, 2006
CHEMTREC: (800) 424-9300 DATE OF ISSUE: August 22, 2006
I - Product Identification
Turf King
PRODUCT CODE: 0322
CHEMICAL FORMULATION: Liquid herbicide concentrate.
NFPA HAZARD IDENTIFICATION SYSTEM: HEALTH: 2 FLAMMABILITY: 2 REACTIVITY: 0
HAZARD RATING: 4 - Extreme; 3 - High; 2 - Moderate; 1 - Slight; 0 - Insignificant
II - Hazardous Ingredients
Values reported as TWA unless noted.
APPROX OSHA ACGIH EPA 40 CFR:
% PEL TLV 302 355 372 CAS #
SUBSTANCE
Petroleum Distillates 70.0-80.0 100 ppm 100 ppm N N N 64741-44-2
Ethylbenzenes < 1.00 100 ppm 100 ppm Y N Y 100-14-4
n-Butanol 1.00-5.00 50 ppm (skin)C 50 ppm (skin)C Y N Y 71-36-3
Xylene 1.00-5.00 100 ppm 100 ppm Y N Y 1330-20-7
Glycol Monophenyl Ether 1.00-5.00 N/E N/E N N Y 122-99-6
1,2,4-Trimethylbenzene 1.00?.00 25 ppm 25 ppm N N Y 95-63-6
2,4-bis(isopropylamino)-6-methoxy-S- 3.73 N/E N/E N N N 1610-18-0
triazine (Prometon)
o-Xylene 1.00-5.00 100 ppm 100 ppm Y N Y 95-47-6
Key: PEL: Permissible Exposure Limit TLV: Threshold Limit Value C: Ceiling level STEL: Short Term Exposure Limit
N/A: Not Applicable N/D: Not Determined N/E: Not Established Y: Yes N: No
302: CERCLA List of Hazardous Substances and Reportable Quantities (40 CFR 302.4).
355: SARA TITLE III / List of Extremely Hazardous Substances for Emergency Planning and Notification (40 CFR 355).
372: SARA TITLE III / List of Toxic Chemicals subject to Release Reporting (Community Right to Know) (40 CFR 372).
III - Physical Data
SPECIFIC GRAVITY (WATER = 1): 0.87
BOILING POINT (癋): N/A
VAPOR PRESSURE (mm Hg): N/D VOC CONTENT (% by weight): < 90.0
VAPOR DENSITY (AIR = 1): N/D EVAPORATION RATE (WATER = 1): > 1.0
SOLUBILITY IN WATER: Emulsifies pH: N/A
APPEARANCE AND ODOR: Reddish-brown liquid; typical petroleum distillate odor.
IV - Fire and Explosion Hazard Data
FLASH POINT (癋): 123 (TEST METHOD): Closed cup
FLAMMABLE LIMITS IN AIR (VOLUME %) UPPER: N/D LOWER: N/D
EXTINGUISHING MEDIA: Foam, carbon dioxide, dry chemical.
SPECIAL FIRE FIGHTING PROCEDURES: Firefighters should be equipped with full protective gear including self-contained
breathing apparatus. Fire may produce hazardous vapors. Minimize amount of water used to fight fire, as runoff may cause pollution.
Contain any runoff for proper disposal. Cool containers with water fog
UNUSUAL FIRE AND EXPLOSION HAZARD: Solvent vapors may flash back.
PRODUCT NAME: Turf King PRODUCT CODE: 0322
V - Reactivity Data
STABILITY: Stable
INCOMPATIBILITY: Strong oxidizing agents.
CONDITIONS TO AVOID: None
HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon and nitrogen.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: None
VI - Health Hazard Data
ROUTES OF ENTRY INHALATION: X EYE CONTACT: X SKIN CONTACT: X INGESTION: X
INGREDIENTS THAT ARE CONSIDERED BY OSHA, NTP, IARC TO BE SUSPECTED HUMAN CARCINOGENS: Xylene
(CAS #1330-20-7), o-Xylene (CAS #95-47-6).
EFFECTS OF OVEREXPOSURE
IF IN EYES: Severe irritation, redness, tearing, blurred vision.
IF ON SKIN: Irritation, with prolonged or repeated exposure.
IF SWALLOWED: Gastrointestinal irritation, nausea, vomiting, diarrhea.
IF INHALED: Respiratory tract irritation, dizziness, weakness, headache, nausea, unconsciousness.
EMERGENCY AND FIRST AID PROCEDURES
IF IN EYES: Flush eyes and under eyelids with plenty of cool water for at least 15 minutes. Obtain medical attention.
IF ON SKIN: Remove contaminated clothing and lauder before re-use. Wash thoroughly with soap and water. If irritation persists,
obtain medical attention.
IF SWALLOWED: Contact physician or poison control center immediately. Do not induce vomiting. Never give anything to an
unconscious person.
IF INHALED: Remove person to fresh air. Perform artificial respiration if indicated. Obtain medical assistance.
VII - Spill or Leak Protection
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Ventilate area and remove all sources of ignition. Soak up
spilled material with an inert absorbent material and place in a properly labeled container for disposal.
WASTE DISPOSAL METHOD: Consult local environmental authorities.
VIII - Special Protection Information
RESPIRATORY PROTECTION: Use with adequate ventilation. Do not breathe vapors or mists. If recommended Exposure Limits
are exceeded wear a NIOSH approved respirator, following manufacturer's recommendations.
VENTILATION LOCAL: Recommended MECHANICAL: Not required
PROTECTIVE GLOVES: Chemical resistant.
EYE PROTECTION: Chemical goggles or face shield.
OTHER PROTECTIVE EQUIPMENT: Emergency shower, eye wash station, and protective clothing.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store in a cool, dry place, away from heat or open flame.
Keep container tightly closed when not in use. Do not contaminate water, feed or seed by storage or disposal.
OTHER PRECAUTIONS: Keep out of reach of children.
IX - Transportation Information (ground transportation only)
DOT PROPER SHIPPING NAME: None
DOT CLASS: None DOT ID NUMBER: None DOT PACKING GROUP: None
The shipping information listed above applies only to non-bulk (< 119 gallons) containers of this product. This product may have more than one proper shipping
name depending on packaging, product properties, & mode of shipment. If any alteration of packaging, product, or mode of transportation is further intended,
different shipping names and labeling may apply.
REVISION DATE: August 10, 2006 Prepared by: Technical Dept. DATE OF ISSUE: August 22, 2006
This information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the
results to be obtained from the use thereof. Total Solutions assumes no responsibility for personal injury or property damage to the vendee, users or third parties
caused by the material such vendees or users assume all risks associated with the use of this material.
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