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122-99-6 65-85-0 520-45-6

File Name: 122-99-6_65-85-0_520-45.asp

                                     Material Safety Data Sheet
2A528D
Revision Date: 02/12/2009
Issued: 02/12/2009
OPTIPHEN ND
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Responsible Party: International Specialty Products
1361 Alps Rd.
Wayne, N.J. 07470
U.S.A.
Telephone: (973) 628-4000

Emergency Telephone Number: CHEMTREC: 1-800-424-9300 or 703-527-3887 (Outside of the USA)
(Spill Related Emergencies)
PROSAR: 1-800-241-7439 (Health Related Emergencies)

Prepared By: Product Stewardship

Product Id: 2A528D

Product Name: OPTIPHEN ND

CAS Registry Number: 122-99-6; 65-85-0; 520-45-6

CAS Name: 2-Phenoxyethanol; Benzoic Acid ; 3-Acetyl-6-methyl-2H-pyran-2,4(3H)-dione

Synonyms: Phenoxyethanol; Benzoic Acid; Dehydroacetic Acid (INCI NAMES)

2. HAZARDS IDENTIFICATION
Emergency Overview
WARNING!
HARMFUL IF SWALLOWED.
CAUSES SEVERE EYE IRRITATION.
Yellow Liquid
Characteristic Odor

Hazard Overview
Target Organs: Eyes
Central Nervous System
Kidney

Primary Route(s) of Exposure: Eyes. Skin. Inhalation.

Acute Health Hazards: Causes severe eye irritation.

Chronic Health Hazards: None known.

Signs and Symptoms of Overexposure
Eye Contact: Causes severe eye irritation. May cause tissue damage.

Skin Contact: Causes mild skin irritation.

Ingestion: Harmful if swallowed.

Inhalation: May cause respiratory tract irritation.

3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
Components: Weight %

2A528D
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3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
Components: Weight %
2-PHENOXYETHANOL 80
122-99-6
Benzoic Acid 12
65-85-0
3-ACETYL-6-METHYL-2H- 8
PYRAN-2,4(3H)-DIONE
520-45-6

4. FIRST AID MEASURES
Eye Contact: In case of contact, or suspected contact, immediately flush eyes with plenty of water
for at least 15 minutes and get medical attention immediately after flushing.

Skin Contact: Wash with soap and water.

Ingestion: Slowly dilute with 1-2 glasses of water and seek medical attention. Never give anything
by mouth to an unconscious person.

Inhalation: No specific treatment is necessary since material is not likely to be hazardous by
inhalation. If exposed to excessive levels of dust or fumes, remove to fresh air and get
medical attention if cough or other symptoms develop.

5. FIRE FIGHTING MEASURES
Extinguishing Media: All standard firefighting media

Unusual Fire/Explosion Hazards: Fire will produce oxides of carbon.

Special Protective Equipment: Fire fighters should wear full protective clothing, including self-contained breathing
equipment.

6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary Use appropriate protective equipment. Wear self-contained breathing apparatus in
Measures: enclosed areas.

Procedure for Contain spill with sand or other inert materials.
Cleaning/Absorption:

7. HANDLING AND STORAGE
Handling: Do not get in eyes. Wash thoroughly with soap and water after handling.

Storage: Keep containers tightly closed when not in use. Store in a cool, dry place, out of direct
sunlight.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls: Use in a well ventilated area.

Respiratory Protection: Wear a NIOSH approved respirator appropriate for airborne exposure at the point of use.

Hand Protection: Use gloves as a standard industrial handling procedure.

Eye Protection: Chemical goggles; also wear a face shield if splashing hazard exists.

Exposure Limits:

Components: ACGIH - Threshold Limit Values - Time U.S. - OSHA - Final PELs - Time Weighted
Weighted Averages (TLV-TWA) Averages (TWAs)
2-PHENOXYETHANOL No TLV/TWA Established No TLV/TWA Established
122-99-6 (80)
Benzoic Acid No TLV/TWA Established No TLV/TWA Established
65-85-0 (12)


2A528D
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Components: ACGIH - Threshold Limit Values - Time U.S. - OSHA - Final PELs - Time Weighted
Weighted Averages (TLV-TWA) Averages (TWAs)
3-ACETYL-6-METHYL-2H- No TLV/TWA Established No TLV/TWA Established
PYRAN-2,4(3H)-DIONE
520-45-6 (8)

9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid

Color: Yellow

Odor: Characteristic

Odor Threshold: Not available

pH: approx. 4.0 @ 100 g/L

Specific Gravity: Not determined

Boiling Point (癋): >302

Melting Point/Freezing Point(癋): Not determined

Vapor Pressure: <0.75 mmHg

Solubility: 5g/L @ 68 癋

Flash Point (癋): >266

10. STABILITY AND REACTIVITY
Chemical Stability: Stable under normal conditions of handling, use and transportation.

Hazardous Polymerization: Will not occur

Conditions to Avoid: None anticipated

Materials to Avoid: Strong acids or alkalies., Strong oxidizing agents.

Hazardous decomposition Carbon oxides.
products:

11. TOXICOLOGICAL INFORMATION
Toxicity Test:
Acute Oral LD50 (mg/kg): >2000 (Rat) (Phenoxyethanol)
(Rat) (Dehydroacetic Acid)

Acute Dermal LD50 (mg/kg): >2000
(Rabbit) (Phenoxyethanol)

Acute Inhalation LC50 (mg/l): Not Determined

Skin Irritation: Non-irritant (Rabbit) (Dehydroacetic Acid)

Sensitization: Non-Sensitizing (Guinea Pig) (Phenoxyethanol)

Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is
identified as a known or anticipated carcinogen by NTP.
No component of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.
No component of this product present at levels greater than or equal to 0.1% is
identified as a carcinogen or potential carcinogen by OSHA.




2A528D
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12. ECOLOGICAL INFORMATION
Biodegradability: Readily Biodegradable, >80% (Phenoxyethanol)

Aquatic Toxicity: Fish, LC50 (96h) >100 mg/L (Phenoxyethanol)
Aquatic invertebrates, EC50 (48h) >500 mg/L (Phenoxyethanol)
Aquatic Plants, EC50 (72h) >500 mg/L (Phenoxyethanol)

Microorganism/Effect on Activated Sludge, EC10 (17h) 320 mg/L (Phenoxyethanol)
Activated Industrial Sludge, EC20 >100 mg/L (Phenoxyethanol

13. DISPOSAL CONSIDERATIONS
Disposal of Waste Method: Dispose of in accordance with local regulations.


14. TRANSPORT INFORMATION
Land Transportation:
DOT (Non-Bulk):
UN/NA Number: NONE

DOT Shipping Name: NOT REGULATED

Hazard Class: NONE

DOT (Bulk):
UN/NA Number: NONE

DOT Shipping Name: NOT REGULATED

Air Transportation (IATA):
UN Number: NONE

Proper Shipping Name: NOT REGULATED

Hazard Classification: NONE

Sea Transportation (IMO):
UN/ID Number: NONE

Proper Shipping Name: NOT REGULATED

Hazard Classification: NONE

TDG (Canada):
Proper Shipping Name: NOT REGULATED

Hazard Class: NONE

15. REGULATORY INFORMATION
TSCA Inventory List: This product and/or its components are listed or exempt from the TSCA Inventory

California Proposition 65 This product does not contain any chemicals known to State of California to cause
Carcinogens & Reproductive cancer, birth, or any other reproductive defects.
Toxicity (CRT) List:

WHMIS Ingredient Disclosure List: One or more components of this product is listed on the WHMIS Ingredient Disclosure
list.

Canada DSL Inventory List: This product and/or its components are listed or exempt from the DSL Inventory

Canada NDSL Inventory List: This product and/or its components does not comply with NDSL

Japan Inventory of Existing & This product and/or its components are listed or exempt from the ENCS
New Chemical Substances
(ENCS):
2A528D
Page 4 of 5
Australia Inventory of Chemical This product and/or its components are listed or exempt from the AICS Inventory
Substances (AICS) List:


European Inventory of Existing This product and/or its components are listed or exempt from the EINECS Inventory
Commercial Chemical
Substances (EINECS):

EU List of Notified Chemical This product and/or its components does not comply with ELINCS
Substances (ELINCS)

Components: EPCRA (SARA Title III) Section EPCRA (SARA Title III) Section EPCRA (SARA Title III) Section
313 Toxic Chemical Data - De 302 Hazardous Substances 302 Extremely Hazardous
minimis concentration: Substance
Benzoic Acid 2270 kg (RQ)
65-85-0 (12) 5000 lb (RQ)

16. OTHER INFORMATION
NFPA Rating: Health: 2 Flammability: 1 Reactivity: 0.

HMIS RATING:
HEALTH 2
FLAMMABILITY 1
PHYSICAL HAZARD 0

Prepared By: Product Stewardship

Reason for revision: This data sheet contains changes from the previous version in section(s) 2,7,8,12 and
16

Legend: N.Av.= Not Available; N.A.= Not Applicable

Important Note: For purposes of this MSDS, International Specialty Products, as responsible party,
provides the information herein which is intended for use by persons who have or should
obtain professional knowledge and experience in the subjects discussed. ISP s
industrial products are used as materials in the production of products by industrial
customers. ISP usually has only limited information about the products of its
customers and their composition, methods of manufacture and use. Accordingly, ISP
MAKES NO WARRANTY, EXPRESS OR IMPLIED, AS TO THE ACCURACY,
COMPLETENESS OR RELIABILITY OF INFORMATION HEREIN EXCEPT THAT
SUCH INFORMATION IS, TO THE BEST OF ISP'S KNOWLEDGE AND BELIEF,
ACCURATE AS OF THE DATE INDICATED. ISP recommends that customers
independently test and evaluate its products and their products and processes in which
ISP products are used in order to decide their safety and effectiveness.

***END OF MSDS***




2A528D
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