Material Safety Data Sheet
Marble floorsoap
Section 1. Chemical product and company identification
2735000
: HG International b.v.
Manufacturer Code :
2.01
: Damsluisweg 70 1332 EJ Almere MSDS# :
Address
4-1-2008.
: Netherlands Validation date :
Country
4-1-2008.
: +31 (0)36 54 94 700 Print date :
Telephone No.:
P. Stienstra
: +31 (0)36 54 94 744 Responsible name :
Fax
: www..hginternational.com +1.705.726.5445
:
Internet: Telephone No.:
Solstrand Trading +1.705.734.0857
Supplier : Fax :
: 60 Lockhart road Barrie, Ontario L4N 9G8 Canada
Address Country :
: A protective cleaner.
Material uses
In Case of Emergency : Chem. Tel Inc. (813) 248 0585 or Toll free (800) 255 3924
Section 2. Composition, Information on Ingredients
CAS # % by weight Exposure limits
Name
Water 7732-18-5 75 - 100 Not available.
alcohols, c9-11, ethoxylated 68439-46-3 1-5 Not available.
glycine, n,n-bis(carboxymethyl)-, 5064-31-3 0-1 Not available.
trisodium salt
Preservative. 0 - 0.5 Not available.
Potassium hydroxide 1310-58-3 0 - 0.5 Not available.
Perfume ingredient. 0 - 0.5 Not available.
Triethylamine 121-44-8 0 - 0.5 Not available.
Styrene 100-42-5 <0.1 Not available.
Section 3. Hazards identification
: Liquid. (Visceus)
Physical State and
Appearance
Emergency overview :
Do not ingest. Avoid contact with eyes, skin and clothing. If swallowed, seek medical advice immediately
and show this container or label. Keep out of the reach of children.
: Dermal contact. Eye contact. Ingestion.
Routes of entry
Potential acute health effects
May cause eye irritation.
Eyes :
May cause skin sensitization.
Skin :
Can cause irritation.
Inhalation :
May be harmful if swallowed.
Ingestion :
: CARCINOGENIC EFFECTS: MUTAGENIC EFFECTS: Not available.
Potential chronic health
TERATOGENIC EFFECTS: Not available.
effects
: Repeated exposure to a highly toxic material may produce general deterioration of health by an
Medical conditions
accumulation in one or many human organs.
aggravated by
overexposure:
: Not available.
Over-exposure
signs/symptoms
See toxicological Information (section 11)
Continued on next page
Page: 2/5
Marble floorsoap
Section 4. First aid measures
: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical
Eye Contact
attention if irritation occurs.
: In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes.
Skin Contact
Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
: If inhaled, remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial
Inhalation
respiration. Get medical attention.
: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to
Ingestion
an unconscious person. Get medical attention if symptoms appear.
: Not available.
Notes to Physician
Section 5. Fire fighting measures
May be combustible at high temperature.
Flammability of the product :
Not available.
Auto-ignition Temperature :
Lowest known value: Closed cup: >150癈 (302癋). (alcohols, c9-11, ethoxylated)
Flash Points :
Not available.
Flammable limits :
Decomposition products may include the following materials: carbon oxides (CO, CO2), nitrogen oxides
Products of combustion :
(NO, NO2...).
: Not considered to be flammable according to our database.
Fire hazards in presence of
various substances
: Not available.
Explosion hazards in
presence of various
substances
: Use an extinguishing agent suitable for surrounding fires.
Fire fighting media and
instructions Wear appropriate respirator when ventilation is inadequate.
No specific hazard.
: Fire fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA)
Special protective equipment
with a full facepiece operated in positive pressure mode.
for fire-fighters
: No additional remark.
Special remarks on fire
hazards
Special remarks on explosion : Not available.
hazards
Section 6. Accidental release measures
: Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective
Personal precautions
equipment (Section 8).
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Environmental precautions
: If emergency personnel are unavailable, contain spilled material. For small spills add absorbent (soil
Methods for cleaning up
may be used in the absence of other suitable materials) scoop up material and place in a sealed, liquid-
proof container for disposal. For large spills dike spilled material or otherwise contain material to ensure
runoff does not reach a waterway. Place spilled material in an appropriate container for disposal.
Section 7. Handling and storage
: Wash thoroughly after handling. Do not ingest. Avoid prolonged contact with eyes, skin, and clothing. If
Handling
swallowed, seek medical advice immediately and show this container or label. Keep out of the reach of
children.
: Keep container tightly closed. Keep container in a cool, well-ventilated area.
Storage
Continued on next page
Page: 3/5
Marble floorsoap
Section 8. Exposure Controls, Personal Protection
: No special ventilation requirements.
Engineering controls
Personal protection
splash goggles
Eyes :
lab coat
:
Skin
A respirator is not needed under normal and intended conditions of product use.
Respiratory :
Gloves.
Hands :
Not available.
:
Other protection
:
Personal protective
equipment (Pictograms)
: Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self-contained breathing apparatus
Personal protection in case
should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient;
of a large spill
consult a specialist BEFORE handling this product.
Consult local authorities for acceptable exposure limits.
Section 9. Physical and chemical properties
: Liquid. (Visceus)
Physical State and
Appearance
White
Color :
Perfumed
Odor :
9.3 (Conc. (% w/w): 100) [Basic.]
pH :
1.007 g/cm3 (20癈 / 68癋)
:
Relative density
Not available.
Viscosity :
Easily soluble in the following materials: cold water, hot water.
Solubility :
Insoluble in the following materials: methanol, diethyl ether, n-octanol, acetone.
Lowest known value: Closed cup: >150癈 (302癋). (alcohols, c9-11, ethoxylated)
:
Flash point
Not applicable.
Flammability (solid, gas) :
Not available.
Explosive properties :
Not available.
Oxidizing properties :
Not available.
Physical chemical comments :
Section 10. Stability and reactivity
: The product is stable.
Stability and Reactivity
: Keep away from heat.
Conditions of instability
: No incompatible product according to our database.
Incompatibility with various
substances
: carbon oxides (CO, CO2) nitrogen oxides (NO, NO2...)
Hazardous Decomposition
Products
: Will not occur.
Hazardous polymerization
Section 11. Toxicological information
alcohols, c9-11, ethoxylated LD50 >2000 mg/kg Oral Rat
LC50 >5 mg/l (0.25 Inhalation Rat
hour(s))
glycine, n,n-bis(carboxymethyl)-, LD50 1100 mg/kg Oral Rat
trisodium salt LD50 681 mg/kg Oral Mouse
LD50 750 mg/kg Oral Monkey.
Potassium hydroxide LD50 273 mg/kg Oral Rat
Styrene LD50 2650 mg/kg Oral Rat
LD50 316 mg/kg Oral Mouse
Continued on next page
Page: 4/5
Marble floorsoap
LD50 >1500 mg/kg Oral Mammal
Triethylamine LD50 460 mg/kg Oral Rat
LD50 546 mg/kg Oral Mouse
:
: CARCINOGENIC EFFECTS: C l a s s i f i e d 2 B ( Po s s i b l e f o r h u m a n .) b y IAR C [g l yc i n e , n ,n -
Chronic effects on humans
bis(carboxymethyl)-, trisodium salt]. Classified A4 (Not classifiable for human or animal.) by ACGIH
[Triethylamine].
: Hazardous by the following route of exposure: of eye contact (irritant).
Other toxic effects on
humans
: Not available.
Special remarks on toxicity
to animals
: Not available.
Special remarks on chronic
effects on humans
: Not available.
Special remarks on other
toxic effects on humans
Specific effects
: Contains material which may cause cancer.. Risk of cancer depends on duration and level of exposure.
Carcinogenic effects
: No known significant effects or critical hazards.
Mutagenic effects
: No known significant effects or critical hazards.
Reproduction toxicity
Section 12. Ecological information
glycine, n,n-bis(carboxymethyl)-, trisodium Fish (LC50) 96 hour(s) >200 mg/l
salt
glycine, n,n-bis(carboxymethyl)-, trisodium Fish (LC50) 96 hour(s) >200 mg/l
salt
Styrene Selenastrum capricornutum 48 hour(s) 0.56 mg/l
(EC50)
Daphnia magna (EC50) 48 hour(s) 4.7 mg/l
Pimephales promelas (LC50) 96 hour(s) 4.02 mg/l
Pimephales promelas (LC50) 96 hour(s) 10 mg/l
Lepomis macrochirus (LC50) 96 hour(s) 25.05 mg/l
Pimephales promelas (LC50) 96 hour(s) 29 mg/l
Not available.
BOD and COD :
Biodegradable
Biodegradable/OECD :
Not available.
Mobility :
Decomposition products may include the following materials: carbon oxides (CO, CO2) and water,
Products of degradation :
nitrogen oxides (NO, NO2...).
: The products of degradation are less toxic than the product itself.
Toxicity of the products of
biodegradation
: Not available.
Special remarks on the
products of biodegradation
Section 13. Disposal considerations
: The generation of waste should be avoided or minimised wherever possible. Avoid dispersal of spilled
Waste information
material and runoff and contact with soil, waterways, drains and sewers. Disposal of this product, solutions
and any by-products should at all times comply with the requirements of environmental protection and
waste disposal legislation and any regional local authority requirements.
: Not available.
Waste stream
Consult your local or regional authorities.
Continued on next page
Page: 5/5
Marble floorsoap
Section 14. Transport information
Regulatory UN Proper shipping name Class Packing group Label Additional information
Information number
Not - - - Remarks
DOT
regulated. Keep in frostfree area
Classification
Not - - - Remarks
TDG
regulated. Keep in frostfree area
Classification
- - -
Not Remarks
ADR/RID
regulated.
Class Keep in frostfree area
- - -
Not Remarks
IMDG Class
regulated. Keep in frostfree area
Not - - - RemarksKeep in
IATA-DGR
regulated.
Class frostfree area
Section 15. Regulatory information
: Not controlled under WHMIS (Canada).
WHMIS (Canada)
No products were found.
International regulations
EINECS : Not available.
DSCL (EEC) : R36- Irritating to eyes.
International lists :
Section 16. Other information
Label Requirements :
Hazardous Material 1 National Fire
Health Flammability
0
Information System Protection
0
Fire hazard
Health Instability
1 0
(U.S.A.) Association
0
Reactivity
(U.S.A.) Special
C
Personal protection
: Not available.
References
Other special considerations : Not available.
4-1-2008.
Date of printing :
4-1-2008.
:
Date of issue
No previous validation.
Date of previous issue :
2.01
Version :
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its
subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should
be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
|