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Hitachi Industrial Equipment Systems Co., Ltd CL-04 Version 2.00 issue 2005.8.31 revision 2008.10.24
MATERIAL SAFETY DATA SHEET
1 IDENTIFICATION
Product name :CL-04
Name of company :Hitachi Industrial Equipment Systems Co., Ltd
Address :1-1,Higashitaga-cho 1-chome, Hitachi-shi, Ibaraki-ken, Japan
Tel :+81-294-36-8682
Fax :+81-294-36-8975
Recommended use of the chemical
and restrictions on use :Printing Ink for industrial Marking
2 HAZARDS IDENTIFICATION
Physico-chemical endpoints :Flammable liquid Category 2
Acute toxicity - oral :Not available
Acute toxicity - dermal :Not available
Acute toxicity - inhalation air :Not identified
Acute toxicity - inhalation vapors :Not identified
Acute toxicity - inhalation dust, mist :Not identified
Skin corrosion/irritation :Category 2
Eye damage/irritation :Category 2
Sensitization - respiratory :Not identified
Sensitization - skin :Not available
Germ cell mutagenicity :Category 1
Carcinogenicity :Not available
Toxic to reproduction :Category 1
Effects on or via lactation :Not identified
Specific target organ systemic toxicity
(Single exposure) :Category 1
(Repeated exposure) :Category 1
Aspiration toxicity :Not available
Hazardous to the aquatic environment
-Acute hazard :Not available
-Chronic hazard :Not available
To the best of our knowledge, the information contained here in is accurate. However, neither the above
named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.
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Hitachi Industrial Equipment Systems Co., Ltd CL-04 Version 2.00 issue 2005.8.31 revision 2008.10.24
GHS label elements
Hazard symbols:Flame,Exclamation mark,Health hazard
Signal word: Danger
Hazard statement and precautionary statement
?Flammable liquid and vapour
?Causes skin irritation
?Causes eye irritation
?May cause genetic defects
?May damage fertility or the unborn child
?Causes damage to organs-single exposure
?Causes damage to organs through prolonged or repeated exposure.
?:Not identified
Precautionary statements:
?Keep out of reach of children. Read label before use. If medical advice is needed: Have product
container or label at hand.
Prevention
?Keep away from ignition sources such as heat/sparks/open flame?No smoking.
?Take precautionary measures against static discharge.
?Wear protective gloves and eye/face protection as specified by the competent authority.
?Do not breathe dust/mist/vapors.
?Use only in a well-ventilated area. Call a doctor/physician if you feel unwell.
?Do not eat, drink or smoke when using this product.
?Avoid contact during pregnancy/while nursing.
?Wash hands thoroughly after handling.
Response
?In case of fire, use dry chemical, CO2, water splay (fog) or form for extinction.
?IF SWALLOWED: Call a doctor/physician if you feel unwell. Rinse mouth.
?IF ON SKIN: Gently wash with plenty of soap and water.
?Wash/Decontaminate removed clothing before reuse.
?If skin irritation occurs, seek medical advice/attention.
?IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
?IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. Immediately call a doctor/physician.
?Collect spillage.
Storage
?Store in cool/well-ventilated place. Store locked up.
?Call a doctor/physician if exposed or you feel unwell.
To the best of our knowledge, the information contained here in is accurate. However, neither the above
named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.
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Hitachi Industrial Equipment Systems Co., Ltd CL-04 Version 2.00 issue 2005.8.31 revision 2008.10.24
Disposal
?Waste must be disposed of according to applicable regulations.
3 Composition/information on ingredients
Substance or mixture; mixture
Composition;
Chemical name concentration (%) CAS number
Ethanol 65-75 64-17-5
Triethylamine 1-2 121-44-8
4 First-aid measures
Inhalation;
Remove the victim from the contamination immediately to fresh air. Keep the victim warm and quiet and
arrange for transport to the neatest medial facility for examination and treatment by a physician as soon
as possible.
Skin contact;
Remove all contaminated clothing, shoes and socks from the affected areas as quickly as possible.
Wash the affected area under running water using a mild soap. If irritation persists, arrange for transport
to the nearest medical facility for examination and treatment by a physician as son as possible.
Eye contact;
Gently rinse the affected eyes with clean water for at least 15 minutes. Remove contact lenses if easily
possible. and refer for medical attention.
Ingestion;
Never give anything by mouth to someone who is unconscious or convulsing. If the victim is responsive,
give him one or two glasses of water. And refer for medial attention.
5 Fire-fighting measures
Suitable extinguishing media;
Use dry chemical, CO2, water splay (fog) or form.
Fire fighting procedures;
Use water spray to cool fire-exposed surfaces and to protect personnel. Shut off "fuel" to fire. If a leak
or spill has not ignited, use water spray to disperse the vapors.
Avoid spraying water directly into storage containers due to danger of boil over.
Unusual fire/explosion hazard;
Flammable liquid, can release vapors that form flammable mixtures at temperatures at or above the
flashpoint.
Special protective equipment and precautions for fire fighters;
Fire fighters should wear boots, overalls, gloves, eye and face protection and breathing apparatus.
6 Accidental release measures
Shut off all sources of ignition; No smoking or flames in area. Absorb spill with inert material (e.g.,
dry sand or earth), then place in closed containers using non-sparking tools. Flush residual spill
To the best of our knowledge, the information contained here in is accurate. However, neither the above
named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.
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Hitachi Industrial Equipment Systems Co., Ltd CL-04 Version 2.00 issue 2005.8.31 revision 2008.10.24
(area) with copious amounts of water.
7 Handling and storage
Handling;
Use only in the well-ventilated areas.
Make available in the work area emergency shower and eyes wash.
Avoid contact with skin or eyes.
Storage;
Close up the container and keep it in dark cool(0~20 ) place.
Keep away from combustible materials and sources of ignition.
8 Exposure controls/personal protection
Exposure guidelines;
ACGIH TLV-TWA (ppm)
Ethanol :1000
Triethylamine :1
ACGIH STEL(ppm)
Ethanol :No data
Triethylamine :3; skin notation
9 Physical and chemical properties
Appearance
Physical state :Liquid
Color :Clear
Odor :Solvent odor
Boiling point : 78.3
Flash point :19.0 closed cup
Upper/lower flammability or explosive limits :Lower 1.2 vol Upper 19 vol
Vapor pressure : 5.9 Pa 20 (ethanol)
Relative density (Air 1) :None known
Relative density :0.87(20 )
Solubility Water :None known
Partition coefficient: n-octanol/water :None known
Auto-ignition temperature :423
Decomposition temperature :No measurement
10 Stability and reactivity
Stability: The product is stable.
Conditions and materials to avoid: Not available
Hazardous decomposition products: These products are carbon oxides
11 Toxicological information
Acute toxicity;
Ethanol
To the best of our knowledge, the information contained here in is accurate. However, neither the above
named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.
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Hitachi Industrial Equipment Systems Co., Ltd CL-04 Version 2.00 issue 2005.8.31 revision 2008.10.24
Not available:Oral 6.2 17.8 (Rat LD50 (g/kg))
Not identified:Dermal No data
Not available:Inhalation 31600 Vaper (Rat LC50(ppm/4h))
Triethylamine
LD50(orl,rat): 460mg/kg(AMIHBC 4, 119, 1951)
LD50(skin,rabbit): 570?L/kg(AMIHBC 4, 119, 1951)
TCLo(ihl,human): 6500?g/m3/4H(OEMEEM 56, 1, 1999)
Skin corrosion/irritation;
Ethanol
Not identified
Triethylamine
Skin; rabbit, Open; 365mg; Mild(UCDS** 3/23/1970)
Serious eye damage/irritation;
Ethanol
Category 2A
Triethylamine
Not identified
Respiratory or skin sensitization;
Ethanol
Not identified
Triethylamine
Not identified
Germ cell mutagenicity;
Ethanol
Category 1B
Triethylamine
Cytogenetic analysis; rat; ihl; 1mg/m3(GISAAA 36(11), 9, 1971)
Carcinogenicity;
Ethanol
Not available Oral 6.2 17.8 (Rat LD50 (g/kg))
Triethylamine
Not available
Reproductive toxicity;
Ethanol
Category 1A
Triethylamine
Not available
STOST-single exposure;
Ethanol
Category 3(Respiratory)
Triethylamine
Not identified
STOST-repeated exposure;
Ethanol
Category 1(Liver) 2(Nervous system)
Triethylamine
Not identified
Aspiration hazard.
Ethanol
To the best of our knowledge, the information contained here in is accurate. However, neither the above
named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.
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Hitachi Industrial Equipment Systems Co., Ltd CL-04 Version 2.00 issue 2005.8.31 revision 2008.10.24
Not identified
Triethylamine
Not identified
12 Ecological information
Toxicity
Ethanol
trout 24h-LC50 g/L :11.2
Carp 96h-LC50 (g/L):18 13.4
Creek Chub 24h-C50(g/L):7
Guppy 7d-LC50(g/L):11
Triethylamine
LC50(fathead minnow): 43.7mg/L/96hr ( BASF AG Ludwigshafen)
LC50(orange-red killifish): 24mg/L/96hr
LC50(daphnids): 34mg/L/48hr
Persistence and degradability:
Ethanol
None known
Triethylamine
This material is not biodegradable.
Bioaccumulative potential:
Ethanol
None known
Triethylamine
This material is low bioaccumulatable.
Mobility in soil:
Ethanol
None known
Triethylamine
Not identified
13 Disposal considerations
Scrap materials may be disposed by licensed contractor or burn in an approved incinerator.
Do not dump into sewer, on the ground or into any body of water.
Follow national and local regulations.
14 Transport information
Follow all regulations in your country.
UN Number :1210
UN Proper Shipping Name :Printing ink, flammable
Transport hazard class :Class 3(Flammable liquid)
Packing Group :
Environmental hazards :No
15 Regulatory information
Follow all regulations in your country.
Content of RoHS Directive material Cd<100ppm Pb, Hg, Hexavalent Cr, PBB, PBDE<1000ppm
To the best of our knowledge, the information contained here in is accurate. However, neither the above
named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.
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Hitachi Industrial Equipment Systems Co., Ltd CL-04 Version 2.00 issue 2005.8.31 revision 2008.10.24
16 References
1) Solvent, dye MSDS
2) Results of Eco-toxicity tests of chemicals conducted by Ministry of the Environment in Japan (-2006)
3) International Chemical Safety Cards
To the best of our knowledge, the information contained here in is accurate. However, neither the above
named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.
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