GRANWAX MATERIAL SAFETY DATA SHEET
CLASSICAL
1.Identification of the Substance / Preparation and Company
Substance: Classical
Supplier: Granwax Products Ltd., West Street, Ridding, Alfreton, Derbyshire. DE55 4EW.
Telephone: 01773 541177 Fax:01773 541429.
This revision February 2006
2.Composition / information on ingredients
Composition and classification of components.
Component EINECS No. CAS No. Concentration range Classification Risk phrases
Triethylamine 612-004-00-5 121-44-8 Less than 1% none below 1%
1-5% Xi R36/37/38
Note ?Triethylamine is present in neutralised form and exposure to free amine vapour is not expected
2-(2-butoxyethoxy)ethanol
603-096-008 112-34-5 Approx. 4% Xi R36
From Approved Supply List eighth edition.
3.Hazards identification
This preparation not classified under the CHIP Regulations 2002 as amended.
4.First aid measures
Skin exposure: If soreness or irritation occurs as the result of skin exposure, wash the affected area with clean running water for at
least 15 minutes. If symptoms persist seek medical advice.
Eye splashes:If the material is splashed into the eye, wash the affected eye with clean running water for at least 15 minutes. Seek
medical advice.
Swallowing (ingestion): If material is accidentally swallowed, do not make patient vomit, seek medical advice. This information
should be taken with the patient when seeking medical advice.
Inhalation; Move patient to fresh air. If patient is unconscious, place in the recovery position and seek medical help immediately.
Do not give victim anything to drink if he is unconscious.
5.Fire fighting measures
Non flammable water based liquid.
Product will produce toxic fumes in a fire if water component boiled off.
Fire fighters to wear self contained breathing apparatus.
6.Accidental release measures
Spillages should be contained with a non-combustible adsorbent material and collected for disposal in accordance with the local
regulations.
Spillages should not be allowed to run to surface waters.
7.Handling and storage
Protect from freezing and temperatures above 40 C.
All chemical preparations should be stored securely where they cannot be interfered with or used by unauthorised persons.
8.Exposure controls and personal protection
UK Workplace Exposure Limits (WEL) as per HSE Doc. EH40/2005
Triethylamine 42 mg/m3 8 hour TWA 17 mg/m3 15 min. STEL Sk
2-(2-butoxyethoxy)ethanol no std 8 hour TWA no std 15 min. STEL Sk
Sk - Can be absorbed through skin
From HSE Doc. EH 40/2005 and manufacturers information.
Exposure controls:
Occupational exposure controls;
Respiratory protection: Provide sufficient ventilation during use to ensure WEL is not reached; if this is not possible organic vapour
filter masks should be used (A1 or A2 EN 141).
Hand protection: All types of protective gloves are suitable to protect the hands during use, product does not attack rubber, latex nitrile
or other similar materials. Suitable work-wear or overalls should used to protect clothing and skin.
Eye protection: Safety glasses/goggles with side shields or face shield should be used when handling this material to protect from
liquid droplets or splashes.
Keep away from foodstuffs, drinks and tobacco. Wash hands before breaks and at end of work. Keep working clothes separate.
Immediately remove contaminated clothing.
Environmental exposure controls;
No specific environmental legislation applies, but good practice should be followed. The product should not be allowed to spill or run
into surface waters.
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GRANWAX MATERIAL SAFETY DATA SHEET
9.Physical and chemical properties
Appearance: white liquid Odour: Organic
pH: Approx. 8.5 Boiling point / range: 100 C
Melting point / range Not applicable Flash point: Above 100 C
Flammability Not applicable Autoflammability: Not applicable
Explosive properties Not applicable Oxidising properties: none
Vapour pressure 23 mbar at 25 C Relative density: SG 1.05
Solubility Fully water soluble Partition coefficient: n-octanol / water Not determined
10. Stability and reactivity This preparation is generally stable.
11.Toxicological information
The product is of low general toxicity.
LD50oral(rat) >2000 mg/kg (Based on raw material information)
Reducing the periods of skin exposure to any substance or preparation will reduce the risk of sensitization or other irritation occurring.
12.Ecological information
Aquatic toxicity: Fish toxicity LC50 :> 500mg/kg.
Bacteria toxicity: ECO :> 10000mg/kg
(Based on raw material information)
13.Disposal considerations Any surplus or waste arising from the normal use of this preparation must be disposed of in accordance
with the Hazardous Waste Regulations 2005 and is classified as 07 02 99
14.Transport considerations Not classified as dangerous goods under ADR, IMDG, IATA Regulations.
15.Regulatory information
This preparation is not classified as hazardous under the CHIP regulations 2002 as amended.
No specific labelling requirement.
This substance is classified as a substance hazardous to health within the definition given in Regulation 2 of the COSHH Regulations.
An assessment of the risks to health caused by the use of this substance and the other requirements of the COSHH regulations must
therefore be made by any employer or self employed person using this preparation at work.
16.Other information
Revision comments ?amendments have been made to sections 1, 2, 4, 5, 8, 11, 12, 13, 14, 15 and 16.
Full text of risk phrases used in section 2;
R36 - Irritating to the eyes
R37 - Irritating to the respiratory system
R38 - Irritating to the skin
It is recommended that all persons using this product be suitably trained in the use of relevant personnel protective equipment.
No other safety information is applicable to the use of this preparation for its intended purpose.
This data sheet was compiled using information from raw material manufacturers, The Chemicals (Hazard Information and Packaging
for Supply) Regulations 2002 (as amended), the Approved classification and labelling guide (fifth edition) for supply, the Approved
Supply List (eighth edition), EH40/2005 and the Approved Carriage List (third edition).
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