Material Safety Data Sheet

CB Glass

1560 Craft Center Drive

Smithville TN 38582

615-597-6801 Ext 124



Emergency Phone (CHEM TREC)..............................1-800-424-9300

For all International transportation accidents.......1-703-527-3887 (collect)

Health: 2                      flammability: 2                   Reactivity: 0

Product name: M 761-159 Liquid Luster

I. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Revision Date: 06/05/02

Supercedes: 21/12/01

MSDS NO.: M761-159

II. COMPOSITION/OINFORMATION ON INGREDIENTS

Chemical name                    %        CAS#                PEL

Solvent naphtha (peuoleum)   41-50      64742-88-7       No PEL established

medium aliphatic

Tung oil                      1-5        8001-20-5         No PEL established

Toluene                      <1        108-88-3       200ppm TWA; C300 ppm

Triethylamine                <1       121-44-8 25ppm TWA; 100mg/m3 TWA

Ethylbenzone                 <1 100-41-4         100ppmTWA;435 mg/m3 TWA

Manganese Carboxylate (Mn Neodecanote, Mn Propiona)

                             <1 7439-96-5 compounds, as Mn; C5 mg/m3; fume,

                              as Mn C5 mg/m3

Cobalt Compounds             <1        7440-48-4         0.1 mg/m3 TWA

III. HAZARDS IDENTIFICATION

Routes of Entry: Skin contact; eye contact; inhalation; none known;

absorption; ingestion.

Medical Condition Aggravated: Kidney disease. Eye disease. Skin disease

including eczema and sensitization. Respiratory disease including asthma

and bronchitis. Liver disease.

Immediate (Acute) Health Effects

Inhalation: Can cause severe central nervous system depression( including

unconsciousness). No hazard in normal industrial use. High concentration in

immediate area can displace oxygen and can cause dizziness,

unconsciousness, and even death with longer exposure. Overexposure to

processing fumes may cause metal fume fever which is an influenza like

illness. Symptoms include headache, metallic taste in the mouth, cough,

thirst, throat irritation, shortness of breath, fever, sweating and pain in the

limbs. This illness is not permanent and recovery usually occurs within 24-

48 hours after onset. It can cause sever respiratory irritation, dizziness,

weakness, fatique, nausea, headache and possible unconsciousness.

Skin Contact:

Substance is corrosive. Cause sever skin burns. Can cause moderate skin

irritation, defatting, and dermatitis. Not likely to cause permanent damage.

Eye contact:

Can cause irritation. Can cause severe irritation. Eye contact may result in

corneal injury. Symptoms may include discomfort or pain, excess blinking

and tear production, with marked redness and swelling of the conjunctiva.

Temporary vision impairment (cloudy or blurred vision) is possible.

Skin Absorption:

Can be absorbed through the skin but exposure must be extensive adverse

health effects occur. ( A single exposure is not likely to result in the product

being absorbed through the skin in harmful amounts.) Substance is harmful

if absorbed through the skin. Large exposure may be fatal. Harmful if

absorbed through the skin. May cause severe irritation and systemic damage.

Ingestion: Aspiration of material into the lungs can cause chemical

pneumonitis which can fatal, May cause vomiting. Harmful if swallowed.

Irritating to mouth, throat and stomach. Can cause abdominal discomfort,

nausea, vomiting and diarrhea.

Target organ Acute Toxicity:

Toluene: CNS, liver, kidney, skin, eyes, respiratory system

Triethylamine: Skin, eyes, respiratory system, CNS, liver Kidney.

Ethyl benzene: Eyes, respiratory system, skin, CNS

Manganese compounds: respiratory system,, CNS, blood, kidneys

Cobalt metal, dust and fume: Respiratory system, skin

Long-term (Chromic) Health Effects

Carcinogenicity: Contains a substance that is a probable cancer hazard

based on human studies.Reproductive and Developmental Toxicity: Possible

reproductive hazard.

Mutagenicity: No data available to indicate product or any cmponents

present at greater than 0.1% is mutagenic or genotoxic.

Skin Contact: prolonged or repeated contact may cause irritation.

Prolonged contact with this product can cause reddening, swelling, rash,

scaling, or blistering. In those who have developed skin sensitization, thses

sytoms can develop as a result of contact with a very small amount of the

liquid material.

Skin absorption: contains methanol. Upon prolonged or repeated exposure,

may cause deterioration of the optic nerve if large quantities are absorbed

through the skin. Repeated absorption of large quantities may lead to

blindness. Skin sensitization, characterized by redness, inflammation, itching

and/or burning may result from prolonged or repeated contact with this

material.

Target Organ Chronic Toxicity: Kidneys. Eyes. Skin. Nervous System.

Respiratory Tract. Liver. Blood.

Supplemental Health Hazard Information: No additional health

information available.

IV. First Aid

Inhalation: Remove to fresh air. If breathing is difficult, have a trained

individual administer oxygen. If not breathing, give artificial respiration and

have a trained individual administer oxygen. Get medical attention

immediately.

Eyes: Immediately flush eyes with plenty of water. Get medical attention, if

irritation persists. Immediately flush eyes with plenty of water for at least 20

minutes retracting eyelids often. Tilt the head to prevent chemical from

transferring to the n contaminated eye. Get immediate medical attention and

monitor the eye daily as advised by your physician.

Skin Contact: Wash with soap and water. Get medical attention if irritation

develops or persists. (Immediately flush skin with plenty of water. Remove

clothing. Get medical attention immediately. Wash cloth separately from

other articles before reuse. Wash with soap and water. Remove

contaminated clothing and launder. Get medical attention if irritation

develops or persists.

Ingestion: Induce vomiting as a last measure. Induces vomiting may lead to

aspiration of the material into the lungs potential causing chemical

puemonitis that may b fatal. Do not induce vomiting and seek medical

attention immediately. Drink two glasses of water of milk to dilute. Provide

medical care provider with this MSDS.

Notes to MD: No additional first aid information available.

V. Fire Fighting Measures Flammability Summary

Flash point:       45C; 113F

Upper flammable/Explosive Limit, % in air: 6.0 @ 77F

Lower Flammable/Explosive Limit, % in air:             0.0 @ 77F

Fire Hazards: vapors may be ignited by heat, sparks, flames or other

sources of ignition at or above the low flash point giving rise to a class B

fire. Vapors are heavier than air and may travel to a source ignition and flash

back.

Extinguishing Media: Alcohol foam sand. Use alcohol resistant foam,

carbon dioxide, or dry chemical extinguishing agents. Water spray or fog

may also be effective for extinguishing if swept across the base of the fire.

Water can also be used to absorbed heat and keep exposed material from

being damaged by fire.

Fire Fighting Instructions: Vapors may be ignites by heat, sparks, flames

or other sources of ignition at or above the low flash point giving rise to a

Class B fire. Vapors are heavier than air and may travel to a source if

ignition and flash back.

Hazardous Combustion Products: Carbon dioxide, Carbon Monoxide.



VI. Accidental Release Measures

Health Consideration for Spill Response: Exposure to the spilled material

may be irritating or harmful. Follow personal protective equipment

recommendations found in Section VIII of this MSDS. Additional

precautions may be necessary based on special circumstances related by the

spill including; the material spill, the quantity of the spill, the area in which

the spill occurred. Also consider the expertise in the area responding to the

spill.

Spill Mitigation Procedures General Methods: Prevent the spread of any

special spill to minimized harm to human health and the environment if safe

to do so. Wear complete and proper personal protective equipment following

material granulated clay. Gather and store in a sealed container pending a

waste disposal evaluation.

VII. Handling and Storage

Handling: Use spark-proof tools and explosion and explosion-proof

equipment. Wash thoroughly after handling. Avoid contact with material.

Storage: Keep away from source of ignition.

VIII. Engineering Controls and Personal Protective Equipment

Engineering Controls: Explosion proof exhaust should be used.

Protective Equipment

Respiratory tract: Respirators should be selected by and by used inder

direction of a trained health and safety professional following requirement

found in OSHA's respirator standard (29 CFR 1910, 134) and ANSI's

standard for respiratory protection (Z88.2-1992). A written respiratory

protection program, including provisions for medical certification, training,

fit testing exposure assessments, maintenance, inspection, cleaning, and

convenient sanitary storage should be implemented.

Eyes: Wear Chemically resistant safety glasses with side shields when

handling this product. Wear additional eye protection such as chemical

splash goggles and/or face shield when the possibility exists for eye contact

with splashing or spraying liquid, or airborne material. Do not wear contact

lenses. Have an eye wash station available.

Skin: Avoid skin contact by wearing chemically resistant gloves, an apron

and other protective equipment depending upon conditions of use, Inspect

gloves for chemical break-through and replace at regular intervals. Clean

protective equipment regularly. Wash hands and other exposed areas with

mild soap and water before eating, drinking and when leaving work.

IX. Physical Data

Physical State:           Colored Liquid

M7 -159-Tung Oil

Odor: Oily Hydrocarb on

Solids Vol %: 26.5297

Solids Wt %: 33

Material VOC lbs/gal: 407181

Material VOC gms/l: 566.6014

Weight per gallon: 7.0681

X. Stability and Reactivity:

Stability information: Stable.

Conditions to avoid: Avoid: heat, sparks, flame and oxidizing agents.

Caustic amines, alkanoamines andinorganic acids. Contact with water.

Chemical Incompatibility: Strong Oxidizing agents. Strong acid. Water.

XI. Toxicological Information

Chemical name CAS Number LD50/LC50

Toluene              108-88-3     Inhalation LC50 Rat: 49 gn/m3/4H LC50 Mouse: 400 ppm/24H

                                         Oral LD50 Rat: 636 mg/kg; Dermal LD50 rabbit: 14100 ul/kg

Triethulamine            121-44-8        Inhalation LC50 Mouse: 6 gm/m3; oral LD50 Rat: 460 mg/kg; Oral LD50

                                         Mouse: 546 mg/kg; Dermal LD50 Rabbit: 570 ul/kg

Benzene, Ethyl-         100-41-4         Oral LD50 Rat: 3500mg.kg; Dermal LD50 Rabbit: 17800 ul/kg



Manganese               7439-96-5        Oral LD50 Rat; 9gm/kg

Cobal                   7440-48-4        Oral LD 50 Rat: 6171 mg/kg



XII. Ecological information

Overview (for ingredients):             No date Available.

Ecological Toxicity Values:



XIII Disposal Considerations

Water Description for Spent Product: The waste may be a characteristic

hazardous waste. Mixing spent or discarded Material with other material nay

render the mixture hazardous. Perform a hazardous waste determination on

mixture. Spent or discarded material is a hazardous waste.

Disposal Methods: Dispose of by incineration following Federal, State,

Local, or Provincial regulations.

Potential EPA Waste Codes: If discarded, this product is considered a

RCRA ignitable waste, D001.





Components Subjects to USEPA Land Disposal Restrictions:

Toluene         108-88-3      0.79%

Triethulamine   121-44-8      0.2%



Ethyl Benzene      100-41-4        0.2%





XIV. Transportation Information

DOT         Paint 3 UN1263 PG II

            Quart or less ORM-D***Label: None

XV/ Regulatory Information

Toxic Substance Control Act (TSCA)

Chemical Name           Regulation           CASRN              %

Toluene                 SARA 313 Reportable: 108-88-3         0.79

Triethylamine          SARA 313 Repertable 121-44-8           0.2

M701-159 Liquid luster