Page 1/7
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 22.01.2008 Revision: 22.01.2008
1 Identification of the substance/preparation and of the company/undertaking
?Product details
?Trade name: 39128 1 Oz Hardener
?Article number: 39128
?Application of the substance / the preparation catalyst
?Manufacturer/Supplier:
SEM Products Inc.
651 Michael Wylie Dr.
Charlotte, NC 28217
(704)522-1006
?Further information obtainable from:
labsupport@sem.ws : SEM Products 651 Michael Wylie Dr. Charlotte, NC 28217 : phone 1-704-522-1006, M -
TH 7am - 4pm EDT
?Information in case of emergency: 24 HR EMERGENCY CHEMTREC 1-800-424-9300
2 Hazards identification
?Hazard description:
Xi Irritant
E Explosive
?Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
R 2 Risk of explosion by shock, friction, fire or other sources of ignition.
R 36 Irritating to eyes.
R 43 May cause sensitisation by skin contact.
?Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature data.
?GHS label elements
Danger
2.1 Unstable explosives.
Warning
3.3/2A - Causes serious eye irritation.
3.4/1 - May cause an allergic skin reaction.
2.15/E - Heating may cause a fire.
?Prevention:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Keep/Store away from clothing/combustible materials.
Keep only in original container.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
(Contd. on page 2)
GB
DR
Page 2/7
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 22.01.2008 Revision: 22.01.2008
Trade name: 39128 1 Oz Hardener
(Contd. of page 1)
Contaminated work clothing should not be allowed out of the workplace.
Wear protective gloves/protective clothing/eye protection/face protection.
Use personal protective equipment as required.
?Response:
IF ON SKIN: Wash with plenty of soap and water.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Specific treatment (see label).
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Wash contaminated clothing before reuse.
In case of fire: Use for extinction: CO2, powder or water spray.
Explosion risk in case of fire.
DO NOT fight fire when fire reaches explosives.
Evacuate area.
?Storage:
Store in accordance with local/regional/national/international regulations.
Store in a well-ventilated place. Keep cool.
Protect from sunlight.
Store away from other materials.
?Disposal:
Dispose of contents/container in accordance with local/regional/national/international regulations.
3 Composition/information on ingredients
?Chemical characterization
?Description: Mixture of substances listed below with nonhazardous additions.
?Dangerous components:
CAS: 94-36-0 dibenzoyl peroxide Xi, E; R 2-36-43 25-50%
EINECS: 202-327-6 Danger: 2.15/B; 2.1 , 2.15/B
Warning: 3.3/2A, 3.4.S/1
CAS: 84-69-5 diisobutyl phthalate 25-50%
EINECS: 201-553-2
?Additional information: For the wording of the listed risk phrases refer to section 16.
4 First aid measures
?After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
?After skin contact: Immediately wash with water and soap and rinse thoroughly.
?After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
?After swallowing: If symptoms persist consult doctor.
5 Fire-fighting measures
?Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
(Contd. on page 3)
GB
DR
Page 3/7
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 22.01.2008 Revision: 22.01.2008
Trade name: 39128 1 Oz Hardener
(Contd. of page 2)
?Protective equipment: No special measures required.
6 Accidental release measures
?Person-related safety precautions: Remove persons from danger area.
?Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
7 Handling and storage
?Handling:
?Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
?Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Prevent impact and friction.
?Storage:
?Requirements to be met by storerooms and receptacles: No special requirements.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions:
Keep container tightly sealed.
Protect from heat and direct sunlight.
8 Exposure controls/personal protection
?Additional information about design of technical facilities: No further data; see item 7.
?Ingredients with limit values that require monitoring at the workplace:
84-69-5 diisobutyl phthalate
WEL Long-term value: 5 mg/m?br>
?Additional information: The lists valid during the making were used as basis.
?Personal protective equipment:
?General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
?Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
self-contained respiratory protective device.
(Contd. on page 4)
GB
DR
Page 4/7
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 22.01.2008 Revision: 22.01.2008
Trade name: 39128 1 Oz Hardener
(Contd. of page 3)
?Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance
of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
?Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
?General Information
Liquid
Form:
According to product specification
Colour:
Characteristic
Odour:
?Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: Undetermined.
84癈
?Flash point:
Product is not selfigniting.
?Self-igniting:
Risk of explosion by shock, friction, fire or other sources of ignition.
?Danger of explosion:
In use, may form flammable/explosive vapour-air mixture.
23 hPa
?Vapour pressure at 20癈:
1.192 g/cm?br>
?Density at 20癈:
?Solubility in / Miscibility with
Emulsifiable.
water:
?Solvent content:
0.0 %
Organic solvents:
20.0 %
Water:
g/l
VOC (EC)
(Contd. on page 5)
GB
DR
Page 5/7
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 22.01.2008 Revision: 22.01.2008
Trade name: 39128 1 Oz Hardener
(Contd. of page 4)
80.0 %
?Solids content:
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known.
?Dangerous decomposition products: No dangerous decomposition products known.
11 Toxicological information
?Acute toxicity:
?Primary irritant effect:
?on the skin: No irritant effect.
?on the eye: Irritating effect.
?Sensitization: Sensitization possible through skin contact.
?Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU Classification
Guidelines for Preparations as issued in the latest version:
Irritant
?Sensitisation May cause sensitisation by skin contact.
12 Ecological information
?General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
13 Disposal considerations
?Product:
?Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
?Uncleaned packaging:
?Recommendation: Disposal must be made according to official regulations.
14 Transport information
?Land transport ADR/RID (cross-border)
3108
?UN-Number:
II
?Packaging group:
(Contd. on page 6)
GB
DR
Page 6/7
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 22.01.2008 Revision: 22.01.2008
Trade name: 39128 1 Oz Hardener
(Contd. of page 5)
?Description of goods: 3108 ORGANIC PEROXIDE TYPE E, SOLID (dibenzoyl peroxide)
?Maritime transport IMDG:
3108
?UN Number:
5.2
?Label
II
?Packaging group:
No
?Marine pollutant:
?Proper shipping name: ORGANIC PEROXIDE TYPE E, SOLID (dibenzoyl peroxide)
?Air transport ICAO-TI and IATA-DGR:
3108
?UN/ID Number:
?Proper shipping name: ORGANIC PEROXIDE TYPE E, SOLID (dibenzoyl peroxide)
?UN "Model Regulation": UN3108; ORGANIC PEROXIDE TYPE E, SOLID; II
15 Regulatory information
?Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous
Materials.
?Code letter and hazard designation of product:
Xi Irritant
E Explosive
?Hazard-determining components of labelling:
dibenzoyl peroxide
?Risk phrases:
2 Risk of explosion by shock, friction, fire or other sources of ignition.
36 Irritating to eyes.
43 May cause sensitisation by skin contact.
?Safety phrases:
3/7 Keep container tightly closed in a cool place.
24 Avoid contact with skin.
37/39 Wear suitable gloves and eye/face protection.
60 This material and its container must be disposed of as hazardous waste.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
2 Risk of explosion by shock, friction, fire or other sources of ignition.
36 Irritating to eyes.
43 May cause sensitisation by skin contact.
?Department issuing MSDS: Environment protection department.
?Contact: Steve Gaver
(Contd. on page 7)
GB
DR
Page 7/7
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 22.01.2008 Revision: 22.01.2008
Trade name: 39128 1 Oz Hardener
(Contd. of page 6)
?Abbreviations and acronyms:
ADR: Accord europ閑n sur le transport des marchandises Dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
RID: Reglement internationale concernent le transport des merchandises dangereuses par chemin de fer (Regulations Concerning the
International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
GefStoffV: Gefahrstoffverordnung (Ordinance on Hazardous Substances, Germany)
VOC: Volatile Organic Compounds (USA, EU)
GB
DR
|