Star Nail International MATERIAL SAFETY DATA SHEET
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
CHEMICAL NAME: Methacrylate Copolymer
PRODUCT NAME: Ultra Bright White Acrylic Powder
PRODUCT USE: Organic Process Chemical
MANUFACTURER: Star Nail International
ADDRESS: 29120 Avenue Paine
Valencia, CA 91355
24 HR. EMERGENCY TELEPHONE: CHEMTEL 1-813-248-0573
PREPARATION/UPDATE DATE: 2/22/06
PRINT DATE: 5/22/07
MSDS ID: P39-01
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
FOR POLYMER:
ITEM CHEMICAL NAME CAS NUMBER: WT/WT %
01 Polymer 25685-29-4 60.0-100.0
02 Benzoyl Peroxide 94-36-0 0.0-5.0
03 Trade Secret NA 0.0-2.0
ACGIH OSHA Company
ITEM TLV-TWA TLV-STEL PEL TWA PEL CEILING Recommendation SKIN
3 3 3
01 10 mg/m NE 15 mg/m NE 15 mg/m NE
3 3 3
02 5 mg/m NE 5 mg/m NE 5 mg/m NE
03 NE NE NE NE NE NE
See Section 16 for Abbreviations.
Page 2
SECTION 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
WARNING:
For Polymer: OSHA classifies this material as Particulates, Not
Otherwise Classified.
Acute Hazards: Eyes: May be irritating to the eyes by gross overexposure, no
matter how generated. Symptoms of overexposure may
include redness, itching, irritation and watering. Keep dust
out of eyes.
Ingestion: Not expected to cause any harmful effects. Ingestion of
large amounts may be irritating if product is swallowed,
may cause nausea, headache, vomiting and/or diarrhea.
Skin: May be irritating to skin in some sensitive individuals,
especially after prolonged and/or repeated contact.
Inhalation: May be irritated by gross overexposure, no matter how
generated.
Chronic Hazards: None known.
CARCINOGENICITY: IARC lists Benzoyl Peroxide as unclassifiable as to
carcinogenicity to humans. Fumed Silica is not
Amorphous Silica and as such is classified as Particulates
Not Otherwise Classified. None of the other components
of this material are listed by IARC, NTP, OSHA, or ACGIH
as carcinogens.
PRIMARY ROUTES OF ENTRY: Inhalation, Skin or Eyes.
SECTION 4 - FIRST AID MEASURES
EMERGENCY AND FIRST AID PROCEDURES:
EYES: If product gets in the eyes, flush with copious amounts of lukewarm water for at
least 15 minutes. If irritation occurs, contact a physician.
INGESTION: If ingested, do not induce vomiting. If product has been swallowed, drink plenty of
water or milk IMMEDIATELY. If the patient is vomiting, continue to offer water or
milk. Never give anything by mouth to an unconscious person. Provide an estimate
of the time at which the material was ingested and the amount of the substance
that was swallowed. Get medical attention immediately.
INHALATION: Remove to fresh air. Seek immediate medical attention.
SKIN: If irritation occurs and product is on the skin, rinse thoroughly with lukewarm water,
followed by a thorough washing of the effected area with soap and water. If
irritation, redness or swelling persists, contact a physician immediately.
CLOTHING: Remove contaminated clothing, wash thoroughly before reuse.
TREATMENT: Treat symptoms conventionally, after thorough decontamination.
Page 3
SECTION 5 - FIRE FIGHTING MEASURES
FLASH POINT: 304 癈, 580 癋
FLAMMABLE LIMIT, AIR VOL% LOWER: NA
UPPER: NA
AUTOIGNITION TEMPERATURE: NE
EXTINGUISHER METHOD: Water, carbon dioxide, dry chemical.
FIRE AND EXPLOSION HAZARDS: Polymer dust is combustible. The explosive limits of the polymer
particles suspended in air are approximately those of coal dust.
SPECIAL FIRE FIGHTING PROCEDURES: Avoid extinguishing methods, which may generate dust clouds.
Water stream can disperse dust into air producing a fire hazard
and possible explosion hazard if exposed to ignition source.
EXPLOSION HAZARD: Firefighters should wear self-contained breathing apparatus.
SENSITIVE TO MECHANICAL IMPACT: For Polymer: No.
SENSITIVE TO STATIC DISCHARGE: For Polymer: No.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
ACCIDENTAL RELEASE: Before cleaning any spill or leak, individuals involved must wear
appropriate Personal Protective Equipment (e.g., goggles, gloves).
Sweep up to avoid slipping hazard. Keep airborne particulates at
a minimum when cleaning up spills. Dispose of properly in
accordance with local, state and federal regulations. Wash all
affected areas with plenty of warm water and soap. Remove any
contaminated clothing and wash thoroughly before reuse.
SECTION 7- HANDLING AND STORAGE
PRECAUTIONS FOR HANDLING: Use in well ventilated areas. Avoid contact with skin, eyes and
clothing. Avoid breathing dust. Use good personal hygiene and
housekeeping.
PRECAUTIONS FOR STORAGE: Store containers in a cool, dry location, away from direct sunlight,
other light sources, or sources of intense heat. Keep container
closed to prevent water absorption and contamination.
INDUSTRIAL HYGIENE PRACTICES: Avoid prolonged contact with the product. Use in a well-ventilated
location (e.g., local exhaust ventilation, fans). After use, wash
hands and exposed skin with soap and water. Do not eat, drink or
smoke while handling product.
Page 4
SECTION 8 - EXPOSURE CONTROL/PERSONAL PROTECTION
VENTILATION: When working with large quantities of product provide adequate
ventilation (e.g., local exhaust ventilation, fans). Ensure that an
eyewash station, sink or washbasin is available in case of
exposure to eyes. Use good local exhaust at processing
equipment, including buffers, sanders, grinders and polishers.
RESPIRATORY PROTECTION: No special respiratory protection is required under typical
circumstances of use or handling. If necessary, use only
respiratory protection authorized per U.S. OSHA's requirement in
29 CFR ?910.134, or applicable U.S. state regulations, or the
appropriate standards of Canada, its provinces, E.C. member
states, or Australia.
EYE PROTECTION: Depending on the use of this product, safety glasses or goggles
may be worn. If necessary, refer to U.S. OSHA 29 CFR
?910.133, Canadian standards, or the European Standard
EN166. Ensure that an eyewash station, sink or washbasin is
available in case of exposure to eyes.
PROTECTIVE GLOVES: If anticipated that prolonged & repeated skin contact will occur
during use of this product, wear gloves for routine industrial use. If
necessary, refer to U.S. OSHA 29 CFR ?910.138, the
appropriate standards of Canada, of the E.C. member states.
OTHER PROTECTIVE EQUIPMENT: No special body protection is required under typical circumstances
of use and handling. If necessary, refer to appropriate standards of
Canada, the E.C. member states, or U.S. OSHA. An eyewash
station and a safety shower are recommended. High temperature
processing equipment should be well ventilated.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: Fine clear to pigmented powder.
ODOR: Faint odor in bulk.
pH: NA
ODOR THRESHOLD: ND
BOILING POINT: NA
FREEZING POINT: NA
VISCOSITY: NA
SPECIFIC GRAVITY (H2O=1): ND
VAPOR PRESSURE: NA
PERCENT VOLATILE W/W%: NA
VAPOR DENSITY (AIR=1): NA
EVAPORATION RATE (BuAc =1): NA
SOLUBILITY IN WATER: Insoluble.
COEFFICIENT OF WATER/OIL DISTRIBUTION: ND
Page 5
SECTION 10 - STABILITY AND REACTIVITY
CONDITIONS TO AVOID: Heating above 240 癈, 464 癋.
INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS: Methacrylate Monomer and Oxides of Carbon when burned.
HAZARDOUS POLYMERIZATION: MAY OCCUR: WILL NOT OCCUR: X
STABILITY: UNSTABLE: STABLE: X
SECTION 11- TOXICOLOGICAL PROPERTIES
TOXICITY DATA:
This product has NOT been tested on animals to obtain toxicology data. There is toxicology data for the
components of the product, which is found in scientific literature. This data has not been presented in this
document.
MUTAGENICITY DATA: This product is not reported to produce mutagenic effects in humans.
REPRODUCTIVE TOXICITY DATA:
Embryotoxicity: This product is not reported to produce embryotoxic effects in humans.
Teratogenicity: This product is not reported to cause teratogenic effects in humans.
Reproductive Toxicity: This product is not reported to cause reproductive effects in humans.
SECTION 12 - ECOLOGICAL INFORMATION
AQUATIC TOXICITY:
There is no specific data available for this product; however, very large releases of this product may be
harmful or fatal to overexposed aquatic life.
ENVIRONMENTAL FATE:
There is no specific data available for this product.
SECTION 13 - DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: Dispose of properly in accordance with Federal, State, and Local
regulations.
DISPOSAL OF EMPTY CONTAINERS: Reuse of empty drums or containers is not recommended.
Employees should be advised of the potential hazards due to
residual material associated with empty containers. Dispose of all
empty containers properly in accordance with Federal, State and
Local regulations.
Page 6
SECTION 14 - TRANSPORTATION
DOT/UN SHIPPING NAME: POLYMER, NOI
DOT/UN CLASS:
NA/UN NUMBER:
PACKING GROUP:
LABEL:
IMDG CLASS:
IMDG PG:
CERCLA RQ:
SECTION 15 - REGULATORY INFORMATION
SARA Reporting Requirements: NA
SARA Threshold Planning Quantity: There are no specific Threshold Planning Quantities for the
components of this product.
TSCA Inventory Status: The components of this product are listed on the TSCA Inventory.
For use in FDA regulated products only.
CERCLA Reportable Quantity (RQ): NA
Other Federal Requirements: This product complies with the appropriate sections of the Food
and Drug Administration's 21 CFR subchapter G (Cosmetics).
Other Canadian Regulations: This product has been classified according to the hazard criteria of
the CPR and the MSDS contains all of the information required by
the CPR. The components of this product are listed on the
DSL/NDSL. None of the components of this product are listed
on the Priorities Substances List.
State Regulatory Information: This product may contain components that are covered under
specific state criteria.
RISK STATEMENTS: R36/37/38 ?Irritating to eyes, respiratory system and skin.
SAFETY STATEMENTS: S3 ?Keep in a cool place.
S7 ?Keep container tightly closed.
S9 ?Keep container in a well-ventilated place.
S20 ?When using do not eat or drink.
S 29 ?Do not empty into drains.
S37/39 ?Wear suitable gloves and eye/face protection.
Page 7
SECTION 16 - OTHER INFORMATION
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS) RATING:
HEALTH: 1
FLAMMABILITY: 1
REACTIVITY: 0
PERSONAL PROTECTIVE EQUIPMENT: Gloves and Safety Glasses or Chemical Goggles.
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD IDENTIFICATION RATING:
HEALTH: 1
FLAMMABILITY: 1
REACTIVITY: 0
ABBREVIATIONS:
NA Not Applicable ND Not Determined
NE Not Established
ppm parts per million G Gallon
mg Milligram L Liter
gm Gram mol Mole
kg Kilogram ! Micro
mm Millimeter p Pico
Pa Pascals
LC Lethal Concentration LD Lethal Dose
TC Toxic Concentration TD Toxic Dose
BOD Biological Oxygen Demand COD Chemical Oxygen Demand
Lo Lowest ThOD Theoretical Oxygen Demand
TLm Threshold Limit
H Hours M Months
D Days Y Years
W Weeks
ACGIH American Conference of Governmental Industrial Hygienist
CPR Controlled Product's Regulation
DSL Canadian Domestic Substances List
NDSL Canadian Non-domestic Substance List
IARC International Agency for Research for Cancer
NOEL No Observed Effect Level
NOAEL No Observed Adverse Effect Level
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
TLV Threshold Limit Value
Page 8
SECTION 16 - OTHER INFORMATION CONTINUED
THE ABOVE INFORMATION MAY BE BASED IN PART ON INFORMATION PROVIDED BY COMPONENT SUPPLIERS AND IS BELIEVED
TO BE CORRECT AS OF THE DATE HEREOF. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY USE, OR ANY
OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OF THESE DATA, THE RESULTS TO BE
OBTAINED FROM THE USE OF THE MATERIAL, OR THE HAZARDS CONNECTED WITH SUCH USE. SINCE THE INFORMATION
CONTAINED HEREIN MAY BE APPLIED UNDER CONDITIONS BEYOND OUR CONTROL AND WITH WHICH WE MAY BE UNFAMILIAR,
AND SINCE DATA MADE AVAILABLE SUBSEQUENT TO THE DATE HEREOF MAY SUGGEST MODIFICATION OF THE INFORMATION,
WE ASSUME NO RESPONSIBILITY FOR THE RESULT OF ITS USE. THIS INFORMATION AND MATERIAL IS FURNISHED ON THE
CONDITION THAT THE PERSON RECEIVING IT SHALL MAKE HIS/HER OWN DETERMINATION AS TO THE SUITABILITY OF THE
MATERIAL FOR HIS/HER PARTICULAR PURPOSE AND ON THE CONDITION THAT HE/SHE ASSUME THE RISK OF HIS/HER USE
THEREOF.
Star Nail International. MATERIAL SAFETY DATA SHEET
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
CHEMICAL NAME: Methacrylate Copolymer/Polymer Blend
PRODUCT NAME: Ultra Clear Acrylic Powder
PRODUCT USE: Organic Process Chemical
MANUFACTURER: Star Nail International
ADDRESS: 29120 Avenue Paine
Valencia, CA 91355
24 HR. EMERGENCY TELEPHONE: CHEMTEL 1-813-248-0573
PHONE: 1-661-257-7827, During Business Hours
PREPARATION/UPDATE DATE: 2/22/06
PRINT DATE: 5/22/07
MSDS ID: P21-01
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
FOR POLYMER:
ITEM CHEMICAL NAME CAS NUMBER: WT/WT %
01 Polymer 25685-29-4 30.0-70.0
02 Polymer 9003-42-3 30.0-70.0
ACGIH OSHA Company
ITEM TLV-TWA TLV-STEL PEL TWA PEL CEILING Recommendation SKIN
3 3 3
01 10 mg/m NE 15 mg/m NE 15 mg/m NE
3 3 3
02 10 mg/m NE 15 mg/m NE 15 mg/m NE
See Section 16 for Abbreviations.
Page 2
SECTION 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
WARNING:
For Polymer: OSHA classifies this material as Particulates, Not
Otherwise Classified.
Acute Hazards: Eyes: May be irritating to the eyes by gross overexposure, no
matter how generated. Symptoms of overexposure may
include redness, itching, irritation and watering. Keep dust
out of eyes.
Ingestion: Not expected to cause any harmful effects. Ingestion of
large amounts may be irritating if product is swallowed,
may cause nausea, headache, vomiting and/or diarrhea.
Skin: May be irritating to skin in some sensitive individuals,
especially after prolonged and/or repeated contact.
Inhalation: May be irritated by gross overexposure, no matter how
generated.
Chronic Hazards: None known.
CARCINOGENICITY: None of the components of this material are listed by
IARC, NTP, OSHA, or ACGIH as carcinogens.
PRIMARY ROUTES OF ENTRY: Inhalation, Skin or Eyes.
SECTION 4 - FIRST AID MEASURES
EMERGENCY AND FIRST AID PROCEDURES:
EYES: If product gets in the eyes, flush with copious amounts of lukewarm water for at
least 15 minutes. If irritation occurs, contact a physician.
INGESTION: If ingested, do not induce vomiting. If product has been swallowed, drink plenty of
water or milk IMMEDIATELY. If the patient is vomiting, continue to offer water or
milk. Never give anything by mouth to an unconscious person. Provide an estimate
of the time at which the material was ingested and the amount of the substance
that was swallowed. Get medical attention immediately.
INHALATION: Remove to fresh air. Seek immediate medical attention.
SKIN: If irritation occurs and product is on the skin, rinse thoroughly with lukewarm water,
followed by a thorough washing of the effected area with soap and water. If
irritation, redness or swelling persists, contact a physician immediately.
CLOTHING: Remove contaminated clothing, wash thoroughly before reuse.
TREATMENT: Treat symptoms conventionally, after thorough decontamination.
Page 3
SECTION 5 - FIRE FIGHTING MEASURES
FLASH POINT: 304 癈, 580 癋
FLAMMABLE LIMIT, AIR VOL% LOWER: NA
UPPER: NA
AUTOIGNITION TEMPERATURE: NE
EXTINGUISHER METHOD: Water, carbon dioxide, dry chemical.
FIRE AND EXPLOSION HAZARDS: Polymer dust is combustible. The explosive limits of the polymer
particles suspended in air are approximately those of coal dust.
SPECIAL FIRE FIGHTING PROCEDURES: Avoid extinguishing methods, which may generate dust clouds.
Water stream can disperse dust into air producing a fire hazard
and possible explosion hazard if exposed to ignition source.
EXPLOSION HAZARD: Firefighters should wear self-contained breathing apparatus.
SENSITIVE TO MECHANICAL IMPACT: For Polymer: No.
SENSITIVE TO STATIC DISCHARGE: For Polymer: No.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
ACCIDENTAL RELEASE: Before cleaning any spill or leak, individuals involved must wear
appropriate Personal Protective Equipment (e.g., goggles, gloves).
Sweep up to avoid slipping hazard. Keep airborne particulates at
a minimum when cleaning up spills. Dispose of properly in
accordance with local, state and federal regulations. Wash all
affected areas with plenty of warm water and soap. Remove any
contaminated clothing and wash thoroughly before reuse.
SECTION 7- HANDLING AND STORAGE
PRECAUTIONS FOR HANDLING: Use in well ventilated areas. Avoid contact with skin, eyes and
clothing. Avoid breathing dust. Use good personal hygiene and
housekeeping.
PRECAUTIONS FOR STORAGE: Store containers in a cool, dry location, away from direct sunlight,
other light sources, or sources of intense heat. Keep container
closed to prevent water absorption and contamination.
INDUSTRIAL HYGIENE PRACTICES: Avoid prolonged contact with the product. Use in a well-ventilated
location (e.g., local exhaust ventilation, fans). After use, wash
hands and exposed skin with soap and water. Do not eat, drink or
smoke while handling product.
Page 4
SECTION 8 - EXPOSURE CONTROL/PERSONAL PROTECTION
VENTILATION: When working with large quantities of product provide adequate
ventilation (e.g., local exhaust ventilation, fans). Ensure that an
eyewash station, sink or washbasin is available in case of
exposure to eyes. Use good local exhaust at processing
equipment, including buffers, sanders, grinders and polishers.
RESPIRATORY PROTECTION: No special respiratory protection is required under typical
circumstances of use or handling. If necessary, use only
respiratory protection authorized per U.S. OSHA's requirement in
29 CFR ?910.134, or applicable U.S. state regulations, or the
appropriate standards of Canada, its provinces, E.C. member
states, or Australia.
EYE PROTECTION: Depending on the use of this product, safety glasses or goggles
may be worn. If necessary, refer to U.S. OSHA 29 CFR
?910.133, Canadian standards, or the European Standard
EN166. Ensure that an eyewash station, sink or washbasin is
available in case of exposure to eyes.
PROTECTIVE GLOVES: If anticipated that prolonged & repeated skin contact will occur
during use of this product, wear gloves for routine industrial use. If
necessary, refer to U.S. OSHA 29 CFR ?910.138, the
appropriate standards of Canada, of the E.C. member states.
OTHER PROTECTIVE EQUIPMENT: No special body protection is required under typical circumstances
of use and handling. If necessary, refer to appropriate standards of
Canada, the E.C. member states, or U.S. OSHA. An eyewash
station and a safety shower are recommended. High temperature
processing equipment should be well ventilated.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: Fine clear to pigmented powder.
ODOR: Faint odor in bulk.
pH: NA
ODOR THRESHOLD: ND
BOILING POINT: NA
FREEZING POINT: NA
VISCOSITY: NA
SPECIFIC GRAVITY (H2O=1): ND
VAPOR PRESSURE: NA
PERCENT VOLATILE W/W%: NA
VAPOR DENSITY (AIR=1): NA
EVAPORATION RATE (BuAc =1): NA
SOLUBILITY IN WATER: Insoluble.
COEFFICIENT OF WATER/OIL DISTRIBUTION: ND
Page 5
SECTION 10 - STABILITY AND REACTIVITY
CONDITIONS TO AVOID: Heating above 240 癈, 464 癋.
INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS: Methacrylate Monomer and Oxides of Carbon when burned.
HAZARDOUS POLYMERIZATION: MAY OCCUR: WILL NOT OCCUR: X
STABILITY: UNSTABLE: STABLE: X
SECTION 11- TOXICOLOGICAL PROPERTIES
TOXICITY DATA:
This product has NOT been tested on animals to obtain toxicology data. There is toxicology data for the
components of the product, which is found in scientific literature. This data has not been presented in this
document.
MUTAGENICITY DATA: This product is not reported to produce mutagenic effects in humans.
REPRODUCTIVE TOXICITY DATA:
Embryotoxicity: This product is not reported to produce embryotoxic effects in humans.
Teratogenicity: This product is not reported to cause teratogenic effects in humans.
Reproductive Toxicity: This product is not reported to cause reproductive effects in humans.
SECTION 12 - ECOLOGICAL INFORMATION
AQUATIC TOXICITY:
There is no specific data available for this product; however, very large releases of this product may be
harmful or fatal to overexposed aquatic life.
ENVIRONMENTAL FATE:
There is no specific data available for this product.
SECTION 13 - DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: Dispose of properly in accordance with Federal, State, and Local
regulations.
DISPOSAL OF EMPTY CONTAINERS: Reuse of empty drums or containers is not recommended.
Employees should be advised of the potential hazards due to
residual material associated with empty containers. Dispose of all
empty containers properly in accordance with Federal, State and
Local regulations.
Page 6
SECTION 14 - TRANSPORTATION
DOT/UN SHIPPING NAME: POLYMER, NOI
DOT/UN CLASS:
NA/UN NUMBER:
PACKING GROUP:
LABEL:
IMDG CLASS:
IMDG PG:
CERCLA RQ:
SECTION 15 - REGULATORY INFORMATION
SARA Reporting Requirements: NA
SARA Threshold Planning Quantity: There are no specific Threshold Planning Quantities for the
components of this product.
TSCA Inventory Status: The components of this product are listed on the TSCA Inventory.
For use in FDA regulated products only.
CERCLA Reportable Quantity (RQ): NA
Other Federal Requirements: This product complies with the appropriate sections of the Food
and Drug Administration's 21 CFR subchapter G (Cosmetics).
Other Canadian Regulations: This product has been classified according to the hazard criteria of
the CPR and the MSDS contains all of the information required by
the CPR. The components of this product are listed on the
DSL/NDSL. None of the components of this product are listed
on the Priorities Substances List.
State Regulatory Information: This product may contain components that are covered under
specific state criteria.
RISK STATEMENTS: R36/37/38 ?Irritating to eyes, respiratory system and skin.
SAFETY STATEMENTS: S3 ?Keep in a cool place.
S7 ?Keep container tightly closed.
S9 ?Keep container in a well-ventilated place.
S20 ?When using do not eat or drink.
S 29 ?Do not empty into drains.
S37/39 ?Wear suitable gloves and eye/face protection.
Page 7
SECTION 16 - OTHER INFORMATION
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS) RATING:
HEALTH: 1
FLAMMABILITY: 1
REACTIVITY: 0
PERSONAL PROTECTIVE EQUIPMENT: Gloves and Safety Glasses or Chemical Goggles.
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD IDENTIFICATION RATING:
HEALTH: 1
FLAMMABILITY: 1
REACTIVITY: 0
ABBREVIATIONS:
NA Not Applicable ND Not Determined
NE Not Established
ppm parts per million G Gallon
mg Milligram L Liter
gm Gram mol Mole
kg Kilogram ! Micro
mm Millimeter p Pico
Pa Pascals
LC Lethal Concentration LD Lethal Dose
TC Toxic Concentration TD Toxic Dose
BOD Biological Oxygen Demand COD Chemical Oxygen Demand
Lo Lowest ThOD Theoretical Oxygen Demand
TLm Threshold Limit
H Hours M Months
D Days Y Years
W Weeks
ACGIH American Conference of Governmental Industrial Hygienist
CPR Controlled Product's Regulation
DSL Canadian Domestic Substances List
NDSL Canadian Non-domestic Substance List
IARC International Agency for Research for Cancer
NOEL No Observed Effect Level
NOAEL No Observed Adverse Effect Level
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
TLV Threshold Limit Value
Page 8
SECTION 16 - OTHER INFORMATION CONTINUED
THE ABOVE INFORMATION MAY BE BASED IN PART ON INFORMATION PROVIDED BY COMPONENT SUPPLIERS AND IS BELIEVED
TO BE CORRECT AS OF THE DATE HEREOF. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY USE, OR ANY
OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OF THESE DATA, THE RESULTS TO BE
OBTAINED FROM THE USE OF THE MATERIAL, OR THE HAZARDS CONNECTED WITH SUCH USE. SINCE THE INFORMATION
CONTAINED HEREIN MAY BE APPLIED UNDER CONDITIONS BEYOND OUR CONTROL AND WITH WHICH WE MAY BE UNFAMILIAR,
AND SINCE DATA MADE AVAILABLE SUBSEQUENT TO THE DATE HEREOF MAY SUGGEST MODIFICATION OF THE INFORMATION,
WE ASSUME NO RESPONSIBILITY FOR THE RESULT OF ITS USE. THIS INFORMATION AND MATERIAL IS FURNISHED ON THE
CONDITION THAT THE PERSON RECEIVING IT SHALL MAKE HIS/HER OWN DETERMINATION AS TO THE SUITABILITY OF THE
MATERIAL FOR HIS/HER PARTICULAR PURPOSE AND ON THE CONDITION THAT HE/SHE ASSUME THE RISK OF HIS/HER USE
THEREOF.
Star Nail International. MATERIAL SAFETY DATA SHEET
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
CHEMICAL NAME: Methacrylate Copolymer
PRODUCT/TRADE NAME: Ultra Extreme Pink Acrylic Powder
PRODUCT USE: Organic Process Chemical
MANUFACTURER: Star Nail International
ADDRESS: 29120 Avenue Paine
Valencia, CA 91355
24 HR. EMERGENCY TELEPHONE: CHEMTEL: 1-813-248-0573
PREPARATION/UPDATE DATE: 2/22/06
PRINT DATE: 5/22/07
MSDS ID: P7-01
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
FOR POLYMER:
ITEM CHEMICAL NAME CAS NUMBER: WT/WT %
01 Polymer 25685-29-4 60.0-100.0
ACGIH OSHA Company
ITEM TLV-TWA TLV-STEL PEL TWA PEL CEILING Recommendation SKIN
3 3 3
01 10 mg/m NE 15 mg/m NE 15 mg/m NE
See Section 16 for Abbreviations.
Page 2
SECTION 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
WARNING:
For Polymer: OSHA classifies this material as Particulates, Not
Otherwise Classified.
Acute Hazards: Eyes: May be irritating to the eyes by gross overexposure, no
matter how generated. Symptoms of overexposure may
include redness, itching, irritation and watering. Keep dust
out of eyes.
Ingestion: Not expected to cause any harmful effects. Ingestion of
large amounts may be irritating if product is swallowed,
may cause nausea, headache, vomiting and/or diarrhea.
Skin: May be irritating to skin in some sensitive individuals,
especially after prolonged and/or repeated contact.
Inhalation: May be irritated by gross overexposure, no matter how
generated.
Chronic Hazards: None known.
CARCINOGENICITY: None of the components of this material are listed by
IARC, NTP, OSHA, or ACGIH as carcinogens.
PRIMARY ROUTES OF ENTRY: Inhalation, Skin or Eyes.
SECTION 4 - FIRST AID MEASURES
EMERGENCY AND FIRST AID PROCEDURES:
EYES: If product gets in the eyes, flush with copious amounts of lukewarm water for at
least 15 minutes. If irritation occurs, contact a physician.
INGESTION: If ingested, do not induce vomiting. If product has been swallowed, drink plenty of
water or milk IMMEDIATELY. If the patient is vomiting, continue to offer water or
milk. Never give anything by mouth to an unconscious person. Provide an estimate
of the time at which the material was ingested and the amount of the substance
that was swallowed. Get medical attention immediately.
INHALATION: Remove to fresh air. Seek immediate medical attention.
SKIN: If irritation occurs and product is on the skin, rinse thoroughly with lukewarm water,
followed by a thorough washing of the effected area with soap and water. If
irritation, redness or swelling persists, contact a physician immediately.
CLOTHING: Remove contaminated clothing, wash thoroughly before reuse.
TREATMENT: Treat symptoms conventionally, after thorough decontamination.
Page 3
SECTION 5 - FIRE FIGHTING MEASURES
FLASH POINT: 304 癈, 580 癋
FLAMMABLE LIMIT, AIR VOL% LOWER: NA
UPPER: NA
AUTOIGNITION TEMPERATURE: NE
EXTINGUISHER METHOD: Water, carbon dioxide, dry chemical.
FIRE AND EXPLOSION HAZARDS: Polymer dust is combustible. The explosive limits of the polymer
particles suspended in air are approximately those of coal dust.
SPECIAL FIRE FIGHTING PROCEDURES: Avoid extinguishing methods, which may generate dust clouds.
Water stream can disperse dust into air producing a fire hazard
and possible explosion hazard if exposed to ignition source.
EXPLOSION HAZARD: Firefighters should wear self-contained breathing apparatus.
SENSITIVE TO MECHANICAL IMPACT: For Polymer: No.
SENSITIVE TO STATIC DISCHARGE: For Polymer: No.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
ACCIDENTAL RELEASE: Before cleaning any spill or leak, individuals involved must wear
appropriate Personal Protective Equipment (e.g., goggles, gloves).
Sweep up to avoid slipping hazard. Keep airborne particulates at
a minimum when cleaning up spills. Dispose of properly in
accordance with local, state and federal regulations. Wash all
affected areas with plenty of warm water and soap. Remove any
contaminated clothing and wash thoroughly before reuse.
SECTION 7- HANDLING AND STORAGE
PRECAUTIONS FOR HANDLING: Use in well ventilated areas. Avoid contact with skin, eyes and
clothing. Avoid breathing dust. Use good personal hygiene and
housekeeping.
PRECAUTIONS FOR STORAGE: Store containers in a cool, dry location, away from direct sunlight,
other light sources, or sources of intense heat. Keep container
closed to prevent water absorption and contamination.
INDUSTRIAL HYGIENE PRACTICES: Avoid prolonged contact with the product. Use in a well-ventilated
location (e.g., local exhaust ventilation, fans). After use, wash
hands and exposed skin with soap and water. Do not eat, drink or
smoke while handling product.
Page 4
SECTION 8 - EXPOSURE CONTROL/PERSONAL PROTECTION
VENTILATION: When working with large quantities of product provide adequate
ventilation (e.g., local exhaust ventilation, fans). Ensure that an
eyewash station, sink or washbasin is available in case of
exposure to eyes. Use good local exhaust at processing
equipment, including buffers, sanders, grinders and polishers.
RESPIRATORY PROTECTION: No special respiratory protection is required under typical
circumstances of use or handling. If necessary, use only
respiratory protection authorized per U.S. OSHA's requirement in
29 CFR ?910.134, or applicable U.S. state regulations, or the
appropriate standards of Canada, its provinces, E.C. member
states, or Australia.
EYE PROTECTION: Depending on the use of this product safety glasses or goggles
may be worn. If necessary, refer to U.S. OSHA 29 CFR
?910.133, Canadian standards, or the European Standard
EN166. Ensure that an eyewash station, sink or washbasin is
available in case of exposure to eyes.
PROTECTIVE GLOVES: If anticipated that prolonged & repeated skin contact will occur
during use of this product, wear gloves for routine industrial use. If
necessary, refer to U.S. OSHA 29 CFR ?910.138, the
appropriate standards of Canada, of the E.C. member states.
OTHER PROTECTIVE EQUIPMENT: No special body protection is required under typical circumstances
of use and handling. If necessary, refer to appropriate standards of
Canada, the E.C. member states, or U.S. OSHA. An eyewash
station and a safety shower are recommended. High temperature
processing equipment should be well ventilated.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: Fine clear to pigmented powder.
ODOR: Faint odor in bulk.
pH: NA
ODOR THRESHOLD: ND
BOILING POINT: NA
FREEZING POINT: NA
VISCOSITY: NA
SPECIFIC GRAVITY (H2O=1): ND
VAPOR PRESSURE: NA
PERCENT VOLATILE W/W%: NA
VAPOR DENSITY (AIR=1): NA
EVAPORATION RATE (BuAc =1): NA
SOLUBILITY IN WATER: Insoluble.
COEFFICIENT OF WATER/OIL DISTRIBUTION: ND
Page 5
SECTION 10 - STABILITY AND REACTIVITY
CONDITIONS TO AVOID: Heating above 240 癈, 464 癋.
INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS: Methacrylate Monomer and Oxides of Carbon when burned.
HAZARDOUS POLYMERIZATION: MAY OCCUR: WILL NOT OCCUR: X
STABILITY: UNSTABLE: STABLE: X
SECTION 11- TOXICOLOGICAL PROPERTIES
TOXICITY DATA:
This product has NOT been tested on animals to obtain toxicology data. There is toxicology data for the
components of the product, which is found in scientific literature. This data has not been presented in this
document.
MUTAGENICITY DATA: This product is not reported to produce mutagenic effects in humans.
REPRODUCTIVE TOXICITY DATA:
Embryotoxicity: This product is not reported to produce embryotoxic effects in humans.
Teratogenicity: This product is not reported to cause teratogenic effects in humans.
Reproductive Toxicity: This product is not reported to cause reproductive effects in humans.
SECTION 12 - ECOLOGICAL INFORMATION
AQUATIC TOXICITY:
There is no specific data available for this product; however, very large releases of this product may be
harmful or fatal to overexposed aquatic life.
ENVIRONMENTAL FATE:
There is no specific data available for this product.
SECTION 13 - DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: Dispose of properly in accordance with Federal, State, and Local
regulations.
DISPOSAL OF EMPTY CONTAINERS: Reuse of empty drums or containers is not recommended.
Employees should be advised of the potential hazards due to
residual material associated with empty containers. Dispose of all
empty containers properly in accordance with Federal, State and
Local regulations.
Page 6
SECTION 14 - TRANSPORTATION
DOT/UN SHIPPING NAME: POLYMER, NOI
DOT/UN CLASS:
NA/UN NUMBER:
PACKING GROUP:
LABEL:
IMDG CLASS:
IMDG PG:
CERCLA RQ:
SECTION 15 - REGULATORY INFORMATION
SARA Reporting Requirements: NA
SARA Threshold Planning Quantity: There are no specific Threshold Planning Quantities for the
components of this product.
TSCA Inventory Status: The components of this product are listed on the TSCA Inventory.
For use in FDA regulated products only.
CERCLA Reportable Quantity (RQ): NA
Other Federal Requirements: This product complies with the appropriate sections of the Food
and Drug Administration's 21 CFR subchapter G (Cosmetics).
Other Canadian Regulations: This product has been classified according to the hazard criteria of
the CPR and the MSDS contains all of the information required by
the CPR. The components of this product are listed on the
DSL/NDSL. None of the components of this product are listed
on the Priorities Substances List.
State Regulatory Information: This product may contain components that are covered under
specific state criteria.
RISK STATEMENTS: R36/37/38 ?Irritating to eyes, respiratory system and skin.
SAFETY STATEMENTS: S3 ?Keep in a cool place.
S7 ?Keep container tightly closed.
S9 ?Keep container in a well-ventilated place.
S20 ?When using do not eat or drink.
S 29 ?Do not empty into drains.
S37/39 ?Wear suitable gloves and eye/face protection.
Page 7
SECTION 16 - OTHER INFORMATION
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS) RATING:
HEALTH: 1
FLAMMABILITY: 1
REACTIVITY: 0
PERSONAL PROTECTIVE EQUIPMENT: Gloves and Safety Glasses or Chemical Goggles.
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD IDENTIFICATION RATING:
HEALTH: 1
FLAMMABILITY: 1
REACTIVITY: 0
ABBREVIATIONS:
NA Not Applicable ND Not Determined
NE Not Established
ppm parts per million G Gallon
mg Milligram L Liter
gm Gram mol Mole
kg Kilogram ! Micro
mm Millimeter p Pico
Pa Pascals
LC Lethal Concentration LD Lethal Dose
TC Toxic Concentration TD Toxic Dose
BOD Biological Oxygen Demand COD Chemical Oxygen Demand
Lo Lowest ThOD Theoretical Oxygen Demand
TLm Threshold Limit
H Hours M Months
D Days Y Years
W Weeks
ACGIH American Conference of Governmental Industrial Hygienist
CPR Controlled Product's Regulation
DSL Canadian Domestic Substances List
NDSL Canadian Non-domestic Substance List
IARC International Agency for Research for Cancer
NOEL No Observed Effect Level
NOAEL No Observed Adverse Effect Level
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
TLV Threshold Limit Value
Page 8
SECTION 16 - OTHER INFORMATION CONTINUED
THE ABOVE INFORMATION MAY BE BASED IN PART ON INFORMATION PROVIDED BY COMPONENT SUPPLIERS AND IS BELIEVED
TO BE CORRECT AS OF THE DATE HEREOF. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY USE, OR ANY
OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OF THESE DATA, THE RESULTS TO BE
OBTAINED FROM THE USE OF THE MATERIAL, OR THE HAZARDS CONNECTED WITH SUCH USE. SINCE THE INFORMATION
CONTAINED HEREIN MAY BE APPLIED UNDER CONDITIONS BEYOND OUR CONTROL AND WITH WHICH WE MAY BE UNFAMILIAR,
AND SINCE DATA MADE AVAILABLE SUBSEQUENT TO THE DATE HEREOF MAY SUGGEST MODIFICATION OF THE INFORMATION,
WE ASSUME NO RESPONSIBILITY FOR THE RESULT OF ITS USE. THIS INFORMATION AND MATERIAL IS FURNISHED ON THE
CONDITION THAT THE PERSON RECEIVING IT SHALL MAKE HIS/HER OWN DETERMINATION AS TO THE SUITABILITY OF THE
MATERIAL FOR HIS/HER PARTICULAR PURPOSE AND ON THE CONDITION THAT HE/SHE ASSUME THE RISK OF HIS/HER USE
THEREOF.
Star Nail International.M A T E R I A L SAFETY DATA SHEET
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
CHEMICAL NAME: Methacrylate Copolymer
PRODUCT/TRADE NAME: Ultra Natural Acrylic Powder
PRODUCT USE: Organic Process Chemical
MANUFACTURER: Star Nail International
ADDRESS: 29120 Avenue Paine
Valencia, CA 91355
24 HR. EMERGENCY TELEPHONE: CHEMTEL: 1-813-248-0573
PREPARATION/UPDATE DATE: 2/22/06
PRINT DATE: 5/22/07
MSDS ID: P7-01
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
FOR POLYMER:
ITEM CHEMICAL NAME CAS NUMBER: WT/WT %
01 Polymer 25685-29-4 60.0-100.0
ACGIH OSHA Company
ITEM TLV-TWA TLV-STEL PEL TWA PEL CEILING Recommendation SKIN
3 3 3
01 10 mg/m NE 15 mg/m NE 15 mg/m NE
See Section 16 for Abbreviations.
Page 2
SECTION 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
WARNING:
For Polymer: OSHA classifies this material as Particulates, Not
Otherwise Classified.
Acute Hazards: Eyes: May be irritating to the eyes by gross overexposure, no
matter how generated. Symptoms of overexposure may
include redness, itching, irritation and watering. Keep dust
out of eyes.
Ingestion: Not expected to cause any harmful effects. Ingestion of
large amounts may be irritating if product is swallowed,
may cause nausea, headache, vomiting and/or diarrhea.
Skin: May be irritating to skin in some sensitive individuals,
especially after prolonged and/or repeated contact.
Inhalation: May be irritated by gross overexposure, no matter how
generated.
Chronic Hazards: None known.
CARCINOGENICITY: None of the components of this material are listed by
IARC, NTP, OSHA, or ACGIH as carcinogens.
PRIMARY ROUTES OF ENTRY: Inhalation, Skin or Eyes.
SECTION 4 - FIRST AID MEASURES
EMERGENCY AND FIRST AID PROCEDURES:
EYES: If product gets in the eyes, flush with copious amounts of lukewarm water for at
least 15 minutes. If irritation occurs, contact a physician.
INGESTION: If ingested, do not induce vomiting. If product has been swallowed, drink plenty of
water or milk IMMEDIATELY. If the patient is vomiting, continue to offer water or
milk. Never give anything by mouth to an unconscious person. Provide an estimate
of the time at which the material was ingested and the amount of the substance
that was swallowed. Get medical attention immediately.
INHALATION: Remove to fresh air. Seek immediate medical attention.
SKIN: If irritation occurs and product is on the skin, rinse thoroughly with lukewarm water,
followed by a thorough washing of the effected area with soap and water. If
irritation, redness or swelling persists, contact a physician immediately.
CLOTHING: Remove contaminated clothing, wash thoroughly before reuse.
TREATMENT: Treat symptoms conventionally, after thorough decontamination.
Page 3
SECTION 5 - FIRE FIGHTING MEASURES
FLASH POINT: 304 癈, 580 癋
FLAMMABLE LIMIT, AIR VOL% LOWER: NA
UPPER: NA
AUTOIGNITION TEMPERATURE: NE
EXTINGUISHER METHOD: Water, carbon dioxide, dry chemical.
FIRE AND EXPLOSION HAZARDS: Polymer dust is combustible. The explosive limits of the polymer
particles suspended in air are approximately those of coal dust.
SPECIAL FIRE FIGHTING PROCEDURES: Avoid extinguishing methods, which may generate dust clouds.
Water stream can disperse dust into air producing a fire hazard
and possible explosion hazard if exposed to ignition source.
EXPLOSION HAZARD: Firefighters should wear self-contained breathing apparatus.
SENSITIVE TO MECHANICAL IMPACT: For Polymer: No.
SENSITIVE TO STATIC DISCHARGE: For Polymer: No.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
ACCIDENTAL RELEASE: Before cleaning any spill or leak, individuals involved must wear
appropriate Personal Protective Equipment (e.g., goggles, gloves).
Sweep up to avoid slipping hazard. Keep airborne particulates at
a minimum when cleaning up spills. Dispose of properly in
accordance with local, state and federal regulations. Wash all
affected areas with plenty of warm water and soap. Remove any
contaminated clothing and wash thoroughly before reuse.
SECTION 7- HANDLING AND STORAGE
PRECAUTIONS FOR HANDLING: Use in well ventilated areas. Avoid contact with skin, eyes and
clothing. Avoid breathing dust. Use good personal hygiene and
housekeeping.
PRECAUTIONS FOR STORAGE: Store containers in a cool, dry location, away from direct sunlight,
other light sources, or sources of intense heat. Keep container
closed to prevent water absorption and contamination.
INDUSTRIAL HYGIENE PRACTICES: Avoid prolonged contact with the product. Use in a well-ventilated
location (e.g., local exhaust ventilation, fans). After use, wash
hands and exposed skin with soap and water. Do not eat, drink or
smoke while handling product.
Page 4
SECTION 8 - EXPOSURE CONTROL/PERSONAL PROTECTION
VENTILATION: When working with large quantities of product provide adequate
ventilation (e.g., local exhaust ventilation, fans). Ensure that an
eyewash station, sink or washbasin is available in case of
exposure to eyes. Use good local exhaust at processing
equipment, including buffers, sanders, grinders and polishers.
RESPIRATORY PROTECTION: No special respiratory protection is required under typical
circumstances of use or handling. If necessary, use only
respiratory protection authorized per U.S. OSHA's requirement in
29 CFR ?910.134, or applicable U.S. state regulations, or the
appropriate standards of Canada, its provinces, E.C. member
states, or Australia.
EYE PROTECTION: Depending on the use of this product safety glasses or goggles
may be worn. If necessary, refer to U.S. OSHA 29 CFR
?910.133, Canadian standards, or the European Standard
EN166. Ensure that an eyewash station, sink or washbasin is
available in case of exposure to eyes.
PROTECTIVE GLOVES: If anticipated that prolonged & repeated skin contact will occur
during use of this product, wear gloves for routine industrial use. If
necessary, refer to U.S. OSHA 29 CFR ?910.138, the
appropriate standards of Canada, of the E.C. member states.
OTHER PROTECTIVE EQUIPMENT: No special body protection is required under typical circumstances
of use and handling. If necessary, refer to appropriate standards of
Canada, the E.C. member states, or U.S. OSHA. An eyewash
station and a safety shower are recommended. High temperature
processing equipment should be well ventilated.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: Fine clear to pigmented powder.
ODOR: Faint odor in bulk.
pH: NA
ODOR THRESHOLD: ND
BOILING POINT: NA
FREEZING POINT: NA
VISCOSITY: NA
SPECIFIC GRAVITY (H2O=1): ND
VAPOR PRESSURE: NA
PERCENT VOLATILE W/W%: NA
VAPOR DENSITY (AIR=1): NA
EVAPORATION RATE (BuAc =1): NA
SOLUBILITY IN WATER: Insoluble.
COEFFICIENT OF WATER/OIL DISTRIBUTION: ND
Page 5
SECTION 10 - STABILITY AND REACTIVITY
CONDITIONS TO AVOID: Heating above 240 癈, 464 癋.
INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS: Methacrylate Monomer and Oxides of Carbon when burned.
HAZARDOUS POLYMERIZATION: MAY OCCUR: WILL NOT OCCUR: X
STABILITY: UNSTABLE: STABLE: X
SECTION 11- TOXICOLOGICAL PROPERTIES
TOXICITY DATA:
This product has NOT been tested on animals to obtain toxicology data. There is toxicology data for the
components of the product, which is found in scientific literature. This data has not been presented in this
document.
MUTAGENICITY DATA: This product is not reported to produce mutagenic effects in humans.
REPRODUCTIVE TOXICITY DATA:
Embryotoxicity: This product is not reported to produce embryotoxic effects in humans.
Teratogenicity: This product is not reported to cause teratogenic effects in humans.
Reproductive Toxicity: This product is not reported to cause reproductive effects in humans.
SECTION 12 - ECOLOGICAL INFORMATION
AQUATIC TOXICITY:
There is no specific data available for this product; however, very large releases of this product may be
harmful or fatal to overexposed aquatic life.
ENVIRONMENTAL FATE:
There is no specific data available for this product.
SECTION 13 - DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: Dispose of properly in accordance with Federal, State, and Local
regulations.
DISPOSAL OF EMPTY CONTAINERS: Reuse of empty drums or containers is not recommended.
Employees should be advised of the potential hazards due to
residual material associated with empty containers. Dispose of all
empty containers properly in accordance with Federal, State and
Local regulations.
Page 6
SECTION 14 - TRANSPORTATION
DOT/UN SHIPPING NAME: POLYMER, NOI
DOT/UN CLASS:
NA/UN NUMBER:
PACKING GROUP:
LABEL:
IMDG CLASS:
IMDG PG:
CERCLA RQ:
SECTION 15 - REGULATORY INFORMATION
SARA Reporting Requirements: NA
SARA Threshold Planning Quantity: There are no specific Threshold Planning Quantities for the
components of this product.
TSCA Inventory Status: The components of this product are listed on the TSCA Inventory.
For use in FDA regulated products only.
CERCLA Reportable Quantity (RQ): NA
Other Federal Requirements: This product complies with the appropriate sections of the Food
and Drug Administration's 21 CFR subchapter G (Cosmetics).
Other Canadian Regulations: This product has been classified according to the hazard criteria of
the CPR and the MSDS contains all of the information required by
the CPR. The components of this product are listed on the
DSL/NDSL. None of the components of this product are listed
on the Priorities Substances List.
State Regulatory Information: This product may contain components that are covered under
specific state criteria.
RISK STATEMENTS: R36/37/38 ?Irritating to eyes, respiratory system and skin.
SAFETY STATEMENTS: S3 ?Keep in a cool place.
S7 ?Keep container tightly closed.
S9 ?Keep container in a well-ventilated place.
S20 ?When using do not eat or drink.
S 29 ?Do not empty into drains.
S37/39 ?Wear suitable gloves and eye/face protection.
Page 7
SECTION 16 - OTHER INFORMATION
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS) RATING:
HEALTH: 1
FLAMMABILITY: 1
REACTIVITY: 0
PERSONAL PROTECTIVE EQUIPMENT: Gloves and Safety Glasses or Chemical Goggles.
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD IDENTIFICATION RATING:
HEALTH: 1
FLAMMABILITY: 1
REACTIVITY: 0
ABBREVIATIONS:
NA Not Applicable ND Not Determined
NE Not Established
ppm parts per million G Gallon
mg Milligram L Liter
gm Gram mol Mole
kg Kilogram ! Micro
mm Millimeter p Pico
Pa Pascals
LC Lethal Concentration LD Lethal Dose
TC Toxic Concentration TD Toxic Dose
BOD Biological Oxygen Demand COD Chemical Oxygen Demand
Lo Lowest ThOD Theoretical Oxygen Demand
TLm Threshold Limit
H Hours M Months
D Days Y Years
W Weeks
ACGIH American Conference of Governmental Industrial Hygienist
CPR Controlled Product's Regulation
DSL Canadian Domestic Substances List
NDSL Canadian Non-domestic Substance List
IARC International Agency for Research for Cancer
NOEL No Observed Effect Level
NOAEL No Observed Adverse Effect Level
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
TLV Threshold Limit Value
Page 8
SECTION 16 - OTHER INFORMATION CONTINUED
. THE ABOVE INFORMATION MAY BE BASED IN PART ON INFORMATION PROVIDED BY COMPONENT SUPPLIERS AND IS BELIEVED
TO BE CORRECT AS OF THE DATE HEREOF. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY USE, OR ANY
OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OF THESE DATA, THE RESULTS TO BE
OBTAINED FROM THE USE OF THE MATERIAL, OR THE HAZARDS CONNECTED WITH SUCH USE. SINCE THE INFORMATION
CONTAINED HEREIN MAY BE APPLIED UNDER CONDITIONS BEYOND OUR CONTROL AND WITH WHICH WE MAY BE UNFAMILIAR,
AND SINCE DATA MADE AVAILABLE SUBSEQUENT TO THE DATE HEREOF MAY SUGGEST MODIFICATION OF THE INFORMATION,
WE ASSUME NO RESPONSIBILITY FOR THE RESULT OF ITS USE. THIS INFORMATION AND MATERIAL IS FURNISHED ON THE
CONDITION THAT THE PERSON RECEIVING IT SHALL MAKE HIS/HER OWN DETERMINATION AS TO THE SUITABILITY OF THE
MATERIAL FOR HIS/HER PARTICULAR PURPOSE AND ON THE CONDITION THAT HE/SHE ASSUME THE RISK OF HIS/HER USE
THEREOF.
Star Nail International MATERIAL SAFETY DATA SHEET
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
CHEMICAL NAME: Methacrylate Copolymer
PRODUCT/TRADE NAME: Ultra Pink Acrylic Powder
PRODUCT USE: Organic Process Chemical
MANUFACTURER: Star Nail International
ADDRESS: 29120 Avenue Paine
Valencia, CA 91355
24 HR. EMERGENCY TELEPHONE: CHEMTEL 1-813-248-0573
PREPARATION/UPDATE DATE: 2/22/06
PRINT DATE: 5/22/07
MSDS ID: P7-01
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
FOR POLYMER:
ITEM CHEMICAL NAME CAS NUMBER: WT/WT %
01 Polymer 25685-29-4 60.0-100.0
ACGIH OSHA Company
ITEM TLV-TWA TLV-STEL PEL TWA PEL CEILING Recommendation SKIN
3 3 3
01 10 mg/m NE 15 mg/m NE 15 mg/m NE
See Section 16 for Abbreviations.
Page 2
SECTION 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
WARNING:
For Polymer: OSHA classifies this material as Particulates, Not
Otherwise Classified.
Acute Hazards: Eyes: May be irritating to the eyes by gross overexposure, no
matter how generated. Symptoms of overexposure may
include redness, itching, irritation and watering. Keep dust
out of eyes.
Ingestion: Not expected to cause any harmful effects. Ingestion of
large amounts may be irritating if product is swallowed,
may cause nausea, headache, vomiting and/or diarrhea.
Skin: May be irritating to skin in some sensitive individuals,
especially after prolonged and/or repeated contact.
Inhalation: May be irritated by gross overexposure, no matter how
generated.
Chronic Hazards: None known.
CARCINOGENICITY: None of the components of this material are listed by
IARC, NTP, OSHA, or ACGIH as carcinogens.
PRIMARY ROUTES OF ENTRY: Inhalation, Skin or Eyes.
SECTION 4 - FIRST AID MEASURES
EMERGENCY AND FIRST AID PROCEDURES:
EYES: If product gets in the eyes, flush with copious amounts of lukewarm water for at
least 15 minutes. If irritation occurs, contact a physician.
INGESTION: If ingested, do not induce vomiting. If product has been swallowed, drink plenty of
water or milk IMMEDIATELY. If the patient is vomiting, continue to offer water or
milk. Never give anything by mouth to an unconscious person. Provide an estimate
of the time at which the material was ingested and the amount of the substance
that was swallowed. Get medical attention immediately.
INHALATION: Remove to fresh air. Seek immediate medical attention.
SKIN: If irritation occurs and product is on the skin, rinse thoroughly with lukewarm water,
followed by a thorough washing of the effected area with soap and water. If
irritation, redness or swelling persists, contact a physician immediately.
CLOTHING: Remove contaminated clothing, wash thoroughly before reuse.
TREATMENT: Treat symptoms conventionally, after thorough decontamination.
Page 3
SECTION 5 - FIRE FIGHTING MEASURES
FLASH POINT: 304 癈, 580 癋
FLAMMABLE LIMIT, AIR VOL% LOWER: NA
UPPER: NA
AUTOIGNITION TEMPERATURE: NE
EXTINGUISHER METHOD: Water, carbon dioxide, dry chemical.
FIRE AND EXPLOSION HAZARDS: Polymer dust is combustible. The explosive limits of the polymer
particles suspended in air are approximately those of coal dust.
SPECIAL FIRE FIGHTING PROCEDURES: Avoid extinguishing methods, which may generate dust clouds.
Water stream can disperse dust into air producing a fire hazard
and possible explosion hazard if exposed to ignition source.
EXPLOSION HAZARD: Firefighters should wear self-contained breathing apparatus.
SENSITIVE TO MECHANICAL IMPACT: For Polymer: No.
SENSITIVE TO STATIC DISCHARGE: For Polymer: No.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
ACCIDENTAL RELEASE: Before cleaning any spill or leak, individuals involved must wear
appropriate Personal Protective Equipment (e.g., goggles, gloves).
Sweep up to avoid slipping hazard. Keep airborne particulates at
a minimum when cleaning up spills. Dispose of properly in
accordance with local, state and federal regulations. Wash all
affected areas with plenty of warm water and soap. Remove any
contaminated clothing and wash thoroughly before reuse.
SECTION 7- HANDLING AND STORAGE
PRECAUTIONS FOR HANDLING: Use in well ventilated areas. Avoid contact with skin, eyes and
clothing. Avoid breathing dust. Use good personal hygiene and
housekeeping.
PRECAUTIONS FOR STORAGE: Store containers in a cool, dry location, away from direct sunlight,
other light sources, or sources of intense heat. Keep container
closed to prevent water absorption and contamination.
INDUSTRIAL HYGIENE PRACTICES: Avoid prolonged contact with the product. Use in a well-ventilated
location (e.g., local exhaust ventilation, fans). After use, wash
hands and exposed skin with soap and water. Do not eat, drink or
smoke while handling product.
Page 4
SECTION 8 - EXPOSURE CONTROL/PERSONAL PROTECTION
VENTILATION: When working with large quantities of product provide adequate
ventilation (e.g., local exhaust ventilation, fans). Ensure that an
eyewash station, sink or washbasin is available in case of
exposure to eyes. Use good local exhaust at processing
equipment, including buffers, sanders, grinders and polishers.
RESPIRATORY PROTECTION: No special respiratory protection is required under typical
circumstances of use or handling. If necessary, use only
respiratory protection authorized per U.S. OSHA's requirement in
29 CFR ?910.134, or applicable U.S. state regulations, or the
appropriate standards of Canada, its provinces, E.C. member
states, or Australia.
EYE PROTECTION: Depending on the use of this product safety glasses or goggles
may be worn. If necessary, refer to U.S. OSHA 29 CFR
?910.133, Canadian standards, or the European Standard
EN166. Ensure that an eyewash station, sink or washbasin is
available in case of exposure to eyes.
PROTECTIVE GLOVES: If anticipated that prolonged & repeated skin contact will occur
during use of this product, wear gloves for routine industrial use. If
necessary, refer to U.S. OSHA 29 CFR ?910.138, the
appropriate standards of Canada, of the E.C. member states.
OTHER PROTECTIVE EQUIPMENT: No special body protection is required under typical circumstances
of use and handling. If necessary, refer to appropriate standards of
Canada, the E.C. member states, or U.S. OSHA. An eyewash
station and a safety shower are recommended. High temperature
processing equipment should be well ventilated.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: Fine clear to pigmented powder.
ODOR: Faint odor in bulk.
pH: NA
ODOR THRESHOLD: ND
BOILING POINT: NA
FREEZING POINT: NA
VISCOSITY: NA
SPECIFIC GRAVITY (H2O=1): ND
VAPOR PRESSURE: NA
PERCENT VOLATILE W/W%: NA
VAPOR DENSITY (AIR=1): NA
EVAPORATION RATE (BuAc =1): NA
SOLUBILITY IN WATER: Insoluble.
COEFFICIENT OF WATER/OIL DISTRIBUTION: ND
Page 5
SECTION 10 - STABILITY AND REACTIVITY
CONDITIONS TO AVOID: Heating above 240 癈, 464 癋.
INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS: Methacrylate Monomer and Oxides of Carbon when burned.
HAZARDOUS POLYMERIZATION: MAY OCCUR: WILL NOT OCCUR: X
STABILITY: UNSTABLE: STABLE: X
SECTION 11- TOXICOLOGICAL PROPERTIES
TOXICITY DATA:
This product has NOT been tested on animals to obtain toxicology data. There is toxicology data for the
components of the product, which is found in scientific literature. This data has not been presented in this
document.
MUTAGENICITY DATA: This product is not reported to produce mutagenic effects in humans.
REPRODUCTIVE TOXICITY DATA:
Embryotoxicity: This product is not reported to produce embryotoxic effects in humans.
Teratogenicity: This product is not reported to cause teratogenic effects in humans.
Reproductive Toxicity: This product is not reported to cause reproductive effects in humans.
SECTION 12 - ECOLOGICAL INFORMATION
AQUATIC TOXICITY:
There is no specific data available for this product; however, very large releases of this product may be
harmful or fatal to overexposed aquatic life.
ENVIRONMENTAL FATE:
There is no specific data available for this product.
SECTION 13 - DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: Dispose of properly in accordance with Federal, State, and Local
regulations.
DISPOSAL OF EMPTY CONTAINERS: Reuse of empty drums or containers is not recommended.
Employees should be advised of the potential hazards due to
residual material associated with empty containers. Dispose of all
empty containers properly in accordance with Federal, State and
Local regulations.
Page 6
SECTION 14 - TRANSPORTATION
DOT/UN SHIPPING NAME: POLYMER, NOI
DOT/UN CLASS:
NA/UN NUMBER:
PACKING GROUP:
LABEL:
IMDG CLASS:
IMDG PG:
CERCLA RQ:
SECTION 15 - REGULATORY INFORMATION
SARA Reporting Requirements: NA
SARA Threshold Planning Quantity: There are no specific Threshold Planning Quantities for the
components of this product.
TSCA Inventory Status: The components of this product are listed on the TSCA Inventory.
For use in FDA regulated products only.
CERCLA Reportable Quantity (RQ): NA
Other Federal Requirements: This product complies with the appropriate sections of the Food
and Drug Administration's 21 CFR subchapter G (Cosmetics).
Other Canadian Regulations: This product has been classified according to the hazard criteria of
the CPR and the MSDS contains all of the information required by
the CPR. The components of this product are listed on the
DSL/NDSL. None of the components of this product are listed
on the Priorities Substances List.
State Regulatory Information: This product may contain components that are covered under
specific state criteria.
RISK STATEMENTS: R36/37/38 ?Irritating to eyes, respiratory system and skin.
SAFETY STATEMENTS: S3 ?Keep in a cool place.
S7 ?Keep container tightly closed.
S9 ?Keep container in a well-ventilated place.
S20 ?When using do not eat or drink.
S 29 ?Do not empty into drains.
S37/39 ?Wear suitable gloves and eye/face protection.
Page 7
SECTION 16 - OTHER INFORMATION
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS) RATING:
HEALTH: 1
FLAMMABILITY: 1
REACTIVITY: 0
PERSONAL PROTECTIVE EQUIPMENT: Gloves and Safety Glasses or Chemical Goggles.
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD IDENTIFICATION RATING:
HEALTH: 1
FLAMMABILITY: 1
REACTIVITY: 0
ABBREVIATIONS:
NA Not Applicable ND Not Determined
NE Not Established
ppm parts per million G Gallon
mg Milligram L Liter
gm Gram mol Mole
kg Kilogram ! Micro
mm Millimeter p Pico
Pa Pascals
LC Lethal Concentration LD Lethal Dose
TC Toxic Concentration TD Toxic Dose
BOD Biological Oxygen Demand COD Chemical Oxygen Demand
Lo Lowest ThOD Theoretical Oxygen Demand
TLm Threshold Limit
H Hours M Months
D Days Y Years
W Weeks
ACGIH American Conference of Governmental Industrial Hygienist
CPR Controlled Product's Regulation
DSL Canadian Domestic Substances List
NDSL Canadian Non-domestic Substance List
IARC International Agency for Research for Cancer
NOEL No Observed Effect Level
NOAEL No Observed Adverse Effect Level
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
TLV Threshold Limit Value
Page 8
SECTION 16 - OTHER INFORMATION CONTINUED
THE ABOVE INFORMATION MAY BE BASED IN PART ON INFORMATION PROVIDED BY COMPONENT SUPPLIERS AND IS BELIEVED
TO BE CORRECT AS OF THE DATE HEREOF. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY USE, OR ANY
OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OF THESE DATA, THE RESULTS TO BE
OBTAINED FROM THE USE OF THE MATERIAL, OR THE HAZARDS CONNECTED WITH SUCH USE. SINCE THE INFORMATION
CONTAINED HEREIN MAY BE APPLIED UNDER CONDITIONS BEYOND OUR CONTROL AND WITH WHICH WE MAY BE UNFAMILIAR,
AND SINCE DATA MADE AVAILABLE SUBSEQUENT TO THE DATE HEREOF MAY SUGGEST MODIFICATION OF THE INFORMATION,
WE ASSUME NO RESPONSIBILITY FOR THE RESULT OF ITS USE. THIS INFORMATION AND MATERIAL IS FURNISHED ON THE
CONDITION THAT THE PERSON RECEIVING IT SHALL MAKE HIS/HER OWN DETERMINATION AS TO THE SUITABILITY OF THE
MATERIAL FOR HIS/HER PARTICULAR PURPOSE AND ON THE CONDITION THAT HE/SHE ASSUME THE RISK OF HIS/HER USE
THEREOF.
Star Nail International. MATERIAL SAFETY DATA SHEET
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
CHEMICAL NAME: Methacrylate Copolymer
PRODUCT/TRADE NAME: Ultra White Acrylic Powder
PRODUCT USE: Organic Process Chemical
MANUFACTURER: Star Nail International
ADDRESS: 29120 Avenue Paine
Valencia, CA 91355
24 HR. EMERGENCY TELEPHONE: CHEMTEL 1-813-248-0573
PREPARATION/UPDATE DATE: 2/22/06
PRINT DATE: 5/22/07
MSDS ID: P7-01
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
FOR POLYMER:
ITEM CHEMICAL NAME CAS NUMBER: WT/WT %
01 Polymer 25685-29-4 60.0-100.0
ACGIH OSHA Company
ITEM TLV-TWA TLV-STEL PEL TWA PEL CEILING Recommendation SKIN
3 3 3
01 10 mg/m NE 15 mg/m NE 15 mg/m NE
See Section 16 for Abbreviations.
Page 2
SECTION 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
WARNING:
For Polymer: OSHA classifies this material as Particulates, Not
Otherwise Classified.
Acute Hazards: Eyes: May be irritating to the eyes by gross overexposure, no
matter how generated. Symptoms of overexposure may
include redness, itching, irritation and watering. Keep dust
out of eyes.
Ingestion: Not expected to cause any harmful effects. Ingestion of
large amounts may be irritating if product is swallowed,
may cause nausea, headache, vomiting and/or diarrhea.
Skin: May be irritating to skin in some sensitive individuals,
especially after prolonged and/or repeated contact.
Inhalation: May be irritated by gross overexposure, no matter how
generated.
Chronic Hazards: None known.
CARCINOGENICITY: None of the components of this material are listed by
IARC, NTP, OSHA, or ACGIH as carcinogens.
PRIMARY ROUTES OF ENTRY: Inhalation, Skin or Eyes.
SECTION 4 - FIRST AID MEASURES
EMERGENCY AND FIRST AID PROCEDURES:
EYES: If product gets in the eyes, flush with copious amounts of lukewarm water for at
least 15 minutes. If irritation occurs, contact a physician.
INGESTION: If ingested, do not induce vomiting. If product has been swallowed, drink plenty of
water or milk IMMEDIATELY. If the patient is vomiting, continue to offer water or
milk. Never give anything by mouth to an unconscious person. Provide an estimate
of the time at which the material was ingested and the amount of the substance
that was swallowed. Get medical attention immediately.
INHALATION: Remove to fresh air. Seek immediate medical attention.
SKIN: If irritation occurs and product is on the skin, rinse thoroughly with lukewarm water,
followed by a thorough washing of the effected area with soap and water. If
irritation, redness or swelling persists, contact a physician immediately.
CLOTHING: Remove contaminated clothing, wash thoroughly before reuse.
TREATMENT: Treat symptoms conventionally, after thorough decontamination.
Page 3
SECTION 5 - FIRE FIGHTING MEASURES
FLASH POINT: 304 癈, 580 癋
FLAMMABLE LIMIT, AIR VOL% LOWER: NA
UPPER: NA
AUTOIGNITION TEMPERATURE: NE
EXTINGUISHER METHOD: Water, carbon dioxide, dry chemical.
FIRE AND EXPLOSION HAZARDS: Polymer dust is combustible. The explosive limits of the polymer
particles suspended in air are approximately those of coal dust.
SPECIAL FIRE FIGHTING PROCEDURES: Avoid extinguishing methods, which may generate dust clouds.
Water stream can disperse dust into air producing a fire hazard
and possible explosion hazard if exposed to ignition source.
EXPLOSION HAZARD: Firefighters should wear self-contained breathing apparatus.
SENSITIVE TO MECHANICAL IMPACT: For Polymer: No.
SENSITIVE TO STATIC DISCHARGE: For Polymer: No.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
ACCIDENTAL RELEASE: Before cleaning any spill or leak, individuals involved must wear
appropriate Personal Protective Equipment (e.g., goggles, gloves).
Sweep up to avoid slipping hazard. Keep airborne particulates at
a minimum when cleaning up spills. Dispose of properly in
accordance with local, state and federal regulations. Wash all
affected areas with plenty of warm water and soap. Remove any
contaminated clothing and wash thoroughly before reuse.
SECTION 7- HANDLING AND STORAGE
PRECAUTIONS FOR HANDLING: Use in well ventilated areas. Avoid contact with skin, eyes and
clothing. Avoid breathing dust. Use good personal hygiene and
housekeeping.
PRECAUTIONS FOR STORAGE: Store containers in a cool, dry location, away from direct sunlight,
other light sources, or sources of intense heat. Keep container
closed to prevent water absorption and contamination.
INDUSTRIAL HYGIENE PRACTICES: Avoid prolonged contact with the product. Use in a well-ventilated
location (e.g., local exhaust ventilation, fans). After use, wash
hands and exposed skin with soap and water. Do not eat, drink or
smoke while handling product.
Page 4
SECTION 8 - EXPOSURE CONTROL/PERSONAL PROTECTION
VENTILATION: When working with large quantities of product provide adequate
ventilation (e.g., local exhaust ventilation, fans). Ensure that an
eyewash station, sink or washbasin is available in case of
exposure to eyes. Use good local exhaust at processing
equipment, including buffers, sanders, grinders and polishers.
RESPIRATORY PROTECTION: No special respiratory protection is required under typical
circumstances of use or handling. If necessary, use only
respiratory protection authorized per U.S. OSHA's requirement in
29 CFR ?910.134, or applicable U.S. state regulations, or the
appropriate standards of Canada, its provinces, E.C. member
states, or Australia.
EYE PROTECTION: Depending on the use of this product safety glasses or goggles
may be worn. If necessary, refer to U.S. OSHA 29 CFR
?910.133, Canadian standards, or the European Standard
EN166. Ensure that an eyewash station, sink or washbasin is
available in case of exposure to eyes.
PROTECTIVE GLOVES: If anticipated that prolonged & repeated skin contact will occur
during use of this product, wear gloves for routine industrial use. If
necessary, refer to U.S. OSHA 29 CFR ?910.138, the
appropriate standards of Canada, of the E.C. member states.
OTHER PROTECTIVE EQUIPMENT: No special body protection is required under typical circumstances
of use and handling. If necessary, refer to appropriate standards of
Canada, the E.C. member states, or U.S. OSHA. An eyewash
station and a safety shower are recommended. High temperature
processing equipment should be well ventilated.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: Fine clear to pigmented powder.
ODOR: Faint odor in bulk.
pH: NA
ODOR THRESHOLD: ND
BOILING POINT: NA
FREEZING POINT: NA
VISCOSITY: NA
SPECIFIC GRAVITY (H2O=1): ND
VAPOR PRESSURE: NA
PERCENT VOLATILE W/W%: NA
VAPOR DENSITY (AIR=1): NA
EVAPORATION RATE (BuAc =1): NA
SOLUBILITY IN WATER: Insoluble.
COEFFICIENT OF WATER/OIL DISTRIBUTION: ND
Page 5
SECTION 10 - STABILITY AND REACTIVITY
CONDITIONS TO AVOID: Heating above 240 癈, 464 癋.
INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS: Methacrylate Monomer and Oxides of Carbon when burned.
HAZARDOUS POLYMERIZATION: MAY OCCUR: WILL NOT OCCUR: X
STABILITY: UNSTABLE: STABLE: X
SECTION 11- TOXICOLOGICAL PROPERTIES
TOXICITY DATA:
This product has NOT been tested on animals to obtain toxicology data. There is toxicology data for the
components of the product, which is found in scientific literature. This data has not been presented in this
document.
MUTAGENICITY DATA: This product is not reported to produce mutagenic effects in humans.
REPRODUCTIVE TOXICITY DATA:
Embryotoxicity: This product is not reported to produce embryotoxic effects in humans.
Teratogenicity: This product is not reported to cause teratogenic effects in humans.
Reproductive Toxicity: This product is not reported to cause reproductive effects in humans.
SECTION 12 - ECOLOGICAL INFORMATION
AQUATIC TOXICITY:
There is no specific data available for this product; however, very large releases of this product may be
harmful or fatal to overexposed aquatic life.
ENVIRONMENTAL FATE:
There is no specific data available for this product.
SECTION 13 - DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: Dispose of properly in accordance with Federal, State, and Local
regulations.
DISPOSAL OF EMPTY CONTAINERS: Reuse of empty drums or containers is not recommended.
Employees should be advised of the potential hazards due to
residual material associated with empty containers. Dispose of all
empty containers properly in accordance with Federal, State and
Local regulations.
Page 6
SECTION 14 - TRANSPORTATION
DOT/UN SHIPPING NAME: POLYMER, NOI
DOT/UN CLASS:
NA/UN NUMBER:
PACKING GROUP:
LABEL:
IMDG CLASS:
IMDG PG:
CERCLA RQ:
SECTION 15 - REGULATORY INFORMATION
SARA Reporting Requirements: NA
SARA Threshold Planning Quantity: There are no specific Threshold Planning Quantities for the
components of this product.
TSCA Inventory Status: The components of this product are listed on the TSCA Inventory.
For use in FDA regulated products only.
CERCLA Reportable Quantity (RQ): NA
Other Federal Requirements: This product complies with the appropriate sections of the Food
and Drug Administration's 21 CFR subchapter G (Cosmetics).
Other Canadian Regulations: This product has been classified according to the hazard criteria of
the CPR and the MSDS contains all of the information required by
the CPR. The components of this product are listed on the
DSL/NDSL. None of the components of this product are listed
on the Priorities Substances List.
State Regulatory Information: This product may contain components that are covered under
specific state criteria.
RISK STATEMENTS: R36/37/38 ?Irritating to eyes, respiratory system and skin.
SAFETY STATEMENTS: S3 ?Keep in a cool place.
S7 ?Keep container tightly closed.
S9 ?Keep container in a well-ventilated place.
S20 ?When using do not eat or drink.
S 29 ?Do not empty into drains.
S37/39 ?Wear suitable gloves and eye/face protection.
Page 7
SECTION 16 - OTHER INFORMATION
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS) RATING:
HEALTH: 1
FLAMMABILITY: 1
REACTIVITY: 0
PERSONAL PROTECTIVE EQUIPMENT: Gloves and Safety Glasses or Chemical Goggles.
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD IDENTIFICATION RATING:
HEALTH: 1
FLAMMABILITY: 1
REACTIVITY: 0
ABBREVIATIONS:
NA Not Applicable ND Not Determined
NE Not Established
ppm parts per million G Gallon
mg Milligram L Liter
gm Gram mol Mole
kg Kilogram ! Micro
mm Millimeter p Pico
Pa Pascals
LC Lethal Concentration LD Lethal Dose
TC Toxic Concentration TD Toxic Dose
BOD Biological Oxygen Demand COD Chemical Oxygen Demand
Lo Lowest ThOD Theoretical Oxygen Demand
TLm Threshold Limit
H Hours M Months
D Days Y Years
W Weeks
ACGIH American Conference of Governmental Industrial Hygienist
CPR Controlled Product's Regulation
DSL Canadian Domestic Substances List
NDSL Canadian Non-domestic Substance List
IARC International Agency for Research for Cancer
NOEL No Observed Effect Level
NOAEL No Observed Adverse Effect Level
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
TLV Threshold Limit Value
Page 8
SECTION 16 - OTHER INFORMATION CONTINUED
THE ABOVE INFORMATION MAY BE BASED IN PART ON INFORMATION PROVIDED BY COMPONENT SUPPLIERS AND IS BELIEVED
TO BE CORRECT AS OF THE DATE HEREOF. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY USE, OR ANY
OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OF THESE DATA, THE RESULTS TO BE
OBTAINED FROM THE USE OF THE MATERIAL, OR THE HAZARDS CONNECTED WITH SUCH USE. SINCE THE INFORMATION
CONTAINED HEREIN MAY BE APPLIED UNDER CONDITIONS BEYOND OUR CONTROL AND WITH WHICH WE MAY BE UNFAMILIAR,
AND SINCE DATA MADE AVAILABLE SUBSEQUENT TO THE DATE HEREOF MAY SUGGEST MODIFICATION OF THE INFORMATION,
WE ASSUME NO RESPONSIBILITY FOR THE RESULT OF ITS USE. THIS INFORMATION AND MATERIAL IS FURNISHED ON THE
CONDITION THAT THE PERSON RECEIVING IT SHALL MAKE HIS/HER OWN DETERMINATION AS TO THE SUITABILITY OF THE
MATERIAL FOR HIS/HER PARTICULAR PURPOSE AND ON THE CONDITION THAT HE/SHE ASSUME THE RISK OF HIS/HER USE
THEREOF.
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