3M General Offices
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6/11/2010 7:34:20 AM
Material Safety Data Sheet
Purchase Order #: 436212
Customer Number: MFR6696
ACCTS PAYABLE DEPT
KELLOGG MARINE INC
5 ENTERPRISE DR
OLD LYME, CT 06371-1568
United States of America
Dear ACCTS PAYABLE DEPT
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MATERIAL SAFETY DATA SHEET 3MTM Blue Cream Hardener 05766 05/07/10
Material Safety Data Sheet
Copyright, 2010, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3MTM Blue Cream Hardener 05766
MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 05/07/10
Supercedes Date: 02/09/10
Document Group: 28-0172-8
Product Use:
Intended Use: Automotive
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
BENZOYL PEROXIDE 94-36-0 30 - 60
WATER 7732-18-5 10 - 30
BENZOIC ACID, C9-11-BRANCHED ALKYL ESTERS 131298-44-7 10 - 30
ZINC STEARATE 557-05-1 5 - 10
CALCIUM SULFATE 7778-18-9 3- 7
OXIRANE, POLYMER WITH METHYLOXIRANE, MONOBUTYL ETHER 9038-95-3 3- 7
FERRIC AMMONIUM FERROCYANIDE 25869-00-5 <1
FERRIC FERROCYANIDE 14038-43-8 <1
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Paste
Odor, Color, Grade: Blue paste with slight ester odor
General Physical Form: Solid
Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and
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MATERIAL SAFETY DATA SHEET 3MTM Blue Cream Hardener 05766 05/07/10
explode. May cause allergic skin reaction.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects:
Prolonged or repeated exposure may cause:
Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and
jaundice.
Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain, increased
protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical
attention. Wash contaminated clothing and clean shoes before reuse.
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MATERIAL SAFETY DATA SHEET 3MTM Blue Cream Hardener 05766 05/07/10
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
No Data Available
Autoignition temperature
Not Applicable
Flash Point
Not Applicable
Flammable Limits - LEL
Not Applicable
Flammable Limits - UEL
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Water may be used to blanket the fire. Wear full protective equipment (Bunker Gear) and a
self-contained breathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures:
Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the
area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in
accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or
vapors in the spill area to burn or explode.
Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible.
Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more information on handling and managing the
spill. Collect as much of the spilled material as possible. Clean up residue.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat,
sparks, open flame, pilot lights and other sources of ignition. Avoid skin contact. Avoid eye contact with vapors, mists, or spray.
Keep out of the reach of children. Keep container closed when not in use. Avoid breathing of dust created by cutting, sanding,
grinding or machining. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below
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MATERIAL SAFETY DATA SHEET 3MTM Blue Cream Hardener 05766 05/07/10
Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment.
7.2 STORAGE
Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area. Do not heat under confinement to avoid
risk of explosion Store in a cool, dry place.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Provide appropriate local exhaust for cutting, grinding, sanding or machining. Use general dilution ventilation and/or local exhaust
ventilation to control airborne exposures to below Occupational Exposure Limits and/or control dust, fume, or airborne particles. If
ventilation is not adequate, use respiratory protection equipment.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact with vapors, mists, or spray. To minimize the risk of injury to face and eyes, always wear eye and face protection
when working at sanding or grinding operations or when near such operations.
The following eye protection(s) are recommended: Safety Glasses with side shields
Indirect Vented Goggles
.
8.2.2 Skin Protection
Avoid skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Polyethylene/Ethylene Vinyl Alcohol
.
8.2.3 Respiratory Protection
Avoid breathing of dust created by cutting, sanding, grinding or machining.
Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with
OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges and P95 particulate prefilters
. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Do not ingest.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
BENZOYL PEROXIDE ACGIH TWA 5 mg/m3
BENZOYL PEROXIDE OSHA TWA 5 mg/m3
CALCIUM SULFATE ACGIH TWA, inhalable 10 mg/m3
fraction
CALCIUM SULFATE OSHA TWA, respirable 5 mg/m3
fraction
CALCIUM SULFATE OSHA TWA, as total dust 15 mg/m3
ZINC STEARATE OSHA TWA, respirable 5 mg/m3
fraction
ZINC STEARATE OSHA TWA, as total dust 15 mg/m3
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MATERIAL SAFETY DATA SHEET 3MTM Blue Cream Hardener 05766 05/07/10
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Paste
Specific Physical Form:
Blue paste with slight ester odor
Odor, Color, Grade:
Solid
General Physical Form:
No Data Available
Autoignition temperature
Not Applicable
Flash Point
Not Applicable
Flammable Limits - LEL
Not Applicable
Flammable Limits - UEL
[Details: Decomposes]
Boiling point
1.2 g/ml
Density
No Data Available
Vapor Density
No Data Available
Vapor Density
No Data Available
Vapor Pressure
No Data Available
Vapor Pressure
1.2 [Ref Std: WATER=1] [Details: @ 25 C]
Specific Gravity
No Data Available
pH
No Data Available
Melting point
No Data Available
Solubility In Water
Negligible
Solubility in Water
No Data Available
Evaporation rate
0 % weight [Test Method: calculated SCAQMD rule 443.1]
Volatile Organic Compounds
[Details: Excluding exempt compounds]
No Data Available
Kow - Oct/Water partition coef
0 g/l [Test Method: calculated SCAQMD rule 443.1]
VOC Less H2O & Exempt Solvents
70000 centipoise - 150000 centipoise
Viscosity
Accelerators [Details: dimethylaniline cobalt napthenate and other
Materials to avoid
promoters reducing agents or any hot materials.]
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid:
10.1 Conditions to avoid
None known
10.2 Materials to avoid
Accelerators
Hazardous Polymerization: Hazardous polymerization will not occur.
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MATERIAL SAFETY DATA SHEET 3MTM Blue Cream Hardener 05766 05/07/10
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Toxic Vapor, Gas, Particulate During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Dispose of completely cured (or polymerized) wastes in a sanitary landfill.
As a disposal alternative, incinerate uncured product in an industrial or commercial incinerator in the presence of a combustible
material.
As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste.
EPA Hazardous Waste Number (RCRA): Not regulated
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
60-9800-3723-2
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
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MATERIAL SAFETY DATA SHEET 3MTM Blue Cream Hardener 05766 05/07/10
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
ZINC STEARATE (ZINC COMPOUNDS) 557-05-1 5 - 10
BENZOYL PEROXIDE 94-36-0 30 - 60
STATE REGULATIONS
Contact 3M for more information.
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
The components of this product are listed on the Canadian Domestic Substances List.
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 2 Reactivity: 0 Special Hazards: Oxidizer
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
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MATERIAL SAFETY DATA SHEET 3MTM Blue Cream Hardener 05766 05/07/10
Revision Changes:
Section 13: Waste disposal method information was modified.
Section 13: EPA hazardous waste number (RCRA) information was modified.
Section 8: Eye/face protection information was modified.
Section 8: Skin protection - recommended gloves information was modified.
Section 8: Respiratory protection - recommended respirators information was modified.
Section 9: Specific gravity information was modified.
Section 1: Initial issue message was modified.
Section 2: Ingredient table was modified.
Section 8: Exposure guidelines ingredient information was modified.
Section 6: Environmental procedures information was modified.
Section 6: Methods for cleaning up information was modified.
Section 10: Materials to avoid physical property was modified.
Section 10: Conditions to avoid physical property was modified.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
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