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Material Safety Data Sheet
acc. to ISO 11014
Printing date 08/11/2009 Reviewed on 08/11/2009
1 Identification of substance
?Product details
?Trade name: Mix- HICAL Acids Method 8270C
?Article number: N9331031
?Application of the substance / the preparation Laboratory chemicals
?Manufacturer/Supplier:
PerkinElmer Life and Analytical Sciences
710 Bridgeport Avenue
Shelton, Connecticut 06484 USA
?Information department:
Technical Support
800-762-4000
?Emergency information:
CHEMTREC (within U.S.) 800 424-9300
CHEMTREC (from outside U.S.) 1(703)-527-3883
2 Composition/Data on components
?Description: Mixture of the substances listed below with nonhazardous additions.
?Hazardous components:
75-09-2 dichloromethane 50-100%
95-95-4 2,4,5-trichlorophenol < 1%
88-06-2 2,4,6-trichlorophenol < 1%
120-83-2 2,4-dichlorophenol < 1%
105-67-9 2,4-xylenol < 1%
51-28-5 2,4-dinitrophenol < 1%
95-57-8 2-chlorophenol < 1%
534-52-1 DNOC < 1%
95-48-7 o-cresol < 1%
106-44-5 p-cresol < 1%
87-86-5 pentachlorophenol < 1%
108-95-2 phenol < 1%
?Additional Components
100-02-7 4-nitrophenol < 1%
65-85-0 Benzoic acid < 1%
88-75-5 2-nitrophenol < 1%
* 3 Hazards identification
?Hazard description:
Harmful
?WHMIS-symbols:
D1B - Toxic material causing immediate and serious toxic effects
(Contd. on page 2)
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Material Safety Data Sheet
acc. to ISO 11014
Printing date 08/11/2009 Reviewed on 08/11/2009
Trade name: Mix- HICAL Acids Method 8270C
(Contd. of page 1)
D2B - Toxic material causing other toxic effects
?Information pertaining to particular dangers for man and environment:
The product has to be labelled due to the calculation procedure of international guidelines.
Harmful by inhalation, in contact with skin and if swallowed.
Limited evidence of a carcinogenic effect.
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
?Classification system:
The classification was made according to the latest editions of international substances lists, and expanded upon
from company and literature data.
?NFPA ratings (scale 0 - 4)
Health = 2
0 Fire = 0
2 0 Reactivity = 0
?HMIS-ratings (scale 0 - 4)
HEALTH *2 Health = *2
Fire = 0
FIRE 0
Reactivity = 0
REACTIVITY 0
* 4 First aid measures
?General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
?After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms
persist.
In case of unconsciousness place patient stably in side position for transportation.
?After skin contact: Generally the product does not irritate the skin.
?After eye contact: Rinse opened eye for several minutes under running water.
?After swallowing: Immediately call a doctor.
5 Fire fighting measures
?Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
?Protective equipment: Mouth respiratory protective device.
6 Accidental release measures
?Person-related safety precautions: Not required.
?Measures for environmental protection:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
(Contd. on page 3)
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Material Safety Data Sheet
acc. to ISO 11014
Printing date 08/11/2009 Reviewed on 08/11/2009
Trade name: Mix- HICAL Acids Method 8270C
(Contd. of page 2)
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
7 Handling and storage
?Handling:
?Information for safe handling:
Store in cool, dry place in tightly closed receptacles.
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
?Information about protection against explosions and fires: No special measures required.
?Storage:
?Requirements to be met by storerooms and receptacles: No special requirements.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions: Keep receptacle tightly sealed.
8 Exposure controls and personal protection
?Additional information about design of technical systems: No further data; see item 7.
?Components with limit values that require monitoring at the workplace:
75-09-2 dichloromethane
EL () 25 ppm
IARC 2B
EV () 175 mg/m? 50 ppm
534-52-1 DNOC
EL () 0.2 mg/m?br>
Skin
EV () 0.2 mg/m?br>
Skin
95-48-7 o-cresol
EL () 10 mg/m?br>
Skin
106-44-5 p-cresol
EL () 10 mg/m?br>
Skin
87-86-5 pentachlorophenol
EL () 0.5 mg/m?br>
Skin
EV () 0.5 mg/m?br>
Skin
108-95-2 phenol
EL () 5 ppm
Skin
?Additional information: The lists that were valid during the creation were used as basis.
(Contd. on page 4)
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Material Safety Data Sheet
acc. to ISO 11014
Printing date 08/11/2009 Reviewed on 08/11/2009
Trade name: Mix- HICAL Acids Method 8270C
(Contd. of page 3)
?Personal protective equipment:
?General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
?Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
?Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance
of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
?Eye protection: Safety glasses
9 Physical and chemical properties
?General Information
Liquid
Form:
Colorless
Color:
Characteristic
Odor:
?Change in condition
Melting point/Melting range: -95.1癈
Boiling point/Boiling range: 40癈
Not applicable.
?Flash point:
605癈
?Ignition temperature:
Product is not selfigniting.
?Auto igniting:
Product does not present an explosion hazard.
?Danger of explosion:
?Explosion limits:
13 Vol %
Lower:
22 Vol %
Upper:
453 hPa
?Vapor pressure at 20癈:
1.33 g/cm?br>
?Density at 20癈:
?Solubility in / Miscibility with
20 g/l
Water at 20癈:
(Contd. on page 5)
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Material Safety Data Sheet
acc. to ISO 11014
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Trade name: Mix- HICAL Acids Method 8270C
(Contd. of page 4)
?Solvent content:
97.6 %
Organic solvents:
2.4 %
?Solids content:
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known.
?Dangerous products of decomposition: No dangerous decomposition products known.
* 11 Toxicological information
?Acute toxicity:
?LD/LC50 values that are relevant for classification:
75-09-2 dichloromethane
Oral LD50 1600 mg/kg (rat)
Inhalative LC50/4 h 88 mg/l (rat)
88-06-2 2,4,6-trichlorophenol
Oral LD50 820 mg/kg (rat)
534-52-1 DNOC
Oral LD50 10 mg/kg (rat)
Dermal LD50 1000 mg/kg (rabbit)
87-86-5 pentachlorophenol
Oral LD50 27 mg/kg (rat)
Dermal LD50 105 mg/kg (rat)
?Primary irritant effect:
?on the skin: No irritant effect.
?on the eye: No irritating effect.
?Sensitization: No sensitizing effects known.
?Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
12 Ecological information
?Ecotoxical effects:
?Remark: Harmful to fish
?General notes:
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Harmful to aquatic organisms
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Material Safety Data Sheet
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Printing date 08/11/2009 Reviewed on 08/11/2009
Trade name: Mix- HICAL Acids Method 8270C
(Contd. of page 5)
13 Disposal considerations
?Product:
?Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
?Uncleaned packagings:
?Recommendation: Disposal must be made according to official regulations.
* 14 Transport information
?DOT regulations:
6.1
?Hazard class:
UN1593
?Identification number:
III
?Packing group:
?Proper shipping name (technical name): DICHLOROMETHANE
6.1
?Label
?TDG (Transport dangerous goods):
6.1 Toxic substances
?TDG class:
60
?Danger code (Kemler):
1593
?UN-Number:
III
?Packaging group:
6.1
?Label:
1593 DICHLOROMETHANE, mixture
?Description of goods:
?Maritime transport IMDG:
6.1
?IMDG Class:
1593
?UN Number:
6.1
?Label
III
?Packaging group:
F-A,S-A
?EMS Number:
No
?Marine pollutant:
DICHLOROMETHANE
?Propper shipping name:
(Contd. on page 7)
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Material Safety Data Sheet
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Trade name: Mix- HICAL Acids Method 8270C
(Contd. of page 6)
?Air transport ICAO-TI and IATA-DGR:
6.1
?ICAO/IATA Class:
1593
?UN/ID Number:
6.1
?Label
III
?Packaging group:
DICHLOROMETHANE
?Proper shipping name:
15 Regulations
?Sara
?Section 355 (extremely hazardous substances):
534-52-1 DNOC
95-48-7 o-cresol
108-95-2 phenol
?Section 313 (Specific toxic chemical listings):
75-09-2 dichloromethane
95-95-4 2,4,5-trichlorophenol
88-06-2 2,4,6-trichlorophenol
120-83-2 2,4-dichlorophenol
105-67-9 2,4-xylenol
51-28-5 2,4-dinitrophenol
534-52-1 DNOC
100-02-7 4-nitrophenol
95-48-7 o-cresol
88-75-5 2-nitrophenol
106-44-5 p-cresol
87-86-5 pentachlorophenol
108-95-2 phenol
?Proposition 65
?Chemicals known to cause cancer:
75-09-2 dichloromethane
88-06-2 2,4,6-trichlorophenol
87-86-5 pentachlorophenol
?Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
?Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
?Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
(Contd. on page 8)
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Material Safety Data Sheet
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Trade name: Mix- HICAL Acids Method 8270C
(Contd. of page 7)
?Cancerogenity categories
?EPA (Environmental Protection Agency)
75-09-2 dichloromethane B2
88-06-2 2,4,6-trichlorophenol B2
95-48-7 o-cresol C
87-86-5 pentachlorophenol B2
108-95-2 phenol I
?IARC (International Agency for Research on Cancer)
75-09-2 dichloromethane 2B
120-83-2 2,4-dichlorophenol 2B
87-86-5 pentachlorophenol 2B
108-95-2 phenol 3
?NTP (National Toxicology Program)
75-09-2 dichloromethane R
88-06-2 2,4,6-trichlorophenol R
?TLV (Threshold Limit Value established by ACGIH)
75-09-2 dichloromethane A3
87-86-5 pentachlorophenol A3
108-95-2 phenol A4
?NIOSH-Ca (National Institute for Occupational Safety and Health)
75-09-2 dichloromethane
?OSHA-Ca (Occupational Safety & Health Administration)
75-09-2 dichloromethane
?Canadian substance listings:
?Canadian Domestic Substances List (DSL)
75-09-2 dichloromethane
120-83-2 2,4-dichlorophenol
105-67-9 2,4-xylenol
51-28-5 2,4-dinitrophenol
95-57-8 2-chlorophenol
534-52-1 DNOC
100-02-7 4-nitrophenol
65-85-0 Benzoic acid
95-48-7 o-cresol
88-75-5 2-nitrophenol
106-44-5 p-cresol
87-86-5 pentachlorophenol
108-95-2 phenol
?Canadian Ingredient Disclosure list (limit 0.1%)
75-09-2 dichloromethane
51-28-5 2,4-dinitrophenol
(Contd. on page 9)
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Material Safety Data Sheet
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Printing date 08/11/2009 Reviewed on 08/11/2009
Trade name: Mix- HICAL Acids Method 8270C
(Contd. of page 8)
?Canadian Ingredient Disclosure list (limit 1%)
None of the ingredients is listed.
?Product related hazard informations:
The product has been classified and marked in accordance with directives on hazardous materials.
?Hazard symbols:
Harmful
?Hazard-determining components of labelling:
dichloromethane
DNOC
pentachlorophenol
?Risk phrases:
Harmful by inhalation, in contact with skin and if swallowed.
Limited evidence of a carcinogenic effect.
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
?Safety phrases:
Keep in a cool place.
Keep container in a well-ventilated place.
Wear suitable protective clothing and gloves.
Avoid release to the environment. Refer to special instructions/safety data sheets.
16 Other information
Disclaimer
The information provided in this Material Safety Data Sheet is based on our present knowledge,
and believed to be correct at the date of publication. However, no representation is made
concerning its accuracy and completeness. It is intended as guidance only, and is not to be
considered a warranty or quality specification. All materials may present unknown hazards, and
should be used with caution. Although certain hazards are described, we cannot guarantee that
these are the only hazards which exist. PerkinElmer Life and Analytical Sciences shall not be held
liable for any damage resulting from handling or from contact with the product.
?Department issuing MSDS: Safety and Health
?Contact:
With in the USA: 1-(800)-762-4000
Out side the USA: 1-(203)-712-8488
?* Data compared to the previous version altered.
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