SIL-ACT?Ep-700 D Part B
(Hardener)
Version 4.0
Material Safety Data Sheet Effective Date 06/30/2008
According to OSHA Hazard Communication Standard,
29 CFR 1910.1200
1. MATERIAL AND COMPANY IDENTIFICATION
SIL-ACT?Ep-700 D Part B
Material Name
Uses Epoxy curing agent
Company Advanced Chemical Technologies, Inc.
100 West Wilshire Blvd., Suite C-1
Oklahoma City, Oklahoma 73116
MSDS Request 1-800-535-0433 www.advchemtech.com
Emergency Telephone Number
ChemTel, Inc. 1-800-255-3924
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical CAS No. Concentration
Solvent Naphtha (Petroleum), 64742-95-6 40-55 %W
Light Aromatic *
TETA, reaction products with 32610-77-8 15-20% W
phenol/formaldehyde
Triethylenetetramine 112-24-3 <6 % W
Phenol 108-95-2 <6% W
Nonylphenol 84852-15-3 10-20 %W
*Contains Xylene (Mixed Isomers), CAS # 1330-20-7; Trimethylbenzene (all isomers), CAS# 25551-13-7;
Cumene, CAS# 98-82-8
3. HAZARDS IDENTIFICATION
Warning Statement
DANGER! CORROSIVE ?CAUSES EYE AND SKIN BURNS
HARMFUL IF ABSORBED THROUGH SKIN
MODERATE SKIN IRRITANT
MAY CAUSE SKIN SENSITIZATION BY SKIN CONTACT
USE WITH ADEQUATE VENTILATION
CAUSES SEVERE RESPIRATORY TRACT IRRITATION AND CAN
CAUSE DAMAGE
ASPIRATION HAZARD IF SWALLOWED ?CAN ENTER LUNGS AND
CAUSE DAMAGE
HARMFUL OR FATAL IF SWALLOWED
COMBUSTIBLE LIQUID AND VAPOR. KEEP AWAY FROM HEAT AND
FLAME. Vapors are heavier than air. Vapors may travel across the ground
and reach remote ignition sources causing a flashback fire danger.
Emergency Overview
Appearance and Odor Colorless to light yellow.
Liquid.
Amine mixed with aromatic hydrocarbon
SIL-ACT?Ep-700 D Part B
(Hardener)
Version 4.0
Material Safety Data Sheet Effective Date 06/30/2008
According to OSHA Hazard Communication Standard,
29 CFR 1910.1200
Health Hazards
Inhalation Irritating to respiratory system. Vapors may cause drowsiness and dizziness.
Vapor or mist, especially as generated from heating the material or from
exposure in poorly ventilated areas or confined spaces, are irritating and
cause nasal discharge, coughing, and discomfort in nose and throat.
Prolonged or repeated overexposure may result in lung damage.
Skin Contact Causes severe irritation with pain, severe excess redness and swelling with
chemical burns, blister formation, and possible tissue destruction.
Eye Contact Eye contact causes severe irritation, experienced as pain, with excess
blinking and tear production, and seen as extreme redness and swelling of
the eye and chemical burns of the eye. Severe eye damage may cause
blindness.
Ingestion Harmful may cause lung damage if swallowed. Causes burning of mouth,
throat, and stomach with abdominal and chest pain, nausea, vomiting,
disrrhea, thirst, weakness, and collapse. Aspiration may occur during
swallowing or vomiting, resulting in lung damage.
Other Information Possibility of organ or organ system damage from prolonged exposure; see
Section 11 for details. Target organ(s):
Auditory system
Cardiovascular system
Central nervous system (CNS)
Signs and Symptoms Respiratory irritation signs and symptoms may include a temporary burning
sensation of the nose and throat, coughing, and/or difficulty breathing.
Breathing of high vapor concentrations may cause central nervous system
(CNS) depression resulting in dizziness, light-headedness, headache,
nausea and loss of coordination. Continued inhalation may result in
unconsciousness and death. If material enters lungs, signs and symptoms
may include coughing, choking, wheezing, difficulty in breathing, chest
congestion, shortness of breath, and/or fever. Defatting dermatitis signs and
symptoms may include a burning sensation and/or a dried/cracked
appearance.
Auditory system effects may include temporary hearing loss and/or ringing in
the ears.
Aggravated Medical Pre-existing medical conditions of the following organ(s) or organ system(s)
Condition may be aggravated by exposure to this material: Liver disorders (such as
jaundice or liver enlargement). Kidney disorders (such as edema, or
proteinuria). Asthma. Adverse respiratory effects (such as cough, Tightness
of chest or shortness of breath). Skin disorders and allergies. Adverse skin
effects (such as rash, irritation, or corrosion). Adverse eye effects( such as
conjunctivitis or corneal damage). Eye disease
Environmental Hazards Toxic to aquatic organisms. May cause long-term adverse effects in the
aquatic environment.
4. FIRST AID MEASURES
General Information Get immediate medical attention. Contact a poison control center.
Inhalation Move to fresh air. If rapid recovery does not occur, transport to nearest
medical facility for additional treatment. If the heart is stopped, trained
personnel should begin cardiopulmonary resuscitation immediately.
Skin Contact Remove contaminated clothing and shoes. Flush exposed area with water
for at least 15 minutes and follow by washing with soap if available. Do not
attempt to neutralize with chemical agents. Discard or decontaminate
MSDS SIL-ACT?Ep-700 D Part B
(Hardener)
Version 4.0
Effective Date 06/30/2008
clothing and shoes prior to reuse.
Eye Contact Flush eyes with water for at least 15 minutes while holding eyelids open.
Rest eyes for 30 minutes. If redness, burning, blurred vision, or swelling
persists, transport to the nearest medical facility for additional treatment.
Ingestion If swallowed, do not induce vomiting, transport to nearest medical facility for
additional treatment. If vomiting occurs spontaneously, keep head below
hips to prevent aspiration.
5. FIRE FIGHTING MEASURES
Clear fire area of all non-emergency personnel.
Flash point 38 - 47.22 ?/ 100 - 117.00 ?(TCC)
C F
Specific Hazards Carbon monoxide may be evolved if incomplete combustion occurs. The
solvent will float and can be reignited on surface water. The vapor is heavier
than air, spreads along the ground and distant ignition is possible. Nitrogen
oxides will form. Ammonia may form.
Extinguishing Media Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or
earth may be used for small fires only. Do not discharge extinguishing
waters into the aquatic environment.
Unsuitable Extinguishing Do not use water in a jet.
Media
Protective Equipment for Wear full protective clothing and self-contained breathing apparatus.
Firefighters
Additional Advice Keep adjacent containers cool by spraying with water. Approach fire from
upwind to avoid hazardous vapors and toxic decomposition products.
6. ACCIDENTAL RELEASE MEASURES
Observe all relevant local and international regulations. Ventilate area. Avoid breathing vapor.
Protective measures Avoid contact with spilled or released material. Immediately remove all
contaminated clothing. Shut off leaks, if possible without personal risks.
Remove all possible sources of ignition in the surrounding area. Use
appropriate containment to avoid environmental contamination. Prevent from
spreading or entering drains, ditches or rivers by using sand, earth, or other
appropriate barriers. Attempt to disperse the vapor or to direct its flow to a
safe location for example by using fog sprays. Take precautionary measures
against static discharge. Ensure electrical continuity by bonding and
grounding (earthing) all equipment. Monitor area with combustible gas
indicator.
Clean Up Methods For small liquid spills (< 1 drum), transfer by mechanical means to a labeled,
sealable container for product recovery or safe disposal. Allow residues to
evaporate or soak up with an appropriate absorbent material and dispose of
safely. Remove contaminated soil and dispose of safely.
For large liquid spills (> 1 drum), transfer by mechanical means such as
vacuum truck to a salvage tank for recovery or safe disposal. Do not flush
away residues with water. Retain as contaminated waste. Allow residues to
evaporate or soak up with an appropriate absorbent material and dispose of
safely. Remove contaminated soil and dispose of safely.
Additional Advice See Section 13 for information on disposal. Notify authorities if any exposure
to the general public or the environment occurs or is likely to occur. U.S.
regulations may require reporting releases of this material to the
environment which exceed the reportable quantity (refer to Section 15) to
the National Response Center at (800) 424-8802. Under Section 311 of the
Clean Water Act (CWA) this material is considered an oil. As such, spills
MSDS SIL-ACT?Ep-700 D Part B
(Hardener)
Version 4.0
Effective Date 06/30/2008
into surface waters must be reported to the National Response Center (US
Coast Guard) at (800) 424-8802. This material is covered by EPA's
Comprehensive Environmental Response, Compensation and Liability Act
(CERCLA) Petroleum Exclusion. Therefore, releases to the environment
may not be reportable under CERCLA.
7. HANDLING AND STORAGE
General Precautions Avoid breathing of or contact with material. Only use in well ventilated areas.
Wash thoroughly after handling.
Handling Extinguish any naked flames. Do Not smoke. Remove ignition sources.
Avoid sparks. Avoid contact with skin, eyes, and clothing. Electrostatic
charges may be generated during pumping. Electrostatic discharge may
cause fire. Ensure electrical continuity by bonding and grounding (earthing)
all equipment. Restrict line velocity during pumping in order to avoid
generation of electrostatic discharge ( 1 m/sec until fill pipe submerged to
twice its diameter, then 7 m/sec). Avoid splash filling. Do NOT use
compressed air for filling, discharging, or handling operations. Do NOT use
sodium nitrite or other nitrosating agents with this product.
Storage Must be stored in a diked well- ventilated area, away from sunlight, ignition
sources and other sources of heat. Bulk storage tanks should be diked.
Keep away from aerosols, flammables, oxidizing agents, corrosives and
from other flammable products which are not harmful or toxic to man or to
the environment. Storage Temperature: Ambient.
Product Transfer Keep containers closed when not in use. Do not use compressed air for
filling, discharging or handling.
Recommended Materials For containers, or container linings use mild steel, stainless steel. For
container paints, use epoxy paint, zinc silicate paint.
Unsuitable Materials Avoid prolonged contact with natural, butyl or nitrile rubbers.
Container Advice Containers, even those that have been emptied, can contain explosive
vapors. Do not cut, drill, grind, weld or perform similar operations on or near
containers.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
OSHA Regulations 29CFR1910.1000 and 29CFR1926.55 provide exposure regulated levels.
3
Trimethyl benzene TWA 25 ppm (125 mg/m )
3 3
Xylenes TWA 100 ppm (435 mg/m ); STEL 150 ppm (655 mg/m )
3
Cumene TWA 50 ppm (245 mg/m )
The ACGIH recommends the following threshold levels.
3
Trimethyl benzene TWA 25 ppm (123 mg/m )
3 3
Xylenes TWA 100 ppm (434 mg/m ); STEL 150 ppm (651 mg/m ) with an A4
designation
3
Cumene TWA 50 ppm (246 mg/m )
3
The solvent manufacturer recommends a TWA of 19 ppm (100 mg/m )
3
Phenol TWA: ACGIH 5 ppm; REL: NIOSH 5 ppm (19 mg/m ); Ceiling Limit
3
Value and Time Period (if specified): NIOSH 15.6 ppm (60 mg/m );
3
PEL, TWA OSHA Z1 5 ppm (19 mg/m ); PEL, TWA US CA OEL 5 ppm
3
(19 mg/m );
3
Triethylenetetramine TWA: WEEL 1 ppm (6 mg/m )
MSDS SIL-ACT?Ep-700 D Part B
(Hardener)
Version 4.0
Effective Date 06/30/2008
Exposure Controls The level of protection and types of controls necessary will vary depending
upon potential exposure conditions. Select controls based on a risk
assessment of local circumstances. Appropriate measures include:
Adequate explosion-proof ventilation to control airborne concentrations
below the exposure guidelines/limits. Eye washes and showers for
emergency use. Wash hands before eating, drinking, smoking and using the
toilet.
Personal Protective Personal protective equipment (PPE) should meet recommended national
Equipment standards. Check with PPE suppliers.
Respiratory Protection If engineering controls do not maintain airborne concentrations to a level
which is adequate to protect worker health, select respiratory protection
equipment suitable for the specific conditions of use and meeting relevant
legislation. Check with respiratory protective equipment suppliers. Where air-
filtering respirators are suitable, select an appropriate combination of mask
and filter. Select a filter suitable for organic amines and for aromatic solvent
vapors [boiling point >65 ?(149 ?meeting EN141. Where air-filtering
C F)]
respirators are unsuitable (e.g., airborne concentrations are high, risk of
oxygen deficiency, confined space) use appropriate positive pressure
breathing apparatus.
Hand Protection Longer term protection: Nitrile rubber gloves Incidental contact/Splash
protection: PVC or neoprene rubber gloves.
Eye Protection Chemical splash goggles (chemical goggles).
Protective Clothing Use protective clothing that is chemical resistant to this material. Safety
shoes and boots should also be chemical resistant.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Colorless to light yellow.
Odor Amine mixed with aromatic odor.
Boiling point Greater than 148 - 182 ?/ 298 - 360 ?br>
C F
Flash point Of combustible component 38 - 47.22 ?/ 100 - 117.00 ?(IP 170)
C F
Vapor Density (Air = 1) >1
pH basic
Vapor pressure 1 mm Hg at 20 ?/ 68 ?br>
C F
Specific gravity 0.92 at 20 ?/ 68 ?br>
C F
Density Typical 920 g/L 20 ?/ 68 ?br>
C
Water solubility Insoluble
Volatile organic carbon content 40-55 %W
Evaporation rate (nBuAc=1) < 1.0 (ASTM D 3539, n-BuAc=1)
10. STABILITY AND REACTIVITY
Stability Stable under normal conditions of use.
Conditions to Avoid Avoid heat, sparks, open flames and other ignition sources. Do not formulate
with nitrites.
Materials to Avoid Strong oxidizing agents, strong acids or bases in bulk. Avoid contact with
acrylates, aldehydes, atmospheric moisture, halogenated organics, ketones.
Hazardous Thermal decomposition is highly dependent on conditions. A complex
Decomposition Products mixture including ammonia, carbon monoxide, carbon dioxide, nitrogen
oxides, aldehydes, ketones, and other organic compounds will be evolved
when this material undergoes combustion or thermal or oxidative
degradation.
Hazardous No
Polymerization
MSDS SIL-ACT?Ep-700 D Part B
(Hardener)
Version 4.0
Effective Date 06/30/2008
11. TOXICOLOGICAL INFORMATION
Basis for Assessment Information given is based on product testing, and/or similar products, and/or
components.
Acute Oral Toxicity Low toxicity: LD50 580 mg/kg , Rat; moderately toxic
Aspiration into the lungs may cause chemical pneumonitis which can be fatal.
Acute Dermal Toxicity Low toxicity: LD50 500 mg/kg Rabbit; moderately toxic
Acute Inhalation Toxicity Low toxicity: LC50 greater than near-saturated vapor concentration. / 1
hours, Rat
High concentrations may cause central nervous system depression resulting
in headaches, dizziness and nausea; continued inhalation may result in
unconsciousness and/or death.
Skin Irritation Corrosive
Eye Irritation Severe Eye irritation
Respiratory Irritation Repeated inhalation of vapors and mists is expected to cause irritation of the
respiratory tract. May cause lung damage.
Sensitization May cause sensitization by skin contact.
Repeated Dose Toxicity Auditory system: prolonged and repeated exposures to high concentrations
have resulted in hearing loss in rats. Solvent abuse and noise interaction in
the work environment may cause hearing loss. Central nervous system:
repeated exposure affects the nervous system. Cardiovascular system:
chronic abuse of similar materials has been associated with irregular heart
rhythms and cardiac arrest. Can cause damage to the kidneys, liver,
pancreas and spleen; and edema of the lungs.
Material Carcinogenicity Classification
Xylene, Mixed Isomers ACGIH Group A4: Not classifiable as a human carcinogen.
Xylene, Mixed Isomers IARC 3: Classification not possible from current data.
Phenol IARC 3: Classification not possible from current data.
Phenol NTP: No evidence
Phenol ACGIH: Group A4: Not classifiable as a human carcinogen
Reproductive and Causes foetotoxicity in animals at doses which are maternally toxic.
Developmental Toxicity
12. ECOLOGICAL INFORMATION
Acute Toxicity Extremely toxic
Fish Toxic: 1 < LC/EC/IC50 <= 1.5 mg/L
Aquatic Invertebrates Toxic: 1 < LC/EC/IC50 <= 4 mg/L
Algae Toxic: 1 < LC/EC/IC50 <= 10 mg/L
Mobility Adsorbs to soil and has low mobility.
Partially floats on water.
Persistence/degradability Unknown for mixture
Bioaccumulation Has the potential to bioaccumulate.
13. DISPOSAL CONSIDERATIONS
Material Disposal Recover or recycle if possible. It is the responsibility of the waste generator
to determine the toxicity and physical properties of the material generated to
determine the proper waste classification and disposal methods in
compliance with applicable regulations.
Container Disposal Drain container thoroughly. After draining, vent in a safe place away from
MSDS SIL-ACT?Ep-700 D Part B
(Hardener)
Version 4.0
Effective Date 06/30/2008
sparks and fire. Residues may cause an explosion hazard. Do not puncture,
cut or weld uncleaned drums. Send to drum recycler or metal reclaimer.
Local Legislation Disposal should be in accordance with applicable regional, national, and local
laws and regulations. Local regulations may be more stringent than regional
or national requirements and must be complied with.
14. TRANSPORT INFORMATION
US Department of Transportation Classification (49CFR)
Identification number UN 1760
Proper shipping name Corrosive Liquid, n.o.s. (nonylphenol)
Class / Division 8
Packing group III
Label 8 (Corrosive)
IIMDG
Identification number UN 2920
Proper shipping name Corrosive Liquid, Flammable, n.o.s. (nonylphenol)
Class / Division 8
Packing group II
Marine pollutant Yes
Label 8+3 (Corrosive + Flammable)
IATA (Country variations may apply)
Identification number UN 2920
Proper shipping name Corrosive Liquid, Flammable, n.o.s. (nonylphenol)
Class / Division 8
Packing group II
Label 8+3 (Corrosive + Flammable)
15. REGULATORY INFORMATION
The regulatory information is not intended to be comprehensive. Other regulations may apply to this
material.
Part A. Federal Regulatory Status
Notification Status
Solvent Naphtha (Petroleum), Light Aromatic (64742-95-6)
Notification Status Legend
DSL Listed
TSCA Listed Substances; DSL = Canadian Domestic
EINECS Listed 265-199-0 Substances List. TSCA = Toxic Substance
WHMIS Listed B3 Control Act; EINECS = European Inventory
of New and Existing Chemicals; WHMIS =
Canadian Workplace Hazardous Materials
Information System
TETA, reaction products with phenol/formaldehyde (64742-95-6)
Notification status Legend
DSL Listed
TSCA Listed See above
MSDS SIL-ACT?Ep-700 D Part B
(Hardener)
Version 4.0
Effective Date 06/30/2008
EINECS Listed Included on
inventory or
polymer
substance,
monomers
included on
inventory or no
longer polymer
WHMIS Listed
Nonylphenol (84852-15-3)
Notification status Legend
DSL Listed
TSCA Listed See above
EINECS Listed 284-325-5
WHMIS Listed Class D: Div 2,
Subdiv B; Irritant
Class E:
Corrosive
Triethylenetetramine (112-24-3)
Notification status Legend
DSL Listed
TSCA Listed See above
EINECS Listed 203-950-6, Xi
WHMIS Listed D1B Toxic, D2B
Toxic, E
Corrosive
Phenol (108-95-2)
Notification status Legend
DSL Listed
TSCA Listed See above
EINECS Listed 203-632-7, C; Xn
WHMIS Listed B3 Combustible;
D1A VeryToxic,
E Corrosive
Comprehensive Environmental Release, Compensation & Liability Act (CERCLA)
Solvent Naphtha (Petroleum), Light Aromatic Reportable Quantity 3,333 lbs
(64742-95-6)*
Cumene (98-82-8) Reportable quantity: 5,000 lbs
Xylene, Mixed Isomers (1330-20-7) Reportable quantity: 100 lbs
Toluene (108-88-3) Reportable quantity: 1,000 lbs
Benzene (71-43-2) Reportable quantity: 10 lbs
Phenol (108-95-2) Reportable quantity: 1,000 lbs
*Material supplier classifies the solvent as an"oil" under the CERCLA Petroleum Exclusion, therefore
releases to the environment are not reportable under CERCLA. The components with RQs are given
for information.
SARA Extremely Hazardous Substances (302/304)
Phenol (108-95-2) Reportable quantity: 10,000/1,000 lbs
Clean Water Act (CWA) Section 311
Xylene, Mixed Isomers (1330-20-7) Reportable quantity: 100 lbs
Toluene (108-88-3) Reportable quantity: 1,000 lbs
MSDS SIL-ACT?Ep-700 D Part B
(Hardener)
Version 4.0
Effective Date 06/30/2008
Benzene (7143-2) Reportable quantity: 10 lbs
Under Section 311 of the Clean Water Act (CWA) this material is considered an oil. As such, spills
into surface waters must be reported to the National Response Center at (800) 424-8802.The
components with RQs are given for information.
SARA Hazard Categories (311/312)
Immediate (Acute) Health Hazard, Chronic Health Hazard, Fire Hazard
SARA Toxic Release Inventory (TRI) (313)
1,2,4-Trimethyl benzene (95-63-6) 22.50%
Cumene (98-82-8) 3.00%
Xylene, Mixed Isomers (1330-20-7) 1.50%
Toluene (108-88-3) 0.013%
Benzene (71-43-2) 0.0035%
Phenol (108-95-2) Reportable
Part B. State Regulatory Status
California Safe Drinking Water and Toxic Enforcement Act (Proposition 65)
Known to the State of California to cause birth defects or other reproductive harm.
Known to the state of California to cause cancer.
Toluene (108-88-3) 0.013% Developmental toxin.
Benzene (71-43-2) 0.003% Carcinogenic.
Developmental toxin.
Male reproductive toxin.
New Jersey Right-To-Know Chemical List
1,2,4-Trimethyl benzene (95-63-6) 22.50% Listed
1,3,5-Trimethyl benzene (108-67-8) 6.00% Listed.
Cumene (98-82-8) 3.00% Listed
1,2,3-Trimethyl benzene (526-73-8) 2.00% Listed.
Xylene, Mixed Isomers (1330-20-7) 1.5% Listed
Toluene (108-88-3) 0.013% Listed
Benzene (71-43-2) 0.003% Listed
TETA, reaction products with phenol/formaldehyde (32610-77-8) Not listed
Triethylenetetramine (112-24-3) Listed
Phenol (108-95-2) Listed
Nonylphenol (84852-15-3) Not Listed
Pennsylvania Right-To-Know Chemical List
1,2,4-Trimethyl benzene (95-63-6) 22.50% Environmental hazard.
Listed.
1,3,5-Trimethyl benzene (108-67-8) 6.00% Listed.
Cumene (98-82-8) 6.00% Environmental hazard.
Listed.
1,2,3-Trimethyl benzene (526-73-8) 2.00% Listed.
Xylene, Mixed Isomers (1330-20-7) 1.50% Environmental hazard.
Listed.
Toluene (108-88-3) 0.013% Environmental hazard.
Listed.
Benzene (71-43-2) 0.003% Special hazard.
MSDS SIL-ACT?Ep-700 D Part B
(Hardener)
Version 4.0
Effective Date 06/30/2008
Environmental hazard.
Listed.
Nonylphenol (84852-15-3) 20-40% Not Listed
TETA, reaction products with phenol/formaldehyde (32610-77-8) Not Listed
Triethylenetetramine (112-24-3) Listed
Phenol (108-95-2) Listed
16. OTHER INFORMATION
HMIS Rating (Health, Fire, 3, 2, 0
Reactivity)
NFPA Rating (Health, Fire, 3, 2, 0
Reactivity)
Disclaimer The information contained herein is based on our current
knowledge of the underlying data and is intended to describe
the product for the purpose of health, safety and environmental
requirements only. No warranty or guarantee is expressed or
implied regarding the accuracy of these data or the results to
be obtained from the use of the product. The information is not
presented as a material specification.
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