MATERIAL SAFETY DATA SHEET
NSN-8010011319194 24052 GREEN GAL Page: 1
PAINT,3,UN1263,PGIII,LTD QTY
PRODUCT NAME: NSN-8010011319194 24052 GREEN GAL HMIS CODES: H F R P
PRODUCT CODE: G011319194 02 120
================== SECTION I - MANUFACTURER IDENTIFICATION =================
MANUFACTURER'S NAME: DAVIS PAINT COMPANY
ADDRESS : 1311 IRON STREET
P.O. BOX 7589
N. KANSAS CITY, MO 64116
EMERGENCY PHONE : (816)-471-4447 DATE PRINTED : 04/25/03
INFORMATION PHONE : (816)-471-4447 NAME OF PREPARER : Sandy Haskins
FOR EMERGENCIES INVOLVING A SPILL, LEAK, FIRE, EXPOSURE, OR ACCIDENT - CONTACT
CHEMTREC PHONE: (800)-424-9300
=============== SECTION II - INGREDIENTS/SARA III INFORMATION ==============
VAPOR PRESSURE
WEIGHT
REPORTABLE COMPONENTS CAS NUMBER mm Hg @ TEMP
PERCENT
--------------------------------------------------------------------------------
---------------------------------------------------------
CALCIUM CARBONATE (Total Dust) 1317-65-3 0 68 25% - 30%
OSHA TWA: 15 mg/m3, ACGIH TLV: 10 mg/m3, DAVIS(REC): 5 mg/m3
#140 NAPHTHA (Aliphatic Hydrocarbon) 64742-48-8.5 68 10% - 15%
OSHA TWA: N/A, ACGIH TLV: N/A, DAVIS(REC): 100 PPM
MINERAL SPIRITS (Stoddard Solvent) 8052-41-3 1.7 68 5% - 10%
OSHA TWA: 100 PPM, ACGIH TLV: 100 PPM, DAVIS(REC): 525 mg/m3
TALC [Silicates] (Respirable Dust) 14807-96-60 68 5% - 10%
OSHA TWA: 20 mppcf, ACGIH TLV: 2 mg/m3, DAVIS(REC): 2 mg/m3
*# ETHYLENE GLYCOL 107-21-1 .08 68 4.4
OSHA TWA: C50 PPM, ACGIH TLV: C50 PPM, DAVIS(REC): C100 mg/m3
IRON OXIDE YELLOW 51274-00-10 68 1% - 5%
OSHA TWA: 10 mg/m3, ACGIH TLV: 5 mg/m3, DAVIS(REC): 5 mg/m3
NONYL PHENOL ETHOXYLATE 9016-45-9 1% - 5%
TALC [Silicates] (Respirable Dust) 14807-96-60 68 1% - 5%
OSHA TWA: 20 mppcf, ACGIH TLV: 2 mg/m3, DAVIS(REC): 2 mg/m3
CARBON BLACK 1333-86-4 0 68 0.55
OSHA TWA: 3.5 mg/m3, ACGIH TLV: 3.5 mg/m3, DAVIS(REC): 3.5 mg/m3
* Indicates toxic chemical(s) subject to the reporting requirements of section
313 of Title III and of 40 CFR 372.
# Indicates chemical(s) is defined as a HAP's by the EPA, and subject to the
reporting requirements of Section 112 of the Clean Air Act.
This material contains ingredients covered by the California "Safe Drinking
Water and Toxic Enforcement Act of 1986".
=============== SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS ============
BOILING RANGE: 316 deg F - 387 deg F SPECIFIC GRAVITY (H2O=1): 1.27
VAPOR DENSITY: HEAVIER THAN AIR EVAPORATION RATE: SLOWER THAN ETHER
VOC EMISSION AS PACKAGED--INCLUDES WATER/EXEMPT SOLVENTS: 2.91 lb/gl, 348 g/l
VOC EMISSION AS REGULATED--EXCLUDES WATER/EXEMPT SOLVENTS: 2.91 lb/gl, 348 g/l
SOLUBILITY IN WATER: Negligible
APPEARANCE AND ODOR: Liquid, aliphatic odor
================= SECTION IV - FIRE AND EXPLOSION HAZARD DATA ==============
FLASH POINT (TCC): 103 deg F
FLAMMABLE LIMITS IN AIR BY VOLUME- LOWER: 1 UPPER: 15.3
EXTINGUISHING MEDIA: FOAM, CO2, DRY CHEMICAL
SPECIAL FIREFIGHTING PROCEDURES
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Full protective equipment and self contained breathing apparatus should be
used.Water spray may be ineffective. Water may be used to cool closed
containers to prevent pressure build-up and possible auto-ignition or explosion
from heating.
UNUSUAL FIRE AND EXPLOSION HAZARDS
Handle as an ignitable liquid. Keep containers tightly closed and isolate from
heat, electrical equipment, sparks or flame. Vapors form an explosive mixture
in air between the upper and lower explosive limits. Never use welding or
cutting torch on or near drum (even empty) because product (even just residue)
can ignite explosively. Avoid spontaneous combustion of soiled rags, steel
wool, spray booth filters, spray residues and other waste material contaminated
with this product by immediately immersing them in a sealed, water-filled metal
container prior to disposal.
======================== SECTION V - REACTIVITY DATA =======================
STABILITY: STABLE
CONDITIONS TO AVOID
Excessive heat, all possible sources of ignition, poor ventilation, corrosive
atmospheres, excessive aging.
INCOMPATIBILITY (MATERIALS TO AVOID)
Alkaline materials, strong acids and oxidizing materials. If this product is
not water reducible, avoid water.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS
Thermal decomposition or combustion can produce fumes containing organic acids,
carbon dioxide and carbon monoxide.
HAZARDOUS POLYMERIZATION:
Will not occur under normal conditions
==================== SECTION VI - HEALTH HAZARD DATA =======================
INHALATION HEALTH RISKS AND SYMPTOMS OF EXPOSURE
Solvent vapor or mist can cause dizziness, breathing difficulty, headaches,
irritation to nose and throat, loss of coordination. Continued over-exposure
can lead to central nervous system depression.
SKIN AND EYE CONTACT HEALTH RISKS AND SYMPTOMS OF EXPOSURE
Eye Contact: Liquid or vapor can cause irritation, tearing, discomfort, redness
and blurred vison. Skin Contact: Can cause irritation. Can cause defatting of
skin which can lead to dermatitus.
SKIN ABSORPTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE
Liquid can be absorbed through skin causing irritation, defatting and
dermatitus.
INGESTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE
Can cause mouth, throat, esophagus and stomach irritation, nausea, vomiting and
diarrhea.
HEALTH HAZARDS (ACUTE AND CHRONIC)
Reports have associated repeated or prolonged occupational overexposure to
solvents with permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents may be harmful or fatal.
CARCINOGENICITY: NTP CARCINOGEN: No IARC MONOGRAPHS: Yes OSHA REGULATED: No
This product contains carbon black which has been identified as possibly
carcinogenic to humans (IARC Group 2B - Based on sufficient evidence for
carcinogenicity in laboratory animal studies, but inadaquate evidence for cancer
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in exposed humans). Normal application procedures pose minimal hazard since the
carbon black is wet and encapsulated. Risk of cancer may be reduced by following
recommended vetilation/control practices, keeping below TWA and/or TLV values
listed in section 2.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
Preexisting eye, skin, liver, kidney and respiratory disorders.
EMERGENCY AND FIRST AID PROCEDURES
Inhalation- Move person to fresh air. If breathing stops, apply artificial
respiration and seek medical attention. Eye contact- Flush immediately with a
large amount of water for at least 15 minutes and get medical attention. Skin
contact- Wash thoroughly with soap and water while removing contaminated
clothing and shoes. Ingestion- Do not induce vomiting! Contact physician or
your local poison control center immediately.
=========== SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE ============
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Eliminate all sources of ignition (flames, hot surfaces, and electrical, static,
or frictional sparks). Avoid breathing vapors. Ventilate area. Contain and
remove with inert absorbent and non-sparking tools. Keep out of sewers.
WASTE DISPOSAL METHOD
Collect absorbent/spilled liquid into metal containers. Dispose of in
accordance with local, state and federal regulations. Do not incinerate closed
containers. Incinerate in approved facility. Obey relevent laws.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
Keep away from excessive heat, sparks or open flames. Keep containers closed
when not in use. Store in cool, well ventilated approved areas. Avoid free
fall of liquid in excess of a few inches and ground container when pouring. Use
non-sparking utensils when handling this material. Keep containers closed and
upright when not in use.
OTHER PRECAUTIONS
Do not take internally. Store large quantities in buildings designed to comply
with OSHA 1910.106. Emptied containers may retain hazardous residue and
explosive vapors. Keep away from heat, sparks and flames. Do not cut, puncture
or weld on or near emptied containers. Wash hands after using and before
smoking or eating. Follow all hazard precautions given in this data sheet until
container is thoroughly cleaned or destroyed. KEEP OUT OF THE REACH OF
CHILDREN. Avoid spontaneous combustion of soiled rags, steel wool, spray booth
filters, spray residues and other material contaminated with this product by
immediately immersing them in a sealed, water-filled metal container prior to
disposal.
===================== SECTION VIII - CONTROL MEASURES ======================
RESPIRATORY PROTECTION
Do not breathe vapors or spray mist. Wear an appropriate, properly fitted
respirator (NIOSH/MSHA approved) during the use of this product until vapor and
mists are exhausted, unless air monitoring demonstrates vapor and mist levels
are below applicable exposure limits. Observe OSHA Standard 29CFR 1910.134.
VENTILATION
Provide general clean air dilution or local exhaust ventilation in volume and
pattern to keep the air contaminant concentration below the lower explosion
limit and applicable exposure limits. Refer to OSHA Standard 29 CFR 1910.94.
PROTECTIVE GLOVES
Use chemical/solvent impermeable gloves to avoid contact with product.
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EYE PROTECTION
Avoid contact with eyes. Use safety eyewear with splash guards or side shields,
chemical goggles, face shields.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT
Provide eyewash station and emergency shower. Use of protective creams, head
caps, etc. is recommended. Avoid contact with contaminated clothing. Wash
contaminated clothing, including shoes, before reuse.
WORK/HYGIENIC PRACTICES
Wash hands before eating or using washroom, smoke in smoking areas only.
========================= SECTION IX - DISCLAIMER ==========================
To the best of our knowledge, the information contained herein is based on data
considered accurate. No warranty expressed or implied is made. Davis Paint
assumes no responsibility for damage to person, property or business caused by
the material. It is the responsibility of the purchaser or user of the material
to ensure that it is properly used.
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