MATERIAL SAFETY 3M
DATA SHEET 3M Center
St. Paul, Minnesota
55144-1000
1-800-364-3577 or (651) 737-6501 (24 hours)
Copyright, 2001, Minnesota Mining and Manufacturing Company.
All rights reserved. Copying and/or downloading of this
information for the purpose of properly utilizing 3M products
is allowed provided that:
1) the information is copied in full with no changes unless
prior agreement is obtained from 3M, and
2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.
DIVISION: SPECIFIED CONSTRUCTION PRODUCTS
TRADE NAME:
3M FIREDAM 150+ CAULK
ID NUMBER/U.P.C.:
98-0400-5315-3 00-51115-11574-5 98-0400-5316-1 00-51115-11575-7
98-0400-5343-5 00-51115-11602-5 98-0400-5375-7 00-51115-11634-6
98-0400-5419-3 00-51115-16528-8 98-0400-5420-1 00-51115-16529-0
ISSUED: May 15, 2001
SUPERSEDES: April 07, 2000
DOCUMENT: 09-2236-9
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1. INGREDIENT C.A.S. NO. PERCENT
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CALCIUM CARBONATE....................... 1317-65-3 50.0
VINYL ACETATE EMULSION.................. Unknown 15.0 - 20.0
WATER................................... 7732-18-5 5.0 - 15.0
MEDIUM ALIPHATIC SOLVENT NAPHTHA........ 64742-88-7 5.0 - 10.0
DIBENZOATE PROPANOL..................... 27138-31-4 2.0 - 4.0
TITANIUM DIOXIDE........................ 13463-67-7 1.0 - 3.0
ETHYLENE GLYCOL......................... 107-21-1 1.0 - 3.0
IN CASE OF EMERGENCY: THE NUMBERS AT THE TOP OF THIS PAGE PROVIDE 24
HOUR RESPONSE FROM ANY PHONE FOR ALL EMERGENCIES WITH THIS PRODUCT.
Non hazardous according to WHMIS criteria. The components of this
product are in compliance with the chemical notification requirements
of TSCA.
This product contains the following toxic chemical or chemicals subject to
the reporting requirements of Section 313 of Title III of the Emergency
Planning and Community Right-To-Know Act of 1986 and 40 CFR Part 372:
ETHYLENE GLYCOL
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2. PHYSICAL DATA
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BOILING POINT:................. 212.0 F
(100 C)
VAPOR PRESSURE:................ N/D
VAPOR DENSITY:................. LIGHTER THAN AIR
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M FIREDAM 150+ CAULK
May 15, 2001 PAGE 2
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2. PHYSICAL DATA (continued)
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EVAPORATION RATE:.............. < 1.0 BuOAc=1
SOLUBILITY IN WATER:........... MISCIBLE IN WET STAGE
SPECIFIC GRAVITY:.............. 1.5 Water=1
PERCENT VOLATILE:.............. 28 %
BY VOLUME
pH:............................ 8.0 - 9.0
VISCOSITY:..................... PASTE
MELTING POINT:................. N/D
APPEARANCE AND ODOR:
PASTE WITH LOW ODOR.
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3. FIRE AND EXPLOSION HAZARD DATA
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FLASH POINT:................... N/A
FLAMMABLE LIMITS - LEL:........ N/A
FLAMMABLE LIMITS - UEL:........ N/A
AUTOIGNITION TEMPERATURE:...... N/A
EXTINGUISHING MEDIA:
Water spray, Carbon dioxide, Dry chemical, Foam
SPECIAL FIRE FIGHTING PROCEDURES:
Wear full protective clothing, including helmet, self-contained,
positive pressure or pressure demand breathing apparatus, bunker coat
and pants, bands around arms, waist and legs, face mask, and
protective covering for exposed areas of the head.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Not applicable.
PRODUCT WILL NOT BURN BUT MAY SPLATTER IF TEMPERATURE EXCEEDS BOILING
POINT OF WATER. DRIED SOLIDS CAN BURN, GIVING OFF OXIDES OF CARBON.
NFPA HAZARD CODES: HEALTH: 1 FIRE: 0 REACTIVITY: 0
UNUSUAL REACTION HAZARD: none
OSHA FIRE HAZARD CLASS: Not applicable
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4. REACTIVITY DATA
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STABILITY: Stable
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M FIREDAM 150+ CAULK
May 15, 2001 PAGE 3
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4. REACTIVITY DATA (continued)
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INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID:
Strong Oxidizing Agents.
HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur.
HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide and Carbon Dioxide.
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5. ENVIRONMENTAL INFORMATION
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SPILL RESPONSE:
Observe precautions from other sections. Ventilate area. Contain
spill. Cover with inorganic absorbent material. Collect spilled
material. Clean up residue with an appropriate organic solvent. Read
and follow safety precautions on the solvent label and MSDS. Place
in a closed container.
RECOMMENDED DISPOSAL:
Incinerate in an industrial or commercial facility in the presence of
a combustible material. Disposal alternative: Dispose of waste
product in a facility permitted to accept chemical waste.
ENVIRONMENTAL DATA:
Not determined.
REGULATORY INFORMATION:
Volatile Organic Compounds: N/D.
VOC Less H2O & Exempt Solvents: N/D.
Since regulations vary, consult applicable regulations or authorities
before disposal. In the event of an uncontrolled release of this
material, the user should determine if the release qualifies as a
reportable quantity. U.S. EPA Hazardous Waste Number = None (Not
U.S. EPA Hazardous).
EPCRA HAZARD CLASS:
FIRE HAZARD: No PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: No
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6. SUGGESTED FIRST AID
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EYE CONTACT:
Immediately flush eyes with large amounts of water. Get immediate
medical attention.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M FIREDAM 150+ CAULK
May 15, 2001 PAGE 4
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6. SUGGESTED FIRST AID (continued)
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SKIN CONTACT:
Flush skin with large amounts of water. If irritation persists, get
medical attention.
INHALATION:
If signs/symptoms occur, remove person to fresh air. If
signs/symptoms continue, call a physician.
IF SWALLOWED:
Do not induce vomiting. Drink two glasses of water. Call a physician.
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7. PRECAUTIONARY INFORMATION
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EYE PROTECTION:
Avoid eye contact. Wear unvented goggles during operations in which
exposure is likely.
SKIN PROTECTION:
Avoid skin contact. Wear appropriate gloves when handling this
material. A pair of gloves made from the following material(s) are
recommended: butyl rubber, neoprene, fluoroelastomer (Viton).
RECOMMENDED VENTILATION:
Use with appropriate local exhaust ventilation. Use in a well-
ventilated area. Use with adequate dilution ventilation. If exhaust
ventilation is not adequate, use appropriate respiratory protection.
RESPIRATORY PROTECTION:
Avoid breathing of vapors. Select one of the following NIOSH
approved respirators based on airborne concentration of contaminants
and in accordance with OSHA regulations: half-mask organic vapor
respirator, full-face organic vapor respirator.
PREVENTION OF ACCIDENTAL INGESTION:
Do not eat, drink or smoke when using this product. Wash exposed
areas thoroughly with soap and water. Wash hands after handling and
before eating. Do not ingest.
RECOMMENDED STORAGE:
Store in a cool place. Store away from acids. Store away from heat.
Keep container dry. Keep container in well-ventilated area. Keep
out of the reach of children.
FIRE AND EXPLOSION AVOIDANCE:
Keep container tightly closed. Keep away from heat, sparks, open
flame, and other sources of ignition. Prevent all sources of
ignition. No smoking while handling this material.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M FIREDAM 150+ CAULK
May 15, 2001 PAGE 5
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7. PRECAUTIONARY INFORMATION (continued)
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OTHER PRECAUTIONARY INFORMATION:
For industrial or professional use only.
EXPOSURE LIMITS
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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CALCIUM CARBONATE.................... 10 MG/M3 TWA ACGIH
CALCIUM CARBONATE.................... 15 MG/M3 TWA OSHA
AS TOTAL DUST
CALCIUM CARBONATE.................... 5 MG/M3 TWA OSHA
RESPIRABLE
VINYL ACETATE EMULSION............... NONE NONE NONE NONE
WATER................................ NONE NONE NONE NONE
MEDIUM ALIPHATIC SOLVENT NAPHTHA..... 100 PPM TWA CMRG
DIBENZOATE PROPANOL.................. NONE NONE NONE NONE
TITANIUM DIOXIDE..................... 10 MG/M3 TWA ACGIH
TITANIUM DIOXIDE..................... 10 MG/M3 TWA OSHAV
AS DUST
OSHA VACATED PEL
TITANIUM DIOXIDE..................... 15 MG/M3 TWA OSHA
AS TOTAL DUST
TITANIUM DIOXIDE..................... 5 MG/M3 TWA CMRG
AS RESPIRABLE DUST
ETHYLENE GLYCOL...................... 50 PPM CEIL OSHA
ETHYLENE GLYCOL...................... 100 MG/M3 CEIL ACGIH
AS AEROSOL
* SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to
the potential contribution to the overall exposure by the cutaneous route
including mucous membrane and eye, either by airborne or, more particularly,
by direct contact with the substance. Vehicles can alter skin absorption.
SOURCE OF EXPOSURE LIMIT DATA:
- ACGIH: American Conference of Governmental Industrial Hygienists
- CMRG: Chemical Manufacturer Recommended Exposure Guidelines
- OSHA: Occupational Safety and Health Administration
- OSHAV: Occupational Safety and Health Administration Vacated PEL.
Vacated Permissible Exposure Limits (PEL) are enforced as
the OSHA PEL in some states. Check with your local
regulatory authority.
- NONE: None Established
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M FIREDAM 150+ CAULK
May 15, 2001 PAGE 6
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8. HEALTH HAZARD DATA
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EYE CONTACT:
Mild Eye Irritation: signs/symptoms can include redness, swelling,
pain, and tearing.
SKIN CONTACT:
Mild Skin Irritation: signs/symptoms can include redness, swelling,
and itching.
INHALATION:
Prolonged or repeated overexposure, above recommended guidelines, may
cause:
Irritation (upper respiratory): signs/symptoms can include
soreness of the nose and throat, coughing and sneezing.
WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR MORE OF THE
INDIVIDUAL INGREDIENTS IN THIS PRODUCT AND ARE REQUIRED TO BE
INCLUDED ON THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD,
THEY ARE NOT EXPECTED EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT.
Prolonged or repeated overexposure, above recommended guidelines, may
cause:
Central Nervous System Depression: signs/symptoms can include
headache, dizziness, drowsiness, incoordination, slowed reaction
time, slurred speech, giddiness and unconsciousness.
IF SWALLOWED:
Ingestion may cause:
Irritation of Gastrointestinal Tissues: signs/symptoms can
include pain, vomiting, abdominal tenderness, nausea, blood in
vomitus, and blood in feces.
WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR MORE OF THE
INDIVIDUAL INGREDIENTS IN THIS PRODUCT AND ARE REQUIRED TO BE
INCLUDED ON THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD,
THEY ARE NOT EXPECTED EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT.
Ingestion may cause:
Central Nervous System Depression: signs/symptoms can include
headache, dizziness, drowsiness, muscular weakness,
incoordination, slowed reaction time, fatigue, blurred vision,
slurred speech, giddiness, tremors and convulsions.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M FIREDAM 150+ CAULK
May 15, 2001 PAGE 7
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SECTION CHANGE DATES
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HEADING SECTION CHANGED SINCE April 07, 2000 ISSUE
ENVIRONMENTAL INFO. SECTION CHANGED SINCE April 07, 2000 ISSUE
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
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The information in this Material Safety Data Sheet (MSDS) is believed to
be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR
IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF
PERFORMANCE OR USAGE OF TRADE. User is responsible for determining
whether the 3M product is fit for a particular purpose and suitable for
user's method of use or application. Given the variety of factors that
can affect the use and application of a 3M product, some of which are
uniquely within the user's knowledge and control, it is essential that
the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers.
Due to the remote possibility that electronic transfer may have resulted
in errors, omissions or alterations in this information, 3M makes no
representations as to its completeness or accuracy. In addition,
information obtained from a database may not be as current as the
information in the MSDS available directly from 3M.
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