MATERIAL SAFETY DATA SHEET
Oil ~ e - ~ e f i n i n g
CO.(ORRCO)
41 50 N Suttle Rd.
Portland. OR. 97217
Prediluted, Fully-Formulated, Heavy- Duty,
Precharged Coolant (50150)
ProducUChemical Name: KOOL GREEN
Product Description: Ethylene Glycol, Ethylene Glycol Solution, Prediluted, Fully-Formulated, Heavy Duty
Precharged Coolant (50150) with Dye
Chemical Family: Inhibited Ethylene Glycol and Water Solution
CAS Registry: Mixture
Manufacturer:
Nuset Industries, Inc.
977 South 700 West
Salt Lake City, UT. 84108
(801) 977-0220
INGREDIENT %
CAS No WT. RANGE EXPOSURE LIMIT
* I ,2-ethanediol (Ethylene Glycol) 107-21-1 48-51 % 50ppm Ceiling-ACGIH
-
Diethlyene glycol 11-46-6 0-3% None established
Proprietary Additives and Inhibitors Not applicable <2.5% Not applicable
Not applicable
Dye
Water 7732-1 8-5 Balance . Not applicable
I
*Hazardous according to OSHA (1910.1200) or one or more state Right-to-Know lists.
1
1
Health: 2
HMlS
Flammability: 0
Reactivity: 0
Special: None
0 = minimal I = slight 2=moderate 3= serious 4= severe
Route(s) of Entry
Inhalation: Yes
Skin: Yes
Ingestion: Yes
Eyes: Yes
Target Organs: Kidneys and Liver
Effects of overexposure:
Acute: Eyes: May cause minimal irritation, experienced as temporary discomfort.
MSDS: Prediluted, Fully-Formulated, Heavy Duty Precharged Coolant (50150)
- - - FOR DISCLAIMER OF LIABILITY SEE FINAL PAGE - - - Page 1 of 6
Brief contact is not irritating. Prolonged contact, as with clothing wetted
Effects of overexposure Skin:
with material may cause defatting of skin or irritation, seen as local
(con't)
redness with possible mild discomfort. Other than the potential skin
Acute:
irritation effects noted above, acute (short term) adverse effects are not
expected from brief skin contact.
Vapors or mist, in excess of permissible concentrations, or in unusually
Inhalation:
high concentrations generated from spraying, heating the material or as
from exposure in poorly ventilated areas or confined spaces, may cause
irritation of the nose and throat, headache, nausea, and.drowsiness.
Prolonged or repeated overexposure may result in the absorption of
potentially harmful amounts of material.
Contains ethylene glycol and/or diethylene glycol, which are toxic when
Ingestion:
swallowed. A lethal dose for an adult is 1-2 ml per kilogram, or about 4
ounces (one-half cup). Symptoms include headache, weakness,
confusion, dizziness, staggering, slurred speech, loss of concentration,
faintness, nausea and vomiting, increased heart rate, decreased blood
pressure, difficulty breathing and seeing, pulmonary edema,
unconsciousness, convulsions, collapse and coma. Symptoms may be
delayed. Decreased urine output and kidney failure may also occur.
Severe poisoning may cause death. Aspiration may occur during
swallowing or vomiting, resulting in lung damage.
Sensitization Properties: Unknown
Signs and Symptoms o f
Exposure: See above "Effects of Overexposure."
Medical Conditions Generally
Aggravated by Long-Term
Exposure: Repeated overexposure may aggravate existing kidney disease.
Chronic Effects: Repeated ingestion may cause kidney damage
Carcinogenicity
NTP: Not listed
IARC Monographs: Not listed
OSHA Regulations: Not listed
ACGlH Not listed
I First Aid Procedures: I
minutes and
Skin contact: Remove excess with cloth or paper towel. Wash thoroughly with
soap and water. If irritation persists, get medical attention.
Ingestion: Immediately contact a physician, poison control center or
emergency treatment center. DO NOT induce vomiting.
Aspiration Hazard: Product may be inhaled into lungs if vomited.
Inhalation: Remove to fresh air. Restore andlor support breathing as
required. Keep victim warm and at rest.
Note t o Physicians: Treat symptomatically
Special PrecautionslProcedures: None known
MSDS: Prediluted, Fully-Formulated, Heavy Duty Precharged Coolant (50150)
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None known
Unusual Fire Fighting procedures:
None at this dilution
Flash Point:
Not applicable
Flash Point Method:
Not applicable
Burning Rate:
Not determined
Autoignition Temperature:
Flammable limits i n air (% by volume):
LEL: Not determined
Not determined
UEL:
Does not burn, but can emit fumes in a fire.
Flammability Classification:
For large fires use alcohol-type or all purpose foam. For small fires use water
Extinguishing Media:
spray, dry chemical, foam or carbon dioxide to extinguish.
None known
Unusual Fire o r Explosion Hazards:
Fire-Fighting Instructions; According to the National Fire Protection Association Guide, use water spray,
dry chemical, foam or carbon dioxide. A direct stream of water or foam may
cause frothing. Use water spray to disperse the vapors and to provide
protection for person attempting to stop the leak.
Fire-Fighting Equipment: Because fire may produce toxic thermal decomposition products, wear a self-
contained breathing apparatus (SCBA) with a full facepiece operated in
pressure-demand or positive-pressure mode.
Unusual Fire Fighting procedures: Not required
Products evolved when subiected to heat or combustion: carbon monoxide
Other Information:
SpiIIILea k Procedures: Ventilate area. Avoid breathing vapor. Wear appropriate personal protective
equipment, including appropriate respiratory protection. Contain spill if
possible. Wipe up or absorb on suitable material and shovel up. Prevent entry
into sewers and waterways. Avoid contact with skin, eyes or clothing.
Regulatory Requirements: If more than 10,539 pounds of product is spilled, then report spill according to
SARA 304 and/or CERCLA 102(a) reauirements, unless product qualifies for
Handling Precautions Minimum feasible handling temperatures should be maintained. Empty
containers contain product residue and may be dangerous.
Storage Requirements: Periods of exposure to high temperature should be minimized. Water
contamination should be avoided. Keep containers away from open flames.
ETHYLENE GLYCOL BASE - Ethylene Glycol has produced birth defects in
Normal to maintain exposure below TLV
Ventilation:
Permissible Concentrations i n Air: IOmg/cubic meter for particulate mist; 50 ppm (125 mglcubic meter) ceiling limit
for Ethylene Glycol (ACGIH 1984-1985)
Respiratory Protection: Supplied air respiratory protection for cleaning large spills or upon entry into
tanks, vessels, or other confined spaces. Use a NlOSH approved organic vapor
and gas respirator with mist filter.
Eye Protection: Chemical type goggles or face shield optional.
Protective ClothinglEquipment: Wear chemically protective gloves, boots, aprons, and gauntlets to prevent
prolonged or repeated skin contact. Wear protective eyeglasses or chemical
safety goggles.
Work and Hygienic Practices: Exposed employees should exercise reasonable personal cleanliness; this
includes cleansing exposed skin areas several times daily with soap and water,
and laundering or dry cleaning soiled work clothing at least weekly.
Prediluted, Fully-Formulated, Heavy Duty Precharged Coolant (50150)
MSDS:
- - FOR DISCLAIMER OF LIABILITY SEE FINAL PAGE - - - Page 3 of 6
Make emergency eyewash stations, safetylquick-drench showers, and washing
Safety Stations:
facilities available in work area.
Separate contaminated work clothes from street clothes. Launder before reuse.
Contaminated Equipment:
Remove this material from your shoes and clean personal protective
equipment.
Never eat, drink, or smoke in work areas. Practice good personal hygiene after
Comments:
using this material, especially before eating, drinking, smoking, using the toilet,
or applying cosmetics.
Clear liquid with a mild odor (may contain dye in one of several colors)
Appearance and odor:
325OF
Boiling Point (760 m m Hg):
FreezinglMelting Point: -34OF
Specific Gravity (water =I): 1.110-1.125
Vapor Density (air =I): 1.8
NIL
Percent Volatile by Volume:
Evaporation Rate (butyl acetate =I): determined
Not
Solubility in Water (% b y wt): 100%
Vapor Pressure (at 20癈): 18mm Hg.
pH: 10-11
Less than 20cst
Stability: Stable
Polymerization: Does not occur
Chemical Incompatibilities: Normally unreactive, but try to avoid strong oxidizers, strong acids and strong
bases at high temperatures.
Conditions t o Avoid: High temperatures above 413OC (775OF) (product can decompose)
Hazardous decomposition products: Carbon dioxide, carbon monoxide
1
Eye Effects: Believed to cause slight eye irritation.
s k i n Effects: Can be irritat~ng skin upon prolonged contact
to
Acute Inhalation Effects: Drowsiness, narcosis, and unconsciousness possible upon exposure to high
concentrations in poorly ventilated confined spaces.
Acute Oral Effects: Can cause irritation to mouth, throat and stomach
Chronic Effects: Liver and kidney damage in a 2 year rat feeding study using 1-2% Ethylene
Glycol. Oral administration of very high doses of Ethylene Glycol produced
birth defects in laboratory animals.
Carcinogenicity: Neither product nor its ingredients are listed by IARC, NTD or OSHA
Mutagenicity: Not mutagenic
Teratogenicity: Not Teratogenic
( Ecotoxicity: 1
Oral: Believed to be 4.7-8.5 g/kg (rat); moderately toxic
- -
Inhalation: Not determined.
Dermal: Believed to be 1-3 glkg (rabbit); slightly toxic
Other: Not determined.
Irritation IndexIEstimation of lrritation (Species)
Skin: Believed to be 0.5-1.818.0 (rabbit); slightly irritating
Eyes: Believed to be 15-251110 (rabbit); slightly irritating
Soil AbsorptionIMobility: Not determined
MSDS: Prediluted, Fully-Formulated, Heavy Duty Precharged Coolant (50150)
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Dispose of waste in accordance with Federal, State and Local laws
/waste D i s ~ o s a~ e t h o d :
l
under RCRA, it is the responsibility of the user of products to determine, at
Disposal degulatory Requirements:
the time of disposal, whether product meets RCRA criteria for hazardous
waste. This is because product uses transformations, mixture, processes,
etc., may render the resulting material hazardous (see waste classification)
Containers should be cleaned of residual product before disposal, and
Container Cleaning and Disposal:
disposed of in accordance with all applicable laws and regulations.
None required if container(s) hold less than 5,000 (-535 gal)
DOT Proper Shipping Name:
Shipping Symbols: Not applicable
Hazard Class: Not applicable
UN Number: Not regulated unless shipping container holds at least 10,539 pounds.
Packing Group: Not applicable
Label: Not applicable
Special Provisions (172.102): Not applicable
Bulk Shipments
DOT Proper Shipping Name: Environmentally hazardous substance, liquid, n.o,s. (Ethlyene glycol)
UN Number: UN 3082
Label Requirement: Class 9, UN 3082
EPA Regulations
RCRA Hazardous Waste Number and RCRA
Hazardous Waste Classification: Unused product is not classified as a hazardous waste by
RCRA criteria
CERCLA Hazardous Substance and CERCLA
.'
Reportable Quantity: Does not contain any ingredients listed as a CERCLA
''
I
hazardous substance.
SARA Toxic Chemical and SARA EHS: Contains following substance which is listed in Title Ill:
Ethylene Glycol.
SARA 313 Information:
SARA Hazard Category: An immediate health hazard A
delayed health hazard
I OSHA Regulations: I
State Regulations
Other: All components listed on both TSCA (USA) and DSL
(Canada) inventory.
CANADIAN WHMlS CLASSIFICATION: Class D, Division 2,
Subdivision B (A toxic material causing other chronic effects)
MSDS: Prediluted, Fully-Formulated, Heavy Duty Precharged Coolant (50150)
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Additive Technologies, technical department
Prepared By:
Additional Hazard Rating Systems: None
Disclaimer: THE INFORMATION GIVEN HEREIN IS GIVEN IN GOOD FAITH AND FROM SOURCES WE BELIEVE
RELIABLE. BUT NO WARRANTY, EXPRESS OR IMPLIED, REGARDING ITS CORRECTNESS IS MADE.
The conditions or methods of handling, storage, use and disposal of this product are beyond our control and may be
beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for
loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of this
product.
This MSDS was prepared and is to be used only for this product. If the product is used as a component in another
product, this MSDS information may not apply.
I I
CONSULT Company listed in Section 1. FOR FURTHER INFORMATION.
MSDS: Prediluted, Fully-Formulated, Heavy Duty Precharged Coolant (50150)
- - - FOR DISCLAIMER OF LIABILITY SEE FINAL PAGE - - - Page 6 of 6
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